Volume 125
Main Index

Issue 01

124 Years of Publishing Original and Primary Chemical Research:  135,149 Publications, 573,453 Pages, and a Century of Excellence P. J. Stang pp 1–8 DOI: 10.1021/ja021403x

Dinitrogen Reduction by Tm(II), Dy(II), and Nd(II) with Simple Amide and Aryloxide Ligands William J. Evans, Gaël Zucchi, and Joseph W. Ziller pp 10–11 DOI: 10.1021/ja0211712 Supporting Info

“Inverse-Electron-Demand” Ligand Substitution in Palladium(0)−Olefin Complexes Shannon S. Stahl, Joseph L. Thorman, Namal de Silva, Ilia A. Guzei, and Robert W. Clark pp 12–13 DOI: 10.1021/ja028738z Supporting Info

Virus−Ligand Interactions:  Identification and Characterization of Ligand Binding by NMR Spectroscopy Andrew J. Benie, Rosita Moser, Englbert Bäuml, Dieter Blaas, and Thomas Peters pp 14–15 DOI: 10.1021/ja027691e Supporting Info

Kinetic and Stereochemical Evidence for the Involvement of Only One Proline Molecule in the Transition States of Proline-Catalyzed Intra- and Intermolecular Aldol Reactions Linh Hoang, S. Bahmanyar, K. N. Houk, and Benjamin List pp 16–17 DOI: 10.1021/ja028634o Supporting Info

13C NMR Spectroscopy of 13C1-Labeled Octanethiol-Protected Au Nanoparticles:  Shifts, Relaxations, and Particle-Size Effect Brian S. Zelakiewicz, Angel C. de Dios, and YuYe Tong pp 18–19 DOI: 10.1021/ja028302j

Designing the Selectivity of the Fluorescent Detection of Amino Acids:  A Chemosensing Ensemble for Histidine Marta Ansa Hortalá, Luigi Fabbrizzi, Nathalie Marcotte, Floriana Stomeo, and Angelo Taglietti pp 20–21 DOI: 10.1021/ja027110l Supporting Info

A Novel Calcium-Dependent Bacterial Phosphatidylinositol-Specific Phospholipase C Displaying Unprecedented Magnitudes of Thio Effect, Inverse Thio Effect, and Stereoselectivity Li Zhao, Yinghui Liu, Karol S. Bruzik, and Ming-Daw Tsai pp 22–23 DOI: 10.1021/ja029019n Supporting Info

The Crystallographic Structure of a Lewis Acid-Assisted Chiral Brønsted Acid as an Enantioselective Protonation Reagent for Silyl Enol Ethers Kazuaki Ishihara, Daisuke Nakashima, Yukihiro Hiraiwa, and Hisashi Yamamoto pp 24–25 DOI: 10.1021/ja021000x Supporting Info

Conformation−Activity Relationships in Polyketide Natural Products:  A New Perspective on the Rational Design of Epothilone Analogues Richard E. Taylor, Yue Chen, and Alicia BeattyDavid C. Myles and Yiqing Zhou pp 26–27 DOI: 10.1021/ja028196l Supporting Info

Remarkably Large Positive and Negative Allosteric Effects on Ion Recognition by the Formation of a Novel Helical Pseudocryptand Tatsuya Nabeshima, Yuko Yoshihira, Toshiyuki Saiki, Shigehisa Akine, and Ernst Horn pp 28–29 DOI: 10.1021/ja028750r Supporting Info

Intramolecular Endo-Dig Hydrosilylation Catalyzed by Ruthenium:  Evidence for a New Mechanistic Pathway Barry M. Trost and Zachary T. Ball pp 30–31 DOI: 10.1021/ja028766h Supporting Info

A Dihydroxo-Bridged Fe(II)−Fe(III) Complex:  A New Member of the Diiron Diamond Core Family Rune Kirk Egdal, Alan Hazell, Frank Bartnik Larsen, Christine J. McKenzie, and Robert C. Scarrow pp 32–33 DOI: 10.1021/ja027219t Supporting Info

Dipole-Induced Polymorphs of trans-2-Hydroxycycloheptanecarboxylic Acid with Virtually the Same Unit Cell Alajos Kálmán, László Fábián, Gyula Argay, Gábor Bernáth, and Zsuzsanna Gyarmati pp 34–35 DOI: 10.1021/ja0289447 Supporting Info

Anodic Cyclization Reactions:  The Total Synthesis of Alliacol A John Mihelcic and Kevin D. Moeller pp 36–37 DOI: 10.1021/ja029064v Supporting Info

Very High-Field EPR Study of Glycyl Radical Enzymes Carole Duboc-Toia, Alia K. Hassan, Etienne Mulliez, Sandrine Ollagnier-de Choudens, Marc Fontecave, Christina Leutwein, and Johann Heider pp 38–39 DOI: 10.1021/ja026690j

An Unusual Equilibrium Chlorine Atom Transfer Process and Its Potential for Assessment of Steric Pressure by Bulky Aryls Rhett C. Smith, Shashin Shah, Eugenijus Urnezius, and John D. Protasiewicz pp 40–41 DOI: 10.1021/ja028422r Supporting Info

G-Quadruplex Formation of Thrombin-Binding Aptamer Detected by Electrospray Ionization Mass Spectrometry M. Vairamani and Michael L. Gross pp 42–43 DOI: 10.1021/ja0284299

High-Accuracy Residual 1HN−13C and 1HN−1HN Dipolar Couplings in Perdeuterated Proteins Sebastian Meier, Daniel Häussinger, Pernille Jensen, Marco Rogowski, and Stephan Grzesiek pp 44–45 DOI: 10.1021/ja028740q Supporting Info

Total Synthesis of Gambierol Isao Kadota, Hiroyoshi Takamura, Kumi Sato, Akio Ohno, Kumiko Matsuda, and Yoshinori Yamamoto pp 46–47 DOI: 10.1021/ja028726d Supporting Info

A DFT-Derived Model Predicts Solvation-Dependent Configurational Stability of Organolithium Compounds:  A Case Study of a Chiral α-Thioallyllithium Compound Peter Brandt and Fredrik Haeffner pp 48–49 DOI: 10.1021/ja0279491 Supporting Info

DNA Interchain Cross-Links Formed by Acrolein and Crotonaldehyde Ivan D. Kozekov, Lubomir V. Nechev, M. Scott Moseley, Constance M. Harris, Carmelo J. Rizzo, Michael P. Stone, and Thomas M. Harris pp 50–61 DOI: 10.1021/ja020778f Supporting Info

NMR Determination of the Conformation of a Trimethylene Interstrand Cross-Link in an Oligodeoxynucleotide Duplex Containing a 5‘-d(GpC) Motif Patricia A. Dooley, Mingzhou Zhang, Gregory A. Korbel, Lubomir V. Nechev, Constance M. Harris, Michael P. Stone, and Thomas M. Harris pp 62–72 DOI: 10.1021/ja0207798 Supporting Info

Tandem Ligation of Multipartite Peptides with Cell-Permeable Activity Khee Dong Eom, Zhenwei Miao, Jin-Long Yang, and James P. Tam pp 73–82 DOI: 10.1021/ja020529r

Single Crystal EPR Studies of the Reduced Active Site of [NiFe] Hydrogenase from Desulfovibrio vulgaris Miyazaki F Stefanie Foerster, Matthias Stein, Marc Brecht, Hideaki Ogata, Yoshiki Higuchi, and Wolfgang Lubitz pp 83–93 DOI: 10.1021/ja027522u

Monolayer Assemblies of a De Novo Designed 4-α-Helix Bundle Carboprotein and Its Sulfur Anchor Fragment on Au(111) Surfaces Addressed by Voltammetry and In Situ Scanning Tunneling Microscopy Jesper Brask, Hainer Wackerbarth, Knud J. Jensen, Jingdong Zhang, Ib Chorkendorff, and Jens Ulstrup pp 94–104 DOI: 10.1021/ja020943r

Activation Barriers in the Homolytic Cleavage of Radicals and Ion Radicals Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 105–112 DOI: 10.1021/ja027287f Supporting Info

Optically Active Iridium Imidazol-2-ylidene-oxazoline Complexes:  Preparation and Use in Asymmetric Hydrogenation of Arylalkenes Marc C. Perry, Xiuhua Cui, Mark T. Powell, Duen-Ren Hou, Joseph H. Reibenspies, and Kevin Burgess pp 113–123 DOI: 10.1021/ja028142b Supporting Info

(Phosphino)(Aryl)Carbenes:  Effect of Aryl Substituents on Their Stabilization Mode Emmanuelle Despagnet-Ayoub, Stéphane Solé, Heinz Gornitzka, Alexander B. Rozhenko, Wolfgang W. Schoeller, Didier Bourissou, and Guy Bertrand pp 124–130 DOI: 10.1021/ja0281986 Supporting Info

Experimental and Theoretical Characterization of the 3,5-Didehydrobenzoate Anion:  A Negatively Charged meta-Benzyne Jason M. Price, Katrina Emilia Nizzi, J. Larry Campbell, Hilkka I. Kenttämaa, Mark Seierstad, and Christopher J. Cramer pp 131–140 DOI: 10.1021/ja021112o Supporting Info

DNA Sequence Context and Multiplex Hybridization Reactions:  Melting Studies of Heteromorphic Duplex DNA Complexes Peter V. Riccelli, Timothy S. Hall, Petr Pancoska, Kathleen E. Mandell, and Albert S. Benight pp 141–150 DOI: 10.1021/ja027955x

Kinetic and Thermodynamic Acidities of Substituted 1-Benzyl-1-methoxy-2-nitroethylenes. Strong Reduction of the Transition State Imbalance Compared to Other Nitroalkanes Claude F. Bernasconi, Mahammad Ali, and Janette C. Gunter pp 151–157 DOI: 10.1021/ja0211398 Supporting Info

Substituent Effects on Regioselective Intramolecular Oxidation of Unactivated C−H Bonds:  Stereoselective Synthesis of Substituted Tetrahydropyrans Man-Kin Wong, Nga-Wai Chung, Lan He, and Dan Yang pp 158–162 DOI: 10.1021/ja028357l Supporting Info

Free Radical-Mediated Aryl Amination and Its Use in a Convergent [3 + 2] Strategy for Enantioselective Indoline α-Amino Acid Synthesis Rajesh Viswanathan, Erode N. Prabhakaran, Michael A. Plotkin, and Jeffrey N. Johnston pp 163–168 DOI: 10.1021/ja0284308 Supporting Info

Low-Temperature Orientationally Ordered Structures of Two-Dimensional C60 Lan-Feng Yuan, Jinlong Yang, Haiqian Wang, Changgan Zeng, Qunxiang Li, Bing Wang, J. G. Hou, Qingshi Zhu, and D. M. Chen pp 169–172 DOI: 10.1021/ja025775h

Highly Selective Binding of Organometallic Ruthenium Ethylenediamine Complexes to Nucleic Acids:  Novel Recognition Mechanisms Haimei Chen, John A. Parkinson, Robert E. Morris, and Peter J. Sadler pp 173–186 DOI: 10.1021/ja027719m Supporting Info

The Mandelamide Keto−Enol System in Aqueous Solution. Generation of the Enol by Hydration of Phenylcarbamoylcarbene Y. Chiang, H.-X. Guo, A. J. Kresge, J. P. Richard, and K. Toth pp 187–194 DOI: 10.1021/ja021017f Supporting Info

Energy Transfer on the MgO Surface, Monitored by UV− Induced H2 Chemisorption Martin Sterrer, Thomas Berger, Oliver Diwald, and Erich Knözinger pp 195–199 DOI: 10.1021/ja028059o

Syntheses, Crystallographic/Computational Characterizations, and Reactions of the First 10-Vertex arachno- and nido-Phosphamonocarbaboranes Alexandra M. Shedlow, Daniel E. Kadlecek, Jude C. Clapper, Scott E. Rathmill, Patrick J. Carroll, and Larry G. Sneddon pp 200–211 DOI: 10.1021/ja020944j Supporting Info

Syntheses and Structural Characterizations of endo-η1-, exo-η1-, η4-, η5-, and η6-Metallaphosphamonocarbaborane Complexes Derived from a Versatile New Polyborane Ligand:  exo-6-R-arachno-6,7-PCB8H12 Daniel E. Kadlecek, Alexandra M. Shedlow, Sang Ook Kang, Patrick J. Carroll, and Larry G. Sneddon pp 212–220 DOI: 10.1021/ja020945b Supporting Info

Design of Novel Inorganic−Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes:  Characteristics of Hydrogen-Bond-Supported Layers toward the Intercalation of Guests Kunimitsu Nagayoshi, Md. Khayrul Kabir, Hiroshi Tobita, Kenji Honda, Mitsuhiro Kawahara, Motomi Katada, Keiichi Adachi, Hiroyuki Nishikawa, Isao Ikemoto, Hitoshi Kumagai, Yuko Hosokoshi, Katsuya Inoue, Susumu Kitagawa, and Satoshi Kawata pp 221–232 DOI: 10.1021/ja027895v Supporting Info

Solvent Coordination in Gas-Phase [Mn·(H2O)n]2+ and [Mn·(ROH)n]2+ Complexes:  Theory and Experiment Hazel Cox, Glen Akibo-Betts, Rossana R. Wright, Nicholas R. Walker, Sharon Curtis, Bridgette Duncombe, and Anthony J. Stace pp 233–242 DOI: 10.1021/ja012367p

Kinetic Isotope Effects for Concerted Multiple Proton Transfer:  A Direct Dynamics Study of an Active-Site Model of Carbonic Anhydrase II Zorka Smedarchina, Willem Siebrand, Antonio Fernández-Ramos, and Qiang Cui pp 243–251 DOI: 10.1021/ja0210594

Time-Dependent Density Functional Theory (TDDFT) Study of the Excited Charge-Transfer State Formation of a Series of Aromatic Donor−Acceptor Systems Christine Jamorski Jödicke and Hans Peter Lüthi pp 252–264 DOI: 10.1021/ja020361+

X- and W-Band EPR and Q-Band ENDOR Studies of the Flavin Radical in the Na+-Translocating NADH:Quinone Oxidoreductase from Vibrio cholerae Blanca Barquera, Joel E. Morgan, Dmitriy Lukoyanov, Charles P. Scholes, Robert B. Gennis, and Mark J. Nilges pp 265–275 DOI: 10.1021/ja0207201

Coverage Effects and the Nature of the Metal−Sulfur Bond in S/Au(111):  High-Resolution Photoemission and Density-Functional Studies José A. Rodriguez, Joseph Dvorak, Tomas Jirsak, Gang Liu, Jan Hrbek, Yosslen Aray, and Carlos González pp 276–285 DOI: 10.1021/ja021007e

How Constant Are Ritchie's “Constant Selectivity Relationships”? A General Reactivity Scale for n-, π-, and σ-Nucleophiles Shinya Minegishi and Herbert Mayr pp 286–295 DOI: 10.1021/ja021010y Supporting Info

Photodetachment of Zwitterions:  Probing Intramolecular Coulomb Repulsion and Attraction in the Gas Phase Using Pyridinium Dicarboxylate Anions Xue-Bin Wang, Jelena E. Dacres, Xin Yang, Katherine M. Broadus, Lev Lis, Lai-Sheng Wang, and Steven R. Kass pp 296–304 DOI: 10.1021/ja028204y Supporting Info

Metal Ions in Biological Systems. Volume 39. Molybdenum and Tungsten:  Their Roles in Biological Processes Edited by Astrid Sigel and Helmut Sigel (University of Basel). 2002. ix + 810 pp. $250.00. ISBN 0-8247-0765-6. Martin L. Kirk pp 305–306 DOI: 10.1021/ja0252633

Issue 02

Aerobic Oxidation of Methyl p-Tolyl Sulfide Catalyzed by a Remarkably Labile Heteroscorpionate Ru(II)−Aqua Complex, fac-[RuII(H2O)(dpp)(tppm)]2+ My Hang V. Huynh, Laura M. Witham, Joanne M. Lasker, Modi Wetzler, Brendan Mort, Donald L. Jameson, Peter S. White, and Kenneth J. Takeuchi pp 308–309 DOI: 10.1021/ja0124111 Supporting Info

Migration of Methyl Groups between Aliphatic Amines in Water Brian P. Callahan and Richard Wolfenden pp 310–311 DOI: 10.1021/ja021212u

An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution Tianbo Liu pp 312–313 DOI: 10.1021/ja028933d

Polyaniline Nanofibers:  Facile Synthesis and Chemical Sensors Jiaxing Huang, Shabnam Virji, Bruce H. Weiller, and Richard B. Kaner pp 314–315 DOI: 10.1021/ja028371y

Preparation of Novel Silica−Cadmium Sulfide Composite Nanoparticles Having Adjustable Void Space by Size-Selective Photoetching Tsukasa Torimoto, Jocelyn Paz Reyes, Kentaro Iwasaki, Bonamali Pal, Tamaki Shibayama, Kenji Sugawara, Heishichiro Takahashi, and Bunsho Ohtani pp 316–317 DOI: 10.1021/ja0278133 Supporting Info

Reduction and Methyl Transfer Kinetics of the α Subunit from Acetyl Coenzyme A Synthase Xiangshi Tan, Christopher Sewell, Qingwu Yang, and Paul A. Lindahl pp 318–319 DOI: 10.1021/ja028442t

Semiconductor Nanocrystals with Multifunctional Polymer Ligands Inga Potapova, Ralf Mruk, Sabine Prehl, Rudolf Zentel, Thomas Basché, and Alf Mews pp 320–321 DOI: 10.1021/ja028641c

A Low-Spin d5 Iron Imide:  Nitrene Capture by Low-Coordinate Iron(I) Provides the 4-Coordinate Fe(III) Complex [PhB(CH2PPh2)3]FeN-p-tolyl Steven D. Brown, Theodore A. Betley, and Jonas C. Peters pp 322–323 DOI: 10.1021/ja028448i Supporting Info

Label-Free DNA Hybridization Probe Based on a Conducting Polymer Liz A. Thompson, Janusz Kowalik, Mira Josowicz, and Jiri Janata pp 324–325 DOI: 10.1021/ja027929z

Charge Ordering in Lithium Vanadium Phosphates:  Electrode Materials for Lithium-Ion Batteries Shih-Chieh Yin, Hiltrud Grondey, Pierre Strobel, Huan Huang, and Linda F. Nazar pp 326–327 DOI: 10.1021/ja028973h

Ultrabright Supramolecular Beacons Based on the Self-Assembly of Two-Photon Chromophores on Metal Nanoparticles Francesco Stellacci, Christina A. Bauer, Timo Meyer-Friedrichsen, Wim Wenseleers, Seth R. Marder, and Joseph W. Perry pp 328–329 DOI: 10.1021/ja0281277 Supporting Info

Reversible Binding of the HPLC6 Isoform of Type I Antifreeze Proteins to Ice Surfaces and the Antifreeze Mechanism Studied by Multiple Quantum Filtering−Spin Exchange NMR Experiment Yong Ba, Jeff Wongskhaluang, and Jiabo Li pp 330–331 DOI: 10.1021/ja027557u

Synthesis of Sodium Tantalate Nanorods by Alkalide Reduction Jennifer A. Nelson and Michael J. Wagner pp 332–333 DOI: 10.1021/ja028125m

Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure Tsuyoshi Murakami, Tokujiro Nishikiori, Toshiyuki Nohira, and Yasuhiko Ito pp 334–335 DOI: 10.1021/ja028891t

Layer-By-Layer Growth of Metal−Metal Bonded Supramolecular Thin Films and Its Use in the Fabrication of Lateral Nanoscale Devices Chun Lin and Cherie R. Kagan pp 336–337 DOI: 10.1021/ja028653y Supporting Info

A Direct Catalytic Asymmetric Mannich-type Reaction to syn-Amino Alcohols Barry M. Trost and Lamont R. Terrell pp 338–339 DOI: 10.1021/ja028782e Supporting Info

Metal Assembly in Novel Dendrimers with Porphyrin Cores Takane Imaoka, Hironori Horiguchi, and Kimihisa Yamamoto pp 340–341 DOI: 10.1021/ja0285060 Supporting Info

The PcoC Copper Resistance Protein Coordinates Cu(I) via Novel S-Methionine Interactions Katrina Peariso, David L. Huffman, James E. Penner-Hahn, and Thomas V. O'Halloran pp 342–343 DOI: 10.1021/ja028935y Supporting Info

DNA Detection and Signal Amplification via an Engineered Allosteric Enzyme Alan Saghatelian, Kevin M. Guckian, Desiree A. Thayer, and M. Reza Ghadiri pp 344–345 DOI: 10.1021/ja027885u Supporting Info

DNA-Based Photonic Logic Gates:  AND, NAND, and INHIBIT Alan Saghatelian, Nicolas H. Völcker, Kevin M. Guckian, Victor S.-Y. Lin, and M. Reza Ghadiri pp 346–347 DOI: 10.1021/ja029009m Supporting Info

Discovery of Novel Dyes with Absorption Maxima at 1.1 μm Minquan Tian, Satoshi Tatsuura, Makoto Furuki, Yasuhiro Sato, Izumi Iwasa, and Lyong Sun Pu pp 348–349 DOI: 10.1021/ja0209666 Supporting Info

Total Synthesis of (+)-13-Deoxytedanolide Amos B. Smith, III, Christopher M. Adams, Stephanie A. Lodise Barbosa, and Andrew P. Degnan pp 350–351 DOI: 10.1021/ja0289649 Supporting Info

α-Helical-within-Discotic Columnar Structures of a Complex between Poly(ethylene oxide)-block-poly(l-lysine) and a Hexa-peri-hexabenzocoronene Andreas F. Thünemann, Stephan Kubowicz, Christian Burger, Mark D. Watson, Natalia Tchebotareva, and Klaus Müllen pp 352–356 DOI: 10.1021/ja0277632

Photoinduced Electron-Transfer along α-Helical and Coiled-Coil Metallopeptides Anna Fedorova, Anita Chaudhari, and Michael Y. Ogawa pp 357–362 DOI: 10.1021/ja026140l

Acetylcholinesterase Complexed with Bivalent Ligands Related to Huperzine A:  Experimental Evidence for Species-Dependent Protein−Ligand Complementarity Dawn M. Wong, Harry M. Greenblatt, Hay Dvir, Paul R. Carlier, Yi-Fan Han, Yuan-Ping Pang, Israel Silman, and Joel L. Sussman pp 363–373 DOI: 10.1021/ja021111w Supporting Info

Nanotube−Vesicle Networks with Functionalized Membranes and Interiors Max Davidson, Mattias Karlsson, Jon Sinclair, Kristin Sott, and Owe Orwar pp 374–378 DOI: 10.1021/ja027699o

Assay for the Enantiomeric Analysis of [2H1]-Fluoroacetic Acid:  Insight into the Stereochemical Course of Fluorination during Fluorometabolite Biosynthesis in Streptomyces cattleya David O'Hagan, Rebecca J. M. Goss, Abdelkrim Meddour, and Jacques Courtieu pp 379–387 DOI: 10.1021/ja026654k

Stability of Cyclic β-Hairpins:  Asymmetric Contributions from Side Chains of a Hydrogen-Bonded Cross-Strand Residue Pair Stephen J. Russell, Tamas Blandl, Nicholas J. Skelton, and Andrea G. Cochran pp 388–395 DOI: 10.1021/ja028075l Supporting Info

The Role of Amine in the Mechanism of Pentathiepin (Polysulfur) Antitumor Agents Edyta M. Brzostowska and Alexander Greer pp 396–404 DOI: 10.1021/ja027416s Supporting Info

Using Nitrile-Derivatized Amino Acids as Infrared Probes of Local Environment Zelleka Getahun, Cheng-Yen Huang, Ting Wang, Brenda De León, William F. DeGrado, and Feng Gai pp 405–411 DOI: 10.1021/ja0285262 Supporting Info

An Efficient RNA-Cleaving DNA Enzyme that Synchronizes Catalysis with Fluorescence Signaling Shirley H. J. Mei, Zhongjie Liu, John D. Brennan, and Yingfu Li pp 412–420 DOI: 10.1021/ja0281232

A New Chiral Probe for Sulfate Anion:  UV, CD, Fluorescence, and NMR Spectral Studies of 1:1 and 2:1 Complex Formation and Structure of Chiral Guanidinium−p-Dimethylaminobenzoate Conjugate with Sulfate Anion Kazuya Kobiro and Yoshihisa Inoue pp 421–427 DOI: 10.1021/ja028401x

Opening of Tartrate Acetals Using Dialkylboron Bromide:  Evidence for Stereoselectivity Downstream from Ring Fission Yvan Guindon, William W. Ogilvie, Josée Bordeleau, Wei Li Cui, Kathy Durkin, Vida Gorys, Hélène Juteau, René Lemieux, Dennis Liotta, Bruno Simoneau, and Christiane Yoakim pp 428–436 DOI: 10.1021/ja012530g Supporting Info

Attaching Perylene Dyes to Polyfluorene:  Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers Christophe Ego, Dirk Marsitzky, Stefan Becker, Jingying Zhang, Andrew C. Grimsdale, Klaus Müllen, J. Devin MacKenzie, Carlos Silva, and Richard H. Friend pp 437–443 DOI: 10.1021/ja0205784 Supporting Info

Supramolecular Recognition. Terpyridyl Palladium and Platinum Molecular Clefts and Their Association with Planar Platinum Complexes Andrew J. Goshe, Ian M. Steele, and B. Bosnich pp 444–451 DOI: 10.1021/ja028910z Supporting Info

Highly Stable Self-Assembly in Water:  Ion Pair Driven Dimerization of a Guanidiniocarbonyl Pyrrole Carboxylate Zwitterion Carsten Schmuck and Wolfgang Wienand pp 452–459 DOI: 10.1021/ja028485+ Supporting Info

Photothermal Patterning of Microgel/Gold Nanoparticle Composite Colloidal Crystals Clinton D. Jones and L. Andrew Lyon pp 460–465 DOI: 10.1021/ja027431x Supporting Info

Spectroscopic and Electronic Structure Studies of the Diamagnetic Side-On CuII-Superoxo Complex Cu(O2)[HB(3-R-5-iPrpz)3]:  Antiferromagnetic Coupling versus Covalent Delocalization Peng Chen, David E. Root, Cecelia Campochiaro, Kiyoshi Fujisawa, and Edward I. Solomon pp 466–474 DOI: 10.1021/ja020969i Supporting Info

Control of Charge Recombination Dynamics in Dye Sensitized Solar Cells by the Use of Conformally Deposited Metal Oxide Blocking Layers Emilio Palomares, John N. Clifford, Saif A. Haque, Thierry Lutz, and James R. Durrant pp 475–482 DOI: 10.1021/ja027945w

Ultrafast Processes in Bimetallic Dyads with Extended Aromatic Bridges. Energy and Electron Transfer Pathways in Tetrapyridophenazine-Bridged Complexes Claudio Chiorboli, Michael A. J. Rodgers, and Franco Scandola pp 483–491 DOI: 10.1021/ja0284916

Perhydrocarbyl ReVII Complexes: Comparison of Molecular and Surface Complexes Mathieu Chabanas, Anne Baudouin, Christophe Copéret, Jean-Marie Basset, Wayne Lukens, Anne Lesage, Sabine Hediger, and Lyndon Emsley pp 492–504 DOI: 10.1021/ja020136s Supporting Info

Measurements of Electron-Transfer Rates of Charge-Storage Molecular Monolayers on Si(100). Toward Hybrid Molecular/Semiconductor Information Storage Devices Kristian M. Roth, Amir A. Yasseri, Zhiming Liu, Rajeev B. Dabke, Vladimir Malinovskii, Karl-Heinz Schweikart, Lianhe Yu, Hugo Tiznado, Francisco Zaera, Jonathan S. Lindsey, Werner G. Kuhr, and David F. Bocian pp 505–517 DOI: 10.1021/ja021169a Supporting Info

Activation of Alkenes and H2 by [Fe]-H2ase Model Complexes Xuan Zhao, Chao-Yi Chiang, Matthew L. Miller, Marilyn V. Rampersad, and Marcetta Y. Darensbourg pp 518–524 DOI: 10.1021/ja0280168 Supporting Info

Sonochemical Production of Fluorescent and Phosphorescent Latex Particles Melanie Bradley, Muthupandian Ashokkumar, and Franz Grieser pp 525–529 DOI: 10.1021/ja0268581

Direct Electrochemistry of a Bacterial Sulfite Dehydrogenase Kondo-François Aguey-Zinsou, Paul V. Bernhardt, Ulrike Kappler, and Alastair G. McEwan pp 530–535 DOI: 10.1021/ja028293e

Intermolecular Coupling in Nanometric Domains of Light-Harvesting Dendrimer Films Studied by Photoluminescence Near-Field Scanning Optical Microscopy (PL NSOM) Lynn F. Lee, Alex Adronov, Richard D. Schaller, Jean M. J. Fréchet, and Richard J. Saykally pp 536–540 DOI: 10.1021/ja028495a

Accurate First Principles Prediction of 17O NMR Parameters in SiO2:  Assignment of the Zeolite Ferrierite Spectrum Mickael Profeta, Francesco Mauri, and Chris J. Pickard pp 541–548 DOI: 10.1021/ja027124r

Ultrafast Electronic Relaxation and Coherent Vibrational Oscillation of Strongly Coupled Gold Nanoparticle Aggregates Christian D. Grant, Adam M. Schwartzberg, Thaddeus J. Norman, Jr., and Jin Z. Zhang pp 549–553 DOI: 10.1021/ja028532y

Fabrication of Complex Three-Dimensional Microchannel Systems in PDMS Hongkai Wu, Teri W. Odom, Daniel T. Chiu, and George M. Whitesides pp 554–559 DOI: 10.1021/ja021045y Supporting Info

Probing the Configurational Space of a Metalloprotein Core:  An ab Initio Molecular Dynamics Study of Duo Ferro 1 Binuclear Zn Cofactor Garegin A. Papoian, William F. DeGrado, and Michael L. Klein pp 560–569 DOI: 10.1021/ja028161l

Internal Degrees of Freedom, Structural Motifs, and Conformational Energetics of the 5‘-Deoxyadenosyl Radical:  Implications for Function in Adenosylcobalamin-Dependent Enzymes. A Computational Study Dmitry V. Khoroshun, Kurt Warncke, Shyue-Chu Ke, Djamaladdin G. Musaev, and Keiji Morokuma pp 570–579 DOI: 10.1021/ja028393k Supporting Info

Dip-Pen Nanolithography in Tapping Mode Gunjan Agarwal, Laura A. Sowards, Rajesh R. Naik, and Morley O. Stone pp 580–583 DOI: 10.1021/ja020471g

Bound State Potential Energy Surface Construction:  Ab Initio Zero-Point Energies and Vibrationally Averaged Rotational Constants Ryan P. A. Bettens pp 584–587 DOI: 10.1021/ja027963d

Toward a Glucose Biosensor Based on Surface-Enhanced Raman Scattering Karen E. Shafer-Peltier, Christy L. Haynes, Matthew R. Glucksberg, and Richard P. Van Duyne pp 588–593 DOI: 10.1021/ja028255v

Macrocyclic Glycoclusters. Self-Aggregation and Phosphate-Induced Agglutination Behaviors of Calix[4]resorcarene-Based Quadruple-Chain Amphiphiles with a Huge Oligosaccharide Pool Osamu Hayashida, Keiji Mizuki, Kazuyuki Akagi, Aki Matsuo, Takuya Kanamori, Takashi Nakai, Shinsuke Sando, and Yasuhiro Aoyama pp 594–601 DOI: 10.1021/ja0275663

Organometallic Complexes for Nonlinear Optics. 30.1 Electrochromic Linear and Nonlinear Optical Properties of Alkynylbis(diphosphine)ruthenium Complexes Clem E. Powell, Marie P. Cifuentes, Joseph P. Morrall, Robert Stranger, Mark G. Humphrey, Marek Samoc, Barry Luther-Davies, and Graham A. Heath pp 602–610 DOI: 10.1021/ja0277125

Issue 03

Small-Molecule Switches for Zinc Finger Transcription Factors Qing Lin, Carlos F. Barbas, III, and Peter G. Schultz pp 612–613 DOI: 10.1021/ja028408e Supporting Info

Correlated Layer Structures:  A Novel Type of Liquid Crystalline Phase with 2D-Lattice Marko Prehm, Siegmar Diele, Malay K. Das, and Carsten Tschierske pp 614–615 DOI: 10.1021/ja0289999 Supporting Info

An HIV Reverse Transcriptase-Selective Nucleoside Chain Terminator Andrew W. Fraley, Dongli Chen, Kenneth Johnson, and Larry W. McLaughlin pp 616–617 DOI: 10.1021/ja020639y Supporting Info

Zeolite-Coated Mesostructured Cellular Silica Foams Do Trong On and Serge Kaliaguine pp 618–619 DOI: 10.1021/ja028656a Supporting Info

Mapping Photogenerated Radicals in Thin Polymer Films:  Fluorescence Imaging Using a Prefluorescent Radical Probe Chris Coenjarts, Olga García, Laura Llauger, J. Palfreyman, Anne L. Vinette, and J. C. Scaiano pp 620–621 DOI: 10.1021/ja028835s Supporting Info

Acetylcholine Esterase-Labeled CdS Nanoparticles on Electrodes:  Photoelectrochemical Sensing of the Enzyme Inhibitors Vered Pardo-Yissar, Eugenii Katz, Julian Wasserman, and Itamar Willner pp 622–623 DOI: 10.1021/ja028922k Supporting Info

Model Aluminum−Poly(p-phenylenevinylene) Interfaces Studied by Surface Raman Spectroscopy Adam M. Hawkridge and Jeanne E. Pemberton pp 624–625 DOI: 10.1021/ja0282902 Supporting Info

Highly Enantioenriched Tetrahydropyridines from Chiral Organosilanes:  Application to the Synthesis of Quinolizidine Alkaloid (−)-217A Hongbing Huang, Thomas F. Spande, and James S. Panek pp 626–627 DOI: 10.1021/ja028937i Supporting Info

Carbonyl-Ene Reactions Catalyzed by Bis(oxazoline) Copper (II) Complexes Proceed by a Facile Stepwise Mechanism:  DFT and ONIOM (DFT:PM3) Studies Iñaki Morao, Jonathan P. McNamara, and Ian H. Hillier pp 628–629 DOI: 10.1021/ja027326n Supporting Info

Patterned Langmuir−Blodgett Films of Monodisperse Nanoparticles of Iron Oxide Using Soft Lithography Qijie Guo, Xiaowei Teng, Saifur Rahman, and Hong Yang pp 630–631 DOI: 10.1021/ja0275764 Supporting Info

On the Stability of a Single-Turn α-Helix:  The Single versus Multiconformation Problem James P. Snyder, Ami S. Lakdawala, and Michael J. Kelso pp 632–633 DOI: 10.1021/ja0278279 Supporting Info

Tuning Copper−Dioxygen Reactivity and Exogenous Substrate Oxidations via Alterations in Ligand Electronics Christiana Xin Zhang, Hong-Chang Liang, Eun-il Kim, Jason Shearer, Matthew E. Helton, Eunsuk Kim, Susan Kaderli, Christopher D. Incarvito, Andreas D. Zuberbühler, Arnold L. Rheingold, and Kenneth D. Karlin pp 634–635 DOI: 10.1021/ja028779v Supporting Info

High-Efficiency Red-Light Emission from Polyfluorenes Grafted with Cyclometalated Iridium Complexes and Charge Transport Moiety Xiwen Chen, Jin-Long Liao, Yongmin Liang, M. O. Ahmed, Hao-En Tseng, and Show-An Chen pp 636–637 DOI: 10.1021/ja0211151 Supporting Info

Double Cyclization via Intramolecular Coupling between Cyclohexadiene−Fe(CO)3 Complexes and Pendant Conjugated Dienes Anthony J. Pearson and Xiaolong Wang pp 638–639 DOI: 10.1021/ja0210188 Supporting Info

Conformationally Homogeneous Cyclic Tetrapeptides:  Useful New Three-Dimensional Scaffolds Matthew P. Glenn, Michael J. Kelso, Joel D. A. Tyndall, and David P. Fairlie pp 640–641 DOI: 10.1021/ja029205t Supporting Info

Are J(Si−H) NMR Coupling Constants Really a Probe for the Existence of Nonclassical H−Si Interactions? Stuart R. Dubberley, Stanislav K. Ignatov, Nicholas H. Rees, Alexei G. Razuvaev, Philip Mountford, and Georgii I. Nikonov pp 642–643 DOI: 10.1021/ja027935v Supporting Info

Dynamic Effects on J-Couplings Across Hydrogen Bonds in Proteins Phineus R. L. Markwick, Remco Sprangers, and Michael Sattler pp 644–645 DOI: 10.1021/ja028875w Supporting Info

A Novel Modified Baylis−Hillman Reaction of Propiolate Yuji Matsuya, Kousuke Hayashi, and Hideo Nemoto pp 646–647 DOI: 10.1021/ja028312k Supporting Info

Palladium-Catalyzed Intramolecular Oxidative Alkylation of Unactivated Olefins Tao Pei, Xiang Wang, and Ross A. Widenhoefer pp 648–649 DOI: 10.1021/ja026317b Supporting Info

Resorcinarenes as Templates:  A General Strategy for the Synthesis of Large Macrocycles Xuehe Li, Thomas G. Upton, Corinne L. D. Gibb, and Bruce C. Gibb pp 650–651 DOI: 10.1021/ja029116g Supporting Info

Evidence for Vesicle Formation during the Synthesis of Catanionic Templated Mesoscopically Ordered Silica as Studied by Cryo-TEM Svetlana Pevzner, Oren Regev, Anna Lind, and Mika Lindén pp 652–653 DOI: 10.1021/ja0289301

Efficient RNase H-Directed Cleavage of RNA Promoted by Antisense DNA or 2‘F-ANA Constructs Containing Acyclic Nucleotide Inserts Maria M. Mangos, Kyung-Lyum Min, Ekaterina Viazovkina, Annie Galarneau, Mohamed I. Elzagheid, Michael A. Parniak, and Masad J. Damha pp 654–661 DOI: 10.1021/ja025557o Supporting Info

Induction of a Remarkable Conformational Change in a Human Telomeric Sequence by the Binding of Naphthyridine Dimer:  Inhibition of the Elongation of a Telomeric Repeat by Telomerase Kazuhiko Nakatani, Shinya Hagihara, Shinsuke Sando, Shigeru Sakamoto, Kentaro Yamaguchi, Chihaya Maesawa, and Isao Saito pp 662–666 DOI: 10.1021/ja027055g

Specific Control of Peptide Assembly with Combined Hydrophilic and Hydrophobic Interfaces Nathan A. Schnarr and Alan J. Kennan pp 667–671 DOI: 10.1021/ja027489b Supporting Info

Insights into the Acylation Mechanism of Class A β-Lactamases from Molecular Dynamics Simulations of the TEM-1 Enzyme Complexed with Benzylpenicillin Natalia Díaz, Tomás L. Sordo, Kenneth M. MerzJr., and Dimas Suárez pp 672–684 DOI: 10.1021/ja027704o Supporting Info

Nanomolar Inhibitors of AmpC β-Lactamase Federica Morandi, Emilia Caselli, Stefania Morandi, Pamela J. Focia, Jesús Blázquez, Brian K. Shoichet, and Fabio Prati pp 685–695 DOI: 10.1021/ja0288338

Antibody Recognition of Chiral Surfaces. Enantiomorphous Crystals of Leucine-Leucine-Tyrosine Merav Geva, Felix Frolow, Miriam Eisenstein, and Lia Addadi pp 696–704 DOI: 10.1021/ja027942j

Molecular Recognition in (+)-α-Pinene Oxidation by Cytochrome P450cam Stephen G. Bell, Xuehui Chen, Rebecca J. Sowden, Feng Xu, Jennifer N. Williams, Luet-Lok Wong, and Zihe Rao pp 705–714 DOI: 10.1021/ja028460a

A Modular Approach toward Functionalized Three-Dimensional Macromolecules:  From Synthetic Concepts to Practical Applications Anton W. Bosman, Robert Vestberg, Andi Heumann, Jean M. J. Fréchet, and Craig J. Hawker pp 715–728 DOI: 10.1021/ja028392s

A New Model for Simulating 3-D Crystal Growth and Its Application to the Study of Antifreeze Proteins Brent Wathen, Michael Kuiper, Virginia Walker, and Zongchao Jia pp 729–737 DOI: 10.1021/ja0267932

Paramagnetic Defect Centers at the MgO Surface. An Alternative Model to Oxygen Vacancies Davide Ricci, Cristiana Di Valentin, Gianfranco Pacchioni, Peter V. Sushko, Alexander L. Shluger, and Elio Giamello pp 738–747 DOI: 10.1021/ja0282240

Activation of 3-Amino-1,2,4-benzotriazine 1,4-Dioxide Antitumor Agents to Oxidizing Species Following Their One-Electron Reduction Robert F. Anderson, Sujata S. Shinde, Michael P. Hay, Swarna A. Gamage, and William A. Denny pp 748–756 DOI: 10.1021/ja0209363

Sugar-Based Gemini Surfactant with a Vesicle-to-Micelle Transition at Acidic pH and a Reversible Vesicle Flocculation near Neutral pH Markus Johnsson, Anno Wagenaar, and Jan B. F. N. Engberts pp 757–760 DOI: 10.1021/ja028195t Supporting Info

Dimethylzinc-Mediated Additions of Alkenylzirconocenes to Aldimines. New Methodologies for Allylic Amine and C-Cyclopropylalkylamine Syntheses Peter Wipf, Christopher Kendall, and Corey R. J. Stephenson pp 761–768 DOI: 10.1021/ja028092a Supporting Info

Secondary Hypervalent I(III)···O Interactions:  Synthesis and Structure of Hypervalent Complexes of Diphenyl-λ3-iodanes with 18-Crown-6 Masahito Ochiai, Takashi Suefuji, Kazunori Miyamoto, Norihiro Tada, Satoru Goto, Motoo Shiro, Shigeru Sakamoto, and Kentaro Yamaguchi pp 769–773 DOI: 10.1021/ja0211205 Supporting Info

Characterization of Chromodulin by X-ray Absorption and Electron Paramagnetic Resonance Spectroscopies and Magnetic Susceptibility Measurements Lilian Jacquamet, Yanjie Sun, Jason Hatfield, Weiwei Gu, Stephen P. Cramer, Michael W. Crowder, Gary A. Lorigan, John B. Vincent, and Jean-Marc Latour pp 774–780 DOI: 10.1021/ja0202661

Palladium(II) Complex as a Sequence-Specific Peptidase:  Hydrolytic Cleavage under Mild Conditions of X-Pro Peptide Bonds in X-Pro-Met and X-Pro-His Segments Nebojša M. Milović and Nenad M. Kostić pp 781–788 DOI: 10.1021/ja027408b Supporting Info

The Role of Oxoammonium Cation in the SOD-Mimic Activity of Cyclic Nitroxides Sara Goldstein, Gabor Merenyi, Angelo Russo, and Amram Samuni pp 789–795 DOI: 10.1021/ja028190w

Reaction of Vinyl Chloride with Group 4 Metal Olefin Polymerization Catalysts Robert A. Stockland, Jr., Stephen R. Foley, and Richard F. Jordan pp 796–809 DOI: 10.1021/ja028530d

Counterion-Dependent Excitonic Spectra of Tetra(p-carboxyphenyl)porphyrin Aggregates in Acidic Aqueous Solution Myong Yong Choi, Jennifer A. Pollard, M. Adam Webb, and Jeanne L. McHale pp 810–820 DOI: 10.1021/ja0274397

Ordered Mesoporous Silica with Large Cage-Like Pores:  Structural Identification and Pore Connectivity Design by Controlling the Synthesis Temperature and Time Jivaldo R. Matos, Michal Kruk, Lucildes P. Mercuri, Mietek Jaroniec, Lan Zhao, Tomoaki Kamiyama, Osamu Terasaki, Thomas J. Pinnavaia, and Yu Liu pp 821–829 DOI: 10.1021/ja0283347 Supporting Info

Silicalite Crystal Growth Investigated by Atomic Force Microscopy Jonathan R. Agger, Noreen Hanif, Colin S. Cundy, Andrew P. Wade, Sally Dennison, Paul A. Rawlinson, and Michael W. Anderson pp 830–839 DOI: 10.1021/ja020899f

Multiple Li Positions inside Oxygen Octahedra in Lithiated TiO2 Anatase Marnix Wagemaker, Gordon J. Kearley, Ad A. van Well, Hannu Mutka, and Fokko M. Mulder pp 840–848 DOI: 10.1021/ja028165q

Functional Condensation Polymers Edited by Charles E. Carraher, Jr. (Florida Atlantic University, Boca Raton, FL and Florida Center for Environmental Studies, Palm Beach Gardens, FL) and Graham G. Swift (G.S.P.C., Chapel Hill, NC). Kluwer Academic/Plenum Publishers:  New York. 2002. xxii + 316 pp. $125.00. ISBN:  0-306-47245-7. p 849 DOI: 10.1021/ja025270r

Progress in the Chemistry of Organic Natural Products, 83 Edited by W. Herz (Florida State University), H. Falk (Johannes-Kepler-University, Linz, Austria), G. W. Kirby (University of Glasgow), and R. E. Moore (University of Hawaii at Manoa). Featuring the Chapter “The Naturally Occurring Coumarins” by R. D. H. Murray. Springer-Verlag:  Wien and New York. 2002. viii + 674 pp. $239.00. ISBN 3-211-83601-2. Paul W. Paré p 849 DOI: 10.1021/ja025280s

Chlorosulfonic Acid:  A Versatile Reagent By R. J. Cremlyn (University of Hertfordshire). Royal Society of Chemistry:  Cambridge. 2002. xiv + 308 pp. $189.00. ISBN 0-85404-498-1. p 849 DOI: 10.1021/ja025296i

Methodologies for Soil and Sediment Fractionation Studies Edited by Ph. Quevauviller (European Commission, DG Research, Brussels). Royal Society of Chemistry:  Cambridge. 2002. xvi + 180 pp. $118.00. ISBN 0-85404-453-1. pp 849–850 DOI: 10.1021/ja025299v

Fundamental Aspects of Electrometallurgy By Konstantin I. Popov (University of Belgrade), Stojan S. Djokić (Westaim Corporation, Fort Saskatchewan, Canada), and Branimir N. Grgur (University of Belgrade). Kluwer Academic/Plenum Publishers:  New York, Boston, Dordrecht, London, and Moscow. 2002. xviii + 305 pp. $135.00. ISBN 0-306-47269-4. KNona Liddell p 850 DOI: 10.1021/ja0252734

Clean Solvents. Alternative Media for Chemical Reactions and Processing Edited by Martin A. Abraham (University of Toledo) and Luc Moens (National Renewable Energy Laboratory). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2002. xiv + 274 pp. $135.00. ISBN 0-8412-3779-4. p 850 DOI: 10.1021/ja0252983

Handbook of Organopalladium Chemistry for Organic Synthesis. Two Volume Set Edited by Ei-ichi Negishi (Purdue University). John Wiley & Sons, Inc.:  Hoboken. 2002. 3424 pp. $595.00. ISBN 0-471-31506-0. p 850 DOI: 10.1021/ja025310r

The Chemistry of Medical and Dental Materials By John W. Nicholson (University of Greenwich, U.K.). Royal Society of Chemistry:  Cambridge. 2002. xii + 242 pp. $108.00. ISBN 0-85404-572-4. pp 850–851 DOI: 10.1021/ja025311j

Metallization of Polymers 2 Edited by Edward Sacher (École Polytechnique, Montréal, Québec). Kluwer Academic/Plenum Publishers:  New York. 2002. viii + 208 pp. $130.00. ISBN 0-306-47253-8. p 851 DOI: 10.1021/ja025312b

Nanoporous Materials III Edited by Abdel Sayari (University of Ottawa) and Mietek Jaroniec (Kent State University). From the Series:  Studies in Surface Science and Catalysis 141. Elsevier:  Amsterdam. 2002. xviii + 692 pp. $210.00. ISBN 0-444-51113-X. p 851 DOI: 10.1021/ja0253134

Recent Advances in Quantum Monte Carlo Methods. Part II Edited by Willaim A. Lester, Jr. (University of California, Berkeley), Stuart M. Rothstein (Brock University, Canada), and Shigenori Tanaka (Toshiba Corporation, Japan). From the Series:  Recent Advances in Computational Chemistry, Volume 2. World Scientific:  New Jersey, London, Singapore, Hong Kong. 2002. xii +316 pp. $72.00. ISBN 981-02-4945-4. p 851 DOI: 10.1021/ja025314w

Glycoscience:  Chemistry and Chemical Biology. Volumes I−III Edited by Bertram Fraser-Reid (Natural Products & Glycotechnology Research Institute, Durham, NC), Kuniaki Tatsuta (Waseda University, Japan), and Joachim Thiem (University of Hamburg, Germany). Springer-Verlag:  Berlin, Heidelberg, New York. 2001. 2970 pp. $995.00 (Set). ISBN 3-540-67764-X (Set). Hung-wen Liu pp 851–852 DOI: 10.1021/ja025258z

Issue 04

Solid State Hydrolysis/Polycondensation of Alkoxysilane:  Access to Crystal-Like Silicon-Based Hybrid Materials Hironobu Muramatsu, Robert Corriu, and Bruno Boury pp 854–855 DOI: 10.1021/ja020975e Supporting Info

DNA Polymerase-Mediated DNA Synthesis on a TNA Template John C. Chaput, Justin K. Ichida, and Jack W. Szostak pp 856–857 DOI: 10.1021/ja028589k

Experimental and Computational Evidence for a Boron-Assisted, σ-Bond Metathesis Pathway for Alkane Borylation Charles Edwin Webster, Yubo Fan, Michael B. Hall, Doris Kunz, and John F. Hartwig pp 858–859 DOI: 10.1021/ja028394c Supporting Info

Competition between C−C and C−H Insertion in Prototype Transition Metal−Hydrocarbon Reactions Ryan Z. Hinrichs, Jonathan J. Schroden, and H. Floyd Davis pp 860–861 DOI: 10.1021/ja0278842 Supporting Info

Highly Unusual Effects of π-Conjugation Extension on the Molecular Linear and Quadratic Nonlinear Optical Properties of Ruthenium(II) Ammine Complexes Benjamin J. Coe, Lathe A. Jones, James A. Harris, Bruce S. Brunschwig, Inge Asselberghs, Koen Clays, and André Persoons pp 862–863 DOI: 10.1021/ja028897i Supporting Info

Zinc Chalcogenolate Complexes as Capping Agents in the Synthesis of Ternary II−II‘−VI Nanoclusters:  Structure and Photophysical Properties of [(N,N‘-tmeda)5Zn5Cd11Se13(SePh)6(thf)2] Marty W. DeGroot, Nicholas J. Taylor, and John F. Corrigan pp 864–865 DOI: 10.1021/ja028800s Supporting Info

UV Raman Spectrum of 1,3-Dimethylcyclopentenyl Cation Adsorbed in Zeolite H-MFI Yek Tann Chua, Peter C. Stair, John B. Nicholas, Weiguo Song, and James F. Haw pp 866–867 DOI: 10.1021/ja028439+

Control of Thiolate Nucleophilicity and Specificity in Zinc Metalloproteins by Hydrogen Bonding:  Lessons from Model Compound Studies Jennifer N. Smith, Zahida Shirin, and Carl J. Carrano pp 868–869 DOI: 10.1021/ja029418i Supporting Info

An Extraordinarily Rapid Polymerization of Vinylpentafluorocyclopropane:  Highly Stereo- and Regioselective Synthesis of Unsaturated Fluoropolymers Zhen-Yu Yang pp 870–871 DOI: 10.1021/ja021289i Supporting Info

Unusual Reactivity of Molecular Oxygen with π-Allylnickel(N-heterocyclic carbene) Chloride Complexes Benjamin R. Dible and Matthew S. Sigman pp 872–873 DOI: 10.1021/ja0286876 Supporting Info

Carbon−Carbon Bonds by Hydrolytic Enzymes Cecilia Branneby, Peter Carlqvist, Anders Magnusson, Karl Hult, Tore Brinck, and Per Berglund pp 874–875 DOI: 10.1021/ja028056b

A New Turn Structure for the Formation of β-Hairpins in Peptides James S. Nowick and Justin O. Brower pp 876–877 DOI: 10.1021/ja028938a

Doubly N-Confused Hexaphyrin:  A Novel Aromatic Expanded Porphyrin that Complexes Bis-metals in the Core Alagar Srinivasan, Tomoya Ishizuka, Atsuhiro Osuka, and Hiroyuki Furuta pp 878–879 DOI: 10.1021/ja029018v Supporting Info

Elucidation of the Structure of a Highly Efficient Blue Electroluminescent Material Annie J. Middleton, William J. Marshall, and Nora S. Radu pp 880–881 DOI: 10.1021/ja027323a Supporting Info

A New Strategy for Neurochemical Photodelivery:  Metal−Ligand Heterolytic Cleavage Leonardo Zayat, Cecilia Calero, Pablo Alborés, Luis Baraldo, and Roberto Etchenique pp 882–883 DOI: 10.1021/ja0278943 Supporting Info

Protonation and Bromination of an Osmabenzyne:  Reactions Leading to the Formation of New Metallabenzynes Ting Bin Wen, Sze Ming Ng, Wai Yiu Hung, Zhong Yuan Zhou, Man Fung Lo, Lai-Yung Shek, Ian D. Williams, Zhenyang Lin, and Guochen Jia pp 884–885 DOI: 10.1021/ja029110r Supporting Info

Selective, Catalytic Carbon−Carbon Bond Activation and Functionalization Promoted by Late Transition Metal Catalysts Suzanne C. Bart and Paul J. Chirik pp 886–887 DOI: 10.1021/ja028912j Supporting Info

Templating and Supersaturation-Driven Anti-Templating:  Principles of Biomineral Architecture Xiang Y. Liu and See Wai Lim pp 888–895 DOI: 10.1021/ja020355d

DNA Hybridization Detection with Water-Soluble Conjugated Polymers and Chromophore-Labeled Single-Stranded DNA Brent S. Gaylord, Alan J. Heeger, and Guillermo C. Bazan pp 896–900 DOI: 10.1021/ja027152+ Supporting Info

Molecular Dynamics and Quantum Chemical Studies on the Catalytic Mechanism of Δ5-3-Ketosteroid Isomerase:  The Catalytic Diad versus the Cooperative Hydrogen Bond Mechanism Hwangseo Park and Kenneth M. Merz, Jr. pp 901–911 DOI: 10.1021/ja0208097

Formation of Pyrene Dimer Radical Cation in DNA Reflecting DNA Dynamics in the Time Range of 1 μs to 1 ms Kiyohiko Kawai, Kei Miyamoto, Sachiko Tojo, and Tetsuro Majima pp 912–915 DOI: 10.1021/ja026754q Supporting Info

Combined Use of NMR Relaxation Measurements and Hydrodynamic Calculations To Study Protein Association. Evidence for Tetramers of Low Molecular Weight Protein Tyrosine Phosphatase in Solution Pau Bernadó, Tomas Åkerud, José García de la Torre, Mikael Akke, and Miquel Pons pp 916–923 DOI: 10.1021/ja027836h

Relative Reactivity of Peracids versus Dioxiranes (DMDO and TFDO) in the Epoxidation of Alkenes. A Combined Experimental and Theoretical Analysis Robert D. Bach, Olga Dmitrenko, Waldemar Adam, and Simon Schambony pp 924–934 DOI: 10.1021/ja026882e Supporting Info

Generation of a Bacterium with a 21 Amino Acid Genetic Code Ryan A. Mehl, J. Christopher Anderson, Stephen W. Santoro, Lei Wang, Andrew B. Martin, David S. King, David M. Horn, and Peter G. Schultz pp 935–939 DOI: 10.1021/ja0284153 Supporting Info

Solid-Phase Chemical Synthesis of Phosphonoacetate and Thiophosphonoacetate Oligodeoxynucleotides Douglas J. Dellinger, David M. Sheehan, Nanna K. Christensen, James G. Lindberg, and Marvin H. Caruthers pp 940–950 DOI: 10.1021/ja027983f

Functionalization and Kinetic Stabilization of the [4]Paracyclophane System and Aromaticity of Its Extremely Bent Benzene Ring Takashi Tsuji, Masahiro Okuyama, Masakazu Ohkita, Hidetoshi Kawai, and Takanori Suzuki pp 951–961 DOI: 10.1021/ja021206y Supporting Info

Novel Photoacid Generators for Photodirected Oligonucleotide Synthesis Pawel J. Serafinowski and Peter B. Garland pp 962–965 DOI: 10.1021/ja017635y Supporting Info

Supramolecular Catalysis of the Enantiodifferentiating [4 + 4] Photocyclodimerization of 2-Anthracenecarboxylate by γ-Cyclodextrin Asao Nakamura and Yoshihisa Inoue pp 966–972 DOI: 10.1021/ja016238k

Mapping the Potential Energy Surface of the Tolylcarbene Rearrangement in the Inner Phase of a Hemicarcerand Jean-Luc Kerdelhué, Kevin J. Langenwalter, and Ralf Warmuth pp 973–986 DOI: 10.1021/ja027831k Supporting Info

Multistate/Multifunctional Systems. A Thermodynamic, Kinetic, and Photochemical Investigation of the 4‘-Dimethylaminoflavylium Compound Ana Roque, Carlos Lodeiro, Fernando Pina, Mauro Maestri, Stephane Dumas, Paolo Passaniti, and Vincenzo Balzani pp 987–994 DOI: 10.1021/ja0287276 Supporting Info

Stereochemical Memory in the Regioselective and Diastereoselective Rearrangement of Tricyclo[3.3.0.02,4]octanes (Housanes) by Electron Transfer (1,3-Cyclopentanediyl Radical Cations) and Acid (Cyclopentyl Carbenium Ions) and Silver-Ion Catalysis Waldemar Adam, Christian P. Librera, Frank-Gerrit Klärner, and Frank Wurche pp 995–1001 DOI: 10.1021/ja028649m Supporting Info

Molecular Tectonics. Use of the Hydrogen Bonding of Boronic Acids To Direct Supramolecular Construction Jean-Hugues Fournier, Thierry Maris, James D. Wuest, Wenzhuo Guo, and Elena Galoppini pp 1002–1006 DOI: 10.1021/ja0276772 Supporting Info

Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer Shunichi Fukuzumi, Ken Okamoto, Yutaka Yoshida, Hiroshi Imahori, Yasuyuki Araki, and Osamu Ito pp 1007–1013 DOI: 10.1021/ja026441v Supporting Info

Gas-Phase SN2 and Bromine Abstraction Reactions of Chloride Ion with Bromomethane:  Reaction Cross Sections and Energy Disposal into Products Laurence A. Angel and Kent M. Ervin pp 1014–1027 DOI: 10.1021/ja021003+

Theoretical Investigation of the Apparently Irregular Behavior of Pt−Pt Nuclear Spin−Spin Coupling Constants Jochen Autschbach, Ciprian D. Igna, and Tom Ziegler pp 1028–1032 DOI: 10.1021/ja027931q Supporting Info

Aurophilic Interactions in Cationic Gold Complexes with Two Isocyanide Ligands. Polymorphic Yellow and Colorless Forms of [(Cyclohexyl Isocyanide)2AuI](PF6) with Distinct Luminescence Rochelle L. White-Morris, Marilyn M. Olmstead, and Alan L. Balch pp 1033–1040 DOI: 10.1021/ja020902v Supporting Info

Role of Copper Ion in Bacterial Copper Amine Oxidase:  Spectroscopic and Crystallographic Studies of Metal-Substituted Enzymes Sei'ichiro Kishishita, Toshihide Okajima, Misa Kim, Hiroshi Yamaguchi, Shun Hirota, Shinnichiro Suzuki, Shun'ichi Kuroda, Katsuyuki Tanizawa, and Minae Mure pp 1041–1055 DOI: 10.1021/ja017899k

Molecular Quantum-Dot Cellular Automata Craig S. Lent, Beth Isaksen, and Marya Lieberman pp 1056–1063 DOI: 10.1021/ja026856g

Cyclopentadiene Annulated Polycyclic Aromatic Hydrocarbons:  Investigations of Electron Affinities Jason M. Gonzales, Christopher J. Barden, Shawn T. Brown, Paul von Ragué Schleyer, Henry F. Schaefer, III, and Qian-Shu Li pp 1064–1071 DOI: 10.1021/ja0210502 Supporting Info

Energetic and Stereochemical Effects of the Protein Environment on Substrate:  A Theoretical Study of Methylmalonyl-CoA Mutase Markus J. Loferer, Ben M. Webb, Guy H. Grant, and Klaus R. Liedl pp 1072–1078 DOI: 10.1021/ja028906n

Theoretical Analysis of the Triplet Excited State of the [Pt2(H2P2O5)4]4- Ion and Comparison with Time-Resolved X-ray and Spectroscopic Results Irina V. Novozhilova, Anatoliy V. Volkov, and Philip Coppens pp 1079–1087 DOI: 10.1021/ja027857b Supporting Info

Hydration of Hydroxypyrrole Influences Binding of ImHpPyPy-β-Dp Polyamide to DNA Bernd Wellenzohn, Markus J. Loferer, Michael Trieb, Christine Rauch, Rudolf H. Winger, Erwin Mayer, and Klaus R. Liedl pp 1088–1095 DOI: 10.1021/ja0277778

Ion Atmosphere Relaxation Control of Electron Transfer Dynamics in a Plasticized Carbon Dioxide Redox Polyether Melt Dongil Lee, Amanda S. Harper, Joseph M. DeSimone, and Royce W. Murray pp 1096–1103 DOI: 10.1021/ja0287128 Supporting Info

A Two-Color Laser Photolysis Method for Determining Reaction Rates of Short-Lived Intermediates by Product Analysis:  Application to the o-Quinodimethane Problem Akihiko Ouchi, Zhong Li, Masako Sakuragi, and Tetsuro Majima pp 1104–1108 DOI: 10.1021/ja027653v Supporting Info

Issue 05

Diastereo- and Enantioselective Catalytic Carbometallative Aldol Cycloreduction:  Tandem Conjugate Addition−Aldol Cyclization David F. Cauble, John D. Gipson, and Michael J. Krische pp 1110–1111 DOI: 10.1021/ja0211095 Supporting Info

3‘-Ferrocene-Labeled Oligonucleotide Chains End-Tethered to Gold Electrode Surfaces:  Novel Model Systems for Exploring Flexibility of Short DNA Using Cyclic Voltammetry Agnès Anne, Agnès Bouchardon, and Jacques Moiroux pp 1112–1113 DOI: 10.1021/ja028640k Supporting Info

Differential Receptors Create Patterns Diagnostic for ATP and GTP Shawn C. McCleskey, Michael J. Griffin, Stephen E. Schneider, John T. McDevitt, and Eric V. Anslyn pp 1114–1115 DOI: 10.1021/ja021230b Supporting Info

A Potent, Water-Soluble and Photoinducible DNA Cross-Linking Agent Ping Wang, Renpeng Liu, Xiaojun Wu, Hongjuan Ma, Xiaoping Cao, Ping Zhou, Jiangye Zhang, Xiaocheng Weng, Xiao-Lian Zhang, Jun Qi, Xiang Zhou, and Linhong Weng pp 1116–1117 DOI: 10.1021/ja029040o Supporting Info

Photoinduced Electron Injection from Ru(dcbpy)2(NCS)2 to SnO2 and TiO2 Nanocrystalline Films Gábor Benkö, Pasi Myllyperkiö, Jie Pan, Arkady P. Yartsev, and Villy Sundström pp 1118–1119 DOI: 10.1021/ja029025j Supporting Info

To Fold or to Assemble? Wei Wang, Lin-Song Li, Greg Helms, Hong-Hui Zhou, and Alexander D. Q. Li pp 1120–1121 DOI: 10.1021/ja027186h Supporting Info

Novel Self-Assembled Monolayers of Dipolar Ruthenium(III/II) Pentaammine(4,4‘-bipyridinium) Complexes on Ultrathin Platinum Films as Redox Molecular Switches Salvatore Sortino, Salvatore Petralia, Sabrina Conoci, and Santo Di Bella pp 1122–1123 DOI: 10.1021/ja029258a Supporting Info

Nerve Agents Detection Using a Cu2+/l-Cysteine Bilayer-Coated Microcantilever Yuming Yang, Hai-Feng Ji, and Thomas Thundat pp 1124–1125 DOI: 10.1021/ja028181n

Selectivity of Calix[4]arene-bis(benzocrown-6) in the Complexation and Transport of Francium Ion Tamara J. Haverlock, Saed Mirzadeh, and Bruce A. Moyer pp 1126–1127 DOI: 10.1021/ja0255251

A Highly Stable N-Heterocyclic Carbene Complex of Trichloro-oxo-vanadium(V) Displaying Novel Cl−Ccarbene Bonding Interactions Colin D. Abernethy, Gareth M. Codd, Mark D. Spicer, and Michelle K. Taylor pp 1128–1129 DOI: 10.1021/ja0276321 Supporting Info

Combinatorial Approach to Organelle-Targeted Fluorescent Library Based on the Styryl Scaffold Gustavo R. Rosania, Jae Wook Lee, Liang Ding, Hai-Shin Yoon, and Young-Tae Chang pp 1130–1131 DOI: 10.1021/ja027587x Supporting Info

Solvent Polarity at an Aqueous/Alkane Interface:  The Effect of Solute Identity William H. Steel and Robert A. Walker pp 1132–1133 DOI: 10.1021/ja028468k

Ionicity of Intramolecular Charge-Transfer Molecule Dδ+−π−Aδ- Based on 1,3,3-Trimethyl-2-methyleneindoline and 7,7,8,8-Tetracyanoquinodimethane Gunzi Saito, Chin-Hong Chong, Masaru Makihara, Akihiro Otsuka, and Hideki Yamochi pp 1134–1135 DOI: 10.1021/ja027749p Supporting Info

Hydrometal Analogues of Aromatic Hydrocarbons:  A New Class of Cyclic Hydrocoppers(I) Athanassios C. Tsipis and Constantinos A. Tsipis pp 1136–1137 DOI: 10.1021/ja028786j Supporting Info

Nonaqueous Synthesis and Selective Crystallization of Gallium Sulfide Clusters into Three-Dimensional Photoluminescent Superlattices Nanfeng Zheng, Xianhui Bu, and Pingyun Feng pp 1138–1139 DOI: 10.1021/ja021274k Supporting Info

Asymmetric Catalysis of Nozaki−Hiyama Allylation and Methallylation with A New Tridentate Bis(oxazolinyl)carbazole Ligand Masahiro Inoue, Takahiro Suzuki, and Masahisa Nakada pp 1140–1141 DOI: 10.1021/ja021243p Supporting Info

A Proton-Doped Calix[4]arene-Based Conducting Polymer Hsiao-hua Yu, Bing Xu, and Timothy M. Swager pp 1142–1143 DOI: 10.1021/ja028545b Supporting Info

Novel PI Analogues Selectively Block Activation of the Pro-survival Serine/Threonine Kinase Akt Alan P. Kozikowski, Haiying Sun, John Brognard, and Phillip A. Dennis pp 1144–1145 DOI: 10.1021/ja0285159 Supporting Info

Spectroscopic Evidence for Site Specific Chemistry at a Unique Iron Site of the [4Fe−4S] Cluster in Ferredoxin:Thioredoxin Reductase Guy N. L. Jameson, Elizabeth M. Walters, Wanda Manieri, Peter Schürmann, Michael K. Johnson, and Boi Hanh Huynh pp 1146–1147 DOI: 10.1021/ja029338e

Label-Free Chiral Detection of Melittin Binding to a Membrane Matthew A. Kriech and John C. Conboy pp 1148–1149 DOI: 10.1021/ja028577z Supporting Info

Supramolecular H-Bonded Assemblies of Redox-Active Metallodendrimers and Positive and Unusual Dendritic Effects on the Recognition of H2PO4- Marie-Christine Daniel, Jaime Ruiz, and Didier Astruc pp 1150–1151 DOI: 10.1021/ja020833k Supporting Info

Novel Cu(I) Dinuclear Complexes Containing μ2-η2,η2-Type Benzoquinone Ligand Shigeyuki Masaoka, George Akiyama, Satoshi Horike, Susumu Kitagawa, Tomohiko Ida, and Kazunaka Endo pp 1152–1153 DOI: 10.1021/ja029023z Supporting Info

A Method for Making Inorganic and Hybrid (Organic/Inorganic) Fibers and Vesicles with Diameters in the Submicrometer and Micrometer Range via Sol−Gel Chemistry and Electrically Forced Liquid Jets Gustavo Larsen, Raffet Velarde-Ortiz, Kevin Minchow, Antonio Barrero, and Ignacio G. Loscertales pp 1154–1155 DOI: 10.1021/ja028983i Supporting Info

Solvent-Free Functionalization of Carbon Nanotubes Christopher A. Dyke and James M. Tour pp 1156–1157 DOI: 10.1021/ja0289806 Supporting Info

Ultratrace Kinetic Measurements of the Reduction of Methylene Blue Alexander J. Hallock, Elena S. F. Berman, and Richard N. Zare pp 1158–1159 DOI: 10.1021/ja028129r

Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans-μ-1,2 End-On Disulfide Complex:  New Directions in Copper−Sulfur Chemistry Matthew E. Helton, Peng Chen, Partha P. Paul, Zoltán Tyeklár, Roger D. Sommer, Lev N. Zakharov, Arnold L. Rheingold, Edward I. Solomon, and Kenneth D. Karlin pp 1160–1161 DOI: 10.1021/ja027574j Supporting Info

Aerobic Oxidations Catalyzed by Chromium Corroles Atif Mahammed, Harry B. Gray, Alexandre E. Meier-Callahan, and Zeev Gross pp 1162–1163 DOI: 10.1021/ja028216j

Excited-State Intramolecular Proton Transfer in o-Hydroxybiaryls:  A New Route to Dihydroaromatic Compounds Matthew Lukeman and Peter Wan pp 1164–1165 DOI: 10.1021/ja029376y

Gelation of Ionic Liquid-Based Electrolytes with Silica Nanoparticles for Quasi-Solid-State Dye-Sensitized Solar Cells Peng Wang, Shaik M. Zakeeruddin, Pascal Comte, Ivan Exnar, and Michael Grätzel pp 1166–1167 DOI: 10.1021/ja029294+

Optical Determination of the Single-Ion Zero-Field Splitting in Large Spin Clusters David Collison, Vasily S. Oganesyan, Stergios Piligkos, Andrew J. Thomson, Richard E. P. Winpenny, and Eric J. L. McInnes pp 1168–1169 DOI: 10.1021/ja029003x

Remarkable Metal-Rich Ternary Chalcogenides Sc14M3Te8 (M = Ru, Os) Ling Chen and John D. Corbett pp 1170–1171 DOI: 10.1021/ja0291540 Supporting Info

15N NMR Study on Site-Selective Binding of Metal Ions to Guanine Runs in DNA:  A Good Correlation with HOMO Distribution Akimitsu Okamoto, Keiichiro Kanatani, Toshiji Taiji, and Isao Saito pp 1172–1173 DOI: 10.1021/ja0279388 Supporting Info

Novel Fluorophores for Single-Molecule Imaging Katherine A. Willets, Oksana Ostroverkhova, Meng He, Robert J. Twieg, and W. E. Moerner pp 1174–1175 DOI: 10.1021/ja029100q

A New Form of Kinetic Isotope Effect. Dynamic Effects on Isotopic Selectivity and Regioselectivity Daniel A. Singleton, Chao Hang, Michael J. Szymanski, and Erin E. Greenwald pp 1176–1177 DOI: 10.1021/ja027221k Supporting Info

p-Benzosemiquinone Radical Anion on Silver Nanoparticles in Water G. N. R. Tripathi pp 1178–1179 DOI: 10.1021/ja029049q

Stereochemistry of Palladium-Mediated Synthesis of PAMP−BH3:  Retention of Configuration at P in Formation of Pd−P and P−C Bonds Jillian R. Moncarz, Tim J. Brunker, David S. Glueck, Roger D. Sommer, and Arnold L. Rheingold pp 1180–1181 DOI: 10.1021/ja029404c Supporting Info

Voltammetry and Electron-Transfer Dynamics in a Molecular Melt of a 1.2 nm Metal Quantum Dot Dongil Lee, Robert L. Donkers, Joseph M. DeSimone, and Royce W. Murray pp 1182–1183 DOI: 10.1021/ja029030n Supporting Info

Novel Z-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Half-Metallocene Complexes Masayoshi Nishiura, Zhaomin Hou, Yasuo Wakatsuki, Taeko Yamaki, and Takeshi Miyamoto pp 1184–1185 DOI: 10.1021/ja027595d Supporting Info

Highly Negative Homotropic Allosteric Binding of Viologens in a Double-Cavity Porphyrin Pall Thordarson, Edward J. A. Bijsterveld, Johannes A. A. W. Elemans, Peter Kasák, Roeland J. M. Nolte, and Alan E. Rowan pp 1186–1187 DOI: 10.1021/ja028463n Supporting Info

Remarkably Favorable Hydration of Carbonyl Substituents in Dicationic Bis(arene) Ruthenium Complexes Elsa L. Velarde, Rosary A. Stephen, Rena N. Mansour, Linh T. Hoang, and David J. Burkey pp 1188–1189 DOI: 10.1021/ja028896q Supporting Info

Catalytic Asymmetric Silane Alcoholysis:  Practical Access to Chiral Silanes Darby R. Schmidt, Steven J. O'Malley, and James L. Leighton pp 1190–1191 DOI: 10.1021/ja0283201 Supporting Info

The First Enantioselective Organocatalytic Mukaiyama−Michael Reaction:  A Direct Method for the Synthesis of Enantioenriched γ-Butenolide Architecture Sean P. Brown, Nicole C. Goodwin, and David W. C. MacMillan pp 1192–1194 DOI: 10.1021/ja029095q Supporting Info

Sequence Specific Fluorescence Detection of Double Strand DNA Victor C. Rucker, Shane Foister, Christian Melander, and Peter B. Dervan pp 1195–1202 DOI: 10.1021/ja021011q Supporting Info

Dual Wavelength Parametric Test of Two-State Models for Circular Dichroism Spectra of Helical Polypeptides:  Anomalous Dichroic Properties of Alanine-Rich Peptides Peter Wallimann, Robert J. Kennedy, Justin S. Miller, William Shalongo, and Daniel S. Kemp pp 1203–1220 DOI: 10.1021/ja0275360

Impact of Azaproline on Amide Cis−Trans Isomerism:  Conformational Analyses and NMR Studies of Model Peptides Including TRH Analogues Wei-Jun Zhang, Anders Berglund, Jeff L.-F. Kao, Jean-Pierre Couty, Marvin C. Gershengorn, and Garland R. Marshall pp 1221–1235 DOI: 10.1021/ja020994o

A New Approach to Mineralization of Biocompatible Hydrogel Scaffolds:  An Efficient Process toward 3-Dimensional Bonelike Composites Jie Song, Eduardo Saiz, and Carolyn R. Bertozzi pp 1236–1243 DOI: 10.1021/ja028559h

Heavy Atom Isotope Effects on the Reaction Catalyzed by the Oxalate Decarboxylase from Bacillus subtilis Laurie A. Reinhardt, Drazenka Svedruzic, Christopher H. Chang, W. Wallace Cleland, and Nigel G. J. Richards pp 1244–1252 DOI: 10.1021/ja0286977

Origin of the Red Shifts in the Optical Absorption Bands of Nonplanar Tetraalkylporphyrins Raid E. Haddad, Stéphanie Gazeau, Jacques Pécaut, Jean-Claude Marchon, Craig J. Medforth, and John A. Shelnutt pp 1253–1268 DOI: 10.1021/ja0280933 Supporting Info

Functional Nanocomposites Prepared by Self-Assembly and Polymerization of Diacetylene Surfactants and Silicic Acid Yi Yang, Yunfeng Lu, Mengcheng Lu, Jinman Huang, Raid Haddad, George Xomeritakis, Nanguo Liu, Anthony P. Malanoski, Dietmar Sturmayr, Hongyou Fan, Darryl Y. Sasaki, Roger A. Assink, John A. Shelnutt, Frank van Swol, Gabriel P. Lopez, Alan R. Burns, and C. Jeffrey Brinker pp 1269–1277 DOI: 10.1021/ja027332j Supporting Info

Detection and Amplification of a Small Enantiomeric Imbalance in α-Amino Acids by a Helical Poly(phenylacetylene) with Crown Ether Pendants Ryuji Nonokawa and Eiji Yashima pp 1278–1283 DOI: 10.1021/ja028348c Supporting Info

Atomic Properties of Selected Biomolecules:  Quantum Topological Atom Types of Carbon Occurring in Natural Amino Acids and Derived Molecules P. L. A. Popelier and F. M. Aicken pp 1284–1292 DOI: 10.1021/ja0284198 Supporting Info

Noninnocence of the Ligand Glyoxal-bis(2-mercaptoanil). The Electronic Structures of [Fe(gma)]2, [Fe(gma)(py)]·py, [Fe(gma)(CN)]1-/0, [Fe(gma)I], and [Fe(gma)(PR3)n] (n = 1, 2). Experimental and Theoretical Evidence for “Excited State” Coordination Prasanta Ghosh, Eckhard Bill, Thomas Weyhermüller, Frank Neese, and Karl Wieghardt pp 1293–1308 DOI: 10.1021/ja021123h Supporting Info

Hydrogen Adsorption in Nanoporous Nickel(II) Phosphates Paul M. Forster, Juergen Eckert, Jong-San Chang, Sang-Eon Park, Gérard Férey, and Anthony K. Cheetham pp 1309–1312 DOI: 10.1021/ja028341v

Structure−Function Relations in Self-Assembled C18- and C20-Sphingosines Monolayers at Gas/Water Interfaces David Vaknin pp 1313–1318 DOI: 10.1021/ja028292m

Mechanism of Ene Reactions of Singlet Oxygen. A Two-Step No-Intermediate Mechanism Daniel A. Singleton, Chao Hang, Michael J. Szymanski, Matthew P. Meyer, Andrew G. Leach, Keith T. Kuwata, Jenny S. Chen, Alexander Greer, Christopher S. Foote, and K. N. Houk pp 1319–1328 DOI: 10.1021/ja027225p Supporting Info

Shock-Wave Resistance of WS2 Nanotubes Yan Qiu Zhu, Toshimori Sekine, Kieren S. Brigatti, Steve Firth, Reshef Tenne, Rita Rosentsveig, Harold W. Kroto, and David R. M. Walton pp 1329–1333 DOI: 10.1021/ja021208i

Mechanistic Studies on the Interaction of Reduced Cobalamin (Vitamin B12r) with Nitroprusside Maria Wolak, Grazyna Stochel, and Rudi van Eldik pp 1334–1351 DOI: 10.1021/ja0210852 Supporting Info

Electrodeposition of Au−Cd Alloy Nanostructures on Au(111) Marcus D. Lay and John L. Stickney pp 1352–1355 DOI: 10.1021/ja0287534

Entropic Barriers in Nanoscale Adhesion Studied by Variable Temperature Chemical Force Microscopy Aleksandr Noy, Salvador Zepeda, Christine A. Orme, Yin Yeh, and James J. De Yoreo pp 1356–1362 DOI: 10.1021/ja026865p

Crown-Annelated Oligothiophenes as Model Compounds for Molecular Actuation Bruno Jousselme, Philippe Blanchard, Eric Levillain, Jacques Delaunay, Magali Allain, Pascal Richomme, David Rondeau, Nuria Gallego-Planas, and Jean Roncali pp 1363–1370 DOI: 10.1021/ja026819p Supporting Info

Ligand Exchange Dynamics in Aluminum Tris-(Quinoline-8-olate):  A Solution State NMR Study Marcel Utz, Changqing Chen, Martha Morton, and Fotios Papadimitrakopoulos pp 1371–1375 DOI: 10.1021/ja027825o

Chemical and Photochemical Electron Transfer of New Helianthrone Derivatives:  Aspects of Their Photodynamic Activity Shai Rahimipour, Cornelia Palivan, Frédérique Barbosa, Itzhak Bilkis, Yitzhak Koch, Lev Weiner, Mati Fridkin, Yehuda Mazur, and Georg Gescheidt pp 1376–1384 DOI: 10.1021/ja028189x

GFT NMR, a New Approach To Rapidly Obtain Precise High-Dimensional NMR Spectral Information Seho Kim and Thomas Szyperski pp 1385–1393 DOI: 10.1021/ja028197d Supporting Info

Structure of the Aqueous Solvated Electron from Resonance Raman Spectroscopy:  Lessons from Isotopic Mixtures Michael J. Tauber and Richard A. Mathies pp 1394–1402 DOI: 10.1021/ja021134a

Normal and Inverse Primary Kinetic Deuterium Isotope Effects for C−H Bond Reductive Elimination and Oxidative Addition Reactions of Molybdenocene and Tungstenocene Complexes:  Evidence for Benzene σ-Complex Intermediates David G. Churchill, Kevin E. Janak, Joshua S. Wittenberg, and Gerard Parkin pp 1403–1420 DOI: 10.1021/ja027670k Supporting Info

Protonation of Gas-Phase Aromatic Molecules:  IR Spectrum of the Fluoronium Isomer of Protonated Fluorobenzene Nicola Solcà and Otto Dopfer pp 1421–1430 DOI: 10.1021/ja021036p

Toxicity Screening by Electrochemical Detection of DNA Damage by Metabolites Generated In Situ in Ultrathin DNA−Enzyme Films Liping Zhou, Jing Yang, Carmelita Estavillo, James D. Stuart, John B. Schenkman, and James F. Rusling pp 1431–1436 DOI: 10.1021/ja0290274 Supporting Info

Pipeline Pilot 2.1 By Scitegic, 9665 Chesapeake Drive, Suite 401, San Diego, CA 92123-1365. www.scitegic.com. See Web Site for Pricing Information James M. Stevenson and Peter D. Mulready pp 1437–1438 DOI: 10.1021/ja025304v

Carbene Chemistry:  From Fleeting Intermediates to Powerful Reagents Edited by Guy Bertrand (Univers-ity of California, Riverside). FontisMedia S. A.:  Lausanne and Marcel Dekker, Inc.:  New York, Basel. 2002. xvi + 302 pp. $165.00. ISBN 0-8247-0831-8. Xavier Creary p 1439 DOI: 10.1021/ja0252882

Fluorescence Spectroscopy, Imaging, and Probes:  New Tools in Chemical, Physical, and Life Sciences Edited by Ruud Kraayenhof (Vrije Universiteit, Amsterdam), Antonie J. W. G. Visser (Wageningen University), and Hans C. Gerritsen (University of Utrecht). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. xxvi + 390 pp. $109.00. ISBN 3-540-42768-6. p 1439 DOI: 10.1021/ja0253235

Fiesers' Reagents for Organic Synthesis, Volume 21 By Tse-Lok Ho (National Chiao Tung University, China). John Wiley & Sons, Inc.:  Hoboken. 2003. xvi + 590 pp. $99.95. ISBN 0-471-21393-4. pp 1439–1440 DOI: 10.1021/ja0253437

Progress in the Chemistry of Organic Natural Products 84 Edited by W. Herz (Florida State University, Tallahassee), H. Falk (Johannes-Kepler-Universität, Linz, Austria), and G. W. Kirby (University of Glasgow, U.K.). Springer-Verlag:  Wein, New York. 2002. 253 pp. $159.00. ISBN 3-211-83707-8. Paul Sampson p 1440 DOI: 10.1021/ja025286h

An Introduction to Laser Spectroscopy, 2nd Edition Edited by David L. Andrews (University of East Anglia, Norwich, U.K.) and Andrey A. Demidov (LaserSharp Corporation, Boston). Kluwer Academic/Plenum Publishers:  New York. 2002. xii + 376 pp. $95.00. ISBN 0-306-47298-8. Nicolo' Omenetto pp 1440–1441 DOI: 10.1021/ja0253033

Targets in Heterocyclic Systems:  Chemistry and Properties. Volume 5 (2001). Reviews and Accounts on Heterocyclic Chemistry Edited by Orazio A. Attanasi (University of Urbino) and Domenico Spinelli (University of Bologna). Italian Society of Chemistry:  Rome. 2002. xviii + 520 pp. $89.95. ISBN 88-86208-19-7. p 1441 DOI: 10.1021/ja025339v

Atlas of Plastics Additives:  Analysis by Spectrometric Methods By Dietrich O. Hummel (University of Cologne, Germany). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. viii + 538 pp. $400.00. ISBN 3-540-42414-8. p 1441 DOI: 10.1021/ja0253484

Structural and Electronic Properties of Molecular Nanostructures. AIP Conference Proceedings, Volume 633 Edited by Hans Kuzmany (Universität Wien), Jörg Fink (Institut für Festkörper-und Werkstoff-Forschung, Dresden), Michael Mehring (Universität Stuttgart), and Siegmar Roth (Max-Planck-Institut für Festkörperforschung, Stuttgart). American Institute of Physics:  Melville, New York. 2002. xx + 636 pp. $210.00. ISBN 0-7354-0088-1. pp 1441–1442 DOI: 10.1021/ja025332d

Issue 06

Direct Observation of an Acyl Nitroso Species in Solution by Time-Resolved IR Spectrocopy Andrew D. Cohen, Bu-Bing Zeng, S. Bruce King, and John P. Toscano pp 1444–1445 DOI: 10.1021/ja028978e Supporting Info

Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst Ana Caballero, M. Mar Díaz-Requejo, Tomás R. Belderraín, M. Carmen Nicasio, Swiatoslaw Trofimenko, and Pedro J. Pérez pp 1446–1447 DOI: 10.1021/ja0291484 Supporting Info

Fluorescence Resonance Energy Transfer in a Novel Two-Photon Absorbing System Darryl W. Brousmiche, Jason M. Serin, Jean M. J. Fréchet, Guang S. He, Tzu-Chau Lin, Sung Jae Chung, and Paras N. Prasad pp 1448–1449 DOI: 10.1021/ja0288688 Supporting Info

Converting the Sacrificial DNA Repair Protein N-Ada into a Catalytic Methyl Phosphotriester Repair Enzyme Chuan He, Hua Wei, and Gregory L. Verdine pp 1450–1451 DOI: 10.1021/ja028046a Supporting Info

The First Structurally Characterized Aluminum Compound with Two SH Groups:  [LAl(SH)2] (L = N(Ar)C(Me)CHC(Me)N(Ar), Ar = 2,6-i-Pr2C6H3) and the Catalytic Properties of the Sulfur P(NMe2)3 System Vojtech Jancik, Ying Peng, Herbert W. Roesky, Jiyang Li, Dante Neculai, Ana M. Neculai, and Regine Herbst-Irmer pp 1452–1453 DOI: 10.1021/ja028801k Supporting Info

A Neutral Xenon-Containing Radical, HXeO Leonid Khriachtchev, Mika Pettersson, Jan Lundell, Hanna Tanskanen, Tiina Kiviniemi, Nino Runeberg, and Markku Räsänen pp 1454–1455 DOI: 10.1021/ja029024r

Wavelength-Dependent Photochemistry of Diazo Meldrum's Acid and Its Spirocyclic Isomer, Diazirino Meldrum's Acid:  Wolff Rearrangement versus Isomerization Aneta Bogdanova and Vladimir V. Popik pp 1456–1457 DOI: 10.1021/ja029528p Supporting Info

Enantioselective Total Synthesis of Borrelidin Matthew O. Duffey, Arnaud LeTiran, and James P. Morken pp 1458–1459 DOI: 10.1021/ja028941u Supporting Info

N,N‘-Dimethyl-N,N‘-diarylurea Anion Radicals:  An Intramolecular Reductive Elimination Todd L. Kurth, Frederick D. Lewis, Chris M. Hattan, Richard C. Reiter, and Cheryl D. Stevenson pp 1460–1461 DOI: 10.1021/ja0291890

A New Valence Tautomerism Example in an Electroactive Ferrocene Substituted Triphenylmethyl Radical Imma Ratera, Daniel Ruiz-Molina, Franz Renz, Jürgen Ensling, Klaus Wurst, Concepció Rovira, Philipp Gütlich, and Jaume Veciana pp 1462–1463 DOI: 10.1021/ja0282590 Supporting Info

Correlation between Hydrogen Bond Lengths and Reduction Potentials in Clostridium pasteurianum Rubredoxin I-Jin Lin, Erika B. Gebel, Timothy E. Machonkin, William M. Westler, and John L. Markley pp 1464–1465 DOI: 10.1021/ja028710n

Modeling a Central Ligand in the Nitrogenase FeMo Cofactor Berit Hinnemann and Jens K. Nørskov pp 1466–1467 DOI: 10.1021/ja029041g Supporting Info

A Fluorescent Sensor with High Selectivity and Sensitivity for Potassium in Water Huarui He, Mark A. Mortellaro, Marc J. P. Leiner, Robert J. Fraatz, and James K. Tusa pp 1468–1469 DOI: 10.1021/ja0284761 Supporting Info

[2,6-Mes2C6H3]2Ga+Li[Al{OCH(CF3)2}4]2- (Mes = 2,4,6-Me3C6H2):  A Compound Containing a Linear Unsolvated Two-Coordinate Gallium Cation Rudolf J. Wehmschulte, Jared M. Steele, Jackie D. Young, and Masood A. Khan pp 1470–1471 DOI: 10.1021/ja029142e Supporting Info

Enzymes Do What Is Expected (Chalcone Isomerase versus Chorismate Mutase) Sun Hur and Thomas C. Bruice pp 1472–1473 DOI: 10.1021/ja0293047 Supporting Info

The Development of a Catalytic Synthesis of Münchnones:  A Simple Four-Component Coupling Approach to α-Amino Acid Derivatives Rajiv Dhawan, Rania D. Dghaym, and Bruce A. Arndtsen pp 1474–1475 DOI: 10.1021/ja027474d Supporting Info

Direct Coupling of Benzene with Olefin Catalyzed by Pd(OAc)2 Combined with Heteropolyoxometalate under Dioxygen Takahiro Yokota, Masayuki Tani, Satoshi Sakaguchi, and Yasutaka Ishii pp 1476–1477 DOI: 10.1021/ja028903a

Coupling of Internal Alkynes in TpMe2Ir Derivatives:  Selective Oxidation of a Noncoordinated Double Bond of the Resulting Iridacycloheptatrienes Eleuterio Álvarez, Margarita Gómez, Margarita Paneque, Cristina M. Posadas, Manuel L. Poveda, Nuria Rendón, Laura L. Santos, Susana Rojas-Lima, Verónica Salazar, Kurt Mereiter, and Caridad Ruiz pp 1478–1479 DOI: 10.1021/ja0290375 Supporting Info

The Addition Polymerization of a PC Bond:  A Route to New Phosphine Polymers Chi-Wing Tsang, Mandy Yam, and Derek P. Gates pp 1480–1481 DOI: 10.1021/ja029120s Supporting Info

Synthesis and Aldol Reactivity of O- and C-Enolate Complexes of Nickel Juan Cámpora, Celia M. Maya, Pilar Palma, Ernesto Carmona, Enrique Gutiérrez-Puebla, and Caridad Ruiz pp 1482–1483 DOI: 10.1021/ja028711f Supporting Info

Oxidative Heck-Type Reaction Involving Cleavage of a Carbon−Phosphorus Bond of Arylphosphonic Acids Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima pp 1484–1485 DOI: 10.1021/ja026758v Supporting Info

Highly Conducting Crystals Based on Single-Component Gold Complexes with Extended-TTF Dithiolate Ligands Wakako Suzuki, Emiko Fujiwara, Akiko Kobayashi, Yuichi Fujishiro, Eiji Nishibori, Masaki Takata, Makoto Sakata, Hideki Fujiwara, and Hayao Kobayashi pp 1486–1487 DOI: 10.1021/ja0292243 Supporting Info

Characterization of 1H−1H Distances in a Uniformly 2H,15N-Labeled SH3 Domain by MAS Solid-State NMR Spectroscopy§ Bernd Reif, Barth J. van Rossum, Federica Castellani, Kristina Rehbein, Anne Diehl, and Hartmut Oschkinat pp 1488–1489 DOI: 10.1021/ja0283697 Supporting Info

Ab Initio Evidence for Slow Fragmentation in RAFT Polymerization Michelle L. Coote and Leo Radom pp 1490–1491 DOI: 10.1021/ja028645h Supporting Info

A New Reaction Manifold for the Barton Radical Intermediates:  Synthesis of N-Heterocyclic Furanosides and Pyranosides via the Formation of the C1−C2 Bond Jong Uk Rhee, Brian I. Bliss, and T. V. RajanBabu pp 1492–1493 DOI: 10.1021/ja028617z Supporting Info

A Simple Method to Synthesize Dy(OH)3 and Dy2O3 Nanotubes An-Wu Xu, Yue-Ping Fang, Li-Ping You, and Han-Qin Liu pp 1494–1495 DOI: 10.1021/ja029181q Supporting Info

On the α → β Transition of Carbon-Coated Highly Oriented PVDF Ultrathin Film Induced by Melt Recrystallization Jijun Wang, Huihui Li, Jichun Liu, Yongxin Duan, Shidong Jiang, and Shouke Yan pp 1496–1497 DOI: 10.1021/ja029352r Supporting Info

Total Synthesis of Ingenol Keiji Tanino, Kei Onuki, Kohei Asano, Masaaki Miyashita, Tsuyoshi Nakamura, Yoshinori Takahashi, and Isao Kuwajima pp 1498–1500 DOI: 10.1021/ja029226n Supporting Info

Designing Protein Dimerizers:  The Importance of Ligand Conformational Equilibria Jonathan C. T. Carlson, Aaron Kanter, Guruvasuthevan R. Thuduppathy, Vivian Cody, Pamela E. Pineda, R. Scott McIvor, and Carston R. Wagner pp 1501–1507 DOI: 10.1021/ja026264y Supporting Info

Synthesis and NMR Structure of P41icf, a Potent Inhibitor of Human Cathepsin L Cristina Chiva, Philippe Barthe, Anna Codina, Margarida Gairí, Franck Molina, Claude Granier, Martine Pugnière, Tatsuya Inui, Hideki Nishio, Yuji Nishiuchi, Terutoshi Kimura, Shumpei Sakakibara, Fernando Albericio, and Ernest Giralt pp 1508–1517 DOI: 10.1021/ja0207908 Supporting Info

Improving the Accuracy of NMR Structures of RNA by Means of Conformational Database Potentials of Mean Force as Assessed by Complete Dipolar Coupling Cross-Validation G. Marius Clore and John Kuszewski pp 1518–1525 DOI: 10.1021/ja028383j

Efficient C2‘α-Hydroxylation of Deoxyribose in Protein-Induced Z-Form DNA Takanori Oyoshi, Kiyohiko Kawai, and Hiroshi Sugiyama pp 1526–1531 DOI: 10.1021/ja028388g

Combined QM/MM Study of the Mechanism and Kinetic Isotope Effect of the Nucleophilic Substitution Reaction in Haloalkane Dehalogenase Lakshmi S. Devi-Kesavan and Jiali Gao pp 1532–1540 DOI: 10.1021/ja026955u

Self-Assembly Mechanism of a Bimetallic Europium Triple-Stranded Helicate Josef Hamacek, Sylvie Blanc, Mourad Elhabiri, Emmanuelle Leize, Alain Van Dorsselaer, Claude Piguet, and Anne-Marie Albrecht-Gary pp 1541–1550 DOI: 10.1021/ja028861q Supporting Info

Transfection Mediated by Gemini Surfactants:  Engineered Escape from the Endosomal Compartment Paul C. Bell, Mark Bergsma, Igor P. Dolbnya, Wim Bras, Marc C. A. Stuart, Alan E. Rowan, Martinus C. Feiters, and Jan B. F. N. Engberts pp 1551–1558 DOI: 10.1021/ja020707g

La3+-Catalyzed Methanolysis of Hydroxypropyl-p-nitrophenyl Phosphate as a Model for the RNA Transesterification Reaction Josephine S. W. Tsang, Alexei A. Neverov, and R. S. Brown pp 1559–1566 DOI: 10.1021/ja021176z Supporting Info

Concise Total Syntheses of the Bioactive Mesotricyclic Diterpenoids Jatrophatrione and Citlalitrione Jiong Yang, Yun Oliver Long, and Leo A. Paquette pp 1567–1574 DOI: 10.1021/ja021177r Supporting Info

High-Throughput Catch-and-Release Synthesis of Oxazoline Hydroxamates. Structure−Activity Relationships in Novel Inhibitors of Escherichia coli LpxC:  In Vitro Enzyme Inhibition and Antibacterial Properties Michael C. Pirrung, L. Nathan Tumey, Amanda L. McClerren, and Christian R. H. Raetz pp 1575–1586 DOI: 10.1021/ja0209114 Supporting Info

Intramolecular Pd-Mediated Processes of Amino-Tethered Aryl Halides and Ketones:  Insight into the Ketone α-Arylation and Carbonyl-Addition Dichotomy. A New Class of Four-Membered Azapalladacycles Daniel Solé, Lluís Vallverdú, Xavier Solans, Mercè Font-Bardía, and Josep Bonjoch pp 1587–1594 DOI: 10.1021/ja029114w Supporting Info

Dimethyl- and Bis[(trimethylsilyl)methyl]cuprates Show Aggregates Higher than Dimers in Diethyl Ether:  Molecular Diffusion Studies by PFG NMR and Aggregation−Reactivity Correlations Xiulan Xie, Carsten Auel, Wolfram Henze, and Ruth M. Gschwind pp 1595–1601 DOI: 10.1021/ja026311m Supporting Info

Determination of Critical Micelle Concentration by Hyper-Rayleigh Scattering Suhrit Ghosh, Anu Krishnan, Puspendu K. Das, and S. Ramakrishnan pp 1602–1606 DOI: 10.1021/ja029070r Supporting Info

Trends in Metal−Biradical Exchange Interaction for First-Row MII(Nitronyl Nitroxide-Semiquinone) Complexes David A. Shultz, Kira E. Vostrikova, Scot H. Bodnar, Hyun-Joo Koo, Myung-Hwan Whangbo, Martin L. Kirk, Ezra C. Depperman, and Jeff W. Kampf pp 1607–1617 DOI: 10.1021/ja020715x Supporting Info

Structure and Dynamics of Metal Ions in Solution:  QM/MM Molecular Dynamics Simulations of Mn2+ and V2+ Christian F. Schwenk, Hannes H. Loeffler, and Bernd M. Rode pp 1618–1624 DOI: 10.1021/ja0286831

Shattering of Peptide Ions on Self-Assembled Monolayer Surfaces Julia Laskin, Thomas H. Bailey, and Jean H. Futrell pp 1625–1632 DOI: 10.1021/ja027915t

The Synthesis, Characterization, and Structure Solution of SSZ-58:  A Novel Two-Dimensional 10-Ring Pore Zeolite with Previously Unseen Double 5-Ring Subunits Allen Burton, Saleh Elomari, Ronald C. Medrud, Ignatius Y. Chan, Cong-Yan Chen, Lucy M. Bull, and E. Steven Vittoratos pp 1633–1642 DOI: 10.1021/ja021242x Supporting Info

What Controls the Melting Properties of DNA-Linked Gold Nanoparticle Assemblies? Rongchao Jin, Guosheng Wu, Zhi Li, Chad A. Mirkin, and George C. Schatz pp 1643–1654 DOI: 10.1021/ja021096v Supporting Info

Chiral Pair Monolayer Adsorption of Iodine-Substituted Octadecanol Molecules on Graphite Yuguang Cai and Steven L. Bernasek pp 1655–1659 DOI: 10.1021/ja0285619

Metal Germylyne Complexes [MGe−R] and Metallogermylenes [M−Ge−R]:  DFT Analysis of the Systems [(Cp)(CO)nMGeMe] (M = Cr, Mo, W, Fe2+, n = 2; M = Fe, n = 1) and [(Cp)(CO)nM−GeMe] (M = Cr, Mo, W, n = 3; M = Fe, n = 2) Krishna K. Pandey, Matthias Lein, and Gernot Frenking pp 1660–1668 DOI: 10.1021/ja020974m Supporting Info

Synthesis of Poly(6-azulenylethynyl)benzene Derivatives as a Multielectron Redox System with Liquid Crystalline Behavior Shunji Ito, Haruki Inabe, Noboru Morita, Kazuchika Ohta, Teruo Kitamura, and Kimiaki Imafuku pp 1669–1680 DOI: 10.1021/ja0209262

Issue 07

Uniaxial Alignment of the Columnar Super-Structure of a Hexa (Alkyl) Hexa-peri-hexabenzocoronene on Untreated Glass by Simple Solution Processing Adam Tracz, Jeremiasz K. Jeszka, Mark D. Watson, Wojciech Pisula, Klaus Müllen, and Tadeusz Pakula pp 1682–1683 DOI: 10.1021/ja028945z

Activity of Candida rugosa Lipase Immobilized on γ-Fe2O3 Magnetic Nanoparticles Ansil Dyal, Katja Loos, Mayumi Noto, Seung W. Chang, Chiara Spagnoli, Kurikka V. P. M. Shafi, Abraham Ulman, Mary Cowman, and Richard A. Gross pp 1684–1685 DOI: 10.1021/ja021223n

Nanoscale Soldering of Metal Nanoparticles for Construction of Higher-Order Structures Fumitaka Mafuné, Jun-ya Kohno, Yoshihiro Takeda, and Tamotsu Kondow pp 1686–1687 DOI: 10.1021/ja021250d

A Planar Tetracoordinate Carbon and Unusual Bonding in an Organodimetallic Propynylidene Complex Arising from Double C−H Activation of an Allene Ligand Jui-Hsien Huang, Jeffrey J. Luci, Ting-Yu Lee, Dale C. Swenson, Jan H. Jensen, and Louis Messerle pp 1688–1689 DOI: 10.1021/ja020369j Supporting Info

Determination of the Enantiomeric Composition of Guest Molecules by Chemometric Analysis of the UV−Visible Spectra of Cyclodextrin Guest−Host Complexes Kenneth W. Busch, Isabel Maya Swamidoss, Sayo O. Fakayode, and Marianna A. Busch pp 1690–1691 DOI: 10.1021/ja025947a Supporting Info

Catalytic Enantioselective Addition of Dialkylzinc to N-Diphenylphosphinoylimines. A Practical Synthesis of α-Chiral Amines Alessandro A. Boezio and André B. Charette pp 1692–1693 DOI: 10.1021/ja027673x Supporting Info

Synthesis and Characterization of the Monomeric Imides Ar‘MNAr‘ ‘ (M = Ga or In; Ar‘ or Ar‘ ‘ = Terphenyl Ligands) with Two-Coordinate Gallium and Indium Robert J. Wright, Andrew D. Phillips, Thomas L. Allen, William H. Fink, and Philip P. Power pp 1694–1695 DOI: 10.1021/ja029422u Supporting Info

Palladium(0)-Catalyzed Amination, Stille Coupling, and Suzuki Coupling of Electron-Deficient Aryl Fluorides Young Mi Kim and Shu Yu pp 1696–1697 DOI: 10.1021/ja028966t Supporting Info

A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Arylboronates:  A New Method for the Arylation of Aromatic Compounds via C−H Bond Cleavage Fumitoshi Kakiuchi, Shintaro Kan, Kimitaka Igi, Naoto Chatani, and Shinji Murai pp 1698–1699 DOI: 10.1021/ja029273f Supporting Info

Facile Synthesis of 2,5-Diarylthiazoles via Palladium-Catalyzed Tandem C−H Substitutions. Design of Tunable Light Emission and Liquid Crystalline Characteristics Atsunori Mori, Akitoshi Sekiguchi, Kentaro Masui, Tomohiro Shimada, Masaki Horie, Kohtaro Osakada, Masuki Kawamoto, and Tomiki Ikeda pp 1700–1701 DOI: 10.1021/ja0289189 Supporting Info

A Method for the Generation of Glycoprotein Mimetics Haitian Liu, Lei Wang, Ansgar Brock, Chi-Huey Wong, and Peter G. Schultz pp 1702–1703 DOI: 10.1021/ja029433n Supporting Info

Tetrathiomolybdate Causes Formation of Hepatic Copper−Molybdenum Clusters in an Animal Model of Wilson's Disease Graham N. George, Ingrid J. Pickering, Hugh H. Harris, Jürgen Gailer, Dominik Klein, Josef Lichtmannegger, and Karl-Heinz Summer pp 1704–1705 DOI: 10.1021/ja029054u Supporting Info

Isotope Effects on the Picosecond Time-Resolved Emission Spectroscopy of Tris(2,2‘-bipyridine)ruthenium (II) Wesley R. Browne, Colin G. Coates, Clare Brady, Pavel Matousek, Michael Towrie, Stanley W. Botchway, Anthony W. Parker, Johannes G. Vos, and John J. McGarvey pp 1706–1707 DOI: 10.1021/ja0289346 Supporting Info

Bis(((S)-binaphthoxy)(isopropoxy)titanium) Oxide as a μ-Oxo-Type Chiral Lewis Acid:  Application to Catalytic Asymmetric Allylation of Aldehydes Hideo Hanawa, Takuya Hashimoto, and Keiji Maruoka pp 1708–1709 DOI: 10.1021/ja020338o Supporting Info

Direct Observation of Insertion Events at rac-(C2H4(1-indenyl)2)Zr(MeB(C6F5)3)−Polymeryl Intermediates:  Distinction between Continuous and Intermittent Propagation Modes Clark R. Landis, Kimberly A. Rosaaen, and Douglass R. Sillars pp 1710–1711 DOI: 10.1021/ja028070o Supporting Info

Total Synthesis of (+)-Phomactin A Using a B-Alkyl Suzuki Macrocyclization Peter J. Mohr and Randall L. Halcomb pp 1712–1713 DOI: 10.1021/ja0296531 Supporting Info

Theoretical Study of Halophilic Reactions of Stable Silylenes with Chloro- and Bromocarbons Ming-Der Su pp 1714–1715 DOI: 10.1021/ja0210751 Supporting Info

Microscopic Hydration of the Sodium Chloride Ion Pair Asao Mizoguchi, Yasuhiro Ohshima, and Yasuki Endo pp 1716–1717 DOI: 10.1021/ja028522x Supporting Info

Δ-[Ru(acac)2L] (L = a Mesogenic Derivative of bpy) as a Novel Chiral Dopant for Nematic Liquid Crystals with Large Helical Twisting Power Naomi Hoshino, Yuki Matsuoka, Kentaro Okamoto, and Akihiko Yamagishi pp 1718–1719 DOI: 10.1021/ja0293960

“The Great Escape” from Antiaromaticity:  Reduction of Strained Pyrenes Ivan Aprahamian, Graham J. Bodwell, James J. Fleming, Gregory P. Manning, Michael R. Mannion, Tuvia Sheradsky, Rudolf J. Vermeij, and Mordecai Rabinovitz pp 1720–1721 DOI: 10.1021/ja0291991 Supporting Info

Potentials of Mean Force between Ionizable Amino Acid Side Chains in Water Artëm Masunov and Themis Lazaridis pp 1722–1730 DOI: 10.1021/ja025521w

HADDOCK:  A Protein−Protein Docking Approach Based on Biochemical or Biophysical Information Cyril Dominguez, Rolf Boelens, and Alexandre M. J. J. Bonvin pp 1731–1737 DOI: 10.1021/ja026939x Supporting Info

Spectroscopic Characterization and Assignment of Reduction Potentials in the Tetraheme Cytochrome c554 from Nitrosomonas Europaea Anup K. Upadhyay, Doros T. Petasis, Dave M. Arciero, Alan B. Hooper, and Michael P. Hendrich pp 1738–1747 DOI: 10.1021/ja020922x

Side Chain Dynamics in Unfolded Protein States:  an NMR Based 2H Spin Relaxation Study of Δ131Δ Wing-Yiu Choy, David Shortle, and Lewis E. Kay pp 1748–1758 DOI: 10.1021/ja021179b Supporting Info

Molecular Dynamics Simulations and Thermodynamics Analysis of DNA−Drug Complexes. Minor Groove Binding between 4‘,6-Diamidino-2-phenylindole and DNA Duplexes in Solution Nad'a Špaková, Thomas E. Cheatham, III, Filip Ryjáek, Filip Lankaš, Luc van Meervelt, Pavel Hobza, and Jiří Šponer pp 1759–1769 DOI: 10.1021/ja025660d Supporting Info

Controlled Assembly of Carbon Nanotubes by Designed Amphiphilic Peptide Helices Gregg R. Dieckmann, Alan B. Dalton, Paul A. Johnson, Joselito Razal, Jian Chen, Geoff M. Giordano, Edgar Muñoz, Inga H. Musselman, Ray H. Baughman, and Rockford K. Draper pp 1770–1777 DOI: 10.1021/ja029084x

ZP4, an Improved Neuronal Zn2+ Sensor of the Zinpyr Family Shawn C. Burdette, Christopher J. Frederickson, Weiming Bu, and Stephen J. Lippard pp 1778–1787 DOI: 10.1021/ja0287377 Supporting Info

Preparation and Characterization of Polypseudorotaxanes Based on Block-Selected Inclusion Complexation between Poly(propylene oxide)-Poly(ethylene oxide)-Poly(propylene oxide) Triblock Copolymers and α-Cyclodextrin Jun Li, Xiping Ni, Zhihan Zhou, and Kam W. Leong pp 1788–1795 DOI: 10.1021/ja026623p Supporting Info

Isolating Benzenium Ion Salts Christopher A. Reed, Kee-Chan Kim, Evgenii S. Stoyanov, Daniel Stasko, Fook S. Tham, Leonard J. Mueller, and Peter D. W. Boyd pp 1796–1804 DOI: 10.1021/ja027336o Supporting Info

Layer-by-Layer Self-Assembled Chitosan/Poly(thiophene-3-acetic acid) and Organophosphorus Hydrolase Multilayers Celeste A. Constantine, Sarita V. Mello, Annie Dupont, Xihui Cao, David Santos, Jr., Osvaldo N. Oliveira, Jr., Francisco T. Strixino, Ernesto C. Pereira, Tu-Chen Cheng, Joseph J. Defrank, and Roger M. Leblanc pp 1805–1809 DOI: 10.1021/ja028691h

Electronic Degeneracies in Symmetric (Jahn−Teller) and Nonsymmetric Aliphatic Radical Cations:  Global Topology of σ-Bonded Molecules Shmuel Zilberg and Yehuda Haas pp 1810–1820 DOI: 10.1021/ja028820u

A New Horner−Wadsworth−Emmons Type Coupling Reaction between Nonstabilized β-Hydroxy Phosphonates and Aldehydes or Ketones John F. Reichwein and Brian L. Pagenkopf pp 1821–1824 DOI: 10.1021/ja027658s Supporting Info

Kemp Elimination in Membrane Mimetic Reaction Media:  Probing Catalytic Properties of Catanionic Vesicles Formed from Double-Tailed Amphiphiles Jaap E. Klijn and Jan B. F. N. Engberts pp 1825–1833 DOI: 10.1021/ja027772a

Group 6 Heteroatom- and Non-Heteroatom-Stabilized Carbene Complexes. β,β‘- and α,β,β‘-Annulation Reactions of Cyclic Enamines José Barluenga, Alfredo Ballesteros, Ramón Bernardo de la Rúa, Javier Santamaría, Eduardo Rubio, and Miguel Tomás pp 1834–1842 DOI: 10.1021/ja0278077 Supporting Info

Total Synthesis of (+)-4,5-Deoxyneodolabelline David R. Williams and Richard W. Heidebrecht, Jr. pp 1843–1850 DOI: 10.1021/ja0279803 Supporting Info

Proton Inventory Study of the Base-Catalyzed Hydrolysis of Formamide. Consideration of the Nucleophilic and General Base Mechanisms H. Ślebocka-Tilk, Alexei A. Neverov, and R. S. Brown pp 1851–1858 DOI: 10.1021/ja021055z

Ordered Polyelectrolyte Multilayers. Rules Governing Layering in Organic Binary Multilayers Xavier Arys, Peter Fischer, Alain M. Jonas, Marc M. Koetse, André Laschewsky, Roger Legras, and Erik Wischerhoff pp 1859–1865 DOI: 10.1021/ja0283807

Proton-Coupled O−O Activation on a Redox Platform Bearing a Hydrogen-Bonding Scaffold Christopher J. Chang, Leng Leng Chng, and Daniel G. Nocera pp 1866–1876 DOI: 10.1021/ja028548o

Total Synthesis of the Ramoplanin A2 and Ramoplanose Aglycon Wanlong Jiang, Jutta Wanner, Richard J. Lee, Pierre-Yves Bounaud, and Dale L. Boger pp 1877–1887 DOI: 10.1021/ja0212314 Supporting Info

Conformational Effects on Optical Rotation. 3-Substituted 1-Butenes Kenneth B. Wiberg, Patrick H. Vaccaro, and James R. Cheeseman pp 1888–1896 DOI: 10.1021/ja0211914 Supporting Info

Synthesis, Structure, and Magnetic Properties of the Fullerene-Based Ferromagnets Eu3C70 and Eu9C70 Taishi Takenobu, Dam H. Chi, Serena Margadonna, Kosmas Prassides, Yoshihiro Kubozono, Andrew N. Fitch, Ken-ichi Kato, and Yoshihiro Iwasa pp 1897–1904 DOI: 10.1021/ja0288690

Identification of Active Sites in Gold-Catalyzed Hydrogenation of Acrolein Christian Mohr, Herbert Hofmeister, Jörg Radnik, and Peter Claus pp 1905–1911 DOI: 10.1021/ja027321q

MIL-50, an Open-Framework GaPO with a Periodic Pattern of Small Water Ponds and Dry Rubidium Atoms:  a Combined XRD, NMR, and Computational Study Lionel Beitone, Jérôme Marrot, Thierry Loiseau, Gérard Férey, Marc Henry, Clarisse Huguenard, Axel Gansmuller, and Francis Taulelle pp 1912–1922 DOI: 10.1021/ja029072b Supporting Info

Density Functional and Reduction Potential Calculations of Fe4S4 Clusters Rhonda A. Torres, Timothy Lovell, Louis Noodleman, and David A. Case pp 1923–1936 DOI: 10.1021/ja0211104

Investigation of Zr−C, Zr−N, and Potential Agostic Interactions in an Organozirconium Complex by Experimental Electron Density Analysis Sebastien Pillet, Guang Wu, Vichien Kulsomphob, Benjamin G. Harvey, Richard D. Ernst, and Philip Coppens pp 1937–1949 DOI: 10.1021/ja021133i Supporting Info

Molecular Dynamics Simulations of End-to-End Contact Formation in Hydrocarbon Chains in Water and Aqueous Urea Solution Raymond D. Mountain and D. Thirumalai pp 1950–1957 DOI: 10.1021/ja020496f

General Rules for Predicting Where a Catalytic Reaction Should Occur on Metal Surfaces:  A Density Functional Theory Study of C−H and C−O Bond Breaking/Making on Flat, Stepped, and Kinked Metal Surfaces Zhi-Pan Liu and P. Hu pp 1958–1967 DOI: 10.1021/ja0207551

Ab Initio Molecular Orbital Study on the G-Selectivity of GGG Triplet in Copper(I)-Mediated One-Electron Oxidation Yasunori Yoshioka, Hiroko Kawai, Tomoko Sato, Kizashi Yamaguchi, and Isao Saito pp 1968–1974 DOI: 10.1021/ja028039m

Enantiomeric Excesses and Electronic Chirality Measure Luca Bellarosa and Francesco Zerbetto pp 1975–1979 DOI: 10.1021/ja028646+

Probing the Dynamic Guest−Host Interactions in Sol−Gel Films Using Single Molecule Spectroscopy C. Ricardo Viteri, James W. Gilliland, and Wai Tak Yip pp 1980–1987 DOI: 10.1021/ja026533k

Physical and Kinetic Analysis of the Cooperative Role of Metal Ions in Catalysis of Phosphodiester Cleavage by a Dinuclear Zn(II) Complex Olga Iranzo, Andrey Y. Kovalevsky, Janet R. Morrow, and John P. Richard pp 1988–1993 DOI: 10.1021/ja027728v Supporting Info

Experimental Study of the Heterogeneous Interaction of SO3 and H2O:  Formation of Condensed Phase Molecular Sulfuric Acid Hydrates Suzanne B. Couling, K. Jessica Sully, and Andrew B. Horn pp 1994–2003 DOI: 10.1021/ja0210704

Heterogeneous Electron-Transfer Kinetics for Ruthenium and Ferrocene Redox Moieties through Alkanethiol Monolayers on Gold John F. Smalley, Harry O. Finklea, Christopher E. D. Chidsey, Matthew R. Linford, Stephen E. Creager, John P. Ferraris, Keli Chalfant, Thomas Zawodzinsk, Stephen W. Feldberg, and Marshall D. Newton pp 2004–2013 DOI: 10.1021/ja028458j

Topospecific Self-Assembly of Mixed-Metal Molecular Hexagons with Diameters of 5.5 nm Using Chiral Control [J. Am. Chem. Soc. 2000, 122, 11527−11528]. Md. Messer Ali and Frederick M. MacDonnell p 2014 DOI: 10.1021/ja025123t

Membraneless Vanadium Redox Fuel Cell Using Laminar Flow   [J. Am. Chem. Soc. 2002, 124, 12930−12931]. Rosaria Ferrigno, Abraham D. Stroock, Thomas D. Clark, Michael Mayer and George M. Whitesides p 2014 DOI: 10.1021/ja025124l

Enantioselective Total Synthesis of (−)-Strychnine Using the Catalytic Asymmetric Michael Reaction and Tandem Cyclization [J. Am. Chem. Soc. 2002, 124, 14546−14547].  Takashi Ohshima, Youjun Xu, Ryo Takita, Satoshi Shimizu, Dafang Zhong, and Masakatsu Shibasaki p 2014 DOI: 10.1021/ja034038y

Issue 08

A [2]Catenane Constructed around a Ru(Diimine)32+ Complex Used as a Template Pierre Mobian, Jean-Marc Kern, and Jean-Pierre Sauvage pp 2016–2017 DOI: 10.1021/ja0209215 Supporting Info

Cryogenic CO Oxidation on TiO2-Supported Gold Nanoclusters Precovered with Atomic Oxygen Tae S. Kim, James D. Stiehl, Christopher T. Reeves, Randall J. Meyer, and C. Buddie Mullins pp 2018–2019 DOI: 10.1021/ja028719p

Benzylation of Aromatic Compounds with Different Crystallites of MgO Boyapati M. Choudary, Ravichandra S. Mulukutla, and Kenneth J. Klabunde pp 2020–2021 DOI: 10.1021/ja0211757 Supporting Info

{Tl[Au(C6Cl5)2]}n:  A Vapochromic Complex Eduardo J. Fernández, José M. López-de-Luzuriaga, Miguel Monge, M. Elena Olmos, Javier Pérez, Antonio Laguna, Ahmed A. Mohamed, and John P. Fackler, Jr. pp 2022–2023 DOI: 10.1021/ja028734u Supporting Info

Binding and Activation of Aromatic Molecules by a Molybdenum π-Base Scott H. Meiere, Joseph M. Keane, T. Brent Gunnoe, Michal Sabat, and W. Dean Harman pp 2024–2025 DOI: 10.1021/ja021057j Supporting Info

A Highly Reduced V23+ Unit with a Metal−Metal Bond Order of 3.5 F. Albert Cotton, Elizabeth A. Hillard, and Carlos A. Murillo pp 2026–2027 DOI: 10.1021/ja029792i Supporting Info

Novel Iminium Ion Equivalents Prepared through C−H Oxidation for the Stereocontrolled Synthesis of Functionalized Propargylic Amine Derivatives James J. Fleming, Kristin Williams Fiori, and J. Du Bois pp 2028–2029 DOI: 10.1021/ja028916o Supporting Info

One-Electron Oxidation of the Guanine Moiety of 2‘-Deoxyguanosine:  Influence of 8-Oxo-7,8-dihydro-2‘-deoxyguanosine Jean-Luc Ravanat, Christine Saint-Pierre, and Jean Cadet pp 2030–2031 DOI: 10.1021/ja028608q Supporting Info

Thermodynamic Coupling of the Loop and Stem in Unusually Stable DNA Hairpins Closed by CG Base Pairs Ellen M. Moody and Philip C. Bevilacqua pp 2032–2033 DOI: 10.1021/ja029831q Supporting Info

Modulation of Substrate Binding to Naphthalene 1,2-Dioxygenase by Rieske Cluster Reduction/Oxidation Tran-Chin Yang, Matt D. Wolfe, Matthew B. Neibergall, Yasmina Mekmouche, John D. Lipscomb, and Brian M. Hoffman pp 2034–2035 DOI: 10.1021/ja028781m

Native Conformational Tendencies in Unfolded Polypeptides:  Development of a Novel Method To Assess Native Conformational Tendencies in the Reduced Forms of Multiple Disulfide-Bonded Proteins Mahesh Narayan, Ervin Welker, and Harold A. Scheraga pp 2036–2037 DOI: 10.1021/ja021252y

Synthesis of 1,2-Diheteroatom-Substituted Alkenes via Rhodium-Catalyzed Intramolecular Hydrogen Transfer M. Mar Diaz-Requejo, Darren DiSalvo, and Maurice Brookhart pp 2038–2039 DOI: 10.1021/ja029393n Supporting Info

Porphyrin Deposition Induced by UV Irradiation Luigi Monsù Scolaro, Andrea Romeo, Maria Angela Castriciano, Giovanna De Luca, Salvatore Patanè, and Norberto Micali pp 2040–2041 DOI: 10.1021/ja029134y Supporting Info

Thiyl Radicals Abstract Hydrogen Atoms from the αC−H Bonds in Model Peptides:  Absolute Rate Constants and Effect of Amino Acid Structure Thomas Nauser and Christian Schöneich pp 2042–2043 DOI: 10.1021/ja0293599

Shishijimicins A−C, Novel Enediyne Antitumor Antibiotics from the Ascidian Didemnum proliferum1 Naoya Oku, Shigeki Matsunaga, and Nobuhiro Fusetani pp 2044–2045 DOI: 10.1021/ja0296780 Supporting Info

Torsional Barriers for Planar versus Twisted Singlet Styrenes Frederick D. Lewis and Xiaobing Zuo pp 2046–2047 DOI: 10.1021/ja029430a Supporting Info

Self-Assembly of Spherical Colloids into Helical Chains with Well-Controlled Handedness Yadong Yin and Younan Xia pp 2048–2049 DOI: 10.1021/ja029408h

Single-Precursor, One-Pot Versatile Synthesis under near Ambient Conditions of Tunable, Single and Dual Band Fluorescing Metal Sulfide Nanoparticles Narayan Pradhan and Shlomo Efrima pp 2050–2051 DOI: 10.1021/ja028887h Supporting Info

Copper Ion-Induced Activation and Asymmetric Benzoylation of 1,2-Diols:  Kinetic Chiral Molecular Recognition Yoshihiro Matsumura, Toshihide Maki, Sachie Murakami, and Osamu Onomura pp 2052–2053 DOI: 10.1021/ja0289402 Supporting Info

Designer Chiral Quaternary Ammonium Bifluorides as an Efficient Catalyst for Asymmetric Nitroaldol Reaction of Silyl Nitronates with Aromatic Aldehydes Takashi Ooi, Kanae Doda, and Keiji Maruoka pp 2054–2055 DOI: 10.1021/ja029660p Supporting Info

Mechanism of the Palladium-Catalyzed Intramolecular Hydroalkylation of 7-Octene-2,4-dione Hua Qian and Ross A. Widenhoefer pp 2056–2057 DOI: 10.1021/ja0293002 Supporting Info

Asymmetric Organocatalysis of 4 + 3 Cycloaddition Reactions Michael Harmata, Sunil K. Ghosh, Xuechuan Hong, Sumrit Wacharasindhu, and Patrick Kirchhoefer pp 2058–2059 DOI: 10.1021/ja029058z Supporting Info

Direct Test of the Gaussian-Chain Model for Treating Residual Charge−Charge Interactions in the Unfolded State of Proteins Huan-Xiang Zhou pp 2060–2061 DOI: 10.1021/ja0298491

Functionalized Boron Nitride Nanotubes with a Stannic Oxide Coating:  A Novel Chemical Route to Full Coverage Wei-Qiang Han and Alex Zettl pp 2062–2063 DOI: 10.1021/ja0292501

Synthetic, Structural and Binding Studies of the 4,6-Dimethyldibenzothiophene Complex [(η5-C5Me5)Ru(CO)2(η1(S)-4,6-Me2DBT)]BF4:  Toward an Understanding of Deep Hydrodesulfurization Paul A. Vecchi, Arkady Ellern, and Robert J. Angelici pp 2064–2065 DOI: 10.1021/ja029230z Supporting Info

Synthesis of Stable Derivatives of C62:  The First Nonclassical Fullerene Incorporating a Four-Membered Ring Wenyuan Qian, Shih-Ching Chuang, Roberto B. Amador, Thibaut Jarrosson, Michael Sander, Susan Pieniazek, Saeed I. Khan, and Yves Rubin pp 2066–2067 DOI: 10.1021/ja029679s Supporting Info

Ring-Opening Reaction of Phosphorus-Bridged [1]Ferrocenophane via Ring Slippage from η5- to η1-Cp Tsutomu Mizuta, Yuki Imamura, and Katsuhiko Miyoshi pp 2068–2069 DOI: 10.1021/ja029297m Supporting Info

Unusual Coordination Modes of Arylthiolates in Mo{η5-SC6H3-2,6-(SiMe3)2}{η7-SC6H3-2,6-(SiMe3)2} Takashi Komuro, Tsukasa Matsuo, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 2070–2071 DOI: 10.1021/ja029541+ Supporting Info

Intercalation of Trioxatriangulenium Ion in DNA:  Binding, Electron Transfer, X-ray Crystallography, and Electronic Structure Jóhannes Reynisson Gary B. Schuster, Sheldon B. Howerton, Loren Dean Williams, Robert N. Barnett, Charles L. Cleveland, Uzi Landman, Niels Harrit, and Jonathan B. Chaires pp 2072–2083 DOI: 10.1021/ja0211196 Supporting Info

Design of Triple Helix Forming C-Glycoside Molecules Jian-Sen Li, Yun-Hua Fan, Yi Zhang, Luis A. Marky, and Barry Gold pp 2084–2093 DOI: 10.1021/ja028033x

Tandem Electrostatic Effect from the First to the Third Aglycon in the Trimeric RNA Owing to the Nearest-Neighbor Interaction P. Acharya, S. Acharya, A. Földesi, and J. Chattopadhyaya pp 2094–2100 DOI: 10.1021/ja028277h

Active-Site Structure and Electron-Transfer Reactivity of Plastocyanins Katsuko Sato, Takamitsu Kohzuma, and Christopher Dennison pp 2101–2112 DOI: 10.1021/ja021005u Supporting Info

Biomimetic Aryl Hydroxylation Derived from Alkyl Hydroperoxide at a Nonheme Iron Center. Evidence for an FeIVO Oxidant Michael P. Jensen, Steven J. Lange, Mark P. Mehn, Emily L. Que, and Lawrence Que, Jr. pp 2113–2128 DOI: 10.1021/ja028478l Supporting Info

Efficient Synthesis of NK1 Receptor Antagonist Aprepitant Using a Crystallization-Induced Diastereoselective Transformation Karel M. J. Brands, Joseph F. Payack, Jonathan D. Rosen, Todd D. Nelson, Alexander Candelario, Mark A. Huffman, Matthew M. Zhao, Jing Li, Bridgette Craig, Zhiguo J. Song, David M. Tschaen, Karl Hansen, Paul N. Devine, Philip J. Pye, Kai Rossen, Peter G. Dormer, Robert A. Reamer, Christopher J. Welch, David J. Mathre, Nancy N. Tsou, James M. McNamara, and Paul J. Reider pp 2129–2135 DOI: 10.1021/ja027458g Supporting Info

Stable Mechanistically-Relevant Aromatic-Based Carbenium Ions in Zeolite Catalysts Louis A. Clark, Marek Sierka, and Joachim Sauer pp 2136–2141 DOI: 10.1021/ja0283302 Supporting Info

Are the Enolates of Amides and Esters Stabilized by Electrostatics? Paul R. Rablen and Keith H. Bentrup pp 2142–2147 DOI: 10.1021/ja029102a Supporting Info

Thermochemistry of Arylselanyl Radicals and the Pertinent Ions in Acetonitrile Allan Hjarbæk Holm, Laura Yusta, Peter Carlqvist, Tore Brinck, and Kim Daasbjerg pp 2148–2157 DOI: 10.1021/ja0291787

Norbornyl Cations of Group 14 Elements Thomas Müller, Christian Bauch, Markus Ostermeier, Michael Bolte, and Norbert Auner pp 2158–2168 DOI: 10.1021/ja021234g Supporting Info

Direct Catalytic Asymmetric Aldol Reaction of Hydroxyketones:  Asymmetric Zn Catalysis with a Et2Zn/Linked-BINOL Complex Naoya Kumagai, Shigeki Matsunaga, Tomofumi Kinoshita, Shinji Harada, Shigemitsu Okada, Shigeru Sakamoto, Kentaro Yamaguchi, and Masakatsu Shibasaki pp 2169–2178 DOI: 10.1021/ja028926p Supporting Info

Group 4 Octahedral Benzamidinate Complexes:  Syntheses, Structures, and Catalytic Activities in the Polymerization of Propylene Modulated by Pressure Victoria Volkis, Elza Nelkenbaum, Anatoli Lisovskii, Gil Hasson, Rafi Semiat, Moshe Kapon, Mark Botoshansky, Yoav Eishen, and Moris S. Eisen pp 2179–2194 DOI: 10.1021/ja020575r Supporting Info

Zeolite-Confined Nano-RuO2:  A Green, Selective, and Efficient Catalyst for Aerobic Alcohol Oxidation Bi-Zeng Zhan, Mary Anne White, Tsun-Kong Sham, James A. Pincock, René J. Doucet, K. V. Ramana Rao, Katherine N. Robertson, and T. Stanley Cameron pp 2195–2199 DOI: 10.1021/ja0282691

Mechanically Linked Polycarbonate Charles-André Fustin, Christian Bailly, Guy J. Clarkson, Philippe De Groote, Trent H. Galow, David A. Leigh, Duncan Robertson, Alexandra M. Z. Slawin, and Jenny K. Y. Wong pp 2200–2207 DOI: 10.1021/ja0292546 Supporting Info

Understanding the Correlation of Structure and Selectivity in the Chiral-Phosphoramide-Catalyzed Enantioselective Allylation Reactions:  Solution and Solid-State Structural Studies of Bisphosphoramide·SnCl4 Complexes Scott E. Denmark and Jiping Fu pp 2208–2216 DOI: 10.1021/ja021280g Supporting Info

DNA−Dye Conjugates for Controllable H* Aggregation1 Hiroyuki Asanuma, Kenji Shirasuka, Tohru Takarada, Hiromu Kashida, and Makoto Komiyama pp 2217–2223 DOI: 10.1021/ja021153k Supporting Info

The Bis-Barium Complex of a Butterfly Crown Ether as a Phototunable Supramolecular Catalyst Roberta Cacciapaglia, Stefano Di Stefano, and Luigi Mandolini pp 2224–2227 DOI: 10.1021/ja029331x

Modeling Random Methyl Branching in Ethylene/ Propylene Copolymers Using Metathesis Chemistry:  Synthesis and Thermal Behavior John C. Sworen, Jason A. Smith, Kenneth B. Wagener, Lisa S. Baugh, and Steven P. Rucker pp 2228–2240 DOI: 10.1021/ja020862v

Cyclopentadienyl Substituent Effects on Reductive Elimination Reactions in Group 4 Metallocenes:  Kinetics, Mechanism, and Application to Dinitrogen Activation Jaime A. Pool, Emil Lobkovsky, and Paul J. Chirik pp 2241–2251 DOI: 10.1021/ja020960g Supporting Info

Induced Alignment of a Solution-Cast Discotic Hexabenzocoronene Derivative for Electronic Devices Investigated by Surface X-ray Diffraction Oliver Bunk, Martin M. Nielsen, Theis I. Sølling, Anick M. van de Craats, and Natalie Stutzmann pp 2252–2258 DOI: 10.1021/ja028509c

Barium Azacryptand Sodide, the First Alkalide with an Alkaline Earth Cation, Also Contains a Novel Dimer, (Na2)2- Mikhail Y. Redko, Rui H. Huang, James E. Jackson, James F. Harrison, and James L. Dye pp 2259–2263 DOI: 10.1021/ja027241m Supporting Info

Enhancement of the ETS-10 Titanosilicate Activity in the Shape-Selective Photocatalytic Degradation of Large Aromatic Molecules by Controlled Defect Production Francesc X. Llabrés i Xamena, Paola Calza, Carlo Lamberti, Carmelo Prestipino Alessandro Damin, Silvia Bordiga, Ezio Pelizzetti, and Adriano Zecchina pp 2264–2271 DOI: 10.1021/ja027382o

Reactivity of Substituted Charged Phenyl Radicals toward Components of Nucleic Acids Luis E. Ramírez-Arizmendi, Jenny L. Heidbrink, Leonard P. Guler, and Hilkka I. Kenttämaa pp 2272–2281 DOI: 10.1021/ja020632g

Electrochemical Infrared Characterization of CO Domains on Ruthenium-Decorated Platinum Nanoparticles Sungho Park, Andrzej Wieckowski, and Michael J. Weaver pp 2282–2290 DOI: 10.1021/ja028154x Supporting Info

Is the Ruthenium Analogue of Compound I of Cytochrome P450 an Efficient Oxidant? A Theoretical Investigation of the Methane Hydroxylation Reaction Pankaz K. Sharma, Sam P. de Visser, François Ogliaro, and Sason Shaik pp 2291–2300 DOI: 10.1021/ja0282487 Supporting Info

Bonding of Atomic Phosphorus to Polycyclic Hydrocarbons and Curved Graphitic Surfaces Santiago Melchor, Jose A. Dobado, J. Andreas Larsson, and James C. Greer pp 2301–2306 DOI: 10.1021/ja027520+

Mechanism of a Chemical Classic:  Quantum Chemical Investigation of the Autocatalyzed Reaction of the Serendipitous Wöhler Synthesis of Urea Constantinos A. Tsipis and Paraskevas A. Karipidis pp 2307–2318 DOI: 10.1021/ja020656n Supporting Info

Mechanism of Charging and Supercharging Molecules in Electrospray Ionization Anthony T. Iavarone and Evan R. Williams pp 2319–2327 DOI: 10.1021/ja021202t

Structural and Vibrational Study of the Tautomerism of Histamine Free-Base in Solution F. Javier Ramírez, Iñaki Tuñón, Juan A. Collado, and Estanislao Silla pp 2328–2340 DOI: 10.1021/ja027103x Supporting Info

Reaction Pathways of the Simmons−Smith Reaction Masaharu Nakamura, Atsushi Hirai, and Eiichi Nakamura pp 2341–2350 DOI: 10.1021/ja026709i Supporting Info

Impact of Multiple Cation−π Interactions upon Calix[4]arene Substrate Binding and Specificity Alba T. Macias, Joseph E. Norton, and Jeffrey D. Evanseck pp 2351–2360 DOI: 10.1021/ja0285971 Supporting Info

Memory Effects Based on Intermolecular Photoinduced Proton Transfer Françisco M. Raymo, Robert J. Alvarado, Silvia Giordani, and Mabel A. Cejas pp 2361–2364 DOI: 10.1021/ja027977j

Issue 09

Electrochemical Desorption of Self-Assembled Monolayers Noninvasively Releases Patterned Cells from Geometrical Confinements Xingyu Jiang, Rosaria Ferrigno, Milan Mrksich, and George M. Whitesides pp 2366–2367 DOI: 10.1021/ja029485c Supporting Info

A Copper-Catalyzed C−N Bond Formation Involving sp-Hybridized Carbons. A Direct Entry to Chiral Ynamides via N-Alkynylation of Amides Michael O. Frederick, Jason A. Mulder, Michael R. Tracey, Richard P. Hsung, Jian Huang, Kimberly C. M. Kurtz, Lichun Shen, and Christopher J. Douglas pp 2368–2369 DOI: 10.1021/ja021304j Supporting Info

Acyclic Stereoselective Boron Alkylation Reactions for the Asymmetric Synthesis of β-Substituted α-Amino Acid Derivatives Martin J. O'Donnell, Jeremy T. Cooper, and Mary M. Mader pp 2370–2371 DOI: 10.1021/ja0298794 Supporting Info

Hexameric Macroring of Gable-Porphyrins as a Light-Harvesting Antenna Mimic Ryoichi Takahashi and Yoshiaki Kobuke pp 2372–2373 DOI: 10.1021/ja028325y Supporting Info

Enantioselective Total Synthesis of (+)-Amphidinolide T1 Arun K. Ghosh and Chunfeng Liu pp 2374–2375 DOI: 10.1021/ja021385j Supporting Info

Aluminosilicate Nanoparticles for Catalytic Hydrocarbon Cracking Yu Liu and Thomas J. Pinnavaia pp 2376–2377 DOI: 10.1021/ja029336u

19F MAS NMR Quantification of Accessible Hydroxyl Sites on Fiberglass Surfaces Roderick A. Fry, Natia Tsomaia, Carlo G. Pantano, and Karl T. Mueller pp 2378–2379 DOI: 10.1021/ja0275717 Supporting Info

A Conformationally Preorganized Universal Solid Support for Efficient Oligonucleotide Synthesis Andrei P. Guzaev and Muthiah Manoharan pp 2380–2381 DOI: 10.1021/ja0284613 Supporting Info

Elimination of 13Cα Splitting in Protein NMR Spectra by Deconvolution with Maximum Entropy Reconstruction Nobuhisa Shimba, Alan S. Stern, Charles S. Craik, Jeffrey C. Hoch, and Volker Dötsch pp 2382–2383 DOI: 10.1021/ja027973e

Synthesis and Characterization of Monodispersed Core−Shell Spherical Colloids with Movable Cores Kaori Kamata, Yu Lu, and Younan Xia pp 2384–2385 DOI: 10.1021/ja0292849 Supporting Info

Formation of a Cyclobutylidene Ring:  Intramolecular [2 + 2] Cycloaddition of Allyl and Vinylidene CC Bonds under Mild Conditions Patricia Alvarez, Elena Lastra, José Gimeno, Mauro Bassetti, and Larry R. Falvello pp 2386–2387 DOI: 10.1021/ja027209s Supporting Info

The Electrodeposition of High-Density, Ordered Arrays of Bi1-xSbx Nanowires Amy L. Prieto, Marisol Martín-González, Jennifer Keyani, Ronald Gronsky, Timothy Sands, and Angelica M. Stacy pp 2388–2389 DOI: 10.1021/ja029394f

Restricting the Conformational Heterogeneity of RNA by Specific Incorporation of 8-Bromoguanosine David J. Proctor, Elzbieta Kierzek, Ryszard Kierzek, and Philip C. Bevilacqua pp 2390–2391 DOI: 10.1021/ja029176m Supporting Info

A New Structural Form of Tin in a Double O-Capped Cluster Vadapalli Chandrasekhar, Viswanathan Baskar, and Jagadese J. Vittal pp 2392–2393 DOI: 10.1021/ja0287478 Supporting Info

New Cyanometalate Building Units: Synthesis and Characterization of [Re(CN)7]3- and [Re(CN)8]3- Miriam V. Bennett and Jeffrey R. Long pp 2394–2395 DOI: 10.1021/ja029795v Supporting Info

Surface Polymerization by Ion-Assisted Deposition for Polythiophene Film Growth Sanja Tepavcevic, Yongsoo Choi, and Luke Hanley pp 2396–2397 DOI: 10.1021/ja029851s Supporting Info

Homonuclear Correlation Experiments of Half-Integer Quadrupolar Nuclei Using Multiple-Quantum Techniques Spinning at a P4 Magic Angle T. G. Ajithkumar and Arno P. M. Kentgens pp 2398–2399 DOI: 10.1021/ja0292647

The Total Synthesis of the Galbulimima Alkaloid GB 13 Lewis N. Mander and Matthew M. McLachlan pp 2400–2401 DOI: 10.1021/ja029725o Supporting Info

Productive Folding of Human Neutrophil α-Defensins in Vitro without the Pro-peptide Zhibin Wu, Robert Powell, and Wuyuan Lu pp 2402–2403 DOI: 10.1021/ja0294257 Supporting Info

A Thermally Stable and Sterically Unprotected Terminal Electrophilic Phosphinidene Complex of Cobalt and Its Conversion to an η1-Phosphirene Javier Sánchez-Nieves, Brian T. Sterenberg, Konstantin A. Udachin, and Arthur J. Carty pp 2404–2405 DOI: 10.1021/ja028303b Supporting Info

Tuning Reactivity and Chemoselectivity in Electron Transfer Initiated Cyclization Reactions:  Applications to Carbon−Carbon Bond Formation John R. Seiders, II, Lijun Wang, and Paul E. Floreancig pp 2406–2407 DOI: 10.1021/ja029139v Supporting Info

Solubilization of Carbon Nanotubes by Nafion toward the Preparation of Amperometric Biosensors Joseph Wang, Mustafa Musameh, and Yuehe Lin pp 2408–2409 DOI: 10.1021/ja028951v Supporting Info

Desymmetrization of Meso 1,3- and 1,4-Diols with a Dinuclear Zinc Asymmetric Catalyst Barry M. Trost and Takashi Mino pp 2410–2411 DOI: 10.1021/ja029708z Supporting Info

Remarkable 1,6-Acyclic Diastereoselection in the Coupling of a Novel Butadienyl Di-indium Compound with Aldehydes Weishi Miao, Wenshuo Lu, and Tak Hang Chan pp 2412–2413 DOI: 10.1021/ja0295467 Supporting Info

(η2-Alkyne)methyl(dioxo)rhenium Complexes as Aldehyde-Olefination Catalysts Ana M. Santos, Carlos C. Romão, and Fritz E. Kühn pp 2414–2415 DOI: 10.1021/ja021315c Supporting Info

A Modular Cross-Linking Approach for Exploring Protein Interactions Michelle Trester-Zedlitz, Katsuhiko Kamada, Stephen K. Burley, David Fenyö, Brian T. Chait, and Tom W. Muir pp 2416–2425 DOI: 10.1021/ja026917a

Synthesis of Lipid A Derivatives and Their Interactions with Polymyxin B and Polymyxin B Nonapeptide Ning Yin, Ryan L. Marshall, Sannali Matheson, and Paul B. Savage pp 2426–2435 DOI: 10.1021/ja0284456

Rapid Ligand Exchange in the MCRred1 Form of Methyl-coenzyme M Reductase Kuljeet Singh, Yih-Chern Horng, and Stephen W. Ragsdale pp 2436–2443 DOI: 10.1021/ja028525+

Deoxyribozymes with 2‘−5‘ RNA Ligase Activity Amber Flynn-Charlebois, Yangming Wang, Tracey K. Prior, Imran Rashid, Kelly A. Hoadley, Rebecca L. Coppins, Amanda C. Wolf, and Scott K. Silverman pp 2444–2454 DOI: 10.1021/ja028774y Supporting Info

Sialic Acid Biosynthesis:  Stereochemistry and Mechanism of the Reaction Catalyzed by the Mammalian UDP-N-Acetylglucosamine 2-Epimerase Wayne K. Chou, Stephan Hinderlich, Werner Reutter, and Martin E. Tanner pp 2455–2461 DOI: 10.1021/ja021309g

Fundamental Reaction Mechanism for Cocaine Hydrolysis in Human Butyrylcholinesterase Chang-Guo Zhan, Fang Zheng, and Donald W. Landry pp 2462–2474 DOI: 10.1021/ja020850+ Supporting Info

Quantum Mechanical Predictions of the Stereoselectivities of Proline-Catalyzed Asymmetric Intermolecular Aldol Reactions S. Bahmanyar, K. N. Houk, Harry J. Martin, and Benjamin List pp 2475–2479 DOI: 10.1021/ja028812d Supporting Info

Design of an Adenosine Analogue that Selectively Improves the Affinity of a Mutant U1A Protein for RNA Ying Zhao and Anne M. Baranger pp 2480–2488 DOI: 10.1021/ja021267w Supporting Info

Experimental Determination of the Absolute Enantioselectivity of an Antibody-Catalyzed Diels−Alder Reaction and Theoretical Explorations of the Origins of Stereoselectivity Carina E. Cannizzaro, Jon A. Ashley, K. D. Janda, and K. N. Houk pp 2489–2506 DOI: 10.1021/ja020879d Supporting Info

Catalytic, Asymmetric Mannich-type Reactions of N-Acylimino Esters:  Reactivity, Diastereo- and Enantioselectivity, and Application to Synthesis of N-Acylated Amino Acid Derivatives Shū Kobayashi, Ryosuke Matsubara, Yoshitaka Nakamura, Hidetoshi Kitagawa, and Masaharu Sugiura pp 2507–2515 DOI: 10.1021/ja0281840 Supporting Info

Chiral Stimuli-Responsive Gels:  Helicity Induction in Poly(phenylacetylene) Gels Bearing a Carboxyl Group with Chiral Amines Hidetoshi Goto, Hao Qian Zhang, and Eiji Yashima pp 2516–2523 DOI: 10.1021/ja029036c Supporting Info

Nitro-Functionalized Oligothiophenes as a Novel Type of Electroactive Molecular Material:  Spectroscopic, Electrochemical, and Computational Study Juan Casado, Ted M. Pappenfus, Larry L. Miller, Kent R. Mann, Enrique Ortí, Pedro M. Viruela, Rosendo Pou-Amérigo, Víctor Hernández, and Juan T. López Navarrete pp 2524–2534 DOI: 10.1021/ja027835p Supporting Info

Protonation of the Pyrimidine Ring at the C(5) Position:  Formation of a Stable Cationic σ-Complex Ádám Demeter, Csaba Wéber, and János Brlik pp 2535–2540 DOI: 10.1021/ja027900v Supporting Info

Slow Diffusion of Macromolecular Assemblies by a New Pulsed Field Gradient NMR Method Fabien Ferrage, Manuela Zoonens, Dror E. Warschawski, Jean-Luc Popot, and Geoffrey Bodenhausen pp 2541–2545 DOI: 10.1021/ja0211407

Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands Tina M. Trnka, John P. Morgan, Melanie S. Sanford, Thomas E. Wilhelm, Matthias Scholl, Tae-Lim Choi, Sheng Ding, Michael W. Day, and Robert H. Grubbs pp 2546–2558 DOI: 10.1021/ja021146w Supporting Info

Isolation of the Latent Precursor Complex in Electron-Transfer Dynamics. Intermolecular Association and Self-Exchange with Acceptor Anion Radicals Vellaichamy Ganesan, Sergiy V. Rosokha, and Jay K. Kochi pp 2559–2571 DOI: 10.1021/ja0211611 Supporting Info

Structural Studies of Ammonia and Metallic Lithium−Ammonia Solutions Helen Thompson, Jonathan C. Wasse, Neal T. Skipper, Shusaku Hayama, Daniel T. Bowron, and Alan K. Soper pp 2572–2581 DOI: 10.1021/ja021227s

Direct Catalytic Asymmetric Michael Reaction of Hydroxyketones:  Asymmetric Zn Catalysis with a Et2Zn/Linked-BINOL Complex Shinji Harada, Naoya Kumagai, Tomofumi Kinoshita, Shigeki Matsunaga, and Masakatsu Shibasaki pp 2582–2590 DOI: 10.1021/ja028928+ Supporting Info

An Enantiomerically Pure Adamantylimido Molybdenum Alkylidene Complex. An Effective New Catalyst for Enantioselective Olefin Metathesis W. C. Peter Tsang, Jesper A. Jernelius, G. A. Cortez, Gabriel S. Weatherhead, Richard R. Schrock, and Amir H. Hoveyda pp 2591–2596 DOI: 10.1021/ja021204d Supporting Info

Formation and Structure of Self-Assembled Monolayers of Alkanethiolates on Palladium J. Christopher Love, Daniel B. Wolfe, Richard Haasch, Michael L. Chabinyc, Kateri E. Paul, George M. Whitesides, and Ralph G. Nuzzo pp 2597–2609 DOI: 10.1021/ja028692+ Supporting Info

Solvent-Controlled Diastereoselective Synthesis of Cyclopentane Derivatives by a [3 + 2] Cyclization Reaction of α,β-Disubstituted (Alkenyl)(methoxy)carbene Complexes with Methyl Ketone Lithium Enolates José Barluenga, Jorge Alonso, and Francisco J. Fañanás pp 2610–2616 DOI: 10.1021/ja029170x Supporting Info

Nanoscopic Assemblies between Supramolecular Redox Active Metallodendrons and Gold Nanoparticles:  Synthesis, Characterization, and Selective Recognition of H2PO4-, HSO4-, and Adenosine-5‘-Triphosphate (ATP2-) Anions Marie-Christine Daniel, Jaime Ruiz, Sylvain Nlate, Jean-Claude Blais, and Didier Astruc pp 2617–2628 DOI: 10.1021/ja021325d Supporting Info

Electron and Hydrogen-Atom Self-Exchange Reactions of Iron and Cobalt Coordination Complexes Jeffrey C. Yoder, Justine P. Roth, Emily M. Gussenhoven, Anna S. Larsen, and James M. Mayer pp 2629–2640 DOI: 10.1021/ja0273905 Supporting Info

Structural Dependence of Thermodynamics of Alkene Binding to Yttrium Alkyl Complexes and of Kinetics of Alkyl Migration to Coordinated Alkenes Charles P. Casey, Jon A. Tunge, Ting-Yu Lee, and Maureen A. Fagan pp 2641–2651 DOI: 10.1021/ja0209971 Supporting Info

Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations W. C. Peter Tsang, Kai C. Hultzsch, John B. Alexander, Peter J. Bonitatebus, Jr., Richard R. Schrock, and Amir H. Hoveyda pp 2652–2666 DOI: 10.1021/ja0210603 Supporting Info

Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr)n (n = 1 or 2) (Ar = Terphenyl or Related Ligand):  An Experimental Investigation of Ga−Ga Multiple Bonding Ned J. Hardman, Robert J. Wright, Andrew D. Phillips, and Philip P. Power pp 2667–2679 DOI: 10.1021/ja028579j Supporting Info

Development of Fluorescent Film Sensors for the Detection of Divalent Copper Yujun Zheng, Jhony Orbulescu, Xiaojun Ji, Fotios M. Andreopoulos, Si M. Pham, and Roger M. Leblanc pp 2680–2686 DOI: 10.1021/ja0293610 Supporting Info

Ultrafast Singlet Excited-State Polarization in Electronically Asymmetric Ethyne-Bridged Bis[(porphinato)zinc(II)] Complexes Igor V. Rubtsov, Kimihiro Susumu, Grigorii I. Rubtsov, and Michael J. Therien pp 2687–2696 DOI: 10.1021/ja021157p Supporting Info

Complex α-MoO3 Nanostructures with External Bonding Capacity for Self-Assembly Xiong Wen Lou and Hua Chun Zeng pp 2697–2704 DOI: 10.1021/ja029086h

HSAB Principle Applied to the Time Evolution of Chemical Reactions Pratim Kumar Chattaraj and Buddhadev Maiti pp 2705–2710 DOI: 10.1021/ja0276063 Supporting Info

Characterization of Electronic Structure and Properties of a Bis(histidine) Heme Model Complex Dayle M. A. Smith, Michel Dupuis, Erich R. Vorpagel, and T. P. Straatsma pp 2711–2717 DOI: 10.1021/ja0280473

Determination of Internuclear Distances in Uniformly Labeled Molecules by Rotational-Resonance Solid-State NMR Philip T. F. Williamson, Aswin Verhoeven, Matthias Ernst, and Beat H. Meier pp 2718–2722 DOI: 10.1021/ja028210u Supporting Info

Aspects of Enantioselective Heterogeneous Catalysis:  Structure and Reactivity of (S)-(−)-1-(1-Naphthyl)ethylamine on Pt{111} Jonathan M. Bonello, Federico J. Williams, and Richard M. Lambert pp 2723–2729 DOI: 10.1021/ja028436x

Motions of Single Molecules and Proteins in Trehalose Glass Erwen Mei, Jianyong Tang, Jane M. Vanderkooi, and Robin M. Hochstrasser pp 2730–2735 DOI: 10.1021/ja021197t

Surface Chemistry on Bimetallic Alloy Surfaces:  Adsorption of Anions and Oxidation of CO on Pt3Sn(111) Vojislav R. Stamenković, Matthias Arenz, Christopher A. Lucas, Mark E. Gallagher, Philip N. Ross, and Nenad M. Marković pp 2736–2745 DOI: 10.1021/ja028771l

Different Surface Chemistries of Water on Ru{0001}:  From Monomer Adsorption to Partially Dissociated Bilayers A. Michaelides, A. Alavi, and D. A. King pp 2746–2755 DOI: 10.1021/ja028855u

Variety of the Molecular Conformation in Peptide Nanorings and Nanotubes Hajime Okamoto, Tsutomu Nakanishi, Yukiko Nagai, Maki Kasahara, and Kyozaburo Takeda pp 2756–2769 DOI: 10.1021/ja0212720

Theoretical Conformational Analysis for Neurotransmitters in the Gas Phase and in Aqueous Solution. Norepinephrine Peter I. Nagy, Giuliano Alagona, Caterina Ghio, and Krisztina Takács-Novák pp 2770–2785 DOI: 10.1021/ja028952n

Computational Studies of the Optical Emission of Silicon Nanocrystals Aaron Puzder, Andrew J. Williamson, Jeffrey C. Grossman, and Giulia Galli pp 2786–2791 DOI: 10.1021/ja0293296

Substituent-Control Exciton in J-Aggregates of Protonated Water-Insoluble Porphyrins Shinsuke Okada and Hiroshi Segawa pp 2792–2796 DOI: 10.1021/ja017768j

Origin of the Acidity Enhancement of Formic Acid over Methanol:  Resonance versus Inductive Effects Jennifer Holt and Joel M. Karty pp 2797–2803 DOI: 10.1021/ja020803h Supporting Info

Relationship between Photoisomerization Path and Intersection Space in a Retinal Chromophore Model Annapaola Migani, Michael A. Robb, and Massimo Olivucci pp 2804–2808 DOI: 10.1021/ja027352l Supporting Info

Does Metal Ion Complexation Make Radical Clocks Run Fast? Anselm H. C. Horn and Timothy Clark pp 2809–2816 DOI: 10.1021/ja020954k Supporting Info

Origin of Asymmetric Charge Partitioning in the Dissociation of Gas-Phase Protein Homodimers John C. Jurchen and Evan R. Williams pp 2817–2826 DOI: 10.1021/ja0211508

Issue 10

Multiple Mixed-Valence Behavior in trans,trans-[(tpy)(Cl)2OsIII(μ-1,3-N3)OsIII(Cl)2(tpy)]+. An Azido Bridge from the Reaction between trans-[OsVI(tpy)(Cl)2(N)]+ and NH3 My Hang V. Huynh, Thomas J. Meyer, Andrea Labouriau, David E. Morris, and Peter S. White pp 2828–2829 DOI: 10.1021/ja021324l Supporting Info

Multicolor Luminescence Patterning by Photoactivation of Semiconductor Nanoparticle Films Ying Wang, Zhiyong Tang, Miguel A. Correa-Duarte, Luis M. Liz-Marzán, and Nicholas A. Kotov pp 2830–2831 DOI: 10.1021/ja029231r Supporting Info

The Cyanoimido Ligand as an Oxo Analogue. Novel Approaches to the Preparations of Cyano(imino)-aza-phosphorus(V) and N-Cyanoaziridine My Hang V. Huynh, Thomas J. Meyer, and R. Thomas Baker pp 2832–2833 DOI: 10.1021/ja021166y Supporting Info

Synthesis, Structure, and Aromaticity of a Hoop-Shaped Cyclic Benzenoid [10]Cyclophenacene Eiichi Nakamura, Kazukuni Tahara, Yutaka Matsuo, and Masaya Sawamura pp 2834–2835 DOI: 10.1021/ja029915z Supporting Info

Stepwise Formation of Heterobimetallic Macrocycles Synthesized via the Weak-Link Approach Adam H. Eisenberg, Maxim V. Ovchinnikov, and Chad A. Mirkin pp 2836–2837 DOI: 10.1021/ja027936n Supporting Info

A Non-Covalent Strategy for the Assembly of Supramolecular Photocurrent-Generating Systems Ernesto Soto, John C. MacDonald, Christopher G. F. Cooper, and W. Grant McGimpsey pp 2838–2839 DOI: 10.1021/ja0289548 Supporting Info

Chloride Transport Across Lipid Bilayers and Transmembrane Potential Induction by an Oligophenoxyacetamide Vladimir Sidorov, Frank W. Kotch, Jennifer L. Kuebler, Yiu-Fai Lam, and Jeffery T. Davis pp 2840–2841 DOI: 10.1021/ja029372t Supporting Info

Novel η3-1-Silaallyl Tungsten Complexes via Si−H Bond Activation of Hydrovinylsilanes:  Structure and Reactivity toward Methanol Hiroyuki Sakaba, Sanae Watanabe, Chizuko Kabuto, and Kuninobu Kabuto pp 2842–2843 DOI: 10.1021/ja028432s Supporting Info

New Cyclic Peptide Assemblies with Hydrophobic Cavities:  The Structural and Thermodynamic Basis of a New Class of Peptide Nanotubes Manuel Amorín, Luis Castedo, and Juan R. Granja pp 2844–2845 DOI: 10.1021/ja0296273 Supporting Info

Migration of Poly-l-lysine through a Lipid Bilayer Fredric M. Menger, Victor A. Seredyuk, Marina V. Kitaeva, Alexander A. Yaroslavov, and Nickolay S. Melik-Nubarov pp 2846–2847 DOI: 10.1021/ja021337z

Direct Observation of Key Reaction Intermediates on Gold Clusters Davor Stolcic, Matthias Fischer, Gerd Ganteför, Young Dok Kim, Qiang Sun, and Puru Jena pp 2848–2849 DOI: 10.1021/ja0293406

Measuring LCSTs by Novel Temperature Gradient Methods:  Evidence for Intermolecular Interactions in Mixed Polymer Solutions Hanbin Mao, Chunmei Li, Yanjie Zhang, David E. Bergbreiter, and Paul S. Cremer pp 2850–2851 DOI: 10.1021/ja029691k Supporting Info

An Exceptionally Mild Catalytic Thioester Aldol Reaction Inspired by Polyketide Biosynthesis Gojko Lalic, Allen D. Aloise, and Matthew D. Shair pp 2852–2853 DOI: 10.1021/ja029452x Supporting Info

Adhesion between Molecules and Calcium Oxalate Crystals:  Critical Interactions in Kidney Stone Formation Xiaoxia Sheng, Michael D. Ward, and Jeffrey A. Wesson pp 2854–2855 DOI: 10.1021/ja029575h

Macromolecular Effect:  Synthesis of a Ferrocenylmethylphosphine-Containing Polymer as Highly Efficient Ligands for Room-Temperature Palladium(0)-Catalyzed Suzuki Cross-Coupling Reactions of Aryl Chlorides Qiao-Sheng Hu, Yong Lu, Zhen-Yu Tang, and Hong-Bin Yu pp 2856–2857 DOI: 10.1021/ja029021e Supporting Info

Electric Field-Induced Cubic Phase in 4‘-n-Docosyloxy-3‘-nitrobiphenyl-4-carboxylic Acid Shoichi Kutsumizu, Makoto Yamada, Takanari Yamaguchi, Katsufumi Tanaka, and Ryuichi Akiyama pp 2858–2859 DOI: 10.1021/ja029014q

Asymmetric Catalysis on the Intramolecular Cyclopropanation of α-Diazo-β-keto Sulfones Masahiro Honma, Takashi Sawada, Yuri Fujisawa, Masayuki Utsugi, Hideaki Watanabe, Akinori Umino, Takehiko Matsumura, Takayuki Hagihara, Masashi Takano, and Masahisa Nakada pp 2860–2861 DOI: 10.1021/ja029534l Supporting Info

σ Aromaticity of the Bimetallic Au5Zn+ Cluster Hiromasa Tanaka, Sven Neukermans, Ewald Janssens, Roger E. Silverans, and Peter Lievens pp 2862–2863 DOI: 10.1021/ja029157c

Polarizability Effects and Dispersion Interactions in Alkene-Br2 π-Complexes Cinzia Chiappe, Heiner Detert, Dieter Lenoir, Christian Silvio Pomelli, and Marie Françoise Ruasse pp 2864–2865 DOI: 10.1021/ja027630g Supporting Info

Conformer-Specific Photoconversion of 25-Hydroxytachysterol to 25-Hydroxyprevitamin D3:  Role in the Production of Vitamin Ds Jack Saltiel, Lenuta Cires, and Andrzej M. Turek pp 2866–2867 DOI: 10.1021/ja029651g

Flavin Catalyzed Oxidations of Sulfides and Amines with Molecular Oxygen Yasushi Imada, Hiroki Iida, Satoshi Ono, and Shun-Ichi Murahashi pp 2868–2869 DOI: 10.1021/ja028276p Supporting Info

Multishell Microspheres with Integrated Chromatographic and Detection Layers for Use in Array Sensors Adrian P. Goodey and John T. McDevitt pp 2870–2871 DOI: 10.1021/ja029696h Supporting Info

A New cine-Substitution of Alkenyl Sulfones with Aryltitanium Reagents Catalyzed by Rhodium:  Mechanistic Studies and Catalytic Asymmetric Synthesis of Allylarenes Kazuhiro Yoshida and Tamio Hayashi pp 2872–2873 DOI: 10.1021/ja0295568 Supporting Info

Anomalous Distance Dependence of Electron Transfer across Peptide Bridges Sabrina Antonello, Fernando Formaggio, Alessandro Moretto, Claudio Toniolo, and Flavio Maran pp 2874–2875 DOI: 10.1021/ja029787e

Synthesis of Polysiloxane Stabilized Palladium Colloids and Evidence of Their Participation in Silaesterification Reactions Bhanu P. S. Chauhan, Jitendra S. Rathore, Moni Chauhan, and Alexandra Krawicz pp 2876–2877 DOI: 10.1021/ja028957k Supporting Info

Enantiocontrolled Synthesis of 2,6-Disubstituted Piperidines by Desymmetrization of meso-η-(3,4,5)-Dihydropyridinylmolybdenum Complexes. Application to the Total Synthesis of (−)-Dihydropinidine and (−)-Andrachcinidine Chutian Shu and Lanny S. Liebeskind pp 2878–2879 DOI: 10.1021/ja029537y Supporting Info

A Titanium-Catalyzed Three-Component Coupling To Generate α,β-Unsaturated β-Iminoamines Changsheng Cao, Yanhui Shi, and Aaron L. Odom pp 2880–2881 DOI: 10.1021/ja0284714 Supporting Info

Synthesis of Unidirectional Alumina Nanostructures without Added Organic Solvents Hyun Chul Lee, Hae Jin Kim, Soo Hyun Chung, Kyung Hee Lee, Hee Cheon Lee, and Jae Sung Lee pp 2882–2883 DOI: 10.1021/ja029494l

A Ratiometric Fluorescent Sensor for AgI with High Selectivity and Sensitivity Rong-Hua Yang, Wing-Hong Chan, Albert W. M. Lee, Ping-Fang Xia, Hong-Kui Zhang, and Ke'AnLi pp 2884–2885 DOI: 10.1021/ja029253d Supporting Info

Chiral Ligand-Controlled Asymmetric Conjugate Addition of Lithium Amides to Enoates Hirohisa Doi, Takeo Sakai, Mayu Iguchi, Ken-ichi Yamada, and Kiyoshi Tomioka pp 2886–2887 DOI: 10.1021/ja029633z Supporting Info

Photomechanical Actuation and Manipulation of the Electronic Properties of Linear π-Conjugated Systems Bruno Jousselme, Philippe Blanchard, Nuria Gallego-Planas, Jacques Delaunay, Magali Allain, Pascal Richomme, Eric Levillain, and Jean Roncali pp 2888–2889 DOI: 10.1021/ja029754z Supporting Info

Copper-Catalyzed Domino Halide Exchange-Cyanation of Aryl Bromides Jacopo Zanon, Artis Klapars, and Stephen L. Buchwald pp 2890–2891 DOI: 10.1021/ja0299708 Supporting Info

Use of Selective Trp Side Chain Labeling To Characterize Protein−Protein and Protein−Ligand Interactions by NMR Spectroscopy Ricard A. Rodriguez-Mias and Maurizio Pellecchia pp 2892–2893 DOI: 10.1021/ja029221q Supporting Info

A Novel Bis(imino)amine Ligand as a Result of Acetonitrile Coupling with the Diiodides of Dy(II) and Tm(II) Mikhail N. Bochkarev, Georgii V. Khoroshenkov, Herbert Schumann, and Sebastian Dechert pp 2894–2895 DOI: 10.1021/ja028311s Supporting Info

Light-Induced Coherent Interactions between Silver Nanoparticles in Two-Dimensional Arrays Serhiy Malynych and George Chumanov pp 2896–2898 DOI: 10.1021/ja029453p

Complex Target-Oriented Total Synthesis in the Drug Discovery Process:  The Discovery of a Highly Promising Family of Second Generation Epothilones Alexey Rivkin, Fumihiko Yoshimura, Ana E. Gabarda, Ting-Chao Chou, Huajin Dong, William P. Tong, and Samuel J. Danishefsky pp 2899–2901 DOI: 10.1021/ja029695p Supporting Info

Docking of Protein−Protein Complexes on the Basis of Highly Ambiguous Intermolecular Distance Restraints Derived from 1HN/15N Chemical Shift Mapping and Backbone 15N−1H Residual Dipolar Couplings Using Conjoined Rigid Body/Torsion Angle Dynamics G. Marius Clore and Charles D. Schwieters pp 2902–2912 DOI: 10.1021/ja028893d

Structural Model for an Alkaline Form of Ferricytochrome c Michael Assfalg, Ivano Bertini, Alessandra Dolfi, Paola Turano, A. Grant Mauk, Federico I. Rosell, and Harry B. Gray pp 2913–2922 DOI: 10.1021/ja027180s Supporting Info

Effects of As(III) Binding on α-Helical Structure Daniel J. Cline, Colin Thorpe, and Joel P. Schneider pp 2923–2929 DOI: 10.1021/ja0282644 Supporting Info

Conformational Flexibility of the Group B Meningococcal Polysaccharide in Solution Terry J. Henderson, Richard M. Venable, and William Egan pp 2930–2939 DOI: 10.1021/ja0210087

Cross-Linked Normal Hexagonal and Bicontinuous Cubic Assemblies via Polymerizable Gemini Amphiphiles Brad A. Pindzola, Jizhu Jin, and Douglas L. Gin pp 2940–2949 DOI: 10.1021/ja0208106 Supporting Info

Structural Effects on the Barrier Properties of Self-Assembled Monolayers Formed from Long-Chain ω-Alkoxy-n-alkanethiols on Copper G. Kane Jennings, Tseh-Hwan Yong, Jeffrey C. Munro, and Paul E. Laibinis pp 2950–2957 DOI: 10.1021/ja020233l

Development of a Highly α-Regioselective Metal-Mediated Allylation Reaction in Aqueous Media:  New Mechanistic Proposal for the Origin of α-Homoallylic Alcohols Kui-Thong Tan, Shu-Sin Chng, Hin-Soon Cheng, and Teck-Peng Loh pp 2958–2963 DOI: 10.1021/ja029276s Supporting Info

Synthesis of Azo-Conjugated Metalladithiolenes and Their Photo- and Proton-Responsive Isomerization Reactions Masayuki Nihei, Masato Kurihara, Jun Mizutani, and Hiroshi Nishihara pp 2964–2973 DOI: 10.1021/ja028080p Supporting Info

Synthesis and Photochromic Properties of Molecules Containing [e]-Annelated Dihydropyrenes. Two and Three Way π-Switches Based on the Dimethyldihydropyrene−Metacyclophanediene Valence Isomerization Reginald H. Mitchell, Timothy R. Ward, Yongsheng Chen, Yunxia Wang, S. Ananda Weerawarna, Peter W. Dibble, Michael J. Marsella, Adah Almutairi, and Zhi-Qiang Wang pp 2974–2988 DOI: 10.1021/ja0288136 Supporting Info

Catalytic Asymmetric Aldol Reactions in Aqueous Media Using Chiral Bis-pyridino-18-crown-6−Rare Earth Metal Triflate Complexes Tomoaki Hamada, Kei Manabe, Shunpei Ishikawa, Satoshi Nagayama, Motoo Shiro, and Shū Kobayashi pp 2989–2996 DOI: 10.1021/ja028698z Supporting Info

Sensing and Fixation of NO2/N2O4 by Calix[4]Arenes Grigory V. Zyryanov, Yanlong Kang, and Dmitry M. Rudkevich pp 2997–3007 DOI: 10.1021/ja029166l

Microenvironmental Polarity Control of Electron-Transfer Photochirogenesis. Enantiodifferentiating Polar Addition of 1,1-Diphenyl-1-alkenes Photosensitized by Saccharide Naphthalenecarboxylates Sadayuki Asaoka, Takehiko Wada, and Yoshihisa Inoue pp 3008–3027 DOI: 10.1021/ja028680o Supporting Info

Ultrafast UV-mid-IR Investigation of the Ring Opening Reaction of a Photochromic Spiropyran Matteo Rini, Ann-Kathrin Holm, Erik T. J. Nibbering, and Henk Fidder pp 3028–3034 DOI: 10.1021/ja028262j

Solvent-Induced Polymorphism of Three-Dimensional Hydrogen-Bonded Networks of Hexakis(4-carbamoylphenyl)benzene Kenji Kobayashi, Azumi Sato, Shigeru Sakamoto, and Kentaro Yamaguchi pp 3035–3045 DOI: 10.1021/ja0293103 Supporting Info

In Situ Generation of Carbenes:  A General and Versatile Platform for Organocatalytic Living Polymerization Gregory W. Nyce, Thierry Glauser, Eric F. Connor, Andreas Möck, Robert M. Waymouth, and James L. Hedrick pp 3046–3056 DOI: 10.1021/ja021084+

Structural Transformation of Fluorinated Carbon Nanotubes Induced by in Situ Electron-Beam Irradiation Kay Hyeok An, Kyung Ah Park, Jeong Gu Heo, Ji Yeong Lee, Kwan Ku Jeon, Seong Chu Lim, Cheol Woong Yang, Young Seak Lee, and Young Hee Lee pp 3057–3061 DOI: 10.1021/ja028453m

Porous Lanthanide-Organic Frameworks:  Synthesis, Characterization, and Unprecedented Gas Adsorption Properties Long Pan, Kristie M. Adams, Hayden E. Hernandez, Xiaotai Wang, Chong Zheng, Yoshiyuki Hattori, and Katsumi Kaneko pp 3062–3067 DOI: 10.1021/ja028996w Supporting Info

Mechanistic Studies of Nickel(II) Alkyl Agostic Cations and Alkyl Ethylene Complexes:  Investigations of Chain Propagation and Isomerization in (α-diimine)Ni(II)-Catalyzed Ethylene Polymerization Mark D. Leatherman, Steven A. Svejda, Lynda K. Johnson, and Maurice Brookhart pp 3068–3081 DOI: 10.1021/ja021071w Supporting Info

Highly Efficient Water Splitting into H2 and O2 over Lanthanum-Doped NaTaO3 Photocatalysts with High Crystallinity and Surface Nanostructure Hideki Kato, Kiyotaka Asakura, and Akihiko Kudo pp 3082–3089 DOI: 10.1021/ja027751g

Palladium Catalyzed Kinetic and Dynamic Kinetic Asymmetric Transformations of γ-Acyloxybutenolides. Enantioselective Total Synthesis of (+)-Aflatoxin B1 and B2a Barry M. Trost and F. Dean Toste pp 3090–3100 DOI: 10.1021/ja020988s Supporting Info

2D Conformationally Sampled Pharmacophore:  A Ligand-Based Pharmacophore To Differentiate δ Opioid Agonists from Antagonists Denzil Bernard, Andrew Coop, and Alexander D. MacKerell, Jr. pp 3101–3107 DOI: 10.1021/ja027644m Supporting Info

Decisive Role of Electronic Polarization of the Protein Environment in Determining the Absorption Maximum of Halorhodopsin Minoru Sakurai, Keiko Sakata, Shino Saito, Sawako Nakajima, and Yoshio Inoue pp 3108–3112 DOI: 10.1021/ja027342k

Simulating the Nucleation of Water/Ethanol and Water/n-Nonane Mixtures:  Mutual Enhancement and Two-Pathway Mechanism Bin Chen, J. Ilja Siepmann, and Michael L. Klein pp 3113–3118 DOI: 10.1021/ja029006+

Specific Ethene Surface Activation on Silver Oxide Covered Ag{111} from the Interplay of STM Experiment and Theory Marie-Laure Bocquet, Philippe Sautet, Jorge Cerda, Christopher I. Carlisle, Matthew J. Webb, and David A. King pp 3119–3125 DOI: 10.1021/ja027634l

Noble Gas−Actinide Complexes of the CUO Molecule with Multiple Ar, Kr, and Xe Atoms in Noble-Gas Matrices Lester Andrews Binyong Liang, Jun Li, and Bruce E. Bursten pp 3126–3139 DOI: 10.1021/ja027819s

Protein-Polyelectrolyte Cluster Formation and Redissolution:  A Monte Carlo Study Fredrik Carlsson, Martin Malmsten, and Per Linse pp 3140–3149 DOI: 10.1021/ja020935a

Molecular Packing of Lysozyme, Fibrinogen, and Bovine Serum Albumin on Hydrophilic and Hydrophobic Surfaces Studied by Infrared−Visible Sum Frequency Generation and Fluorescence Microscopy Joonyeong Kim and Gabor A. Somorjai pp 3150–3158 DOI: 10.1021/ja028987n

Cyclic Vinylogous TTF:  a Potential Molecular Clip Triggered by Electron Transfer Michel Guerro, Roger Carlier, Kamal Boubekeur, Dominique Lorcy, and Philippe Hapiot pp 3159–3167 DOI: 10.1021/ja0289090 Supporting Info

First−Second Shell Interactions in Metal Binding Sites in Proteins:  A PDB Survey and DFT/CDM Calculations Todor Dudev, Yen-lin Lin, Minko Dudev, and Carmay Lim pp 3168–3180 DOI: 10.1021/ja0209722 Supporting Info

Carbon Dioxide-in-Water Microemulsions C. Ted Lee, Jr., Won Ryoo, P. Griffin Smith, Jr., Jose Arellano, Daniel R. Mitchell, Richard J. Lagow, Stephen E. Webber, and Keith P. Johnston pp 3181–3189 DOI: 10.1021/ja025735d Supporting Info

Total Synthesis of Epothilone B, Epothilone D, and cis- and trans-9,10-Dehydroepothilone D  [J. Am. Chem. Soc. 2001, 123, 5407−5413].  James D. White, Rich G. Carter, Kurt F. Sundermann, and Markus Wartmann p 3190 DOI: 10.1021/ja0251221

Issue 11

Bioconjugation by Copper(I)-Catalyzed Azide-Alkyne [3 + 2] Cycloaddition Qian Wang, Timothy R. Chan, Robert Hilgraf, Valery V. Fokin, K. Barry Sharpless, and M. G. Finn pp 3192–3193 DOI: 10.1021/ja021381e Supporting Info

[(FeIII(OH2)2)3(A-α-PW9O34)2]9- on Cationic Silica Nanoparticles, a New Type of Material and Efficient Heterogeneous Catalyst for Aerobic Oxidations Nelya M. Okun, Travis M. Anderson, and Craig L. Hill pp 3194–3195 DOI: 10.1021/ja0267223 Supporting Info

Nanostructured Anisotropic Ion-Conductive Films Kenji Kishimoto, Masafumi Yoshio, Tomohiro Mukai, Masahiro Yoshizawa, Hiroyuki Ohno, and Takashi Kato pp 3196–3197 DOI: 10.1021/ja029750u Supporting Info

Structure and Mechanism of Action of Isopentenylpyrophosphate-Dimethylallylpyrophosphate Isomerase Johan Wouters, Yamina Oudjama, Subhash Ghosh, Victor Stalon, Louis Droogmans, and Eric Oldfield pp 3198–3199 DOI: 10.1021/ja029171p Supporting Info

Peptides Derived from Two Dynamically Disordered Proteins Self-Assemble into Amyloid-like Fibrils Brian Bothner, Yves Aubin, and Richard W. Kriwacki pp 3200–3201 DOI: 10.1021/ja028265w

Ligand Effects on Charge Transport in Platinum(II) Acetylides Terence L. Schull, James G. Kushmerick, Charles H. Patterson, Clifford George, Martin H. Moore, Steven K. Pollack, and Ranganathan Shashidhar pp 3202–3203 DOI: 10.1021/ja029564o Supporting Info

Isomeric Forms of Divalent Heavier Group 14 Element Hydrides:  Characterization of Ar‘(H)GeGe(H)Ar‘ and Ar‘(H)2GeGeAr‘·PMe3 (Ar‘ = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) Anne F. Richards, Andrew D. Phillips, Marilyn M. Olmstead, and Philip P. Power pp 3204–3205 DOI: 10.1021/ja029772g Supporting Info

Selective Stabilization of the Chorismate Mutase Transition State by a Positively Charged Hydrogen Bond Donor Alexander Kienhöfer, Peter Kast, and Donald Hilvert pp 3206–3207 DOI: 10.1021/ja0341992 Supporting Info

Unfunctionalized, α-Epimerizable Nonracemic Ketones and Aldehydes Can Be Accessed by Crystallization-Induced Dynamic Resolution of Imines Janez Košmrlj, Leland O. Weigel, David A. Evans, C. Wade Downey, and Jimmy Wu pp 3208–3209 DOI: 10.1021/ja029715n Supporting Info

A One-Pot Diastereoselective Synthesis of cis-3-Hexene-1,6-diols via an Unusually Reactive Organozinc Intermediate Celina García, Eric R. Libra, Patrick J. Carroll, and Patrick J. Walsh pp 3210–3211 DOI: 10.1021/ja029449d Supporting Info

Radical Anion of Isolable Dialkylsilylene S. Ishida, T. Iwamoto, and M. Kira pp 3212–3213 DOI: 10.1021/ja028192g Supporting Info

Electrochemical Coding Technology for Simultaneous Detection of Multiple DNA Targets Joseph Wang, Guodong Liu, and Arben Merkoçi pp 3214–3215 DOI: 10.1021/ja029668z Supporting Info

Diastereoselective Addition of Alcohol to Diastereotopic Silylenes Takanobu Sanji, Hideyuki Fujiyama, Kaname Yoshida, and Hideki Sakurai pp 3216–3217 DOI: 10.1021/ja028754w Supporting Info

(Z)-α-Haloacrylates:  An Exceptionally Stereoselective Preparation via Cr(II)-Mediated Olefination of Aldehydes with Trihaloacetates D. K. Barma, Abhijit Kundu, Hongming Zhang, Charles Mioskowski, and J. R. Falck pp 3218–3219 DOI: 10.1021/ja029938d Supporting Info

Asymmetric Skeletal Rearrangement of Symmetrically α,α-Disubstituted α-Amino Aldehydes:  A New Entry to Optically Active α-Hydroxy Ketones Takashi Ooi, Akira Saito, and Keiji Maruoka pp 3220–3221 DOI: 10.1021/ja0292851 Supporting Info

Coordination of Alkenes and Alkynes to a Cationic d0 Zirconocene Alkoxide Complex Edward J. Stoebenau, III and Richard F. Jordan pp 3222–3223 DOI: 10.1021/ja029963j Supporting Info

Evidence for Substrate Activation of Electron Transfer from Methylamine Dehydrogenase to Amicyanin Victor L. Davidson and Dapeng Sun pp 3224–3225 DOI: 10.1021/ja0297133

Inert Site in a Protein Zinc Cluster: Isotope Exchange by High Resolution Mass Spectrometry Claudia A. Blindauer, Nick C. Polfer, Stella E. Keiper, Mark D. Harrison, Nigel J. Robinson, Pat R. R. Langridge-Smith, and Peter J. Sadler pp 3226–3227 DOI: 10.1021/ja0284409 Supporting Info

The First Stable Mononuclear Silyl Palladium Hydrides Robert C. Boyle, Joel T. Mague, and Mark J. Fink pp 3228–3229 DOI: 10.1021/ja029853c Supporting Info

The Synthesis of a Dicyclopenta[a,e]pentalene via a Molybdenum Hexacarbonyl-Mediated Tandem Allenic Pauson−Khand Reaction1 Hui Cao, Judith Flippen-Anderson, and James M. Cook pp 3230–3231 DOI: 10.1021/ja021159+ Supporting Info

A Mild, Catalytic, and Highly Selective Method for the Oxidation of α,β-Enones to 1,4-Enediones Jin-Quan Yu and E. J. Corey pp 3232–3233 DOI: 10.1021/ja0340735 Supporting Info

Hydrosilylation of a Dinuclear Tantalum Dinitrogen Complex:  Cleavage of N2 and Functionalization of Both Nitrogen Atoms Michael D. Fryzuk, Bruce A. MacKay, and Brian O. Patrick pp 3234–3235 DOI: 10.1021/ja034303f Supporting Info

Application of Brønsted-Type LFER in the Study of the Phospholipase C Mechanism Cornelia Mihai, Alexander V. Kravchuk, Ming-Daw Tsai, and Karol S. Bruzik pp 3236–3242 DOI: 10.1021/ja029362s Supporting Info

Cavity-Directed Synthesis within a Self-Assembled Coordination Cage:  Highly Selective [2 + 2] Cross-Photodimerization of Olefins Michito Yoshizawa, Yoshihisa Takeyama, Takashi Okano, and Makoto Fujita pp 3243–3247 DOI: 10.1021/ja020718+

Trimethyl Phosphite as a Trap for Alkoxy Radicals Formed from the Ring Opening of Oxiranylcarbinyl Radicals. Conversion to Alkenes. Mechanistic Applications to the Study of C−C versus C−O Ring Cleavage Bangwei Ding and Wesley G. Bentrude pp 3248–3259 DOI: 10.1021/ja020761x Supporting Info

Amphiphilic Janus Micelles with Polystyrene and Poly(methacrylic acid) Hemispheres Rainer Erhardt, Mingfu Zhang, Alexander Böker, Heiko Zettl, Clarissa Abetz, Peter Frederik, Georg Krausch, Volker Abetz, and Axel H. E. Müller pp 3260–3267 DOI: 10.1021/ja028982q

Twisted Amide Reduction under Wolff−Kishner Conditions:  Synthesis of a Benzo-1-Aza-Adamantane Derivative Crystal G. Bashore, Ivan J. Samardjiev, Jon Bordner, and Jotham W. Coe pp 3268–3272 DOI: 10.1021/ja028152c Supporting Info

Charge-Transfer Mechanism for Electrophilic Aromatic Nitration and Nitrosation via the Convergence of (ab Initio) Molecular-Orbital and Marcus−Hush Theories with Experiments Steven R. Gwaltney, Sergiy V. Rosokha, Martin Head-Gordon, and Jay K. Kochi pp 3273–3283 DOI: 10.1021/ja021152s Supporting Info

Optimization of Tether Length in Nonglycosidically Linked Bivalent Ligands That Target Sites 2 and 1 of a Shiga-like Toxin Pavel I. Kitov, Hiroki Shimizu, Steven W. Homans, and David R. Bundle pp 3284–3294 DOI: 10.1021/ja0258529

Single Crystalline Commensurate Metallic Assemblages of π-slabs and CdI2-Type Layers:  Synthesis and Properties of β-(EDT-TTF-I2)2[Pb5/61/6I2]3 and β-(EDT-TTF-I2)2[Pb2/3+xAg1/3-2xxI2]3, x = 0.05 Thomas Devic, Michel Evain, Yves Moëlo, Enric Canadell, Pascale Auban-Senzier, Marc Fourmigué, and Patrick Batail pp 3295–3301 DOI: 10.1021/ja0290431 Supporting Info

Self-Assembly of Fluid-Filled KHCO3 Microfibers Hugo Celio, Jose Lozano, Hyacinth Cabibil, Lynette Ballast, and J. M. White pp 3302–3310 DOI: 10.1021/ja021419n Supporting Info

First X-ray Characterization and Theoretical Study of π-Alkyne, Alkynyl-Hydride, and Vinylidene Isomers for the Same Transition Metal Fragment [Cp*Ru(PEt3)2]+ Emilio Bustelo, Jorge J. Carbó, Agustí Lledós, Kurt Mereiter, M. Carmen Puerta, and Pedro Valerga pp 3311–3321 DOI: 10.1021/ja0291181 Supporting Info

Photonic Crystal Carbohydrate Sensors:  Low Ionic Strength Sugar Sensing Sanford A. Asher, Vladimir L. Alexeev, Alexander V. Goponenko, Anjal C. Sharma, Igor K. Lednev, Craig S. Wilcox, and David N. Finegold pp 3322–3329 DOI: 10.1021/ja021037h

Evidence for a Lack of Reactivity of Carotenoid Addition Radicals towards Oxygen:  A Laser Flash Photolysis Study of the Reactions of Carotenoids with Acylperoxyl Radicals in Polar and Non-polar Solvents Ali El-Agamey and David J McGarvey pp 3330–3340 DOI: 10.1021/ja027986s Supporting Info

On the Dissolution Processes of Na2I+ and Na3I2+ with the Association of Water Molecules:  Mechanistic and Energetic Details Qiang Zhang, Catherine J. Carpenter, Paul R. Kemper, and Michael T. Bowers pp 3341–3352 DOI: 10.1021/ja028411y Supporting Info

Mechanism and Energetics of Intramolecular Hydrogen Transfer in Amide and Peptide Radicals and Cation-Radicals František Tureek and Erik A. Syrstad pp 3353–3369 DOI: 10.1021/ja021162t Supporting Info

A Route for Bulk Separation of Semiconducting from Metallic Single-Wall Carbon Nanotubes Debjit Chattopadhyay, Izabela Galeska, and Fotios Papadimitrakopoulos pp 3370–3375 DOI: 10.1021/ja028599l Supporting Info

Relaxation-Assisted Separation of Chemical Sites in NMR Spectroscopy of Static Solids Adonis Lupulescu, Mrignayani Kotecha, and Lucio Frydman pp 3376–3383 DOI: 10.1021/ja021173m

Catalytic Gas Phase Oxidation of Methanol to Formaldehyde Tom Waters, Richard A. J. O'Hair, and Anthony G. Wedd pp 3384–3396 DOI: 10.1021/ja028839x Supporting Info

Bistable Ferroelectric Liquid Crystal Photoswitch Triggered by a Dithienylethene Dopant [J. Am. Chem. Soc. 2002, 124, 7898−7899]. Kenneth E. Maly, Michael D. Wand, and Robert P. Lemieux p 3397 DOI: 10.1021/ja0334412

Detection of Chiral Perturbations in Ferroelectric Liquid Crystals Induced by an Atropisomeric Biphenyl Dopant [J. Am. Chem. Soc. 2002, 124, 13513−13518]. C. Scott Hartley, Carmen Lazar, Michael D. Wand, and Robert P. Lemieux p 3397 DOI: 10.1021/ja033442u

Electroanalytical Methods:  Guide to Experiments and Applications Edited by Fritz Scholz (E.-M.-Arndt-Universität Greifswald). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. xxii + 332 pp. $69.95. ISBN 3-540-42229-3. Anna Brajter-Toth p 3398 DOI: 10.1021/ja025275o

Scale-Up and Optimization in Preparative Chromatography:  Principles and Biopharmaceutical Applications. Chromatographic Science Series, Volume 88 Edited by Anurag S. Rathore (Pharmacia Corporation, Chesterfield, MO) and Ajoy Velayudhan (Oregon State University). Marcel Dekker, Inc.:  New York, Basel. 2002. xvi + 342 pp. $150.00. ISBN 0-8247-0826-1. Giorgio Carta pp 3398–3399 DOI: 10.1021/ja025322c

Group 13 Chemistry I:  Fundamental New Develop-ments. Structure & Bonding, Volume 103 Edited by Herbert W. Roesky (University of Göttingen, Germany) and David A. Atwood (University of Kentucky, Lexing-ton). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. x + 172 pp. $129.00. ISBN 3-540-43615-4. Guy Bertrand p 3399 DOI: 10.1021/ja025331l

Handbook of Radical Polymerization Edited by Krzysztof Matyjaszewski (Carnegie Mellon University) and Thomas P. Davis (University of New South Wales). John Wiley & Sons, Inc.:  Hoboken. 2002. xvi + 920 pp. $200.00. ISBN 0-471-39274-X. Rebecca Braslau pp 3399–3400 DOI: 10.1021/ja0253078

Surfactants and Polymers in Drug Delivery. Drugs and the Pharmaceutical Sciences. Volume 122 By Martin Malmsten (Royal Institute of Technology, Stockholm, Sweden). Marcel Dekker, Inc.:  New York, Basel. 2002. x + 348 pp. $165.00. ISBN 0-8247-0804-0. Surita R. Bhatia p 3400 DOI: 10.1021/ja025301i

Issue 12

Synthesis of Monoglucosylated High-Mannose-Type Dodecasaccharide, a Putative Ligand for Molecular Chaperone, Calnexin, and Calreticurin Ichiro Matsuo, Megumi Wada, Shino Manabe, Yoshiki Yamaguchi, Keisuke Otake, Koichi Kato, and Yukishige Ito pp 3402–3403 DOI: 10.1021/ja021288q Supporting Info

Electrochromism in Photochromic Dithienylcyclopentenes Andrea Peters and Neil R. Branda pp 3404–3405 DOI: 10.1021/ja028764x Supporting Info

Epoxidation of Olefins by Hydroperoxo−Ferric Cytochrome P450 Shengxi Jin, Thomas M. Makris, Thomas A. Bryson, Stephen G. Sligar, and John H. Dawson pp 3406–3407 DOI: 10.1021/ja029272n

Synthesis and Optical Properties of Colloidal Tungsten Oxide Nanorods Kwangyeol Lee, Won Seok Seo, and Joon T. Park pp 3408–3409 DOI: 10.1021/ja034011e

The Complex of a Designer Antibiotic with a Model Aminoacyl Site of the 30S Ribosomal Subunit Revealed by X-ray Crystallography Rupert J. M. Russell, James B. Murray, Georg Lentzen, Jalal Haddad, and Shahriar Mobashery pp 3410–3411 DOI: 10.1021/ja029736h Supporting Info

The Polymer Incarcerated Method for the Preparation of Highly Active Heterogeneous Palladium Catalysts Ryo Akiyama and Shū Kobayashi pp 3412–3413 DOI: 10.1021/ja029146j Supporting Info

The First Stable β-Fluorosilylanion Roland Fischer, Judith Baumgartner, Guido Kickelbick, and Christoph Marschner pp 3414–3415 DOI: 10.1021/ja0291639 Supporting Info

Miniature Homeodomains:  High Specificity without an N-Terminal Arm Jin Kim Montclare and Alanna Schepartz pp 3416–3417 DOI: 10.1021/ja028628s Supporting Info

Coupling Selectivity with Sensitivity in an Integrated Chemosensor Framework:  Design of a Hg2+-Responsive Probe, Operating above 500 nm Ana B. Descalzo, Ramón Martínez-Máñez, Reiner Radeglia, Knut Rurack, and Juan Soto pp 3418–3419 DOI: 10.1021/ja0290779 Supporting Info

Fluorescent Detection of Chemical Warfare Agents:  Functional Group Specific Ratiometric Chemosensors Shi-Wei Zhang and Timothy M. Swager pp 3420–3421 DOI: 10.1021/ja029265z Supporting Info

Catalytic Transamidation under Moderate Conditions Sarah E. Eldred, David A. Stone, Samuel H. Gellman, and Shannon S. Stahl pp 3422–3423 DOI: 10.1021/ja028242h

Cross-Linked Dendrimer Hosts Containing Reporter Groups for Amine Guests Eric Mertz and Steven C. Zimmerman pp 3424–3425 DOI: 10.1021/ja0294515 Supporting Info

Regio- and Enantioselective Iridium-Catalyzed Intermolecular Allylic Etherification of Achiral Allylic Carbonates with Phenoxides Fernando López, Toshimichi Ohmura, and John F. Hartwig pp 3426–3427 DOI: 10.1021/ja029790y Supporting Info

Epothilone C Macrolactonization and Hydrolysis Are Catalyzed by the Isolated Thioesterase Domain of Epothilone Polyketide Synthase Christopher N. Boddy, Tanya L. Schneider, Kinya Hotta, Christopher T. Walsh, and Chaitan Khosla pp 3428–3429 DOI: 10.1021/ja0298646 Supporting Info

A New Highly Asymmetric Chelation-Controlled Heck Arylation Peter Nilsson, Mats Larhed, and Anders Hallberg pp 3430–3431 DOI: 10.1021/ja029646c Supporting Info

Assembly of Resorcinarene Capsules in Wet Solvents Alexander Shivanyuk and Julius Rebek, Jr. pp 3432–3433 DOI: 10.1021/ja027982n

Nanometer Distance Measurements on RNA Using PELDOR Olav Schiemann, Axel Weber, Thomas E. Edwards, Thomas F. Prisner, and Snorri T. Sigurdsson pp 3434–3435 DOI: 10.1021/ja0274610 Supporting Info

A Rare Earth-DOTA-Binding Antibody:  Probe Properties and Binding Affinity across the Lanthanide Series Todd M. Corneillie, Paul A. Whetstone, Andrew J. Fisher, and Claude F. Meares pp 3436–3437 DOI: 10.1021/ja029363k Supporting Info

A New Approach in 1D and 2D 13C High-Resolution Solid-State NMR Spectroscopy of Paramagnetic Organometallic Complexes by Very Fast Magic-Angle Spinning Yoshitaka Ishii, Nalinda P. Wickramasinghe, and Sandra Chimon pp 3438–3439 DOI: 10.1021/ja0291742 Supporting Info

Synthesis of InP Nanotubes Erik P. A. M. Bakkers and Marcel A. Verheijen pp 3440–3441 DOI: 10.1021/ja0299102

Catalytic Asymmetric Reductive Coupling of Alkynes and Aldehydes:  Enantioselective Synthesis of Allylic Alcohols and α-Hydroxy Ketones Karen M. Miller, Wei-Sheng Huang, and Timothy F. Jamison pp 3442–3443 DOI: 10.1021/ja034366y Supporting Info

Direct Preparation of Nanoporous Carbon by Nanocasting Bao-Hang Han, Wuzong Zhou, and Abdelhamid Sayari pp 3444–3445 DOI: 10.1021/ja029635j

An Outer-Sphere Two-Electron Platinum Reagent Hershel Jude, Jeanette A. Krause Bauer, and William B. Connick pp 3446–3447 DOI: 10.1021/ja034003y Supporting Info

Aromatic δ-Peptides Hua Jiang, Jean-Michel Léger, and Ivan Huc pp 3448–3449 DOI: 10.1021/ja029887k Supporting Info

Polymer-Directed Synthesis of Penniform BaWO4 Nanostructures in Reverse Micelles Hongtao Shi, Limin Qi, Jiming Ma, and Humin Cheng pp 3450–3451 DOI: 10.1021/ja029958f Supporting Info

Amplified DNA Sensing and Immunosensing by the Rotation of Functional Magnetic Particles Yossi Weizmann, Fernando Patolsky, Eugenii Katz, and Itamar Willner pp 3452–3454 DOI: 10.1021/ja028850x Supporting Info

Artificial Viruses and Their Application to Gene Delivery. Size-Controlled Gene Coating with Glycocluster Nanoparticles Yasuhiro Aoyama, Takuya Kanamori, Takashi Nakai, Toshinori Sasaki, Shohei Horiuchi, Shinsuke Sando, and Takuro Niidome pp 3455–3457 DOI: 10.1021/ja029608t Supporting Info

NMR Structure of Two Novel Polyethylene Glycol Conjugates of the Human Growth Hormone-Releasing Factor, hGRF(1−29)−NH2 Giuseppe Digilio, Luca Barbero, Chiara Bracco, Davide Corpillo, Pierandrea Esposito, Gilles Piquet, Silvio Traversa, and Silvio Aime pp 3458–3470 DOI: 10.1021/ja021264j Supporting Info

Highly Efficient Sequence-Specific DNA Interstrand Cross-Linking by Pyrrole/Imidazole CPI Conjugates Toshikazu Bando, Akihiko Narita, Isao Saito, and Hiroshi Sugiyama pp 3471–3485 DOI: 10.1021/ja028459b

Design of a New Fluorescent Cofactor for DNA Methyltransferases and Sequence-Specific Labeling of DNA Goran Pljevaljcic, Marc Pignot, and Elmar Weinhold pp 3486–3492 DOI: 10.1021/ja021106s

Anomalous Binding Profile of Phenylboronic Acid with N-Acetylneuraminic Acid (Neu5Ac) in Aqueous Solution with Varying pH Hidenori Otsuka, Eiichiro Uchimura, Hiroyuki Koshino, Teruo Okano, and Kazunori Kataoka pp 3493–3502 DOI: 10.1021/ja021303r Supporting Info

Electronic Control of the Regiochemistry in the Heck Reaction Henrik von Schenck, Björn Åkermark, and Mats Svensson pp 3503–3508 DOI: 10.1021/ja028755o Supporting Info

Amine- and Ether-Chelated Aryllithium ReagentsStructure and Dynamics Hans J. Reich, Wayne S. Goldenberg, Aaron W. Sanders, Kevin L. Jantzi, and C. Christoph Tzschucke pp 3509–3521 DOI: 10.1021/ja028301r Supporting Info

Supramolecular Pseudorotaxane Polymers from Complementary Pairs of Homoditopic Molecules Harry W. Gibson, Nori Yamaguchi, and Jason W. Jones pp 3522–3533 DOI: 10.1021/ja020900a Supporting Info

Application of Chiral Mixed Phosphorus/Sulfur Ligands to Enantioselective Rhodium-Catalyzed Dehydroamino Acid Hydrogenation and Ketone Hydrosilylation Processes David A. Evans, Forrest E. Michael, Jason S. Tedrow, and Kevin R. Campos pp 3534–3543 DOI: 10.1021/ja012639o Supporting Info

Modeling H-Bonding and Solvent Effects in the Alkylation of Pyrimidine Bases by a Prototype Quinone Methide:  A DFT Study Mauro Freccero, Cristiana Di Valentin, and Mirko Sarzi-Amadè pp 3544–3553 DOI: 10.1021/ja028732+ Supporting Info

Ladderlike Ferromagnetic Spin Coupling Network on a π-Conjugated Pendant Polyradical Takashi Kaneko, Takahisa Makino, Hiroshi Miyaji, Masahiro Teraguchi, Toshiki Aoki, Makoto Miyasaka, and Hiroyuki Nishide pp 3554–3557 DOI: 10.1021/ja026929w Supporting Info

Photodissociation of the Phosphine-Substituted Transition Metal Carbonyl Complexes Cr(CO)5L and Fe(CO)4L:  A Theoretical Study T. P. M. Goumans, Andreas W. Ehlers, Marc C. van Hemert, Angela Rosa, Evert-Jan Baerends, and Koop Lammertsma pp 3558–3567 DOI: 10.1021/ja029135q Supporting Info

Redoxable Nanosheet Crystallites of MnO2 Derived via Delamination of a Layered Manganese Oxide Yoshitomo Omomo, Takayoshi Sasaki, Lianzhou Wang, and Mamoru Watanabe pp 3568–3575 DOI: 10.1021/ja021364p Supporting Info

Single-Molecule Magnets:  Two-Electron Reduced Version of a Mn12 Complex and Environmental Influences on the Magnetization Relaxation of (PPh4)2[Mn12O12(O2CCHCl2)16(H2O)4] Monica Soler, Wolfgang Wernsdorfer, Khalil A. Abboud, John C. Huffman, Ernest R. Davidson, David N. Hendrickson, and George Christou pp 3576–3588 DOI: 10.1021/ja021066s Supporting Info

Suppression of Binary Nucleation in Amorphous La−Fe−Sb Mixtures Joshua R. Williams, Mark B. Johnson, and David C. Johnson pp 3589–3592 DOI: 10.1021/ja0205380

Understanding the Formation of New Clusters of Alkali and Alkaline Earth Metals:  A New Synthetic Approach, Single-Crystal Structures, and Theoretical Calculations Katharina M. Fromm, E. D. Gueneau, G. Bernardinelli, H. Goesmann, J. Weber, M.-J. Mayor-López, P. Boulet, and H. Chermette pp 3593–3604 DOI: 10.1021/ja0205737 Supporting Info

Mechanism of Ketone and Alcohol Formations from Alkenes and Alkynes on the Head-to-head 2-Pyridonato-Bridged cis-Diammineplatinum(III) Dinuclear Complex Nami Saeki, Noriko Nakamura, Takayuki Ishibashi, Moritatsu Arime, Hideo Sekiya, Koji Ishihara, and Kazuko Matsumoto pp 3605–3616 DOI: 10.1021/ja020953s Supporting Info

Covalent Sidewall Functionalization of Single Wall Carbon Nanotubes Rajesh K. Saini, Ivana W. Chiang, Haiqing Peng, R. E. Smalley, W. E. Billups, Robert H. Hauge, and John L. Margrave pp 3617–3621 DOI: 10.1021/ja021167q

Complexity of Coordinative Bonding in Thallium(I) Anthranilates and Salicylates Frank Wiesbrock and Hubert Schmidbaur pp 3622–3630 DOI: 10.1021/ja0287783 Supporting Info

The Influence of Short Strong Hydrogen Bonding on the Structure and the Physicochemical Properties of Alkyl-N-iminodiacetic Acids in Solid State and Aqueous Systems Leif Häggman, Cecilia Lindblad, Hans Oskarsson, Ann-Sofi Ullström, and Ingmar Persson pp 3631–3641 DOI: 10.1021/ja021012i Supporting Info

Modeling the Reaction Mechanisms of the Imide Formation in an N-(o-Carboxybenzoyl)-l-amino Acid Zhijian Wu, Fuqiang Ban, and Russell J. Boyd pp 3642–3648 DOI: 10.1021/ja020700z Supporting Info

DFT Analysis of NMR Scalar Interactions Across the Glycosidic Bond in DNA Markéta L. Munzarová and Vladimír Sklenář pp 3649–3658 DOI: 10.1021/ja028931t Supporting Info

Infrared Spectroscopy of Niobium Oxide Cluster Cations in a Molecular Beam:  Identifying the Cluster Structures André Fielicke, Gerard Meijer, and Gert von Helden pp 3659–3667 DOI: 10.1021/ja0288946 Supporting Info

The Origin of Diastereofacial Control in Allylboration Reactions Using Tartrate Ester Derived Allylboronates:  Attractive Interactions between the Lewis Acids Coordinated Aldehyde Carbonyl Group and an Ester Carbonyl Oxygen [J. Am. Chem. Soc. 2002, 124, 10692−10697].  Benjamin W. Gung, Xiaowen Xue, and William R. Roush p 3668 DOI: 10.1021/ja025125d

Entropic Barriers in Nanoscale Adhesion Studied by Variable Temperature Chemical Force Microscopy  [J. Am. Chem. Soc. 2003, 125 (5), 1356−1362].  Aleksandr Noy, Salvador Zepeda, Christine A. Orme, Yin Yeh, and James J. De Yoreo p 3668 DOI: 10.1021/ja033443m

Origin 7.0 OriginLab Corporation, One Roundhouse Plaza, Northampton, MA 01060. 1-800-969-7720. www.OriginLab.com. Suggested Price $699.00 (Retail, Single User), $529.00 (Educational, Single User). Contact Company for Other Pricing Options. Timothy J. Smith and Keith J. Stevenson p 3669 DOI: 10.1021/ja025326h

Encyclopedia of Nuclear Magnetic Resonance. Volume 9. Advances in NMR Edited by David M. Grant (University of Utah) and Robin K. Harris (University of Durham). John Wiley and Sons:  Chichester. 2002. xviii + 862 pp. $610.00. ISBN 0-471-49082-2. Cecil Dybowski p 3670 DOI: 10.1021/ja025345r

Advances in Lithium-Ion Batteries Edited by Walter A. van Schalkwijk (University of Washington, Seattle) and Bruno Scrosati (University of Rome, “La Sapienza”). Kluwer Academic/Plenum Publishers:  New York. 2002. x + 514 pp. $120.00. ISBN 0-306-47356-9. John B. Kerr pp 3670–3671 DOI: 10.1021/ja025282c

Van Nostrand's Scientific Encyclopedia. Ninth Edi-tion. Volumes 1−2 Edited by Glenn D. Considine (Editor-in-Chief) and Peter H. Kulik (Associate Editor). John Wiley & Sons, Inc.:  New York. 2002. 3936 pp. $350.00. ISBN 0-471-33230-5. p 3671 DOI: 10.1021/ja025344z

Modern Advances in Chromatography. Advances in Biochemical Engineering/Biotechnology, Volume 76 Edited by Ruth Freitag (Ecole Polytechnique Fédérale Lausanne). Springer-Verlag:  Berlin, Heidelberg, New York. xii + 272 pp. $169.00. ISBN 3-540-43042-3. Donald J. Pietrzyk pp 3671–3672 DOI: 10.1021/ja025302a

Issue 13

Do Aviram−Ratner Diodes Rectify? Kurt Stokbro, Jeremy Taylor, and Mads Brandbyge pp 3674–3675 DOI: 10.1021/ja028229x Supporting Info

Probing Cooperative Effects in Bimetallic Clusters:  Indications of C−N Coupling of CH4 and NH3 Mediated by the Cluster Ion PtAu+ in the Gas Phase Konrad Koszinowski, Detlef Schröder, and Helmut Schwarz pp 3676–3677 DOI: 10.1021/ja029791q

Fe2+-Catalyzed Heterolytic RO−OH Bond Cleavage and Substrate Oxidation:  A Functional Synthetic Non-Heme Iron Monooxygenase System Trina L. Foster and John P. Caradonna pp 3678–3679 DOI: 10.1021/ja0286268

Formate, an Active Intermediate for Direct Oxidation of Methanol on Pt Electrode Yan Xia Chen, Atsushi Miki, Shen Ye, Hidetada Sakai, and Masatoshi Osawa pp 3680–3681 DOI: 10.1021/ja029044t

Catalytic Diastereoselective Synthesis of Diquinanes from Acyclic Precursors Jian-Cheng Wang, Sze-Sze Ng, and Michael J. Krische pp 3682–3683 DOI: 10.1021/ja030022w Supporting Info

Enhancing Vapor Sensor Discrimination by Mimicking a Canine Nasal Cavity Flow Environment Shannon E. Stitzel, Deborah R. Stein, and David R. Walt pp 3684–3685 DOI: 10.1021/ja028239y Supporting Info

Sub-Tc Electron Transfer at the Hg-HTSC/Liquid-Electrolyte Interface Stephen J. Green, Nicolas Le-Poul, Peter P. Edwards, and Graeme Peacock pp 3686–3687 DOI: 10.1021/ja034010m

Vanadium Haloperoxidase-Catalyzed Bromination and Cyclization of Terpenes Jayme N. Carter-Franklin, Jon D. Parrish, Richard A. Tschirret-Guth, R. Daniel Little, and Alison Butler pp 3688–3689 DOI: 10.1021/ja029271v Supporting Info

Diastereoselective Addition of Chlorotitanium Enolate of N-Acyl Thiazolidinethione to O-Methyl Oximes:  A Novel, Stereoselective Synthesis of α,β-Disubstituted β-Amino Carbonyl Compounds via Chiral Auxiliary Mediated Azetine Formation Narendra B. Ambhaikar, James P. Snyder, and Dennis C. Liotta pp 3690–3691 DOI: 10.1021/ja029871u Supporting Info

Synthesis of a β-Estradiol-Biotin Chimera that Potently Heterodimerizes Estrogen Receptor and Streptavidin Proteins in a Yeast Three-Hybrid System Stephen L. Hussey, Smita S. Muddana, and Blake R. Peterson pp 3692–3693 DOI: 10.1021/ja0293305 Supporting Info

An Ab Initio Study of the Ligand Field and Charge-Transfer Transitions of Cr(CN)63- and Mo(CN)63- Marc F. A. Hendrickx, Vladimir S. Mironov, Liviu F. Chibotaru, and Arnout Ceulemans pp 3694–3695 DOI: 10.1021/ja029207d Supporting Info

Arrays of Mobile Tethered Vesicles on Supported Lipid Bilayers Chiaki Yoshina-Ishii and Steven G. Boxer pp 3696–3697 DOI: 10.1021/ja029783+ Supporting Info

A Rare η2-Butadienyl Complex from an Alkyne Double Insertion with Double Vinylidene Rearrangement Xingwei Li, Christopher D. Incarvito, and Robert H. Crabtree pp 3698–3699 DOI: 10.1021/ja0297281 Supporting Info

Highly Enantioselective Conjugate Addition of Dialkylzinc Reagents to Acyclic Nitroalkenes:  A Catalytic Route to β2-Amino Acids, Aldehydes, and Alcohols Ate Duursma, Adriaan J. Minnaard, and Ben L. Feringa pp 3700–3701 DOI: 10.1021/ja029817d Supporting Info

Spatially and Temporally Resolved Delivery of Stimuli to Single Cells Bingyun Sun and Daniel T. Chiu pp 3702–3703 DOI: 10.1021/ja029942p Supporting Info

Identification of General Linear Relationships between Activation Energies and Enthalpy Changes for Dissociation Reactions at Surfaces Angelos Michaelides, Z.-P. Liu, C. J. Zhang, Ali Alavi, David A. King, and P. Hu pp 3704–3705 DOI: 10.1021/ja027366r Supporting Info

Synthesis of β-Lactams from a N-Rhenaimine:  Effect of the Transition Metal on the Energetic Profile of the Staudinger Reaction Eva Hevia, Julio Pérez, Víctor Riera, Daniel Miguel, Pablo Campomanes, M. Isabel Menéndez, Tomás L. Sordo, and Santiago García-Granda pp 3706–3707 DOI: 10.1021/ja034070s Supporting Info

Bimetallic Palladium−Platinum Dendrimer-Encapsulated Catalysts Robert W. J. Scott, Abhaya K. Datye, and Richard M. Crooks pp 3708–3709 DOI: 10.1021/ja034176n Supporting Info

Unusual Nondispersive Ambipolar Carrier Transport and High Electron Mobility in Amorphous Ter(9,9-diarylfluorene)s Chung-chih Wu, Tsung-Li Liu, Wen-Yi Hung, Yu-Ting Lin, Ken-Tsung Wong, Ruei-Tang Chen, You-Ming Chen, and Yuh-Yih Chien pp 3710–3711 DOI: 10.1021/ja029630m Supporting Info

Intelligent Colloidal Hybrids via Reversible pH-Induced Complexation of Polyelectrolyte and Silica Nanoparticles Hideharu Mori, Axel H. E. Müller, and Joachim E. Klee pp 3712–3713 DOI: 10.1021/ja0297887 Supporting Info

Discovery of a Potent Small Molecule IL-2 Inhibitor through Fragment Assembly Andrew C. Braisted, Johan D. Oslob, Warren L. Delano, Jennifer Hyde, Robert S. McDowell, Nathan Waal, Chul Yu, Michelle R. Arkin, and Brian C. Raimundo pp 3714–3715 DOI: 10.1021/ja034247i Supporting Info

Ochratoxin A Forms a Carbon-Bonded C8-Deoxyguanosine Nucleoside Adduct:  Implications for C8 Reactivity by a Phenolic Radical Jian Dai, Marcus W. Wright, and Richard A. Manderville pp 3716–3717 DOI: 10.1021/ja034221r Supporting Info

Room-Temperature Stille Cross-Couplings of Alkenyltin Reagents and Functionalized Alkyl Bromides that Possess β Hydrogens Karsten Menzel and Gregory C. Fu pp 3718–3719 DOI: 10.1021/ja0344563 Supporting Info

Tandem N-Alkylation−C-Allylation Reaction of α-Imino Esters with Organoaluminums and Allyltributyltin Yasuki Niwa and Makoto Shimizu pp 3720–3721 DOI: 10.1021/ja029639o Supporting Info

Distance Dependence of Electron Transfer Across Peptides with Different Secondary Structures:  The Role of Peptide Energetics and Electronic Coupling Yeung-gyo K. Shin, Marshall D. Newton, and Stephan S. Isied pp 3722–3732 DOI: 10.1021/ja020358q Supporting Info

Neomycin Binding to Watson−Hoogsteen (W−H) DNA Triplex Groove:  A Model Dev P. Arya, Ljiljana Micovic, I. Charles, R. Lane Coffee, Jr., Bert Willis, and Liang Xue pp 3733–3744 DOI: 10.1021/ja027765m Supporting Info

Effect of Mutation on Enzyme Motion in Dihydrofolate Reductase James B. Watney, Pratul K. Agarwal, and Sharon Hammes-Schiffer pp 3745–3750 DOI: 10.1021/ja028487u

Adsorption of β-Hairpin Peptides on the Surface of Water:  A Neutron Reflection Study Jian R. Lu, Shiamalee Perumal, Evan T. Powers, Jeffery W. Kelly, John R. P. Webster, and Jeff Penfold pp 3751–3757 DOI: 10.1021/ja0292290

PNA for One-Base Differentiating Protection of DNA from Nuclease and Its Use for SNPs Detection Makoto Komiyama, Sheng Ye, Xingguo Liang, Yoji Yamamoto, Takafumi Tomita, Jing-Min Zhou, and Hiroyuki Aburatani pp 3758–3762 DOI: 10.1021/ja0295220 Supporting Info

Kinetics of Unfolding the Human Telomeric DNA Quadruplex Using a PNA Trap Jeremy J. Green, Liming Ying, David Klenerman, and Shankar Balasubramanian pp 3763–3767 DOI: 10.1021/ja029149w

Solid-State 67Zn NMR Spectroscopic Studies and ab Initio Molecular Orbital Calculations on a Synthetic Analogue of Carbonic Anhydrase Andrew S. Lipton, Catherine Bergquist, Gerard Parkin, and Paul D. Ellis pp 3768–3772 DOI: 10.1021/ja021328q

Micelle-Sequestered Dissociation of Cationic DNA−Intercalated Drugs:  Unexpected Surfactant-Induced Rate Enhancement Fredrik Westerlund, L. Marcus Wilhelmsson, Bengt Nordén, and Per Lincoln pp 3773–3779 DOI: 10.1021/ja029243c

Oxygen Equilibrium Properties of Myoglobin Locked in the Liganded and Unliganded Conformations Naoya Shibayama and Satoshi Saigo pp 3780–3783 DOI: 10.1021/ja029237g

Pore Formation by 6-Ketocholestanol in Phospholipid Monolayers and Its Interpretation by a General Nucleation-and-Growth Model Accounting for the Sigmoidal Shape of Voltage-Clamp Curves of Ion Channels Lucia Becucci, Maria Rosa Moncelli, and Rolando Guidelli pp 3784–3792 DOI: 10.1021/ja029428j

Chiral Hetero Diels−Alder Products by Enantioselective and Diastereoselective Zirconium Catalysis. Scope, Limitation, Mechanism, and Application to the Concise Synthesis of (+)-Prelactone C and (+)-9-Deoxygoniopypyrone Yasuhiro Yamashita, Susumu Saito, Haruro Ishitani, and Shū Kobayashi pp 3793–3798 DOI: 10.1021/ja028186k Supporting Info

Tuning the Photoinduced Electron-Transfer Thermodynamics in 1,3,5-Triaryl-2-pyrazoline Fluorophores:  X-ray Structures, Photophysical Characterization, Computational Analysis, and in Vivo Evaluation Christoph J. Fahrni, Liuchun Yang, and Donald G. VanDerveer pp 3799–3812 DOI: 10.1021/ja028266o Supporting Info

Equilibrium O2 Distribution in the Zn2+-Protoporphyrin IX Deoxymyoglobin Mimic:  Application to Oxygen Migration Pathway Analysis Lynn McNaughton, Griselda Hernández, and David M. LeMaster pp 3813–3820 DOI: 10.1021/ja028064s

Detection of Nitroaromatic Explosives Based on Photoluminescent Polymers Containing Metalloles Honglae Sohn, Michael J. Sailor, Douglas Magde, and William C. Trogler pp 3821–3830 DOI: 10.1021/ja021214e

A Versatile Method for Tuning the Chemistry and Size of Nanoscopic Features by Living Free Radical Polymerization Timothy A. von Werne, David S. Germack, Erik C. Hagberg, Valerie V. Sheares, Craig J. Hawker, and Kenneth R. Carter pp 3831–3838 DOI: 10.1021/ja028866n

Model Studies of DNA C5‘ Radicals. Selective Generation and Reactivity of 2‘-Deoxyadenosin-5‘-yl Radical Chryssostomos Chatgilialoglu, Maurizio Guerra, and Quinto G. Mulazzani pp 3839–3848 DOI: 10.1021/ja029374d

Sanglifehrin−Cyclophilin Interaction:  Degradation Work, Synthetic Macrocyclic Analogues, X-ray Crystal Structure, and Binding Data Richard Sedrani, Jörg Kallen, Luisa M. Martin Cabrejas, Charles D. Papageorgiou, Francesco Senia, Stefan Rohrbach, Dieter Wagner, Binh Thai, Anne-Marie Jutzi Eme, Julien France, Lukas Oberer, Grety Rihs, Gerhard Zenke, and Jürgen Wagner pp 3849–3859 DOI: 10.1021/ja021327y Supporting Info

Dynamics of a Triphenylene Discotic Molecule, HAT6, in the Columnar and Isotropic Liquid Phases Fokko M. Mulder, John Stride, Stephen J. Picken, Paul H. J. Kouwer, Mathijs P. de Haas, Laurens D. A. Siebbeles, and Gordon J. Kearley pp 3860–3866 DOI: 10.1021/ja029227f

New Chemical Synthesis of Functionalized Arylzinc Compounds from Aromatic or Thienyl Bromides under Mild Conditions Using a Simple Cobalt Catalyst and Zinc Dust Hyacinthe Fillon, Corinne Gosmini, and Jacques Périchon pp 3867–3870 DOI: 10.1021/ja0289494

Direct Episulfidation of Alkenes and Allenes with Elemental Sulfur and Thiiranes as Sulfur Sources, Catalyzed by Molybdenum Oxo Complexes Waldemar Adam, Rainer M. Bargon, and Wolfdieter A. Schenk pp 3871–3876 DOI: 10.1021/ja029292p Supporting Info

Can the Ebselen Derivatives Catalyze the Isomerization of Peroxynitrite to Nitrate? Djamaladdin G. Musaev, Yurii V. Geletii, Craig L. Hill, and Kimihiko Hirao pp 3877–3888 DOI: 10.1021/ja0286324 Supporting Info

Coordination and Fluorescence of the Intracellular Zn2+ Probe [2-methyl-8-(4-Toluenesulfonamido)-6-quinolyloxy]acetic Acid (Zinquin A) in Ternary Zn2+ Complexes Kym M. Hendrickson, Jason P. Geue, Oska Wyness, Stephen F. Lincoln, and A. David Ward pp 3889–3895 DOI: 10.1021/ja020685y Supporting Info

Two-Level Structured Self-Adaptive Surfaces with Reversibly Tunable Properties Sergiy Minko, Marcus Müller, Michail Motornov, Mirko Nitschke, Karina Grundke, and Manfred Stamm pp 3896–3900 DOI: 10.1021/ja0279693

Luminescent CdSe/CdS Core/Shell Nanocrystals in Dendron Boxes:  Superior Chemical, Photochemical and Thermal Stability Wenzhuo Guo, J. Jack Li, Y. Andrew Wang, and Xiaogang Peng pp 3901–3909 DOI: 10.1021/ja028469c

Synthesis of a Molecular Mo2Fe6S9 Cluster with the Topology of the PN Cluster of Nitrogenase by Rearrangement of an Edge-Bridged Mo2Fe6S8 Double Cubane Yugen Zhang and R. H. Holm pp 3910–3920 DOI: 10.1021/ja0214633 Supporting Info

Mapping the Influence of Molecular Structure on Rates of Electron Transfer Using Direct Measurements of the Electron Spin−Spin Exchange Interaction Aaron S. Lukas, Patrick J. Bushard, Emily A. Weiss, and Michael R. Wasielewski pp 3921–3930 DOI: 10.1021/ja029062a Supporting Info

Protein Side-Chain Motion and Hydration in Proton-Transfer Pathways. Results for Cytochrome P450cam Srabani Taraphder and Gerhard Hummer pp 3931–3940 DOI: 10.1021/ja016860c

The Energy Landscape of Unsolvated Peptides:  The Role of Context in the Stability of Alanine/Glycine Helices Matthew R. Hartings, Brian S. Kinnear, and Martin F. Jarrold pp 3941–3947 DOI: 10.1021/ja020610u

Multistability in a BEDT-TTF Based Molecular Conductor Elena Laukhina, José Vidal-Gancedo, Vladimir Laukhin, Jaume Veciana, Igor Chuev, Vladislava Tkacheva, Klaus Wurst, and Concepció Rovira pp 3948–3953 DOI: 10.1021/ja0280123 Supporting Info

Inverse Sodium Hydride:  A Theoretical Study Agnieszka Sawicka, Piotr Skurski, and Jack Simons pp 3954–3958 DOI: 10.1021/ja021136v

Ab Initio Simulation of Paramagnetic NMR Spectra: the 31P NMR in Oxovanadium Phosphates Sébastien Petit, Serguei A. Borshch, and Vincent Robert pp 3959–3966 DOI: 10.1021/ja0292602 Supporting Info

Molecular and Electronic Structures of Iron Complexes Containing N,S-Coordinated, Open-Shell o-Iminothionebenzosemiquinonate(1−) π Radicals Prasanta Ghosh, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt pp 3967–3979 DOI: 10.1021/ja021409m Supporting Info

Reversible Dioxygen Binding to Hemerythrin Maria Wirstam, Stephen J. Lippard, and Richard A. Friesner pp 3980–3987 DOI: 10.1021/ja017692r

Configurational Entropy and Cooperativity between Ligand Binding and Dimerization in Glycopeptide Antibiotics Sutjano Jusuf, Patrick J. Loll, and Paul H. Axelsen pp 3988–3994 DOI: 10.1021/ja027780r

Calorimetry of Polymer Metallization:  Copper, Calcium, and Chromium on PMDA-ODA Polyimide Richard Murdey and J. Todd Stuckless pp 3995–3998 DOI: 10.1021/ja028829w

Peroxynitrate and Peroxynitrite:  A Complete Basis Set Investigation of Similarities and Differences between These NOx Species Leif P. Olson, Michael D. Bartberger, and K. N. Houk pp 3999–4006 DOI: 10.1021/ja029619m

Issue 14

Lithium Hexamethyldisilazide/Triethylamine-Mediated Ketone Enolization:  Remarkable Rate Accelerations Stemming from a Dimer-Based Mechanism Pinjing Zhao and David B. Collum pp 4008–4009 DOI: 10.1021/ja021284l Supporting Info

A New Route to Alumoxane Gel:  A Versatile Precursor to γ-Alumina and Alumina-Based Ceramic Oxides Kurikka V. P. M. Shafi, Abraham Ulman, Jriuan Lai, Nan-Loh Yang, and Min-Hui Cui pp 4010–4011 DOI: 10.1021/ja0213625 Supporting Info

Hybridization-Based Unquenching of DNA Hairpins on Au Surfaces:  Prototypical “Molecular Beacon” Biosensors Hui Du, Matthew D. Disney, Benjamin L. Miller, and Todd D. Krauss pp 4012–4013 DOI: 10.1021/ja0290781 Supporting Info

Measurement of the Kinetic Isotope Effect for the Oxidation of NADH at a Poly(aniline)-Modified Electrode Philip N. Bartlett and Evelyne Simon pp 4014–4015 DOI: 10.1021/ja028943e Supporting Info

Observation of Fe−H/D Modes by Nuclear Resonant Vibrational Spectroscopy Uwe Bergmann, Wolfgang Sturhahn, Donald E. Linn, Jr., Francis E. Jenney, Jr., Michael W. W. Adams, Kresimir Rupnik, Brian J. Hales, Ercan E. Alp, Aaron Mayse, and Stephen P. Cramer pp 4016–4017 DOI: 10.1021/ja028767+ Supporting Info

Efficient and Practical Ag-Catalyzed Cycloadditions between Arylimines and the Danishefsky Diene Nathan S. Josephsohn, Marc L. Snapper, and Amir H. Hoveyda pp 4018–4019 DOI: 10.1021/ja030033p Supporting Info

The Niobaziridine−Hydride Functional Group:  Synthesis and Divergent Reactivity Joshua S. Figueroa and Christopher C. Cummins pp 4020–4021 DOI: 10.1021/ja028446y Supporting Info

Helix Macrodipole Control of β3-Peptide 14-Helix Stability in Water Scott A. Hart, Adilah B. F. Bahadoor, Erin E. Matthews, Xiaoyan J. Qiu, and Alanna Schepartz pp 4022–4023 DOI: 10.1021/ja029868a Supporting Info

Synthesis of the C59N+ Carbocation. A Monomeric Azafullerene Isoelectronic to C60 Kee-Chan Kim, Frank Hauke, Andreas Hirsch, Peter D. W. Boyd, Elizabeth Carter, Robert S. Armstrong, Peter A. Lay, and Christopher A. Reed pp 4024–4025 DOI: 10.1021/ja034014r Supporting Info

C3v Symmetric Receptors Show High Selectivity and High Affinity for Phosphate Suzanne L. Tobey, Benjamin D. Jones, and Eric V. Anslyn pp 4026–4027 DOI: 10.1021/ja021390n

MgI2-Mediated Ring Expansions of Secondary Methylenecyclopropyl Amides Mark Lautens, Wooseok Han, and Jack Hung-Chang Liu pp 4028–4029 DOI: 10.1021/ja028967l Supporting Info

SmI2 Reduced Thioesters as Synthons of Unstable Acyl Radicals:  Direct Synthesis of Potential Protease Inhibitors via Intermolecular Radical Addition Peter Blakskjær, Bettina Høj, Ditte Riber, and Troels Skrydstrup pp 4030–4031 DOI: 10.1021/ja029662+ Supporting Info

Effect of Magnesium Ions on Oriented Growth of Calcite on Carboxylic Acid Functionalized Self-Assembled Monolayer Yong-Jin Han and Joanna Aizenberg pp 4032–4033 DOI: 10.1021/ja034094z

Control of Ethylene Epoxidation Selectivity by Surface Oxametallacycles Suljo Linic and Mark A. Barteau pp 4034–4035 DOI: 10.1021/ja029076g Supporting Info

Enol Ester as an Olefinic Partner in Enyne Cyclization. A Novel Tandem Cyclization to Stereodefined Bicyclo[3.3.0]octenes Hirokazu Urabe, Daisuke Suzuki, Misa Sasaki, and Fumie Sato pp 4036–4037 DOI: 10.1021/ja034369a Supporting Info

A General Methodology for the Synthesis of Transition Metal Pnictide Nanoparticles from Pnictate Precursors and Its Application to Iron−Phosphorus Phases Kimber L. Stamm, Jayne C. Garno, Gang-yu Liu, and Stephanie L. Brock pp 4038–4039 DOI: 10.1021/ja028180v Supporting Info

Thermal and Photochemical Transformation of Conformational Chirality into Configurational Chirality in the Crystalline State Kenneth C. W. Chong and John R. Scheffer pp 4040–4041 DOI: 10.1021/ja029182i Supporting Info

Prospecting for a 5-Center 4-Electron (C- - -H- - -C- - -H- - -C)+ Bonding Array Dean J. Tantillo and Roald Hoffmann pp 4042–4043 DOI: 10.1021/ja021394s Supporting Info

Hydroxystilbene Isomer-Specific Photoisomerization versus Proton Transfer Frederick D. Lewis and Elizabeth M. Crompton pp 4044–4045 DOI: 10.1021/ja029873e Supporting Info

One-Pot Preparation of Subnanometer-Sized Gold Clusters via Reduction and Stabilization by meso-2,3-Dimercaptosuccinic Acid Yuichi Negishi and Tatsuya Tsukuda pp 4046–4047 DOI: 10.1021/ja0297483 Supporting Info

Total Synthesis of Leustroducsin B Kousei Shimada, Yosuke Kaburagi, and Tohru Fukuyama pp 4048–4049 DOI: 10.1021/ja0340679 Supporting Info

Catalytic Enantioselective Synthesis of Quaternary Stereocenters via Intermolecular C-Acylation of Silyl Ketene Acetals:  Dual Activation of the Electrophile and the Nucleophile Ara H. Mermerian and Gregory C. Fu pp 4050–4051 DOI: 10.1021/ja028554k Supporting Info

Synthesis of the P-Cluster Inorganic Core of Nitrogenases Yasuhiro Ohki, Yusuke Sunada, Masaru Honda, Motomi Katada, and Kazuyuki Tatsumi pp 4052–4053 DOI: 10.1021/ja029383m Supporting Info

New Organolithium Addition Methodology to Diversely Functionalized Indoles Claire M. Coleman and Donal F. O'Shea pp 4054–4055 DOI: 10.1021/ja034283h Supporting Info

Reversing the Role of the Metal−Oxygen π-Bond. Chemoselective Catalytic Reductions with a Rhenium(V)-Dioxo Complex Joshua J. Kennedy-Smith, Kristine A. Nolin, Haluna P. Gunterman, and F. Dean Toste pp 4056–4057 DOI: 10.1021/ja029498q Supporting Info

Conformational Isomerization of Formic Acid by Vibrational Excitation at Energies below the Torsional Barrier Mika Pettersson, Ermelinda M. S. Maçôas, Leonid Khriachtchev, Rui Fausto, and Markku Räsänen pp 4058–4059 DOI: 10.1021/ja0295016

A Photocurable Poly(dimethylsiloxane) Chemistry Designed for Soft Lithographic Molding and Printing in the Nanometer Regime Kyung M. Choi and John A. Rogers pp 4060–4061 DOI: 10.1021/ja029973k Supporting Info

The Barbier−Grignard-Type Carbonyl Alkylation Using Unactivated Alkyl Halides in Water Charlene C. K. Keh, Chunmei Wei, and Chao-Jun Li pp 4062–4063 DOI: 10.1021/ja029649p Supporting Info

Polymer Scrambling:  Macromolecular Radical Crossover Reaction between the Main Chains of Alkoxyamine-Based Dynamic Covalent Polymers Hideyuki Otsuka, Koichiro Aotani, Yuji Higaki, and Atsushi Takahara pp 4064–4065 DOI: 10.1021/ja0340477

Structure of the First Parallel DNA Quadruplex-Drug Complex George R. Clark, Patrycja D. Pytel, Christopher J. Squire, and Stephen Neidle pp 4066–4067 DOI: 10.1021/ja0297988

Diarylurea-Linked Zinc Porphyrin Dimer as a Dual-Mode Artificial Receptor:  Supramolecular Control of Complexation-Facilitated Photoinduced Electron Transfer Shigeyuki Yagi, Masayuki Ezoe, Isamu Yonekura, Toru Takagishi, and Hiroyuki Nakazumi pp 4068–4069 DOI: 10.1021/ja0294717 Supporting Info

Membrane Insertion of a Lipidated Ras Peptide Studied by FTIR, Solid-State NMR, and Neutron Diffraction Spectroscopy Daniel Huster, Alexander Vogel, Catherine Katzka, Holger A. Scheidt, Hans Binder, Silvia Dante, Thomas Gutberlet, Olaf Zschörnig, Herbert Waldmann, and Klaus Arnold pp 4070–4079 DOI: 10.1021/ja0289245

Kinetic Results Implicating a Polar Radical Reaction Pathway in the Rearrangement Catalyzed by α-Methyleneglutarate Mutase Martin Newcomb and Neil Miranda pp 4080–4086 DOI: 10.1021/ja028686d Supporting Info

Discovery of a Potent, Selective Protein Tyrosine Phosphatase 1B Inhibitor Using a Linked-Fragment Strategy Bruce G. Szczepankiewicz, Gang Liu, Philip J. Hajduk, Cele Abad-Zapatero, Zhonghua Pei, Zhili Xin, Thomas H. Lubben, James M. Trevillyan, Michael A. Stashko, Stephen J. Ballaron, Heng Liang, Flora Huang, Charles W. Hutchins, Stephen W. Fesik, and Michael R. Jirousek pp 4087–4096 DOI: 10.1021/ja0296733 Supporting Info

Intermodular Communication in Modular Polyketide Synthases:  Structural and Mutational Analysis of Linker Mediated Protein−Protein Recognition Pawan Kumar, Qing Li, David E. Cane, and Chaitan Khosla pp 4097–4102 DOI: 10.1021/ja0297537 Supporting Info

Coupled Oxidation vs Heme Oxygenation:  Insights from Axial Ligand Mutants of Mitochondrial Cytochrome b5 Ludivina Avila, Hong-wei Huang, Christopher O. Damaso, Shen Lu, Pierre Moënne-Loccoz, and Mario Rivera pp 4103–4110 DOI: 10.1021/ja029311v Supporting Info

Formation of a PNA2−DNA2 Hybrid Quadruplex Bhaskar Datta, Christoph Schmitt, and Bruce A. Armitage pp 4111–4118 DOI: 10.1021/ja028323d Supporting Info

Design of Radical-Resistant Amino Acid Residues:  A Combined Theoretical and Experimental Investigation Anna K. Croft, Christopher J. Easton, and Leo Radom pp 4119–4124 DOI: 10.1021/ja029674v Supporting Info

Impact of Ionic Liquid Physical Properties on Lipase Activity and Stability Joel L. Kaar, Anita M. Jesionowski, Jason A. Berberich, Roger Moulton, and Alan J. Russell pp 4125–4131 DOI: 10.1021/ja028557x

Solvent-Sensitive Dyes to Report Protein Conformational Changes in Living Cells Alexei Toutchkine, Vadim Kraynov, and Klaus Hahn pp 4132–4145 DOI: 10.1021/ja0290882

Anomeric Configuration, Glycosidic Linkage, and the Solution Conformational Entropy of O-Linked Disaccharides André M. Striegel pp 4146–4148 DOI: 10.1021/ja0214173

Isolation and Crystal Structure of a Water-Soluble Iridium Hydride:  A Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media Tsutomu Abura, Seiji Ogo, Yoshihito Watanabe, and Shunichi Fukuzumi pp 4149–4154 DOI: 10.1021/ja0288237 Supporting Info

2,3-Anhydro Sugars in Glycoside Bond Synthesis. Highly Stereoselective Syntheses of Oligosaccharides Containing α- and β-Arabinofuranosyl Linkages Rajendrakumar Reddy Gadikota, Christopher S. Callam, Timothy Wagner, Brian Del Fraino, and Todd L. Lowary pp 4155–4165 DOI: 10.1021/ja029302m Supporting Info

A Highly Enantioselective Phosphabicyclooctane Catalyst for the Kinetic Resolution of Benzylic Alcohols Edwin Vedejs and Olafs Daugulis pp 4166–4173 DOI: 10.1021/ja021224f Supporting Info

1H Fast MAS NMR Studies of Hydrogen-Bonding Interactions in Self-Assembled Monolayers Shane Pawsey, Mark McCormick, Susan De Paul, Robert Graf, Y. S. Lee, Linda Reven, and Hans W. Spiess pp 4174–4184 DOI: 10.1021/ja029008u

A Double Arene Hydroxylation Mediated by Dicopper(II)−Hydroperoxide Species Giuseppe Battaini, Enrico Monzani, Angelo Perotti, Cristina Para, Luigi Casella, Laura Santagostini, Michele Gullotti, Renée Dillinger, Christian Näther, and Felix Tuczek pp 4185–4198 DOI: 10.1021/ja0280776 Supporting Info

Regioselective Coupling of Pentafluorophenyl Substituted Alkynes:  Mechanistic Insight into the Zirconocene Coupling of Alkynes and a Facile Route to Conjugated Polymers Bearing Electron-Withdrawing Pentafluorophenyl Substituents Samuel A. Johnson, Feng-Quan Liu, Min Chul Suh, Stefan Zürcher, Markus Haufe, Shane S. H. Mao, and T. Don Tilley pp 4199–4211 DOI: 10.1021/ja0209161 Supporting Info

Mechanism of the Stille Reaction Catalyzed by Palladium Ligated to Arsine Ligand:  PhPdI(AsPh3)(DMF) Is the Species Reacting with Vinylstannane in DMF Christian Amatore, Ali A. Bahsoun, Anny Jutand, Gilbert Meyer, Alexandre Ndedi Ntepe, and Louis Ricard pp 4212–4222 DOI: 10.1021/ja0204978 Supporting Info

An Experimental and Theoretical Study of the 13C and 31P Chemical Shielding Tensors in Solid O-Phosphorylated Amino Acids Marek J. Potrzebowski, Xavier Assfeld, Katarzyna Ganicz, Sebastian Olejniczak, Alain Cartier, Carole Gardiennet, and Piotr Tekely pp 4223–4232 DOI: 10.1021/ja029840z Supporting Info

2-Aminopyrimidine Directed Self-Assembly of Zinc Porphyrins Containing Bulky 3,5-Di-tert-butylphenyl Groups Teodor Silviu Balaban, Richard Goddard, Myriam Linke-Schaetzel, and Jean-Marie Lehn pp 4233–4239 DOI: 10.1021/ja029548r Supporting Info

Synthesis of 8-Desbromohinckdentine A1 Yahua Liu and William W. McWhorter, Jr. pp 4240–4252 DOI: 10.1021/ja021380m Supporting Info

Mussel Adhesive Protein Mimetic Polymers for the Preparation of Nonfouling Surfaces Jeffrey L. Dalsin, Bi-Huang Hu, Bruce P. Lee, and Phillip B. Messersmith pp 4253–4258 DOI: 10.1021/ja0284963 Supporting Info

From Weak Interactions to Covalent Bonds:  A Continuum in the Complexes of 1,8-Bis(dimethylamino)naphthalene Paul R. Mallinson, Garry T. Smith, Chick C. Wilson, Eugeniusz Grech, and Krzysztof Wozniak pp 4259–4270 DOI: 10.1021/ja029389b Supporting Info

Theoretical Elucidation of Kinetic and Thermodynamic Control of Radical Addition Regioselectivity Andrew G. Leach, Renxiao Wang, G. Erich Wohlhieter, Saeed I. Khan, Michael E. Jung, and K. N. Houk pp 4271–4278 DOI: 10.1021/ja029342q Supporting Info

Sulfonic Acid-Functionalized Gold Nanoparticles:  A Colloid-Bound Catalyst for Soft Lithographic Application on Self-Assembled Monolayers Xue-Mei Li, Vasile Paraschiv, Jurriaan Huskens, and David N. Reinhoudt pp 4279–4284 DOI: 10.1021/ja0271431 Supporting Info

Topochemical Anion Metathesis Routes to the Zr2N2S Phases and the Na2S and ACl Derivatives (A = Na, K, Rb) C. Stoltz, K. Ramesha, S. A. Sirchio, Z. S. Gönen, B. W. Eichhorn, L. Salamanca-Riba, and J. Gopalakrishnan pp 4285–4292 DOI: 10.1021/ja0210650

Syndiospecific Living Propylene Polymerization Catalyzed by Titanium Complexes Having Fluorine-Containing Phenoxy−Imine Chelate Ligands Makoto Mitani, Rieko Furuyama, Jun-ichi Mohri, Junji Saito, Seiichi Ishii, Hiroshi Terao, Takashi Nakano, Hidetsugu Tanaka, and Terunori Fujita pp 4293–4305 DOI: 10.1021/ja029560j Supporting Info

A Fully Integrated High-Throughput Screening Methodology for the Discovery of New Polyolefin Catalysts:  Discovery of a New Class of High Temperature Single-Site Group (IV) Copolymerization Catalysts Thomas R. Boussie, Gary M. Diamond, Christopher Goh, Keith A. Hall, Anne M. LaPointe, Margarete Leclerc, Cheryl Lund, Vince Murphy, James A. W. Shoemaker, Ursula Tracht, Howard Turner, Jessica Zhang, Tetsuo Uno, Robert K. Rosen, and James C. Stevens pp 4306–4317 DOI: 10.1021/ja020868k Supporting Info

A Priori Assessment of the Stereoelectronic Profile of Phosphines and Phosphites Katharine D. Cooney, Thomas R. Cundari, Norris W. Hoffman, Karl A. Pittard, M. Danielle Temple, and Yong Zhao pp 4318–4324 DOI: 10.1021/ja021254i Supporting Info

Synthesis, Spectroscopy, and Catalytic Properties of Cationic Organozirconium Adsorbates on “Super Acidic” Sulfated Alumina. “Single-Site” Heterogeneous Catalysts with Virtually 100 Active Sites Christopher P. Nicholas, Hongsang Ahn, and Tobin J. Marks pp 4325–4331 DOI: 10.1021/ja0212213 Supporting Info

Gold Nanoparticles Deposited on SiO2/Si(100):  Correlation between Size, Electron Structure, and Activity in CO Oxidation László Guczi, Gábor Petö, Andrea Beck, Krisztina Frey, Olga Geszti, György Molnár, and Csaba Daróczi pp 4332–4337 DOI: 10.1021/ja0213928

Oscillatory Growth of Silica Tubes in Chemical Gardens Stephanie Thouvenel-Romans and Oliver Steinbock pp 4338–4341 DOI: 10.1021/ja0298343

An X-ray Diffraction and MAS NMR Study of the Thermal Expansion Properties of Calcined Siliceous Ferrierite Ivor Bull, Philip Lightfoot, Luis A. Villaescusa, Lucy M. Bull, Richard K. B. Gover, John S. O. Evans, and Russell E. Morris pp 4342–4349 DOI: 10.1021/ja0292400 Supporting Info

Reaction of Vinyl Chloride with Late Transition Metal Olefin Polymerization Catalysts Stephen R. Foley, Robert A. Stockland, Jr., Han Shen, and Richard F. Jordan pp 4350–4361 DOI: 10.1021/ja029823+ Supporting Info

Quantitative 2D HSQC (Q-HSQC) via Suppression of J-Dependence of Polarization Transfer in NMR Spectroscopy:  Application to Wood Lignin Sami Heikkinen, Merja M. Toikka, Pirkko T. Karhunen, and Ilkka A. Kilpeläinen pp 4362–4367 DOI: 10.1021/ja029035k

Continuous Symmetry Numbers and Entropy Ernesto Estrada and David Avnir pp 4368–4375 DOI: 10.1021/ja020619w

High-Resolution NMR Correlation Spectra of Disordered Solids Dimitris Sakellariou, Steven P. Brown, Anne Lesage, Sabine Hediger, Michel Bardet, Carlos A. Meriles, Alexander Pines, and Lyndon Emsley pp 4376–4380 DOI: 10.1021/ja0292389

Absorption Spectrum and Solvatochromism of the [Ru(4,4‘-COOH-2,2‘-bpy)2(NCS)2] Molecular Dye by Time Dependent Density Functional Theory Simona Fantacci, Filippo De Angelis, and Annabella Selloni pp 4381–4387 DOI: 10.1021/ja0207910 Supporting Info

ER-BOC Calculations of Crystal Bulk Properties from Smallest-Cluster Models Yun Hang Hu pp 4388–4390 DOI: 10.1021/ja021293u Supporting Info

Lanthanoid Endohedral Metallofullerenols for MRI Contrast Agents Haruhito Kato, Yoko Kanazawa, Masafumi Okumura, Atsushi Taninaka, Takashi Yokawa, and Hisanori Shinohara pp 4391–4397 DOI: 10.1021/ja027555+ Supporting Info

A General Mass Spectrometry-Based Assay for the Quantitation of Protein−Ligand Binding Interactions in Solution [J. Am. Chem. Soc. 2002, 124, 10256−10257]. Kendall D. Powell, Sina Ghaemmaghami, Michael Z. Wang, Liyuan Ma, Terrance G. Oas, and Michael C. Fitzgerald p 4398 DOI: 10.1021/ja0251266

CrossFire Commander V6 MDL Information Systems, Inc. 14600 Catalina Street, San Leandro, CA 94577. www.mdl.com. See Web Site for Pricing Information Song Yu and F. Bartow Culp pp 4399–4400 DOI: 10.1021/ja025305n

Issue 15

Formation of a New Iad Cubic Meso-Structured Silica via Triblock Copolymer-Assisted Synthesis Katarina Flodström, Viveka Alfredsson, and Niklas Källrot pp 4402–4403 DOI: 10.1021/ja029353j

Synthesis of Spiro Diphosphines and Their Application in Asymmetric Hydrogenation of Ketones Jian-Hua Xie, Li-Xin Wang, Yu Fu, Shuo-Fei Zhu, Bao-Min Fan, Hai-Feng Duan, and Qi-Lin Zhou pp 4404–4405 DOI: 10.1021/ja029907i Supporting Info

Direct Sulfonation of Methane to Methanesulfonic Acid with SO2 Using Ca Salts as Promoters Sudip Mukhopadhyay and Alexis T. Bell pp 4406–4407 DOI: 10.1021/ja0281737

Stereoselective Synthesis of α- and β-Glycosylamide Derivatives from Glycopyranosyl Azides via Isoxazoline Intermediates Fehmi Damkaci and Philip DeShong pp 4408–4409 DOI: 10.1021/ja028694u Supporting Info

Characterization of Chlorovinylcobalamin, A Putative Intermediate in Reductive Degradation of Chlorinated Ethylenes Kevin M. McCauley, Scott R. Wilson, and Wilfred A. van der Donk pp 4410–4411 DOI: 10.1021/ja029692c Supporting Info

New Colorimetric and Fluorometric Chemosensor Based on a Cationic Polythiophene Derivative for Iodide-Specific Detection Hoang A. Ho and Mario Leclerc pp 4412–4413 DOI: 10.1021/ja028765p Supporting Info

Controlling the Intrachain Segregation on a Single DNA Molecule Anatoly A. Zinchenko, Vladimir G. Sergeyev, Shizuaki Murata, and Kenichi Yoshikawa pp 4414–4415 DOI: 10.1021/ja028804x Supporting Info

Oligo-2‘-deoxyribonucleotides Containing Uracil Modified at the 5-Position with Linkers Ending with Guanidinium Groups Victoria Roig and Ulysse Asseline pp 4416–4417 DOI: 10.1021/ja029467v Supporting Info

Trimethylamine N-Oxide Stabilizes RNA Tertiary Structure and Attenuates the Denaturating Effects of Urea Thomas C. Gluick and Sushma Yadav pp 4418–4419 DOI: 10.1021/ja0292997 Supporting Info

Directed Denaturation:  Room Temperature and Stoichiometric Unfolding of Cytochrome c by a Metalloporphyrin Dimer Andrew J. Wilson, Kevin Groves, Rishi K. Jain, Hyung Soon Park, and Andrew D. Hamilton pp 4420–4421 DOI: 10.1021/ja028574m Supporting Info

Thiolate-Bridged Nickel−Copper Complexes:  A Binuclear Model for the Catalytic Site of Acetyl Coenzyme A Synthase? Rangan Krishnan, Janis K. Voo, Charles G. Riordan, Lev Zahkarov, and Arnold L. Rheingold pp 4422–4423 DOI: 10.1021/ja0346577 Supporting Info

Dendrimers as Ligands. Formation of a 2:1 Luminescent Complex between a Dendrimer with a 1,4,8,11-Tetraazacyclotetradecane (Cyclam) Core and Zn2+ Christophe Saudan, Vincenzo Balzani, Marius Gorka, Sang-Kyu Lee, Mauro Maestri, Veronica Vicinelli, and Fritz Vögtle pp 4424–4425 DOI: 10.1021/ja029756j

Solubilization of Single-Wall Carbon Nanotubes by Supramolecular Encapsulation of Helical Amylose Oh-Kil Kim, Jongtae Je, Jeffrey W. Baldwin, Steven Kooi, Pehr E. Pehrsson, and Leonard J. Buckley pp 4426–4427 DOI: 10.1021/ja029233b Supporting Info

Monocyclic Boron Carbonyls:  Novel Aromatic Compounds Hai-Shun Wu, Haijun Jiao, Zhi-Xiang Wang, and Paul v. R. Schleyer pp 4428–4429 DOI: 10.1021/ja034605h Supporting Info

Hydrothermal Synthesis of ZnO Nanorods in the Diameter Regime of 50 nm Bin Liu and Hua Chun Zeng pp 4430–4431 DOI: 10.1021/ja0299452 Supporting Info

First Isocyanoazulene and Its Homoleptic Complexes Randall E. Robinson, Thomas C. Holovics, Stephan F. Deplazes, Gerald H. Lushington, Douglas R. Powell, and Mikhail V. Barybin pp 4432–4433 DOI: 10.1021/ja034706f Supporting Info

Rhodopsin Exhibits a Preference for Solvation by Polyunsaturated Docosohexaenoic Acid Scott E. Feller, Klaus Gawrisch, and Thomas B. Woolf pp 4434–4435 DOI: 10.1021/ja0345874

Selective Transport of ATP across a Phospholipid Bilayer by a Molecular Umbrella Vaclav Janout, Bingwen Jing, Irina V. Staina, and Steven L. Regen pp 4436–4437 DOI: 10.1021/ja0291336 Supporting Info

Palladium-Catalyzed Asymmetric Addition of Pronucleophiles to Allenes Barry M. Trost, Christoph Jäkel, and Bernd Plietker pp 4438–4439 DOI: 10.1021/ja029190z Supporting Info

Intramolecular C−H Activation by Inferred Terminal Cobalt Imido Intermediates Sunita Thyagarajan, Daniel T. Shay, Christopher D. Incarvito, Arnold L. Rheingold, and Klaus H. Theopold pp 4440–4441 DOI: 10.1021/ja028267g Supporting Info

Highly Enantioselective, Catalytic Conjugate Addition of Cyanide to α,β-Unsaturated Imides Glenn M. Sammis and Eric N. Jacobsen pp 4442–4443 DOI: 10.1021/ja034635k Supporting Info

Discovery of Aminoglycoside Mimetics by NMR-Based Screening of Escherichia coli A-site RNA Liping Yu, Thorsten K. Oost, Jeffrey M. Schkeryantz, Jianguo Yang, Dave Janowick, and Stephen W. Fesik pp 4444–4450 DOI: 10.1021/ja021354o Supporting Info

A Mesoporous Silica Nanosphere-Based Carrier System with Chemically Removable CdS Nanoparticle Caps for Stimuli-Responsive Controlled Release of Neurotransmitters and Drug Molecules Cheng-Yu Lai, Brian G. Trewyn, Dusan M. Jeftinija, Ksenija Jeftinija, Shu Xu, Srdija Jeftinija, and Victor S.-Y. Lin pp 4451–4459 DOI: 10.1021/ja028650l Supporting Info

Biosynthesis of Riboflavin. Single Turnover Kinetic Analysis of 6,7-Dimethyl-8-ribityllumazine Synthase Nicholas Schramek, Ilka Haase, Markus Fischer, and Adelbert Bacher pp 4460–4466 DOI: 10.1021/ja028226k

Single, Double, and Multiple Double Strand Breaks Induced in DNA by 3−100 eV Electrons Michael A. Huels, Badia Boudaïffa, Pierre Cloutier, Darel Hunting, and Leon Sanche pp 4467–4477 DOI: 10.1021/ja029527x

Gas-Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates:  Mechanistic and Conformational Considerations in Metal-Mediated Wolff Rearrangements Ryan R. Julian, Jeremy A. May, Brian M. Stoltz, and J. L. Beauchamp pp 4478–4486 DOI: 10.1021/ja028337j

Electron Transfer between Two Silyl-Substituted Phenylene Rings:  EPR/ENDOR Spectra, DFT Calculations, and Crystal Structure of the One-Electron Reduction Compound of a Di(m-silylphenylenedisiloxane) Cosmina Dutan, Sylvie Choua, Théo Berclaz, Michel Geoffroy, Nicolas Mézailles, Audrey Moores, Louis Ricard, and Pascal Le Floch pp 4487–4494 DOI: 10.1021/ja0209060 Supporting Info

Radical-Anionic Cyclizations of Enediynes:  Remarkable Effects of Benzannelation and Remote Substituents on Cyclorearomatization Reactions Igor V. Alabugin and Mariappan Manoharan pp 4495–4509 DOI: 10.1021/ja029664u Supporting Info

Direct Evidence of Singlet Molecular Oxygen [O2 (1Δg)] Production in the Reaction of Linoleic Acid Hydroperoxide with Peroxynitrite Sayuri Miyamoto, Glaucia R. Martinez, Ana Paula B. Martins, Marisa H. G. Medeiros, and Paolo Di Mascio pp 4510–4517 DOI: 10.1021/ja029262m

Atom Economy. Palladium-Catalyzed Formation of Coumarins by Addition of Phenols and Alkynoates via a Net C−H Insertion Barry M. Trost, F. Dean Toste, and Kevin Greenman pp 4518–4526 DOI: 10.1021/ja0286573 Supporting Info

Supramolecular Helical Stacking of Metallomesogens Derived from Enantiopure and Racemic Polycatenar Oxazolines Joaquín Barberá, Emma Cavero, Matthias Lehmann, José-Luis Serrano, Teresa Sierra, and Jesús T. Vázquez pp 4527–4533 DOI: 10.1021/ja0294313 Supporting Info

Using Bifunctional Polymers Presenting Vancomycin and Fluorescein Groups To Direct Anti-Fluorescein Antibodies to Self-Assembled Monolayers Presenting d-Alanine-d-Alanine Groups Steven J. Metallo, Ravi S. Kane, R. Erik Holmlin, and George M. Whitesides pp 4534–4540 DOI: 10.1021/ja030045a

Biomimetic Entry to the Sarpagan Family of Indole Alkaloids:  Total Synthesis of (+)-Geissoschizine and (+)-N-Methylvellosimine Alexander Deiters, Kevin Chen, C. Todd Eary, and Stephen F. Martin pp 4541–4550 DOI: 10.1021/ja0296024 Supporting Info

Synthesis of Periodic Hexagonal Surfactant Templated Platinum Tin Tellurides:  Narrow Band Gap Inorganic/Organic Composites Andrew E. Riley and Sarah H. Tolbert pp 4551–4559 DOI: 10.1021/ja0275919

Single Complexation Force of 18-Crown-6 with Ammonium Ion Evaluated by Atomic Force Microscopy Shinpei Kado and Keiichi Kimura pp 4560–4564 DOI: 10.1021/ja029397s

Uranium Tris-aryloxide Derivatives Supported by Triazacyclononane:  Engendering a Reactive Uranium(III) Center with a Single Pocket for Reactivity Ingrid Castro-Rodriguez, Kristian Olsen, Peter Gantzel, and Karsten Meyer pp 4565–4571 DOI: 10.1021/ja028342n Supporting Info

Pressure-Induced Cation Migration and Volume Expansion in the Defect Pyrochlores ANbWO6 (A = NH4+, Rb+, H+, K+) Paris W. Barnes, Patrick M. Woodward, Yongjae Lee, Thomas Vogt, and Joseph A. Hriljac pp 4572–4579 DOI: 10.1021/ja0292187 Supporting Info

The Involvement of Metal-to-CO Charge Transfer and Ligand-Field Excited States in the Spectroscopy and Photochemistry of Mixed-Ligand Metal Carbonyls. A Theoretical and Spectroscopic Study of [W(CO)4(1,2-Ethylenediamine)] and [W(CO)4(N,N‘-Bis-alkyl-1,4-diazabutadiene)] Stanislav Záliš, Ian R. Farrell, and Antonín Vlek, Jr. pp 4580–4592 DOI: 10.1021/ja021022j Supporting Info

Cooperative Binding at Lipid Bilayer Membrane Surfaces Emma L. Doyle, Christopher A. Hunter, Helen C. Phillips, Simon J. Webb, and Nicholas H. Williams pp 4593–4599 DOI: 10.1021/ja021048a Supporting Info

A Sphere-Based Model for the Electrostatics of Globular Proteins Philipp Werner and Amedeo Caflisch pp 4600–4608 DOI: 10.1021/ja021093i

Modeling NMR Parameters by DFT Methods as an Aid to the Conformational Analysis of cis-Fused 7a(8a)-Methyl Octa(hexa)hydrocyclopenta[d][1,3]oxazines and [3,1]benzoxazines Petri Tähtinen, Alessandro Bagno, Karel D. Klika, and Kalevi Pihlaja pp 4609–4618 DOI: 10.1021/ja021237t

Ionic Conductivity in the Crystalline Polymer Electrolytes PEO6:LiXF6, X = P, As, Sb Zlatka Stoeva, Isabelle Martin-Litas, Edward Staunton, Yuri G. Andreev, and Peter G. Bruce pp 4619–4626 DOI: 10.1021/ja029326t

Doping-Controlled Ion Diffusion in Polyelectrolyte Multilayers:  Mass Transport in Reluctant Exchangers Tarek R. Farhat and Joseph B. Schlenoff pp 4627–4636 DOI: 10.1021/ja021448y Supporting Info

Interfacial Electron Transfer in FeII(CN)64-−Sensitized TiO2 Nanoparticles:  A Study of Direct Charge Injection by Electroabsorption Spectroscopy Mikhail Khoudiakov, Alejandro R. Parise, and Bruce S. Brunschwig pp 4637–4642 DOI: 10.1021/ja0299607

α,2-, α,3-, and α,4-Dehydrophenol Radical Anions:  Formation, Reactivity, and Energetics Leading to the Heats of Formation of α,2-, α,3-, and α,4-Oxocyclohexadienylidene Dana R. Reed, Michael C. Hare, Alireza Fattahi, Gyusung Chung, Mark S. Gordon, and Steven R. Kass pp 4643–4651 DOI: 10.1021/ja029571c

A Theoretical Study on the Mechanism of Camphor Hydroxylation by Compound I of Cytochrome P450 Takashi Kamachi and Kazunari Yoshizawa pp 4652–4661 DOI: 10.1021/ja0208862

Inhibition Mode of a Bisubstrate Inhibitor of KDO8P Synthase:  A Frequency-Selective REDOR Solid-State and Solution NMR Characterization Lilia Kaustov, Shifi Kababya, Valery Belakhov, Timor Baasov, Yuval Shoham, and Asher Schmidt pp 4662–4669 DOI: 10.1021/ja028688y

A Non-Covalent Strategy for the Assembly of Supramolecular Photocurrent-Generating Systems. [J. Am. Chem. Soc. 2003, 125, 2838−2839]. Ernesto Soto, John C. MacDonald, Christopher G. F. Cooper, and Grant McGimpsey p 4670 DOI: 10.1021/ja033982r

Issue 16

Glucose Binding Isotope Effects in the Ternary Complex of Brain Hexokinase Demonstrate Partial Relief of Ground-State Destabilization Brett E. Lewis and Vern L. Schramm pp 4672–4673 DOI: 10.1021/ja029852k

Heme Cleavage with Remarkable Ease:  Paramagnetic Intermediates Formed by Aerobic Oxidation of a Meso-Amino-Substituted Iron Porphyrin Heather Kalish, Hon Man Lee, Marilyn M. Olmstead, Lechosław Latos-Grażyński, Sankar Prasad Rath, and Alan L. Balch pp 4674–4675 DOI: 10.1021/ja021253q Supporting Info

Detection of Scalar Couplings Involving 2‘-Hydroxyl Protons Across Hydrogen Bonds in a Frameshifting mRNA Pseudoknot David P. Giedroc, Peter V. Cornish, and Mirko Hennig pp 4676–4677 DOI: 10.1021/ja029286t Supporting Info

The C-Glycosyltransferase UrdGT2 Is Unselective toward d- and l-Configured Nucleotide-Bound Rhodinoses Dirk Hoffmeister, Gerald Dräger, Koji Ichinose, Jürgen Rohr, and Andreas Bechthold pp 4678–4679 DOI: 10.1021/ja029645k Supporting Info

Total Synthesis of Elisabethin A:  Intramolecular Diels−Alder Reaction under Biomimetic Conditions Thilo J. Heckrodt and Johann Mulzer pp 4680–4681 DOI: 10.1021/ja034397t Supporting Info

Iterative Chain Elongation by a Pikromycin Monomodular Polyketide Synthase Brian J. Beck, Courtney C. Aldrich, Robert A. Fecik, Kevin A. Reynolds, and David H. Sherman pp 4682–4683 DOI: 10.1021/ja029974c Supporting Info

Enantioselective Mercuriocyclization of γ-Hydroxy-cis-alkenes Sung Ho Kang and Mihyong Kim pp 4684–4685 DOI: 10.1021/ja029777d Supporting Info

Activity-Based Protein Profiling in Vivo Using a Copper(I)-Catalyzed Azide-Alkyne [3 + 2] Cycloaddition Anna E. Speers, Gregory C. Adam, and Benjamin F. Cravatt pp 4686–4687 DOI: 10.1021/ja034490h Supporting Info

Functionalization on Silica Gel with Allylsilanes. A New Method of Covalent Attachment of Organic Functional Groups on Silica Gel Toyoshi Shimada, Kazuko Aoki, Yo Shinoda, Tomoaki Nakamura, Norihito Tokunaga, Shinji Inagaki, and Tamio Hayashi pp 4688–4689 DOI: 10.1021/ja034691l Supporting Info

Enantioselective Synthesis of α-Alkyl-β,γ-unsaturated Esters through Efficient Cu-Catalyzed Allylic Alkylations Kerry E. Murphy and Amir H. Hoveyda pp 4690–4691 DOI: 10.1021/ja0300618 Supporting Info

Highly Selective Catalyst-Directed Pathways to Dihydropyrroles from Vinyldiazoacetates and Imines Michael P. Doyle, Ming Yan, Wenhao Hu, and Luisa S. Gronenberg pp 4692–4693 DOI: 10.1021/ja029745q Supporting Info

Synthesis and Stability of Reactive Salts of Dodecafluoro-closo-dodecaborate(2−) Sergei V. Ivanov, Susie M. Miller, Oren P. Anderson, Konstantin A. Solntsev, and Steven H. Strauss pp 4694–4695 DOI: 10.1021/ja0296374 Supporting Info

Fluorine-Free Organoxenon Chemistry:  HXeCCH, HXeCC, and HXeCCXeH Leonid Khriachtchev, Hanna Tanskanen, Jan Lundell, Mika Pettersson, Harri Kiljunen, and Markku Räsänen pp 4696–4697 DOI: 10.1021/ja034485d

Experimental Evidence for the Formation of HXeCCH:  The First Hydrocarbon with an Inserted Rare-Gas Atom Vladimir I. Feldman, Fedor F. Sukhov, Aleksei Yu. Orlov, and Irina V. Tyulpina pp 4698–4699 DOI: 10.1021/ja034585j

Multifunctional Gold Nanoparticle−Peptide Complexes for Nuclear Targeting Alexander G. Tkachenko, Huan Xie, Donna Coleman, Wilhelm Glomm, Joseph Ryan, Miles F. Anderson, Stefan Franzen, and Daniel L. Feldheim pp 4700–4701 DOI: 10.1021/ja0296935 Supporting Info

The Synthesis of Functionalized Nanoscale Molecular Rods of Defined Length Christopher G. Levins and Christian E. Schafmeister pp 4702–4703 DOI: 10.1021/ja0293958 Supporting Info

Highly Enantioselective Quinoline Synthesis via Ene-type Cyclization of 1,7-Enynes Catalyzed by a Cationic BINAP−Palladium(II) Complex Manabu Hatano and Koichi Mikami pp 4704–4705 DOI: 10.1021/ja0292748 Supporting Info

Molecular Dynamics Study of Gas Hydrate Formation Changman Moon, Paul C. Taylor, and P. Mark Rodger pp 4706–4707 DOI: 10.1021/ja028537v Supporting Info

A Fluorogenic Dye Activated by the Staudinger Ligation George A. Lemieux, Christopher L. de Graffenried, and Carolyn R. Bertozzi pp 4708–4709 DOI: 10.1021/ja029013y Supporting Info

Posttranslational Hydroxylation of Human Phenylalanine Hydroxylase Is a Novel Example of Enzyme Self-Repair within the Second Coordination Sphere of Catalytic Iron Sylvia Daoud Kinzie, Mario Thevis, Khanh Ngo, Julian Whitelegge, Joseph A. Loo, and Mahdi M. Abu-Omar pp 4710–4711 DOI: 10.1021/ja034452y Supporting Info

anti-Selective Direct Catalytic Asymmetric Mannich-type Reaction of Hydroxyketone Providing β-Amino Alcohols Shigeki Matsunaga, Naoya Kumagai, Shinji Harada, and Masakatsu Shibasaki pp 4712–4713 DOI: 10.1021/ja034787f Supporting Info

Selective Ortho C−H Activation of Haloarenes by an Ir(I) System Eyal Ben-Ari, Mark Gandelman, Haim Rozenberg, Linda J. W. Shimon, and David Milstein pp 4714–4715 DOI: 10.1021/ja028362p Supporting Info

An Expedient Phosphine-Catalyzed [4 + 2] Annulation:  Synthesis of Highly Functionalized Tetrahydropyridines Xue-Feng Zhu, Jie Lan, and Ohyun Kwon pp 4716–4717 DOI: 10.1021/ja0344009 Supporting Info

Preparation of Graded Materials by Laterally Controlled Template Synthesis Tali Sehayek, Alexander Vaskevich, and Israel Rubinstein pp 4718–4719 DOI: 10.1021/ja029877j Supporting Info

Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine Masahiro Murakami and Seiji Hori pp 4720–4721 DOI: 10.1021/ja029829z Supporting Info

Long-Range Jump versus Stepwise Hops:  Magnetic Field Effects on the Charge-Transfer Fluorescence from Photoconductive Polymer Films Fuyuki Ito, Tadaaki Ikoma, Kimio Akiyama, Yasuhiro Kobori, and Shozo Tero-Kubota pp 4722–4723 DOI: 10.1021/ja029443o Supporting Info

One-Step Nanocasting Synthesis of Highly Ordered Single Crystalline Indium Oxide Nanowire Arrays from Mesostructured Frameworks Haifeng Yang, Qihui Shi, Bozhi Tian, Qingyi Lu, Feng Gao, Songhai Xie, Jie Fan, Chengzhong Yu, Bo Tu, and Dongyuan Zhao pp 4724–4725 DOI: 10.1021/ja034005i Supporting Info

Structure of Subtilosin A, an Antimicrobial Peptide from Bacillus subtilis with Unusual Posttranslational Modifications Linking Cysteine Sulfurs to α-Carbons of Phenylalanine and Threonine Karen Kawulka, Tara Sprules, Ryan T. McKay, Pascal Mercier, Christopher M. Diaper, Peter Zuber, and John C. Vederas pp 4726–4727 DOI: 10.1021/ja029654t Supporting Info

Dendritic Nanowire Ultraviolet Laser Array Haoquan Yan, Rongrui He, Justin Johnson, Matthew Law, Richard J. Saykally, and Peidong Yang pp 4728–4729 DOI: 10.1021/ja034327m

Molecular Monolayer-Mediated Control over Semiconductor Surfaces:  Evidence for Molecular Depolarization of Silane Monolayers on Si/SiOx Olga Gershevitz, Chaim N. Sukenik, Jamal Ghabboun, and David Cahen pp 4730–4731 DOI: 10.1021/ja029529h Supporting Info

Selective Recognition of G-Quadruplex Telomeric DNA by a Bis(quinacridine) Macrocycle Marie-Paule Teulade-Fichou, Carolina Carrasco, Lionel Guittat, Christian Bailly, Patrizia Alberti, Jean-Louis Mergny, Arnaud David, Jean-Marie Lehn, and W. David Wilson pp 4732–4740 DOI: 10.1021/ja021299j

Parallel Synthesis of H-pin Polyamides by Alkene Metathesis on Solid Phase Bogdan Olenyuk, Cristian Jitianu, and Peter B. Dervan pp 4741–4751 DOI: 10.1021/ja0213221 Supporting Info

Inhibition of Transcription at a Coding Sequence by Alkylating Polyamide Takanori Oyoshi, Wakana Kawakami, Akihiko Narita, Toshikazu Bando, and Hiroshi Sugiyama pp 4752–4754 DOI: 10.1021/ja029196o

Spectroscopic and Photophysical Properties of Hexanuclear Rhenium(III) Chalcogenide Clusters Thomas G. Gray, Christina M. Rudzinski, Emily E. Meyer, R. H. Holm, and Daniel G. Nocera pp 4755–4770 DOI: 10.1021/ja0286371 Supporting Info

Structure-Switching Signaling Aptamers Razvan Nutiu and Yingfu Li pp 4771–4778 DOI: 10.1021/ja028962o Supporting Info

Investigations of Bivalent Antibody Binding on Fluid-Supported Phospholipid Membranes:  The Effect of Hapten Density Tinglu Yang, Olga K. Baryshnikova, Hanbin Mao, Matthew A. Holden, and Paul S. Cremer pp 4779–4784 DOI: 10.1021/ja029469f Supporting Info

Binding Equilibrium Isotope Effects for Glucose at the Catalytic Domain of Human Brain Hexokinase Brett E. Lewis and Vern L. Schramm pp 4785–4798 DOI: 10.1021/ja0298242 Supporting Info

E Stereoregular 1,1 and 1,3 Constitutional Units from 1,3-Butadiene in Copolymerizations Catalyzed by a Highly Hindered C2 Symmetric Metallocene Pasquale Longo, Stefania Pragliola, Giuseppe Milano, and Gaetano Guerra pp 4799–4803 DOI: 10.1021/ja028462v Supporting Info

Palladium-Catalyzed Carbonylative Cyclization of Unsaturated Aryl Iodides and Dienyl Triflates, Iodides, and Bromides to Indanones and 2-Cyclopentenones Steve V. Gagnier and Richard C. Larock pp 4804–4807 DOI: 10.1021/ja0212009 Supporting Info

Mechanisms of Electron-Transfer Oxidation of NADH Analogues and Chemiluminescence. Detection of the Keto and Enol Radical Cations Shunichi Fukuzumi, Osamu Inada, and Tomoyoshi Suenobu pp 4808–4816 DOI: 10.1021/ja029623y Supporting Info

Highly Regio- and Stereoselective Halohydroxylation Reaction of 1,2-Allenyl Phenyl Sulfoxides. Reaction Scope, Mechanism, and the Corresponding Pd- or Ni-Catalyzed Selective Coupling Reactions Shengming Ma, Hongjun Ren, and Qi Wei pp 4817–4830 DOI: 10.1021/ja034039q Supporting Info

Self-Sorting:  The Exception or the Rule? Anxin Wu and Lyle Isaacs pp 4831–4835 DOI: 10.1021/ja028913b Supporting Info

Unified Mechanistic Concept of Electrophilic Aromatic Nitration:  Convergence of Computational Results and Experimental Data Pierre M. Esteves, José Walkimar de M. Carneiro, Sheila P. Cardoso, André G. H. Barbosa, Kenneth K. Laali, Golam Rasul, G. K. Surya Prakash, and George A. Olah pp 4836–4849 DOI: 10.1021/ja021307w Supporting Info

Dynamics and Energetics of Single-Step Hole Transport in DNA Hairpins Frederick D. Lewis, Jianqin Liu, Xiaobing Zuo, Ryan T. Hayes, and Michael R. Wasielewski pp 4850–4861 DOI: 10.1021/ja029390a

Photoinduced Electron Transfer at Liquid|Liquid Interfaces:  Dynamics of the Heterogeneous Photoreduction of Quinones by Self-Assembled Porphyrin Ion Pairs Nicolas Eugster, David J. Fermín, and Hubert H. Girault pp 4862–4869 DOI: 10.1021/ja029589n

A Folded, Secondary Structure in Step-Growth Oligomers from Covalently Linked, Crowded Aromatics Wei Zhang, Dana Horoszewski, John Decatur, and Colin Nuckolls pp 4870–4873 DOI: 10.1021/ja034001d Supporting Info

A Novel Methodology for the Synthesis of Cyclic Carbonates Based on the Palladium-Catalyzed Cascade Reaction of 4-Methoxycarbonyloxy-2-butyn-1-ols with Phenols, Involving a Novel Carbon Dioxide Elimination-Fixation Process Masahiro Yoshida, Mika Fujita, Tooru Ishii, and Masataka Ihara pp 4874–4881 DOI: 10.1021/ja0340681 Supporting Info

Porphyrin and Tetrabenzoporphyrin Dendrimers:  Tunable Membrane-Impermeable Fluorescent pH Nanosensors Olga Finikova, Alexander Galkin, Vladimir Rozhkov, Maria Cordero, Cecilia Hägerhäll, and Sergei Vinogradov pp 4882–4893 DOI: 10.1021/ja0341687

Electrostatic Bubbles and Supramolecular Assistance of Photosensitization by Carboxylated Ru(II) Complexes Pierre G. Potvin, Phuong Uyen Luyen, and Jan Bräckow pp 4894–4906 DOI: 10.1021/ja028671f Supporting Info

Conformational Change in an Isolated Single Synthetic Polymer Chain on a Mica Surface Observed by Atomic Force Microscopy Jiro Kumaki and Takeji Hashimoto pp 4907–4917 DOI: 10.1021/ja0290429

Mechanistic Studies of the Tellurium(II)/Tellurium(IV) Redox Cycle in Thiol Peroxidase-like Reactions of Diorganotellurides in Methanol Youngjae You, Khalid Ahsan, and Michael R. Detty pp 4918–4927 DOI: 10.1021/ja029590m Supporting Info

Competition and Selectivity in the Reaction of Nitriles on Ge(100)−2×1 Michael A. Filler, Collin Mui, Charles B. Musgrave, and Stacey F. Bent pp 4928–4936 DOI: 10.1021/ja027887e

A Theoretical Study of the Large Hg−Hg Spin−Spin Coupling Constants in Hg22+, Hg32+, and Hg22+−Crown Ether Complexes Jochen Autschbach, Ciprian D. Igna, and Tom Ziegler pp 4937–4942 DOI: 10.1021/ja028721g

Anomalous NMR Behavior of Meso Compounds with Remote Stereogenic Centers on Addition of Chiral Shift Reagent or Chiral Solvating Agent Serap Beşli, Simon J. Coles, David B. Davies, Robert J. Eaton, Michael B. Hursthouse, Adem Kılıç, Robert A. Shaw, Gönül Yenilmez Çiftçi, and Serkan Yeşilot pp 4943–4950 DOI: 10.1021/ja028871r Supporting Info

Long Tethers Binding Redox Centers to Polymer Backbones Enhance Electron Transport in Enzyme “Wiring” Hydrogels Fei Mao, Nicolas Mano, and Adam Heller pp 4951–4957 DOI: 10.1021/ja029510e Supporting Info

Total Synthesis of A-315675:  A Potent Inhibitor of Influenza Neuraminidase. [J. Am. Chem. Soc. 2002, 124 (17), 4716−4721]. Stephen Hanessian, Malken Bayrakdarian, and Xuehong Luo p 4958 DOI: 10.1021/ja0334457

Issue 17

Expanding the DNA-Recognition Repertoire for Zinc Finger Proteins beyond 20 Amino Acids Derek Jantz and Jeremy M. Berg pp 4960–4961 DOI: 10.1021/ja029671i Supporting Info

Bis(tri-tert-butylsilyl)silylene:  Triplet Ground State Silylene Akira Sekiguchi, Takashi Tanaka, Masaaki Ichinohe, Kimio Akiyama, and Shozo Tero-Kubota pp 4962–4963 DOI: 10.1021/ja020929e Supporting Info

Ancillary Ligand Effect on Single-Site Styrene Polymerization:  Isospecificity of Group 4 Metal Bis(phenolate) Catalysts Carmine Capacchione, Antonio Proto, Henner Ebeling, Rolf Mülhaupt, Klaus Möller, Thomas P. Spaniol, and Jun Okuda pp 4964–4965 DOI: 10.1021/ja029968g Supporting Info

Self-Assembly of Microporous Manganese Oxide Octahedral Molecular Sieve Hexagonal Flakes into Mesoporous Hollow Nanospheres Jikang Yuan, Kate Laubernds, Qiuhua Zhang, and Steven L. Suib pp 4966–4967 DOI: 10.1021/ja0294459

Molecular Structure and Conformation of Dinitrosylheme Jeanet Conradie, Tebikie Wondimagegn, and Abhik Ghosh pp 4968–4969 DOI: 10.1021/ja021439p Supporting Info

Intramolecular [4 + 2] Cycloadditions of Iminoacetonitriles:  A New Class of Azadienophiles for Hetero Diels−Alder Reactions David T. Amos, Adam R. Renslo, and Rick L. Danheiser pp 4970–4971 DOI: 10.1021/ja034629o Supporting Info

Clear Distinction of Purine Bases on the Complementary Strand by a Fluorescence Change of a Novel Fluorescent Nucleoside Akimitsu Okamoto, Kazuki Tainaka, and Isao Saito pp 4972–4973 DOI: 10.1021/ja034090u Supporting Info

Loop-Contraction Mutagenesis of a Type 1 Copper Site Sachiko Yanagisawa and Christopher Dennison pp 4974–4975 DOI: 10.1021/ja0345827 Supporting Info

General Synthesis of Mesoporous Spheres of Metal Oxides and Phosphates Angang Dong, Nan Ren, Yi Tang, Yajun Wang, Yahong Zhang, Weiming Hua, and Zi Gao pp 4976–4977 DOI: 10.1021/ja029964b Supporting Info

A Domino Copper-Catalyzed C−O Coupling−Claisen Rearrangement Process Gero Nordmann and Stephen L. Buchwald pp 4978–4979 DOI: 10.1021/ja034809y Supporting Info

Etchant Solutions for the Removal of Cu(0) in a Supercritical CO2-Based “Dry” Chemical Mechanical Planarization Process for Device Fabrication Carol A. Bessel, Ginger M. Denison, Joseph M. DeSimone, James DeYoung, Stephen Gross, Cynthia K. Schauer, and Pamela M. Visintin pp 4980–4981 DOI: 10.1021/ja034091m

Selected-Control Synthesis of PbO2 and Pb3O4 Single-Crystalline Nanorods Minhua Cao, Changwen Hu, Ge Peng, Yanjuan Qi, and Enbo Wang pp 4982–4983 DOI: 10.1021/ja029620l

Two-Dimensional Homochiral Manganese(II)-Azido Frameworks Incorporating an Achiral Ligand:  Partial Spontaneous Resolution and Weak Ferromagnetism En-Qing Gao, Shi-Qiang Bai, Zhe-Ming Wang, and Chun-Hua Yan pp 4984–4985 DOI: 10.1021/ja034129v Supporting Info

Electrochemically Induced Surface-Enhanced Infrared Difference Absorption (SEIDA) Spectroscopy of a Protein Monolayer Kenichi Ataka and Joachim Heberle pp 4986–4987 DOI: 10.1021/ja0346532

Coenzyme B Induced Coordination of Coenzyme M via Its Thiol Group to Ni(I) of F430 in Active Methyl-Coenzyme M Reductase Cinzia Finazzo, Jeffrey Harmer, Carsten Bauer, Bernhard Jaun, Evert C. Duin, Felix Mahlert, Meike Goenrich, Rudolf K. Thauer, Sabine Van Doorslaer, and Arthur Schweiger pp 4988–4989 DOI: 10.1021/ja0344314 Supporting Info

A Novel and General α-Regioselective and Highly Enantioselective Prenylation of Aldehydes Hin-Soon Cheng and Teck-Peng Loh pp 4990–4991 DOI: 10.1021/ja029700p Supporting Info

A Gene-Expression Inhibitor that Targets an α-Helix-Mediated Protein Interaction Shinichi Asada, Yongmun Choi, and Motonari Uesugi pp 4992–4993 DOI: 10.1021/ja0292703 Supporting Info

Bimetallo-Radical Carbon−Hydrogen Bond Activation of Methanol and Methane Weihong Cui, X. Peter Zhang, and Bradford B. Wayland pp 4994–4995 DOI: 10.1021/ja034494m Supporting Info

Small Molecules That Mimic the Thiol-Triggered Alkylating Properties Seen in the Natural Product Leinamycin Tonika Chatterji, Murat Kizil, Kripa Keerthi, Goutam Chowdhury, Tomás Pospísil, and Kent S. Gates pp 4996–4997 DOI: 10.1021/ja029169y Supporting Info

Nucleic Acid Base Pair Dynamics:  The Impact of Sequence and Structure Using Free-Energy Calculations Emmanuel Giudice and Richard Lavery pp 4998–4999 DOI: 10.1021/ja034095r

Functional Reassembly of a Split PH Domain Kenji Sugimoto, Yasuo Mori, Keisuke Makino, Katsutoshi Ohkubo, and Takashi Morii pp 5000–5004 DOI: 10.1021/ja029477w Supporting Info

Pulsed High-Frequency EPR Study on the Location of Carotenoid and Chlorophyll Cation Radicals in Photosystem II K. V. Lakshmi, Oleg G. Poluektov, Michael J. Reifler, Arlene M. Wagner, Marion C. Thurnauer, and Gary W. Brudvig pp 5005–5014 DOI: 10.1021/ja0295671

Nitric Oxide-Releasing Fumed Silica Particles:  Synthesis, Characterization, and Biomedical Application Huiping Zhang, Gail M. Annich, Judiann Miskulin, Kelly Stankiewicz, Kathryn Osterholzer, Scott I. Merz, Robert H. Bartlett, and Mark E. Meyerhoff pp 5015–5024 DOI: 10.1021/ja0291538 Supporting Info

Frozen Density Functional Free Energy Simulations of Redox Proteins:  Computational Studies of the Reduction Potential of Plastocyanin and Rusticyanin Mats H. M. Olsson, Gongyi Hong, and Arieh Warshel pp 5025–5039 DOI: 10.1021/ja0212157

Intermolecular Interactions in π-Stacked Conjugated Molecules. Synthesis, Structure, and Spectral Characterization of Alkyl Bithiazole Oligomers Amy B. Koren, M. David Curtis, Anthony H. Francis, and Jeff W. Kampf pp 5040–5050 DOI: 10.1021/ja029216m Supporting Info

Chiral Molecular Assemblies from a Novel Achiral Amphiphilic 2-(Heptadecyl) Naphtha[2,3]imidazole through Interfacial Coordination Jing Yuan and Minghua Liu pp 5051–5056 DOI: 10.1021/ja0288486

Comparison of Nanotube Structures Constructed from α-, β-, and γ-Cyclodextrins by Potential-Controlled Adsorption Akihiro Ohira, Masayo Sakata, Isao Taniguchi, Chuichi Hirayama, and Masashi Kunitake pp 5057–5065 DOI: 10.1021/ja021351b

Rational Design of a DNA Wire Possessing an Extremely High Hole Transport Ability Akimitsu Okamoto, Kazuo Tanaka, and Isao Saito pp 5066–5071 DOI: 10.1021/ja0294008 Supporting Info

Origins of Inward Torquoselectivity by Silyl Groups and Other σ-Acceptors in Electrocyclic Reactions of Cyclobutenes Patrick S. Lee, Xiyun Zhang, and K. N. Houk pp 5072–5079 DOI: 10.1021/ja0287635 Supporting Info

Formation Process of Cyclodextrin Necklace−Analysis of Hydrogen Bonding on a Molecular Level Koji Miyake, Satoshi Yasuda, Akira Harada, Jun Sumaoka, Makoto Komiyama, and Hidemi Shigekawa pp 5080–5085 DOI: 10.1021/ja026224u

Evaluation of Multivalent Dendrimers Based on Melamine:  Kinetics of Thiol−Disulfide Exchange Depends on the Structure of the Dendrimer Wen Zhang, Shane E. Tichy, Lisa M. Pérez, Gheorghe C. Maria, Paul A. Lindahl, and Eric E. Simanek pp 5086–5094 DOI: 10.1021/ja0210906 Supporting Info

Total Synthesis of the Quinone Epoxide Dimer (+)-Torreyanic Acid:  Application of a Biomimetic Oxidation/Electrocyclization/Diels−Alder Dimerization Cascade1 Chaomin Li, Richard P. Johnson, and John A. Porco, Jr. pp 5095–5106 DOI: 10.1021/ja021396c Supporting Info

Photochemistry of Dianthrylsilanes:  A Study of σ,π*-Interaction Ding-Djung H. Yang, Nien-chu C. Yang, Ian M. Steele, Hui Li, Ying-Zhong Ma, and Graham R. Fleming, pp 5107–5110 DOI: 10.1021/ja020403u Supporting Info

Mechanism of cis-Enamide Formation from N-(α-Silyl)allyl Amides:  Synthetic Potential of Stepwise Dyotropic Rearrangements Xiyun Zhang, K. N. Houk, Songnian Lin, and Samuel J. Danishefsky pp 5111–5114 DOI: 10.1021/ja029576+ Supporting Info

Hydrogen Bond Directed Highly Regioselective Palladium-Catalyzed Allylic Substitution Gregory R. Cook, Hui Yu, S. Sankaranarayanan, and P. Sathya Shanker pp 5115–5120 DOI: 10.1021/ja028426w Supporting Info

Synthesis and Characterization of Gels from Polyallylamine and Carbon Dioxide as Gellant Emiliano Carretti, Luigi Dei, Piero Baglioni, and Richard G. Weiss pp 5121–5129 DOI: 10.1021/ja034399d Supporting Info

Modeling the Stereoselectivity of the β-Amino Alcohol-Promoted Addition of Dialkylzinc to Aldehydes Torben Rasmussen and Per-Ola Norrby pp 5130–5138 DOI: 10.1021/ja0292952 Supporting Info

Design of N-Spiro C2-Symmetric Chiral Quaternary Ammonium Bromides as Novel Chiral Phase-Transfer Catalysts:  Synthesis and Application to Practical Asymmetric Synthesis of α-Amino Acids Takashi Ooi, Minoru Kameda, and Keiji Maruoka pp 5139–5151 DOI: 10.1021/ja021244h Supporting Info

Self-Assembly of a Tripodal Pseudorotaxane on the Surface of a Titanium Dioxide Nanoparticle Brenda Long, Kirill Nikitin, and Donald Fitzmaurice pp 5152–5160 DOI: 10.1021/ja028870z

Lanthanum Strontium Manganite/Yttria-Stabilized Zirconia Nanocomposites Derived from a Surfactant Assisted, Co-assembled Mesoporous Phase Marc Mamak, Gabriella S. Métraux, Srebri Petrov, Neil Coombs, Geoffrey A. Ozin, and M. A. Green pp 5161–5175 DOI: 10.1021/ja027881p

Nanometer-Resolved Interfacial Fluidity Richard C. Bell, Hanfu Wang, Martin J. Iedema, and James P. Cowin pp 5176–5185 DOI: 10.1021/ja0291437

Resonance Raman Investigation of Equatorial Ligand Donor Effects on the Cu2O22+ Core in End-On and Side-On μ-Peroxo-Dicopper(II) and Bis-μ-oxo-Dicopper(III) Complexes Mark J. Henson, Michael A. Vance, Christiana Xin Zhang, Hong-Chang Liang, Kenneth D. Karlin, and Edward I. Solomon pp 5186–5192 DOI: 10.1021/ja0276366 Supporting Info

Coordination-Driven Self-Assembly of Predesigned Supramolecular Triangles Yury K. Kryschenko, S. Russell Seidel, Atta M. Arif, and Peter J. Stang pp 5193–5198 DOI: 10.1021/ja030018k Supporting Info

Conformation and Luminescence of Isolated Molecular Semiconductor Molecules Melissa A. Summers, Paul R. Kemper, John E. Bushnell, Matthew R. Robinson, Guillermo C. Bazan, Michael T. Bowers, and Steven K. Buratto pp 5199–5203 DOI: 10.1021/ja028241p

Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes William J. Evans, Jeremy M. Perotti, Jason C. Brady, and Joseph W. Ziller pp 5204–5212 DOI: 10.1021/ja020957x Supporting Info

Simultaneous Direct Electrochemiluminescence and Catalytic Voltammetry Detection of DNA in Ultrathin Films Lynn Dennany, Robert J. Forster, and James F. Rusling pp 5213–5218 DOI: 10.1021/ja0296529

Quantitative Analysis and Characterization of DNA Immobilized on Gold Dmitri Y. Petrovykh, Hiromi Kimura-Suda, Lloyd J. Whitman, and Michael J. Tarlov pp 5219–5226 DOI: 10.1021/ja029450c

Great Structural Variety of Complexes in Copper(II)−Oligoglycine Systems:  Microspeciation and Coordination Modes as Studied by the Two-Dimensional Simulation of Electron Paramagnetic Resonance Spectra Nóra Veronika Nagy, Terézia Szabó-Plánka, Antal Rockenbauer, Gábor Peintler, István Nagypál, and László Korecz pp 5227–5235 DOI: 10.1021/ja021245+ Supporting Info

Absolute Rate Calculations for Atom Abstractions by Radicals:  Energetic, Structural and Electronic Factors Luis G. Arnaut, Alberto A. C. C. Pais, Sebastião J. Formosinho, and Monica Barroso pp 5236–5246 DOI: 10.1021/ja029298e Supporting Info

Issue 18

Alternating DNA and π-Conjugated Sequences. Thermophilic Foldable Polymers Wei Wang, Wei Wan, Hong-Hui Zhou, Shuqiang Niu, and Alexander D. Q. Li pp 5248–5249 DOI: 10.1021/ja0341900 Supporting Info

Efficient Epoxidation of Electron-Deficient Olefins with a Cationic Manganese Complex Andrew Murphy, Geraud Dubois, and T. D. P. Stack pp 5250–5251 DOI: 10.1021/ja029962r Supporting Info

Quantification of Protein−Ligand Interactions by Mass Spectrometry, Titration, and H/D Exchange:  PLIMSTEX Mei M. Zhu, Don L. Rempel, Zhaohui Du, and Michael L. Gross pp 5252–5253 DOI: 10.1021/ja029460d Supporting Info

Fabrication of Silica Nanotube Arrays from Vertical Silicon Nanowire Templates Rong Fan, Yiying Wu, Deyu Li, Min Yue, Arun Majumdar, and Peidong Yang pp 5254–5255 DOI: 10.1021/ja034163+ Supporting Info

Metallocene Polymerization Catalyst Ion-Pair Aggregation by Cryoscopy and Pulsed Field Gradient Spin−Echo NMR Diffusion Measurements Nicholas G. Stahl, Cristiano Zuccaccia, Tryg R. Jensen, and Tobin J. Marks pp 5256–5257 DOI: 10.1021/ja0346375 Supporting Info

Excitation Energy Transfer in Branched Dendritic Macromolecules at Low (4 K) Temperatures Mahinda I. Ranasinghe, Ying Wang, and Theodore Goodson, III pp 5258–5259 DOI: 10.1021/ja029242k Supporting Info

Carboxylate-Substituted Radicals from Phenylselenide Derivatives. Designs on Models for Coenzyme B12-Dependent Enzyme-Catalyzed Rearrangements Neil Miranda, Pierre Daublain, John H. Horner, and Martin Newcomb pp 5260–5261 DOI: 10.1021/ja034888d Supporting Info

Novel Small Organic Molecules for a Highly Enantioselective Direct Aldol Reaction Zhuo Tang, Fan Jiang, Luo-Ting Yu, Xin Cui, Liu-Zhu Gong, Ai-Qiao Mi, Yao-Zhong Jiang, and Yun-Dong Wu pp 5262–5263 DOI: 10.1021/ja034528q Supporting Info

Determination of an Acidic Scale in Room Temperature Ionic Liquids Cécile Thomazeau, Hélène Olivier-Bourbigou, Lionel Magna, Stéphane Luts, and Bernard Gilbert pp 5264–5265 DOI: 10.1021/ja0297382 Supporting Info

Evidence of Surfactant-Induced Formation of Transient Pores in Lipid Bilayers by Using Magnetic-Fluid-Loaded Liposomes Sylviane Lesieur, Cécile Grabielle-Madelmont, Christine Ménager, Valérie Cabuil, Delphine Dadhi, Pascale Pierrot, and Katarina Edwards pp 5266–5267 DOI: 10.1021/ja021471j Supporting Info

Protein Assembly by Orthogonal Chemical Ligation Methods Bradley L. Nilsson, Robert J. Hondal, Matthew B. Soellner, and Ronald T. Raines pp 5268–5269 DOI: 10.1021/ja029752e Supporting Info

Observation of Symmetry Lowering and Electron Localization in the Doublet-States of a Spin-Frustrated Equilateral Triangular Lattice:  Cu3(O2C16H23)·1.2C6H12 Brant Cage, F. Albert Cotton, Naresh S. Dalal, Elizabeth A. Hillard, Boris Rakvin, and Chris M. Ramsey pp 5270–5271 DOI: 10.1021/ja0286829

First Cr(III)−SNS Complexes and Their Use as Highly Efficient Catalysts for the Trimerization of Ethylene to 1-Hexene David S. McGuinness, Peter Wasserscheid, Wilhelm Keim, David Morgan, John T. Dixon, Annette Bollmann, Hulisani Maumela, Fiona Hess, and Ulli Englert pp 5272–5273 DOI: 10.1021/ja034752f Supporting Info

Selective C-Arylation of Free (NH)-Heteroarenes via Catalytic C−H Bond Functionalization Bengü Sezen and Dalibor Sames pp 5274–5275 DOI: 10.1021/ja034848+ Supporting Info

Size-Selective Organization of Enthalpic Compatibilized Nanocrystals in Ternary Block Copolymer/Particle Mixtures Michael R. Bockstaller, Yonit Lapetnikov, Shlomo Margel, and Edwin L. Thomas pp 5276–5277 DOI: 10.1021/ja034523t Supporting Info

Subpicosecond Photoinduced Charge Injection from “Molecular Tripods” into Mesoporous TiO2 Over the Distance of 24 Angstroms Piotr Piotrowiak, Elena Galoppini, Qian Wei, Gerald J. Meyer, and Piotr Wiewiór pp 5278–5279 DOI: 10.1021/ja034268c Supporting Info

A Water-Soluble and “Self-Assembled” Polyoxometalate as a Recyclable Catalyst for Oxidation of Alcohols in Water with Hydrogen Peroxide Dorit Sloboda-Rozner, Paul L. Alsters, and Ronny Neumann pp 5280–5281 DOI: 10.1021/ja0344821

4H-1,2-Benzoxazines with Electron-Withdrawing Substituents on the Benzene Ring:  Synthesis and Application as Potent Intermediates for Oxygen-Functionalized Aromatic Compounds Satoshi Nakamura, Masanobu Uchiyama, and Tomohiko Ohwada pp 5282–5283 DOI: 10.1021/ja0343151 Supporting Info

Titanium Disulfide Nanotubes as Hydrogen-Storage Materials Jun Chen, Suo-Long Li, Zhan-Liang Tao, Yu-Tian Shen, and Chun-Xiang Cui pp 5284–5285 DOI: 10.1021/ja034601c

Synthesis and Spectroscopic Properties of a Series of β-Blocked Long Oligothiophenes up to the 96-mer:  Revaluation of Effective Conjugation Length Tsuyoshi Izumi, Seiji Kobashi, Kazuo Takimiya, Yoshio Aso, and Tetsuo Otsubo pp 5286–5287 DOI: 10.1021/ja034333i Supporting Info

Polymer Catalysts from Polymerization Catalysts:  Direct Encapsulation of Metal Catalyst into Star Polymer Core during Metal-Catalyzed Living Radical Polymerization Takaya Terashima, Masami Kamigaito, Kyung-Youl Baek, Tsuyoshi Ando, and Mitsuo Sawamoto pp 5288–5289 DOI: 10.1021/ja034973l Supporting Info

Chemical Lithography of a Conductive Polymer Using a Traceless Removable Group Horacio J. Salavagione, María C. Miras, and César Barbero pp 5290–5291 DOI: 10.1021/ja0298693 Supporting Info

Microlens Formation in Microgel/Gold Colloid Composite Materials via Photothermal Patterning Clinton D. Jones, Michael J. Serpe, Laura Schroeder, and L. Andrew Lyon pp 5292–5293 DOI: 10.1021/ja034076h Supporting Info

A Miniaturized, Parallel, Serially Diluted Immunoassay for Analyzing Multiple Antigens Xingyu Jiang, Jessamine M. K. Ng, Abraham D. Stroock, Stephan K. W. Dertinger, and George M. Whitesides pp 5294–5295 DOI: 10.1021/ja034566+ Supporting Info

Spirastrellolide A, An Antimitotic Macrolide Isolated from the Caribbean Marine Sponge Spirastrella coccinea David E. Williams, Michel Roberge, Rob Van Soest, and Raymond J. Andersen pp 5296–5297 DOI: 10.1021/ja0348602 Supporting Info

An Unnatural Hydrophobic Base Pair with Shape Complementarity between Pyrrole-2-carbaldehyde and 9-Methylimidazo[(4,5)-b]pyridine Tsuneo Mitsui, Aya Kitamura, Michiko Kimoto, Taiko To, Akira Sato, Ichiro Hirao, and Shigeyuki Yokoyama pp 5298–5307 DOI: 10.1021/ja028806h Supporting Info

Aromatic−Aromatic Interactions in Crystal Structures of Helical Peptide Scaffolds Containing Projecting Phenylalanine Residues Subrayashastry Aravinda, Narayanaswamy Shamala, Chittaranjan Das, Arumugam Sriranjini, Isabella L. Karle, and Padmanabhan Balaram pp 5308–5315 DOI: 10.1021/ja0341283 Supporting Info

Parallel Synthesis and Biophysical Characterization of a Degradable Polymer Library for Gene Delivery Akin Akinc, David M. Lynn, Daniel G. Anderson, and Robert Langer pp 5316–5323 DOI: 10.1021/ja034429c

Measurement of Submicrosecond Intramolecular Contact Formation in Peptides at the Single-Molecule Level Hannes Neuweiler, Andreas Schulz, Martin Böhmer, Jörg Enderlein, and Markus Sauer pp 5324–5330 DOI: 10.1021/ja034040p

Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometric Analysis of Metal-Ion Selected Dynamic Protein Libraries Helen J. Cooper, Martin A. Case, George L. McLendon, and Alan G. Marshall pp 5331–5339 DOI: 10.1021/ja021138f

Strings of Vesicles:  Flow Behavior in an Unusual Type of Aqueous Gel Fredric M. Menger and Andrey V. Peresypkin pp 5340–5345 DOI: 10.1021/ja021298r

In Vitro Evolution of an RNA-Cleaving DNA Enzyme into an RNA Ligase Switches the Selectivity from 3‘−5‘ to 2‘−5‘ Amber Flynn-Charlebois, Tracey K. Prior, Kelly A. Hoadley, and Scott K. Silverman pp 5346–5350 DOI: 10.1021/ja0340331 Supporting Info

Synthesis and Characterization of Cross-Linked Reverse Micelles Hyun M. Jung, Kristin E. Price, and D. Tyler McQuade pp 5351–5355 DOI: 10.1021/ja0271983

Ruthenium(II) Dendrimers Containing Carbazole-Based Chromophores as Branches Nathan D. McClenaghan, Rosalba Passalacqua, Frédérique Loiseau, Sebastiano Campagna, Bert Verheyde, Ahmed Hameurlaine, and Wim Dehaen pp 5356–5365 DOI: 10.1021/ja021373y Supporting Info

Mechanistic Analysis of Acyl Transferase Domain Exchange in Polyketide Synthase Modules Marcus Hans, Andreas Hornung, Agnieszka Dziarnowski, David E. Cane, and Chaitan Khosla pp 5366–5374 DOI: 10.1021/ja029539i

The Azulene-to-Naphthalene Rearrangement Revisited:  a DFT Study of Intramolecular and Radical-Promoted Mechanisms Roger W. Alder, Stephen P. East, Jeremy N. Harvey, and Mark T. Oakley pp 5375–5387 DOI: 10.1021/ja029584q Supporting Info

Concerning the Denticity of the Dimethylsulfinyl Anion in Meisenheimer Complexation Erwin Buncel, Kuk-Tae Park, Julian M. Dust, and Richard A. Manderville pp 5388–5392 DOI: 10.1021/ja0298489

An Enantioselective Synthesis of FR182877 Provides a Chemical Rationalization of Its Structure and Affords Multigram Quantities of Its Direct Precursor Christopher D. Vanderwal, David A. Vosburg, Sven Weiler, and Erik J. Sorensen pp 5393–5407 DOI: 10.1021/ja021472b Supporting Info

Facile Access to Monodisperse Ultralarge Rings Muhammad Raza Shah, Stefan Duda, Beate Müller, Adelheid Godt, and Abdul Malik pp 5408–5414 DOI: 10.1021/ja034147c Supporting Info

Total Synthesis of (+)-Asteltoxin Khee Dong Eom, J. Venkat Raman, Heejin Kim, and Jin Kun Cha pp 5415–5421 DOI: 10.1021/ja034332q Supporting Info

An Experimental and Theoretical Study of the Type C Enone Rearrangement:  Mechanistic and Exploratory Organic Photochemistry1 Howard E. Zimmerman and Evgueni E. Nesterov pp 5422–5430 DOI: 10.1021/ja028631b Supporting Info

Tyrosine 89 Accelerates Co−Carbon Bond Homolysis in Methylmalonyl-CoA Mutase Monica D. Vlasie and Ruma Banerjee pp 5431–5435 DOI: 10.1021/ja029420+

Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers:  Syntheses, Structures, and Electrochemistry F. Albert Cotton, James P. Donahue, and Carlos A. Murillo pp 5436–5450 DOI: 10.1021/ja029101i Supporting Info

“Oscillating” Metallocene Catalysts:  What Stops the Oscillation? Vincenzo Busico, Valeria Van Axel Castelli, Paola Aprea, Roberta Cipullo, Annalaura Segre, Giovanni Talarico, and Michele Vacatello pp 5451–5460 DOI: 10.1021/ja0284557

Non-Localized Ligand-to-Metal Charge Transfer Excited States in (Cp)2Ti(IV)(NCS)2 Elizabeth L. Patrick, Chad J. Ray, Grant D. Meyer, Theodore P. Ortiz, Jason A. Marshall, James A. Brozik, Melissa A. Summers, and John W. Kenney, III pp 5461–5470 DOI: 10.1021/ja028769u Supporting Info

First Soluble M@C60 Derivatives Provide Enhanced Access to Metallofullerenes and Permit in Vivo Evaluation of Gd@C60[C(COOH)2]10 as a MRI Contrast Agent Robert D. Bolskar, Angelo F. Benedetto, Lars O. Husebo, Roger E. Price, Edward F. Jackson, Sidney Wallace, Lon J. Wilson, and J. Michael Alford pp 5471–5478 DOI: 10.1021/ja0340984 Supporting Info

Exfoliated Nanosheets as a New Strong Solid Acid Catalyst Atsushi Takagaki, Mariko Sugisawa, Darling Lu, Junko N. Kondo, Michikazu Hara, Kazunari Domen, and Shigenobu Hayashi pp 5479–5485 DOI: 10.1021/ja034085q

Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers:  Absorption Spectra and Electronic Structures F. Albert Cotton, James P. Donahue, Carlos A. Murillo, and Lisa M. Pérez pp 5486–5492 DOI: 10.1021/ja0343555 Supporting Info

Vibrational Spectroscopy of Mechanically Compressed Monolayers Otto Berg and David Klenerman pp 5493–5500 DOI: 10.1021/ja027128w Supporting Info

Asymmetric Alternating Copolymerization of Cyclohexene Oxide and CO2 with Dimeric Zinc Complexes Koji Nakano, Kyoko Nozaki, and Tamejiro Hiyama pp 5501–5510 DOI: 10.1021/ja028666b Supporting Info

Thermal and Electrochemical C−X Activation (X = Cl, Br, I) by the Strong Lewis Acid Pd3(dppm)3(CO)2+ Cluster and Its Catalytic Applications Frédéric Lemaître, Dominique Lucas, Katherine Groison, Philippe Richard, Yves Mugnier, and Pierre D. Harvey pp 5511–5522 DOI: 10.1021/ja0297786 Supporting Info

Alcoholysis of Acylpalladium(II) Complexes Relevant to the Alternating Copolymerization of Ethene and Carbon Monoxide and the Alkoxycarbonylation of Alkenes:  the Importance of Cis-Coordinating Phosphines Piet W. N. M. van Leeuwen, Martin A. Zuideveld, Bert H. G. Swennenhuis, Zoraida Freixa, Paul C. J. Kamer, Kees Goubitz, Jan Fraanje, Martin Lutz, and Anthony L. Spek pp 5523–5539 DOI: 10.1021/ja029341y Supporting Info

The Rh4(CO)12-Catalyzed Hydroformylation of 3,3-Dimethylbut-1-ene Promoted with HMn(CO)5. Bimetallic Catalytic Binuclear Elimination as an Origin for Synergism in Homogeneous Catalysis Chuanzhao Li, Effendi Widjaja, and Marc Garland pp 5540–5548 DOI: 10.1021/ja029499i Supporting Info

Solution versus Solid-State Structure of Ytterbium Heterobimetallic Catalysts Lorenzo Di Bari, Moreno Lelli, Guido Pintacuda, Gennaro Pescitelli, Fabio Marchetti, and Piero Salvadori pp 5549–5558 DOI: 10.1021/ja0297640 Supporting Info

Adsorption Morphology, Light Absorption, and Sensitization Yields for Squaraine Dyes on SnS2 Surfaces Norihiko Takeda and Bruce A. Parkinson pp 5559–5571 DOI: 10.1021/ja0278483 Supporting Info

Scratching the Surface of Buckminsterfullerene:  The Barriers for Stone−Wales Transformation through Symmetric and Asymmetric Transition States Holger F. Bettinger, Boris I. Yakobson, and Gustavo E. Scuseria pp 5572–5580 DOI: 10.1021/ja0288744

Intercalators. 1. Nature of Stacking Interactions between Intercalators (Ethidium, Daunomycin, Ellipticine, and 4‘,6‘-Diaminide-2-phenylindole) and DNA Base Pairs. Ab Initio Quantum Chemical, Density Functional Theory, and Empirical Potential Study  [J. Am. Chem. Soc. 2002, 124, 3366−3367].   David Řeha, Martin Kabelá, Filip Ryjáek, Jiří Šponer, Judit E. Šponer, Marcus Elstner, Sándor Suhai, and Pavel Hobza p 5581 DOI: 10.1021/ja033983j Supporting Info

Surface Chemistry and Catalysis Edited by Albert F. Carley, Philip R. Davies, Graham J. Hutchings, and Michael S. Spencer (Cardiff University, Wales). Kluwer Academic/Plenum Publishers:  New York. 2002. xviii + 382 pp. $150.00. ISBN 0-306-47393-3. p 5582 DOI: 10.1021/ja025349w

Chemistry of Taste:  Mechanisms, Behaviors, and Mimics Edited by Peter Given (Pepsi-Cola Company) and Dulce Paredes (Kraft Foods). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2002. xiv + 362 pp. $150.00. ISBN 0-8412-3734-4. p 5582 DOI: 10.1021/ja025351n

DNA-Based Molecular Construction. AIP Conference Proceedings, 640 Edited by Wolfgang Fritzsche (IPHT, Jena, Germany). American Institute of Physics:  Melville, New York. 2002. xii + 134 pp. $120.00. ISBN 0-7354-0095-4. p 5582 DOI: 10.1021/ja0253538

Progress in Heterocyclic Chemistry. Volume 14 Edited by Gordon W. Gribble (Dartmouth College) and Thomas L. Gilchrist (University of Liverpool). Pergamon (An Imprint of Elsevier Science):  Oxford. 2002. viii + 376 pp. $210.00. ISBN 0-08-044190-4. p 5582 DOI: 10.1021/ja025355s

Issue 19

The Biosynthesis of GDP-l-Colitose:  C-3 Deoxygenation Is Catalyzed by a Unique Coenzyme B6-Dependent Enzyme Noelle Beyer, Jenefer Alam, Tina M. Hallis, Zhihong Guo, and Hung-wen Liu pp 5584–5585 DOI: 10.1021/ja030088r

Structural Biasing Elements for In-Cell Histone Deacetylase Paralog Selectivity Jason C. Wong, Roger Hong, and Stuart L. Schreiber pp 5586–5587 DOI: 10.1021/ja0341440 Supporting Info

Protein Nanostructures Formed via Direct-Write Dip-Pen Nanolithography Ki-Bum Lee, Jung-Hyurk Lim, and Chad A. Mirkin pp 5588–5589 DOI: 10.1021/ja034236p Supporting Info

A Remarkable [2.2.2]Propellane Yigang He, Christopher P. Junk, John J. Cawley, and David M. Lemal pp 5590–5591 DOI: 10.1021/ja030077y Supporting Info

Environment-Independent 14-Helix Formation in Short β-Peptides:  Striking a Balance between Shape Control and Functional Diversity Tami L. Raguse, Jonathan R. Lai, and Samuel H. Gellman pp 5592–5593 DOI: 10.1021/ja0341485 Supporting Info

G-Quadruplex-Specific Peptide−Hemicyanine Ligands by Partial Combinatorial Selection James A. Schouten, Sylvain Ladame, Stephen J. Mason, Matthew A. Cooper, and Shankar Balasubramanian pp 5594–5595 DOI: 10.1021/ja029356w Supporting Info

Self-Consistency Analysis of Dipolar Couplings in Multiple Alignments of Ubiquitin Jean-Christophe Hus, Wolfgang Peti, Christian Griesinger, and Rafael Brüschweiler pp 5596–5597 DOI: 10.1021/ja029719s Supporting Info

Charge Optimization Increases the Potency and Selectivity of a Chorismate Mutase Inhibitor Ajay Mandal and Donald Hilvert pp 5598–5599 DOI: 10.1021/ja029447t Supporting Info

Liquid Poly(ethylene glycol) and Supercritical Carbon Dioxide:  A Benign Biphasic Solvent System for Use and Recycling of Homogeneous Catalysts David J. Heldebrant and Philip G. Jessop pp 5600–5601 DOI: 10.1021/ja029131l

Discovery of a New Phosphotyrosine Mimetic for PTP1B Using Breakaway Tethering Daniel A. Erlanson, Robert S. McDowell, Molly M. He, Mike Randal, Robert L. Simmons, Jenny Kung, Andrew Waight, and Stig K. Hansen pp 5602–5603 DOI: 10.1021/ja034440c Supporting Info

The Interstitial Atom of the Nitrogenase FeMo-Cofactor:  ENDOR and ESEEM Show It Is Not an Exchangeable Nitrogen Hong-In Lee, Paul M. C. Benton, Mikhail Laryukhin, Robert Y. Igarashi, Dennis R. Dean, Lance C. Seefeldt, and Brian M. Hoffman pp 5604–5605 DOI: 10.1021/ja034383n

Novel Alkenylative Cyclization Using a Ruthenium Catalyst Miwako Mori, Nozomi Saito, Daisuke Tanaka, Masanori Takimoto, and Yoshihiro Sato pp 5606–5607 DOI: 10.1021/ja029747a Supporting Info

Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes Masaru Utsunomiya, Ryoichi Kuwano, Motoi Kawatsura, and John F. Hartwig pp 5608–5609 DOI: 10.1021/ja0293608 Supporting Info

Reversible Light-Driven Redox Switching of Multifunctional Dipolar Ruthenium(III/II) Pentaammine(4,4‘-bipyridinium) Complexes Salvatore Sortino, Salvatore Petralia, and Santo Di Bella pp 5610–5611 DOI: 10.1021/ja034712b Supporting Info

Light-Driven Open−Close Motion of Chiral Molecular Scissors Takahiro Muraoka, Kazushi Kinbara, Yuka Kobayashi, and Takuzo Aida pp 5612–5613 DOI: 10.1021/ja034994f Supporting Info

Generation and Characterization of Highly Strained Dibenzotetrakisdehydro[12]annulene Yoshito Tobe, Ichiro Ohki, Motohiro Sonoda, Hiroyuki Niino, Tadatake Sato, and Tomonari Wakabayashi pp 5614–5615 DOI: 10.1021/ja035079x Supporting Info

Room-Temperature Hiyama Cross-Couplings of Arylsilanes with Alkyl Bromides and Iodides Jae-Young Lee and Gregory C. Fu pp 5616–5617 DOI: 10.1021/ja0349352 Supporting Info

A Catalytically Active, Charge-Neutral Rh(I) Zwitterion Featuring a P,N-Substituted “Naked” Indenide Ligand Mark Stradiotto, Judy Cipot, and Robert McDonald pp 5618–5619 DOI: 10.1021/ja034543v Supporting Info

New Insights into Ethene Epoxidation on Two Oxidized Ag{111} Surfaces Marie-Laure Bocquet, Angelos Michaelides, David Loffreda, Philippe Sautet, Ali Alavi, and David A. King pp 5620–5621 DOI: 10.1021/ja0297741 Supporting Info

Cationic Organoscandium β-Diketiminato Chemistry:  Arene Exchange Kinetics in Solvent Separated Ion Pairs Paul G. Hayes, Warren E. Piers, and Masood Parvez pp 5622–5623 DOI: 10.1021/ja034680s Supporting Info

Multielectron Transfer in Clusters of Polar-Polarizable Chromophores Anna Painelli and Francesca Terenziani pp 5624–5625 DOI: 10.1021/ja034155t

Self-Assembly of an Environmentally Responsive Polymer/Silica Nanocomposite Georg Garnweitner, Bernd Smarsly, Roger Assink, Wilhelm Ruland, Evelyn Bond, and C. Jeffrey Brinker pp 5626–5627 DOI: 10.1021/ja0342648 Supporting Info

Short, Enantioselective Total Synthesis of Okaramine N Phil S. Baran, Carlos A. Guerrero, and E. J. Corey pp 5628–5629 DOI: 10.1021/ja034491+ Supporting Info

The First Oxovanadium Ring in [{OV(salen)}2(μ-F)][VO(salen)][BF4]·(CH2Cl2)x Crystals Kenichi Oyaizu and Eishun Tsuchida pp 5630–5631 DOI: 10.1021/ja021374q Supporting Info

Broad-Spectrum Radical Cyclizations Boosted by Polarity Matching. Carbonylative Access to α-Stannylmethylene Lactams from Azaenynes and CO Ilhyong Ryu, Hironari Miyazato, Hiroki Kuriyama, Kazutoshi Matsu, Mami Tojino, Takahide Fukuyama, Satoshi Minakata, and Mitsuo Komatsu pp 5632–5633 DOI: 10.1021/ja034896u Supporting Info

Catalytic Enantioselective Strecker Reaction of Ketoimines Shuji Masumoto, Hiroyuki Usuda, Masato Suzuki, Motomu Kanai, and Masakatsu Shibasaki pp 5634–5635 DOI: 10.1021/ja034980+ Supporting Info

Growth of Millimeter-Long and Horizontally Aligned Single-Walled Carbon Nanotubes on Flat Substrates Shaoming Huang, Xinyu Cai, and Jie Liu pp 5636–5637 DOI: 10.1021/ja034475c Supporting Info

Solventless Synthesis of Copper Sulfide Nanorods by Thermolysis of a Single Source Thiolate-Derived Precursor Travis H. Larsen, Michael Sigman, Ali Ghezelbash, R. Christopher Doty, and Brian A. Korgel pp 5638–5639 DOI: 10.1021/ja0342087 Supporting Info

Photoaquation of Methylated cis-Dichlorobis(1,10-phenanthroline)rhodium(III)chloride Compounds by Direct Population of a Photoactive Triplet Excited State Devanesan Loganathan, Jorge H. Rodriguez, and Harry Morrison pp 5640–5641 DOI: 10.1021/ja021190b Supporting Info

Chromium-Mediated Asymmetric Synthesis of Both Enantiomers of Acetoxytubipofuran E. Peter Kündig, Rita Cannas, Mundruppady Laxmisha, Liu Ronggang, and Sylvie Tchertchian pp 5642–5643 DOI: 10.1021/ja029957n Supporting Info

A New Method for the Catalytic Aldol Reaction to Ketones Kounosuke Oisaki, Yutaka Suto, Motomu Kanai, and Masakatsu Shibasaki pp 5644–5645 DOI: 10.1021/ja034993n Supporting Info

Ni- or Cu-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Grignard Reagents Jun Terao, Aki Ikumi, Hitoshi Kuniyasu, and Nobuaki Kambe pp 5646–5647 DOI: 10.1021/ja034201p Supporting Info

Measurements of Carbon to Amide-Proton Distances by C−H Dipolar Recoupling with 15N NMR Detection Klaus Schmidt-Rohr and Mei Hong pp 5648–5649 DOI: 10.1021/ja0344415

Micelle-Encapsulated Carbon Nanotubes:  A Route to Nanotube Composites Youngjong Kang and T. Andrew Taton pp 5650–5651 DOI: 10.1021/ja034082d Supporting Info

Synthesis of Tin-Encapsulated Spherical Hollow Carbon for Anode Material in Lithium Secondary Batteries Kyu T. Lee, Yoon S. Jung, and Seung M. Oh pp 5652–5653 DOI: 10.1021/ja0345524 Supporting Info

Four-Stranded DNA Structure Stabilized by a Novel G:C:A:T Tetrad Núria Escaja, Josep Lluis Gelpí, Modesto Orozco, Manuel Rico, Enrique Pedroso, and Carlos González pp 5654–5662 DOI: 10.1021/ja0344157 Supporting Info

Selection of a High-Energy Bioactive Conformation of a Sulfonium-Ion Glycosidase Inhibitor by the Enzyme Glucoamylase G2 Margaret A. Johnson, Morten T. Jensen, Birte Svensson, and B. Mario Pinto pp 5663–5670 DOI: 10.1021/ja0212617 Supporting Info

Expression and Kinetic Analysis of the Substrate Specificity of Modules 5 and 6 of the Picromycin/Methymycin Polyketide Synthase Yifeng Yin, Hongxiang Lu, Chaitan Khosla, and David E. Cane pp 5671–5676 DOI: 10.1021/ja034574q Supporting Info

Spectroscopic and Kinetic Studies of PKU−Inducing Mutants of Phenylalanine Hydroxylase:  Arg158Gln and Glu280Lys Jyllian N. Kemsley, Erik C. Wasinger, Supratim Datta, Nataša Mitić, Tara Acharya, Britt Hedman, John P. Caradonna, Keith O. Hodgson, and Edward I. Solomon pp 5677–5686 DOI: 10.1021/ja029106f Supporting Info

Site-Specific Synthesis and Reactivity of Oligonucleotides Containing Stereochemically Defined 1,N2-Deoxyguanosine Adducts of the Lipid Peroxidation Product trans-4-Hydroxynonenal Hao Wang, Ivan D. Kozekov, Thomas M. Harris, and Carmelo J. Rizzo pp 5687–5700 DOI: 10.1021/ja0288800 Supporting Info

Side Chain Assignments of Ile δ1 Methyl Groups in High Molecular Weight Proteins:  an Application to a 46 ns Tumbling Molecule Vitali Tugarinov and Lewis E. Kay pp 5701–5706 DOI: 10.1021/ja021452+

Imidazopyridine/Pyrrole and Hydroxybenzimidazole/Pyrrole Pairs for DNA Minor Groove Recognition Dorte Renneberg and Peter B. Dervan pp 5707–5716 DOI: 10.1021/ja0300158 Supporting Info

Quantitative Formation of [2]Catenanes Using Copper(I) and Palladium(II) as Templating and Assembling Centers:  The Entwining Route and the Threading Approach Christiane Dietrich-Buchecker, Benoît Colasson, Makoto Fujita, Akiko Hori, Neri Geum, Shigeru Sakamoto, Kentaro Yamaguchi, and Jean-Pierre Sauvage pp 5717–5725 DOI: 10.1021/ja021370l

Silylated Cyclohexadienes as New Radical Chain Reducing Reagents:  Preparative and Mechanistic Aspects Armido Studer, Stephan Amrein, Florian Schleth, Tobias Schulte, and John C. Walton pp 5726–5733 DOI: 10.1021/ja0341743 Supporting Info

Highly Efficient and Selective Epoxidation of Alkenes by Photochemical Oxygenation Sensitized by a Ruthenium(II) Porphyrin with Water as Both Electron and Oxygen Donor Shigeaki Funyu, Takehiko Isobe, Shinsuke Takagi, Donald A. Tryk, and Haruo Inoue pp 5734–5740 DOI: 10.1021/ja0295218

Stereochemical Memory versus Curtin−Hammett Behavior in the Rearrangement of 1,3-Cyclopentanediyl Radical Cations Derived from Housanes through Structural Effects on Conformational Control Waldemar Adam, Christian P. Librera, and Alexei V. Trofimov pp 5741–5744 DOI: 10.1021/ja028984a Supporting Info

Mithramycin SK, A Novel Antitumor Drug with Improved Therapeutic Index, Mithramycin SA, and Demycarosyl-mithramycin SK:  Three New Products Generated in the Mithramycin Producer Streptomyces argillaceus through Combinatorial Biosynthesis Lily L. Remsing, Ana M. González, Mohammad Nur-e-Alam, M. José Fernández-Lozano, Alfredo F. Braña, Uwe Rix, Marcos A. Oliveira, Carmen Méndez, José A. Salas, and Jürgen Rohr pp 5745–5753 DOI: 10.1021/ja034162h

The Intramolecular, Stereoselective Addition of Sulfoximine Carbanions to α,β-Unsaturated Esters Michael Harmata and Xuechuan Hong pp 5754–5756 DOI: 10.1021/ja034744z Supporting Info

Intramolecular Reactions of Alkynes with Furans and Electron Rich Arenes Catalyzed by PtCl2:  The Role of Platinum Carbenes as Intermediates Belén Martín-Matute, Cristina Nevado, Diego J. Cárdenas, and Antonio M. Echavarren pp 5757–5766 DOI: 10.1021/ja029125p Supporting Info

A Disilapentalene and a Stable Diradical from the Reaction of a Dilithiosilole with a Dichlorocyclopropene Irina S. Toulokhonova, Thomas C. Stringfellow, Sergei A. Ivanov, Artem Masunov, and Robert West pp 5767–5773 DOI: 10.1021/ja020763h Supporting Info

Bis(calix[4]diquinone) Receptors:  Cesium- and Rubidium-Selective Redox-Active Ionophores Philip R. A. Webber, Paul D. Beer, George Z. Chen, Vitor Felix, and Michael G. B. Drew pp 5774–5785 DOI: 10.1021/ja029740t Supporting Info

Synthesis, Characterization, and Coordination Chemistry of the 2-Azaphenalenyl Radical Shijun Zheng, Jie Lan, Saeed I. Khan, and Yves Rubin pp 5786–5791 DOI: 10.1021/ja029236o Supporting Info

Benzoxazine Oligomers:  Evidence for a Helical Structure from Solid-State NMR Spectroscopy and DFT-Based Dynamics and Chemical Shift Calculations Gillian R. Goward, Daniel Sebastiani, Ingo Schnell, Hans Wolfgang Spiess, Ho-Dong Kim, and Hatsuo Ishida pp 5792–5800 DOI: 10.1021/ja029059r

Theoretical Calculations of Carbon−Oxygen Bond Dissociation Enthalpies of Peroxyl Radicals Formed in the Autoxidation of Lipids Derek A. Pratt, Jeremy H. Mills, and Ned A. Porter pp 5801–5810 DOI: 10.1021/ja034182j Supporting Info

Self-Activated Supramolecular Reactions: Effects of Host−Guest Recognition on the Kinetics of the Diels−Alder Reaction of Open-Chain Oligoether Quinones with Cyclopentadiene Akihiko Tsuda, Chikako Fukumoto, and Takumi Oshima pp 5811–5822 DOI: 10.1021/ja021444t Supporting Info

Glycopeptide-Membrane Interactions:  Glycosyl Enkephalin Analogues Adopt Turn Conformations by NMR and CD in Amphipathic Media Michael M. Palian, V. I. Boguslavsky, David F. O'Brien, and Robin Polt pp 5823–5831 DOI: 10.1021/ja0268635 Supporting Info

A Polyphenylene Dendrimer−Detergent Complex as a Highly Fluorescent Probe for Bioassays Claire Minard-Basquin, Tanja Weil, Andreas Hohner, Joachim O. Rädler, and Klaus Müllen pp 5832–5838 DOI: 10.1021/ja0285058 Supporting Info

Altering the Allowed/Forbidden Gap in Cyclobutene Electrocyclic Reactions:  Experimental and Theoretical Evaluations of the Effect of Planarity Constraints Patrick S. Lee, Shogo Sakai, Peter Hörstermann, Wolfgang R. Roth, E. Adam Kallel, and K. N. Houk pp 5839–5848 DOI: 10.1021/ja028963g Supporting Info

Excitation Energy Transport Processes of Porphyrin Monomer, Dimer, Cyclic Trimer, and Hexamer Probed by Ultrafast Fluorescence Anisotropy Decay Hyun Sun Cho, Hanju Rhee, Jae Kyu Song, Chang-Ki Min, Masayoshi Takase, Naoki Aratani, Sung Cho, Atsuhiro Osuka, Taiha Joo, and Dongho Kim pp 5849–5860 DOI: 10.1021/ja021476g

Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents:  A “Greener” Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation Marc Wende and J. A. Gladysz pp 5861–5872 DOI: 10.1021/ja029241s

Au Nanocrystal Growth on Nanotubes Controlled by Conformations and Charges of Sequenced Peptide Templates Ramin Djalali, Yung-fou Chen, and Hiroshi Matsui pp 5873–5879 DOI: 10.1021/ja0299598 Supporting Info

Molecular Wires Built from Binuclear Cyclometalated Complexes Sandrine Fraysse, Christophe Coudret, and Jean-Pierre Launay pp 5880–5888 DOI: 10.1021/ja0299506 Supporting Info

Adsorption of CF4 on the Internal and External Surfaces of Opened Single-Walled Carbon Nanotubes:  A Vibrational Spectroscopy Study Oleg Byl, Petro Kondratyuk, Scott T. Forth, Stephen A. FitzGerald, Liang Chen, J. Karl Johnson, and John T. Yates, Jr. pp 5889–5896 DOI: 10.1021/ja020949g

Spectroscopic and Computational Studies of Co3+-Corrinoids:  Spectral and Electronic Properties of the B12 Cofactors and Biologically Relevant Precursors Troy A. Stich, Amanda J. Brooks, Nicole R. Buan, and Thomas C. Brunold pp 5897–5914 DOI: 10.1021/ja029328d Supporting Info

Axial Solvent Coordination in “Base-Off” Cob(II)alamin and Related Co(II)-Corrinates Revealed by 2D-EPR Sabine Van Doorslaer, Gunnar Jeschke, Boris Epel, Daniella Goldfarb, Rüdiger-Albert Eichel, Bernhard Kräutler, and Arthur Schweiger pp 5915–5927 DOI: 10.1021/ja021218j Supporting Info

51V Magic Angle Spinning NMR Spectroscopy of Six-Coordinate Lindqvist Oxoanions:  A Sensitive Probe for the Electronic Environment in Vanadium-Containing Polyoxometalates. Counterions Dictate the 51V Fine Structure Constants in Polyoxometalate Solids Wenlin Huang, Louis Todaro, Lynn C. Francesconi, and Tatyana Polenova pp 5928–5938 DOI: 10.1021/ja029246p Supporting Info

Contributions of Symmetric and Asymmetric Normal Coordinates to the Intervalence Electronic Absorption and Resonance Raman Spectra of a Strongly Coupled p-Phenylenediamine Radical Cation Susan E. Bailey, Jeffrey I. Zink, and Stephen F. Nelsen pp 5939–5947 DOI: 10.1021/ja021343v

Long-Range Electron Transfer through Monolayers and Bilayers of Alkanethiols in Electrochemically Controlled Hg−Hg Tunneling Junctions Roger L. York, Phuong T. Nguyen, and Krzysztof Slowinski pp 5948–5953 DOI: 10.1021/ja0211353

NCα Bond Dissociation Energies and Kinetics in Amide and Peptide Radicals. Is the Dissociation a Non-ergodic Process? František Tureek pp 5954–5963 DOI: 10.1021/ja021323t

Comparison of Formation of Reactive Conformers (NACs) for the Claisen Rearrangement of Chorismate to Prephenate in Water and in the E. coli Mutase:  The Efficiency of the Enzyme Catalysis Sun Hur and Thomas C. Bruice pp 5964–5972 DOI: 10.1021/ja0210648

Electronic Basis of Improper Hydrogen Bonding:  A Subtle Balance of Hyperconjugation and Rehybridization Igor V. Alabugin, Mariappan Manoharan, Scott Peabody, and Frank Weinhold pp 5973–5987 DOI: 10.1021/ja034656e Supporting Info

Interference between the Hydrogen Bonds to the Two Rings of Nicotine Jérôme Graton, Tanja van Mourik, and Sarah L. Price pp 5988–5997 DOI: 10.1021/ja029213+ Supporting Info

Solution-Processed Anodes from Layer-Structure Materials for High-Efficiency Polymer Light-Emitting Diodes Gitti L. Frey, Kieran J. Reynolds, Richard H. Friend, Hagai Cohen, and Yishay Feldman pp 5998–6007 DOI: 10.1021/ja020913o

Metal Ions in Biological Systems. Volume 39. Molybdenum and Tungsten:  Their Roles in Biological Processes Edited by Astrid Sigel and Helmut Sigel [J. Am. Chem. Soc. 2003, 125, 305]. Book Review by Martin L. Kirk M. L. Kirk p 6008 DOI: 10.1021/ja033444e

Sequence Specific Fluorescence Detection of Double Strand DNA  [J. Am. Chem. Soc. 2003, 125, 1195−1202]. Victor C. Rucker, Shane Foister, Christian Melander, and Peter B. Dervan p 6008 DOI: 10.1021/ja033984b Supporting Info

Issue 20

Bulk Microphase Segregation of an Asymmetric Organometallic-Inorganic Diblock Copolymer:  A Remarkable Example of Concentric Cylinders Jose Raez, Yuanming Zhang, Lan Cao, Srebri Petrov, Kurt Erlacher, Ulrich Wiesner, Ian Manners, and Mitchell A. Winnik pp 6010–6011 DOI: 10.1021/ja0300160 Supporting Info

A Chemical Trick:  How To Make a Digermene from a Disilene, Formation of 3Δ-1,2,3,4-Disiladigermetene Vladimir Ya. Lee, Kazunori Takanashi, Masaaki Ichinohe, and Akira Sekiguchi pp 6012–6013 DOI: 10.1021/ja021480s Supporting Info

Interlocked Chiral Nanotubes Assembled from Quintuple Helices Yong Cui, Suk Joong Lee, and Wenbin Lin pp 6014–6015 DOI: 10.1021/ja029926s Supporting Info

Validation of a Model for the Complex of HIV-1 Reverse Transcriptase with Nonnucleoside Inhibitor TMC125 Marina Udier-Blagović, Julian Tirado-Rives, and William L. Jorgensen pp 6016–6017 DOI: 10.1021/ja034308c

[3 + 2] Annulation of Allylic Silanes in Acyclic Stereocontrol:  Total Synthesis of (9S)-Dihydroerythronolide A Zhi-Hui Peng and K. A. Woerpel pp 6018–6019 DOI: 10.1021/ja034865z Supporting Info

Reversible, Electrochemical Interconversion of NADH and NAD+ by the Catalytic (Iλ) Subcomplex of Mitochondrial NADH:Ubiquinone Oxidoreductase (Complex I) Yanbing Zu, Richard J. Shannon, and Judy Hirst pp 6020–6021 DOI: 10.1021/ja0343961

A Free, Tricoordinate Stannylium Cation Joseph B. Lambert, Lijun Lin, Shahar Keinan, and Thomas Müller pp 6022–6023 DOI: 10.1021/ja034362t Supporting Info

Templated Assembly of Sulfide Nanoclusters into Cubic-C3N4 Type Framework Xianhui Bu, Nanfeng Zheng, Yuqi Li, and Pingyun Feng pp 6024–6025 DOI: 10.1021/ja030103s Supporting Info

(C5M2-n)n- (M = Li, Na, K, and n = 0, 1, 2). A New Family of Molecules Containing Planar Tetracoordinate Carbons Gabriel Merino, Miguel A. Méndez-Rojas, and Alberto Vela pp 6026–6027 DOI: 10.1021/ja034307k Supporting Info

Copper(I) and Copper(II) Complexes Possessing Cross-Linked Imidazole-Phenol Ligands:  Structures and Dioxygen Reactivity Kaliappan Kamaraj, Eunsuk Kim, Benedikt Galliker, Lev N. Zakharov, Arnold L. Rheingold, Andreas D. Zuberbühler, and Kenneth D. Karlin pp 6028–6029 DOI: 10.1021/ja034263f Supporting Info

Cruciform π-Systems for Molecular Electronics Applications Jennifer E. Klare, George S. Tulevski, Kenji Sugo, Anat de Picciotto, Kiley A. White, and Colin Nuckolls pp 6030–6031 DOI: 10.1021/ja0350942 Supporting Info

Dynamic NMR Line-Shape Analysis Demonstrates that the Villin Headpiece Subdomain Folds on the Microsecond Time Scale Minghui Wang, Yuefeng Tang, Satoshi Sato, Liliya Vugmeyster, C. James McKnight, and Daniel P. Raleigh pp 6032–6033 DOI: 10.1021/ja028752b Supporting Info

Generation of Phosphoranes Derived from Phosphites. A New Class of Phosphorus Ylides Leading to High E Selectivity with Semi-stabilizing Groups in Wittig Olefinations Varinder K. Aggarwal, J. Robin Fulton, Chris G. Sheldon, and Javier de Vicente pp 6034–6035 DOI: 10.1021/ja029573x Supporting Info

Pressure-Induced Hydration at 0.6 GPa in a Synthetic Gallosilicate Zeolite Yongjae Lee, Joseph A. Hriljac, Sun Jin Kim, Jonathan C. Hanson, and Thomas Vogt pp 6036–6037 DOI: 10.1021/ja034423n Supporting Info

Catalytic Enantioselective Synthesis of α-Aminooxy and α-Hydroxy Ketone Using Nitrosobenzene Norie Momiyama and Hisashi Yamamoto pp 6038–6039 DOI: 10.1021/ja0298702 Supporting Info

Total Synthesis of the Salicylate Enamide Macrolide Oximidine II1 Xiang Wang and John A. Porco, Jr. pp 6040–6041 DOI: 10.1021/ja034030o Supporting Info

The Total Synthesis of (+)-Migrastatin Christoph Gaul, Jon T. Njardarson, and Samuel J. Danishefsky pp 6042–6043 DOI: 10.1021/ja0349103 Supporting Info

ZSM-5 Monolith of Uniform Mesoporous Channels Yousheng Tao, Hirofumi Kanoh, and Katsumi Kaneko pp 6044–6045 DOI: 10.1021/ja0299405 Supporting Info

The First Suzuki Cross-Couplings of Aryltrimethylammonium Salts Simon B. Blakey and David W. C. MacMillan pp 6046–6047 DOI: 10.1021/ja034908b Supporting Info

Infrared Measurements and Calculations on H2O·HO Paul D. Cooper, Henrik G. Kjaergaard, Vaughan S. Langford, Allan J. McKinley, Terence I. Quickenden, and Daniel P. Schofield pp 6048–6049 DOI: 10.1021/ja034388k

Inorganic Electride:  Theoretical Study on Structural and Electronic Properties Zhenyu Li, Jinlong Yang, J. G. Hou, and Qingshi Zhu pp 6050–6051 DOI: 10.1021/ja034020n Supporting Info

A Terminal and Four-Coordinate Titanium Alkylidene Prepared by Oxidatively Induced α-Hydrogen Abstraction Falguni Basuli, Brad C. Bailey, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola pp 6052–6053 DOI: 10.1021/ja034786n Supporting Info

The First Conjugate Addition Reaction of Terminal Alkynes Catalytic in Copper:  Conjugate Addition of Alkynes in Water Thomas F. Knöpfel and Erick M. Carreira pp 6054–6055 DOI: 10.1021/ja035311z Supporting Info

Carbon−Carbon Bond Formation in Palladium(II)-Catalyzed Allylic Oxidation:  A Novel Oxidative Carbocyclization of Allene-Substituted Olefins Johan Franzén and Jan-E. Bäckvall pp 6056–6057 DOI: 10.1021/ja029505a Supporting Info

Efficient and Rapid C−Si Bond Cleavage in Supercritical Water Kenichiro Itami, Koji Terakawa, Jun-ichi Yoshida, and Okitsugu Kajimoto pp 6058–6059 DOI: 10.1021/ja034227g Supporting Info

Ruthenium-Catalyzed Carbon−Carbon Bond Formation between Propargylic Alcohols and Alkenes via the Allenylidene-Ene Reaction Yoshiaki Nishibayashi, Youichi Inada, Masanobu Hidai, and Sakae Uemura pp 6060–6061 DOI: 10.1021/ja035106j Supporting Info

A Novel 4-Methylideneimidazole-5-one-Containing Tyrosine Aminomutase in Enediyne Antitumor Antibiotic C-1027 Biosynthesis Steven D. Christenson, Wen Liu, Michael D. Toney, and Ben Shen pp 6062–6063 DOI: 10.1021/ja034609m

Kinetic Isotope Effects Implicate Two Electrophilic Oxidants in Cytochrome P450-Catalyzed Hydroxylations Martin Newcomb, David Aebisher, Runnan Shen, R. Esala P. Chandrasena, Paul F. Hollenberg, and Minor J. Coon pp 6064–6065 DOI: 10.1021/ja0343858 Supporting Info

Palladium-Catalyzed Deracemization of Allylic Carbonates in Water with Formation of Allylic Alcohols:  Hydrogen Carbonate Ion as Nucleophile in the Palladium-Catalyzed Allylic Substitution and Kinetic Resolution Bernhard J. Lüssem and Hans-Joachim Gais pp 6066–6067 DOI: 10.1021/ja034109t Supporting Info

Surface-Localized Release of Nitric Oxide via Sol−Gel Chemistry Mary E. Robbins and Mark H. Schoenfisch pp 6068–6069 DOI: 10.1021/ja034019o Supporting Info

Hemoglobin Dendrimers:  Functional Protein Clusters Ronald Kluger and Jie Zhang pp 6070–6071 DOI: 10.1021/ja034376z

Supramolecular Interactions between Fullerenes and Porphyrins Yi-Bo Wang and Zhenyang Lin pp 6072–6073 DOI: 10.1021/ja028998g Supporting Info

Titanium Alkoxide Complex of Functionalized Conjugated Dienes. A Versatile Bis-anionic Template for Stereoselective Construction of Carbon Frameworks Hirokazu Urabe, Kazuhisa Mitsui, Shinya Ohta, and Fumie Sato pp 6074–6075 DOI: 10.1021/ja0341844 Supporting Info

A Mild C−O Bond Formation Catalyzed by a Rhenium-Oxo Complex Benjamin D. Sherry, Alexander T. Radosevich, and F. Dean Toste pp 6076–6077 DOI: 10.1021/ja0343050 Supporting Info

Iron−Sulfur Cluster Biosynthesis. Characterization of Frataxin as an Iron Donor for Assembly of [2Fe-2S] Clusters in ISU-Type Proteins Taejin Yoon and J. A. Cowan pp 6078–6084 DOI: 10.1021/ja027967i

Cross-Reactive Arrays Based on Three-Way Junctions Milan N. Stojanović, Eric G. Green, Stanka Semova, Dragan B. Nikić, and Donald W. Landry pp 6085–6089 DOI: 10.1021/ja0289550 Supporting Info

NMR Studies of DNA Single Strands and DNA:RNA Hybrids with and without 1-Propynylation at C5 of Oligopyrimidines, Brent M. Znosko, Thomas W. Barnes, III, Thomas R. Krugh, and Douglas H. Turner pp 6090–6097 DOI: 10.1021/ja021285d Supporting Info

Base Sequence Effects in Radical Cation Migration in Duplex DNA:  Support for the Polaron-Like Hopping Model Chu-Sheng Liu and Gary B. Schuster pp 6098–6102 DOI: 10.1021/ja029333h Supporting Info

Synthesis and Biological Evaluation of Rhizobium sin-1 Lipid A Derivatives Alexei V. Demchenko, Margreet A. Wolfert, Balaji Santhanam, James N. Moore, and Geert-Jan Boons pp 6103–6112 DOI: 10.1021/ja029316s Supporting Info

Synthesis and Characterization of Model Compounds of the Lysine Tyrosyl Quinone Cofactor of Lysyl Oxidase Minae Mure, Sophie X. Wang, and Judith P. Klinman pp 6113–6125 DOI: 10.1021/ja0214274 Supporting Info

Reverse Proteolysis Promoted by in Situ Generated Peptide Ester Fragments Nicole Wehofsky, Norman Koglin, Sven Thust, and Frank Bordusa pp 6126–6133 DOI: 10.1021/ja0344213

The Effect of Minor-Groove Hydrogen-Bond Acceptors and Donors on the Stability and Replication of Four Unnatural Base Pairs Shigeo Matsuda, Allison A. Henry, Peter G. Schultz, and Floyd E. Romesberg pp 6134–6139 DOI: 10.1021/ja034099w Supporting Info

Surface Plasmon Resonance Imaging Studies of Protein-Carbohydrate Interactions Emily A. Smith, William D. Thomas, Laura L. Kiessling, and Robert M. Corn pp 6140–6148 DOI: 10.1021/ja034165u Supporting Info

Chemoselective Ligation Applied to the Synthesis of a Biantennary N-Linked Glycoform of CD52 Matthew R. Pratt and Carolyn R. Bertozzi pp 6149–6159 DOI: 10.1021/ja029346v Supporting Info

Synthesis, Structural Characterization, and Immunological Properties of Carbon Nanotubes Functionalized with Peptides Davide Pantarotto, Charalambos D. Partidos, Roland Graff, Johan Hoebeke, Jean-Paul Briand, Maurizio Prato, and Alberto Bianco pp 6160–6164 DOI: 10.1021/ja034342r Supporting Info

Rational Design of a Calcium-Binding Protein Wei Yang, Lisa M. Jones, Leanne Isley, Yiming Ye, Hsiau-Wei Lee, Anna Wilkins, Zhi-ren Liu, Homme W. Hellinga, Russell Malchow, Mohammed Ghazi, and Jenny J. Yang pp 6165–6171 DOI: 10.1021/ja034724x

Singlet Molecular Oxygen Generated from Lipid Hydroperoxides by the Russell Mechanism:  Studies Using 18O-Labeled Linoleic Acid Hydroperoxide and Monomol Light Emission Measurements Sayuri Miyamoto, Glaucia R. Martinez, Marisa H. G. Medeiros, and Paolo Di Mascio pp 6172–6179 DOI: 10.1021/ja029115o Supporting Info

A Novel and Rapid Encoding Method Based on Mass Spectrometry for “One-Bead-One-Compound” Small Molecule Combinatorial Libraries Aimin Song, Jinhua Zhang, Carlito B. Lebrilla, and Kit S. Lam pp 6180–6188 DOI: 10.1021/ja034539j Supporting Info

Protonation and Reactivity towards Carbon Dioxide of the Mononuclear Tetrahedral Zinc and Cobalt Hydroxide Complexes, [TpBut,Me]ZnOH and [TpBut,Me]CoOH:  Comparison of the Reactivity of the Metal Hydroxide Function in Synthetic Analogues of Carbonic Anhydrase Catherine Bergquist, Tauqir Fillebeen, Melissa M. Morlok, and Gerard Parkin pp 6189–6199 DOI: 10.1021/ja034711j Supporting Info

Molecular Recognition of α,β-Unsaturated Carbonyl Compounds Using Aluminum Tris(2,6-diphenylphenoxide) (ATPH):  Structural and Conformational Analysis of ATPH Complexes and Application to the Selective Vinylogous Aldol Reaction Susumu Saito, Takashi Nagahara, Masahito Shiozawa, Masakazu Nakadai, and Hisashi Yamamoto pp 6200–6210 DOI: 10.1021/ja0205941 Supporting Info

Bicarbonate Surfoxidants:  Micellar Oxidations of Aryl Sulfides with Bicarbonate-Activated Hydrogen Peroxide Huirong Yao and David E. Richardson pp 6211–6221 DOI: 10.1021/ja0274756 Supporting Info

Spectroscopic Investigations of Bis(sulfoximine) Copper(II) Complexes and Their Relevance in Asymmetric Catalysis Carsten Bolm, Marc Martin, Georg Gescheidt, Cornelia Palivan, Dmytro Neshchadin, Helmut Bertagnolli, Martin Feth, Arthur Schweiger, George Mitrikas, and Jeffrey Harmer pp 6222–6227 DOI: 10.1021/ja027870w

Synthesis, Structures, and Conformational Characteristics of Calixarene Monoanions and Dianions Tracy A. Hanna, Lihua Liu, Alfredo M. Angeles-Boza, Xiaodi Kou, C. David Gutsche, Krzysztof Ejsmont, William H. Watson, Lev N. Zakharov, Christopher D. Incarvito, and Arnold L. Rheingold pp 6228–6238 DOI: 10.1021/ja0289797 Supporting Info

Asymmetric Environments in Encapsulation Complexes Alessandro Scarso, Alexander Shivanyuk, Osamu Hayashida, and Julius Rebek, Jr. pp 6239–6243 DOI: 10.1021/ja029574p

Dendrimer-Tuned Formation of Luminescent Organic Microcrystals Franck Bertorelle, Dominique Lavabre, and Suzanne Fery-Forgues pp 6244–6253 DOI: 10.1021/ja029822h Supporting Info

Using Soluble Polymers in Latent Biphasic Systems David E. Bergbreiter, Philip L. Osburn, Thomas Smith, Chunmei Li, and Jonathon D. Frels pp 6254–6260 DOI: 10.1021/ja0342852 Supporting Info

Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions Amy B. Dounay, Keiko Hatanaka, Jeremy J. Kodanko, Martin Oestreich, Larry E. Overman, Lance A. Pfeifer, and Matthew M. Weiss pp 6261–6271 DOI: 10.1021/ja034525d Supporting Info

Stability of Thin-Film Solid-State Electroluminescent Devices Based on Tris(2,2‘-bipyridine)ruthenium(II) Complexes Gregory Kalyuzhny, Mihai Buda, Jason McNeill, Paul Barbara, and Allen J. Bard pp 6272–6283 DOI: 10.1021/ja029550i Supporting Info

Three Dimensional Architectures of Ultra-High Density Semiconducting Nanowires Deposited on Chip Kevin M. Ryan, Donats Erts, Hakan Olin, Michael A. Morris, and Justin D. Holmes pp 6284–6288 DOI: 10.1021/ja0345064

Theoretical and Experimental Consideration of the Reactions between VxOy+ and Ethylene Dina R. Justes, Roland Mitrić, Nelly A. Moore, Vlasta Bonaić-Koutecký, and A. Welford Castleman, Jr. pp 6289–6299 DOI: 10.1021/ja021349k

Temperature Dependence of the Distribution of the First Passage Time:  Results from Discontinuous Molecular Dynamics Simulations of an All-Atom Model of the Second β-Hairpin Fragment of Protein G Yaoqi Zhou, Chi Zhang, George Stell, and Jin Wang pp 6300–6305 DOI: 10.1021/ja029855x

Standing Wave Enhancement of Red Absorbance and Photocurrent in Dye-Sensitized Titanium Dioxide Photoelectrodes Coupled to Photonic Crystals Suzushi Nishimura, Neal Abrams, Bradley A. Lewis, Lara I. Halaoui, Thomas E. Mallouk, Kurt D. Benkstein, Jao van de Lagemaat, and Arthur J. Frank pp 6306–6310 DOI: 10.1021/ja034650p

Theoretical Studies on the Mechanism of Inhibition of Ribonucleotide Reductase by (E)-2‘-Fluoromethylene-2‘-deoxycitidine-5‘-diphosphate Pedro Alexandrino Fernandes and Maria João Ramos pp 6311–6322 DOI: 10.1021/ja0208613 Supporting Info

Modeling the Polymorphism of Pentacene Christine C. Mattheus, Gilles A. de Wijs, Robert A. de Groot, and Thomas T. M. Palstra pp 6323–6330 DOI: 10.1021/ja0211499

8-Oxoguanine Enhances Bending of DNA that Favors Binding to Glycosylases John H. Miller, Cheng-Chih P. Fan-Chiang, T. P. Straatsma, and Michael A. Kennedy pp 6331–6336 DOI: 10.1021/ja029312n

Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations  [J. Am. Chem. Soc. 2003, 125, 2652−2666].  W. C. Peter Tsang, Kai C. Hultzsch, John B. Alexander, Peter J. Bonitatebus, Jr., Richard R. Schrock, and Amir H. Hoveyda p 6337 DOI: 10.1021/ja033446z

Dynamic Effects on J-Couplings Across Hydrogen Bonds in Proteins.  [J. Am. Chem. Soc. 2003, 125, 644−645].  Phineus R. L. Markwick, Remco Sprangers, and Michael Sattler p 6337 DOI: 10.1021/ja0339854

Organic Ion Radicals:  Chemistry and Applications By Zory V. Todres (Columbus, OH). Marcel Dekker, Inc.:  New York and Basel. 2003. xvi + 444 pp. $185.00. ISBN 0-8247-0810-5. R. Daniel Little p 6338 DOI: 10.1021/ja0253080

Polymer Films with Embedded Metal Nanoparticles. Springer Series in Materials Science. Volume 52 By Andreas Heilmann (Fraunhofer-Institut für Werkstoffmechanik). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 216 pp. $79.95. ISBN 3-540-43151-9. Patty Wisian-Neilson pp 6338–6339 DOI: 10.1021/ja025352f

Annual Reports on NMR Spectroscopy Volume 45. Edited by G. A. Webb (Royal Society of Chemistry, London). Academic Press (An Imprint of Elsevier Science):  London, San Diego. 2002. x + 202 pp. $139.95. ISBN 0-12-505448-3. Mary Hatcher-Skeers p 6339 DOI: 10.1021/ja025350v

Solvent Mixtures:  Properties and Selective Solvation By Yizhak Marcus (The Hebrew University of Jerusalem). Marcel Dekker, Inc.:  New York, Basel. 2002. xviii + 258 pp. $150.00. ISBN 0-8247-0837-7. Alexander Van Hook pp 6339–6340 DOI: 10.1021/ja025309s

Principles and Applications of Ion Scattering Spec-trometry:  Surface Chemical and Structural Analy-sis By J. Wayne Rabalais (University of Houston). John Wiley & Sons, Inc.:  Hoboken, NJ. 2003. xvi + 306 pp. $94.95. ISBN 0-471-20277-0. Vaneica Y. Young pp 6340–6341 DOI: 10.1021/ja025336i

Encyclopedia of Catalysis, Volumes 1−6 Edited by Istvan T. Horvath (Eotvos Lorand University, Budapest). John Wiley & Sons, Inc.:  Hoboken. 2002. 4918 pp. $1995.00. ISBN 0-471-24183-0. p 6341 DOI: 10.1021/ja025360w

Encyclopedia of Agrochemicals, Volumes 1−3 Edited by Jack R. Plimmer. John Wiley & Sons, Inc.:  Hoboken. 2002. 1664 pp. $975.00. ISBN 0-471-19363-1. p 6341 DOI: 10.1021/ja025361o

Mass Spectrometry and Hyphenated Techniques in Neuropepetide Research Edited by Jerzy Silberring (Jagiellonian University, Krakow, Poland) and Rolf Ekman (Göteborg University/Sahlgrenska University Hospital, Molndal, Sweden). J. Wiley & Sons:  New York. 2002. xiv + 558 pp. $99.95. ISBN 0-471-35493-7. Susan E. Martin pp 6341–6342 DOI: 10.1021/ja025294y

Issue 21

Enantioselective Total Synthesis of (+)-Dibromophakellstatin Karine G. Poullennec and Daniel Romo pp 6344–6345 DOI: 10.1021/ja034575i Supporting Info

Helix-Sense-Selective Polymerization of Phenylacetylene Having Two Hydroxy Groups Using a Chiral Catalytic System Toshiki Aoki, Takashi Kaneko, Naoki Maruyama, Atsushi Sumi, Masahiko Takahashi, Takashi Sato, and Masahiro Teraguchi pp 6346–6347 DOI: 10.1021/ja021233o Supporting Info

Reversal of the Apparent Regiospecificity of NAD(P)H-Dependent Hydride Transfer:  The Properties of the Difluoromethylene Group, A Carbonyl Mimic Caroline Leriche, Xuemei He, Cheng-wei T. Chang, and Hung-wen Liu pp 6348–6349 DOI: 10.1021/ja021487+ Supporting Info

pH- and Thermosensitive Supramolecular Assembling System:  Rapidly Responsive Properties of β-Cyclodextrin-Conjugated Poly(ε-lysine) Hak Soo Choi, Kang Moo Huh, Tooru Ooya, and Nobuhiko Yui pp 6350–6351 DOI: 10.1021/ja034149x Supporting Info

Vanadium-Binding Protein in a Vanadium-Rich Ascidian Ascidia sydneiensis samea:  CW and Pulsed EPR Studies Kôichi Fukui, Tatsuya Ueki, Hiroaki Ohya, and Hitoshi Michibata pp 6352–6353 DOI: 10.1021/ja034507w Supporting Info

Metal Incorporation in Modified PNA Duplexes Delia-Laura Popescu, Terry J. Parolin, and Catalina Achim pp 6354–6355 DOI: 10.1021/ja029714v Supporting Info

Cationic Terminal Borylenes by Halide Abstraction:  Synthesis and Spectroscopic and Structural Characterization of an FeB Double Bond Deborah L. Coombs, Simon Aldridge, Cameron Jones, and David J. Willock pp 6356–6357 DOI: 10.1021/ja0346936 Supporting Info

Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes Michinori Suginome, Akihiko Yamamoto, and Masahiro Murakami pp 6358–6359 DOI: 10.1021/ja0349195 Supporting Info

Complexation Promoted Additions to N-Benzoyliminopyridinium Ylides. A Novel and Highly Regioselective Approach to Polysubstituted Piperidines Claude Legault and André B. Charette pp 6360–6361 DOI: 10.1021/ja0348647 Supporting Info

Enantioselective Synthesis of α-Substituted Ketones by Asymmetric Addition of Chiral Zinc Enamides to 1-Alkenes Masaharu Nakamura, Takuji Hatakeyama, Kenji Hara, and Eiichi Nakamura pp 6362–6363 DOI: 10.1021/ja035091p Supporting Info

pH-Triggered Strand Exchange in Coiled-Coil Heterotrimers Nathan A. Schnarr and Alan J. Kennan pp 6364–6365 DOI: 10.1021/ja029344a Supporting Info

Catalytic Alcoholysis of Tetramethylsilane via Pt-Mediated C−H Bond Activation Alan F. Heyduk, Jay A. Labinger, and John E. Bercaw pp 6366–6367 DOI: 10.1021/ja029099v Supporting Info

Directed Self-Assembly of Two Kinds of Nanoparticles Utilizing Monolayer Films of Diblock Copolymer Micelles Byeong-Hyeok Sohn, Jeong-Min Choi, Seong Il Yoo, Sang-Hyun Yun, Wang-Cheol Zin, Jin Chul Jung, Masayuki Kanehara, Takuji Hirata, and Toshiharu Teranishi pp 6368–6369 DOI: 10.1021/ja035069w Supporting Info

Novel Rhodium-Catalyzed Cycloisomerization of 1,6-Enynes with an Intramolecular Halogen Shift Xiaofeng Tong, Zhaoguo Zhang, and Xumu Zhang pp 6370–6371 DOI: 10.1021/ja034096j Supporting Info

A Hydroacylation-Triggered Carbon−Carbon Triple Bond Cleavage in Alkynes via Retro-Mannich Type Fragmentation Dae-Yon Lee, Boo-Sun Hong, Eung-Goo Cho, Hyuk Lee, and Chul-Ho Jun pp 6372–6373 DOI: 10.1021/ja034337n Supporting Info

Gold Nanoparticles as Spectroscopic Enhancers for in Vitro Studies on Single Viruses Bogdan Dragnea, Chao Chen, Eun-Soo Kwak, Barry Stein, and C. Cheng Kao pp 6374–6375 DOI: 10.1021/ja0343609 Supporting Info

Preparation of Unidirectional End-Grafted α-Helical Polypeptides by Solvent Quenching Yuli Wang and Ying Chih Chang pp 6376–6377 DOI: 10.1021/ja034428k Supporting Info

Superior Duplex DNA Strand Invasion by Acridine Conjugated Peptide Nucleic Acids Thomas Bentin and Peter E. Nielsen pp 6378–6379 DOI: 10.1021/ja029936t

Nucleation of One Polymorph by Another Lian Yu pp 6380–6381 DOI: 10.1021/ja0351544

Simulation of Pore Formation in Lipid Bilayers by Mechanical Stress and Electric Fields D. Peter Tieleman, Hari Leontiadou, Alan E. Mark, and Siewert-Jan Marrink pp 6382–6383 DOI: 10.1021/ja029504i

Diradical Mechanism for the [2 + 2] Cycloaddition of Ethylene on Si(100) Surface Xin Lu pp 6384–6385 DOI: 10.1021/ja034779z

Interfacial Synthesis of Hollow TiO2 Microspheres in Ionic Liquids Takuya Nakashima and Nobuo Kimizuka pp 6386–6387 DOI: 10.1021/ja034954b Supporting Info

Triflimide Activation of a Chiral Oxazaborolidine Leads to a More General Catalytic System for Enantioselective Diels−Alder Addition Do Hyun Ryu and E. J. Corey pp 6388–6390 DOI: 10.1021/ja035393r Supporting Info

Exploiting Amyloid Fibril Lamination for Nanotube Self-Assembly Kun Lu, Jaby Jacob, Pappannan Thiyagarajan, Vincent P. Conticello, and David G. Lynn pp 6391–6393 DOI: 10.1021/ja0341642 Supporting Info

Spectroscopy and Bonding in Side-On and End-On Cu2(S2) Cores:  Comparison to Peroxide Analogues Peng Chen, Kiyoshi Fujisawa, Matthew E. Helton, Kenneth D. Karlin, and Edward I. Solomon pp 6394–6408 DOI: 10.1021/ja0214678 Supporting Info

Polyunsaturated Docosahexaenoic vs Docosapentaenoic AcidDifferences in Lipid Matrix Properties from the Loss of One Double Bond Nadukkudy V. Eldho, Scott E. Feller, Stephanie Tristram-Nagle, Ivan V. Polozov, and Klaus Gawrisch pp 6409–6421 DOI: 10.1021/ja029029o Supporting Info

Effect of 3-Hydroxyproline Residues on Collagen Stability Cara L. Jenkins, Lynn E. Bretscher, Ilia A. Guzei, and Ronald T. Raines pp 6422–6427 DOI: 10.1021/ja034015j Supporting Info

Surfaces Designed for Charge Reversal James R. Matthews, Dönüs Tuncel, Robert M. J. Jacobs, Colin D. Bain, and Harry L. Anderson pp 6428–6433 DOI: 10.1021/ja028338b Supporting Info

Metal−Ligand Charge-Transfer-Promoted Photoelectronic Bergman Cyclization of Copper Metalloenediynes:  Photochemical DNA Cleavage via C-4‘ H-Atom Abstraction Pedro J. Benites, Rebecca C. Holmberg, Diwan S. Rawat, Brian J. Kraft, Lee J. Klein, Dennis G. Peters, H. Holden Thorp, and Jeffrey M. Zaleski pp 6434–6446 DOI: 10.1021/ja020939f

Supramolecular Assembly of Poly(phenylene vinylene) with Crown Ether Substituents To Form Nanoribbons Yan-Hong Luo, Hong-Wei Liu, Fu Xi, Lin Li, Xi-Gao Jin, Charles C. Han, and Chi-Ming Chan pp 6447–6451 DOI: 10.1021/ja0297739

A Novel Family of Ordered, Mesoporous Inorganic/Organic Hybrid Polymers Containing Covalently and Multiply Bound Microporous Organic Hosts Chunqing Liu, Joseph B. Lambert, and Lei Fu pp 6452–6461 DOI: 10.1021/ja0213930 Supporting Info

New Strategic Reactions for Organic Synthesis:  Catalytic Asymmetric C−H Activation α to Nitrogen as a Surrogate for the Mannich Reaction Huw M. L. Davies, Chandrasekar Venkataramani, Tore Hansen, and Darrin W. Hopper pp 6462–6468 DOI: 10.1021/ja0290072 Supporting Info

Aminoglycoside Complexation with a DNA·RNA Hybrid Duplex:  The Thermodynamics of Recognition and Inhibition of RNA Processing Enzymes Christopher M. Barbieri, Tsai-Kun Li, Susan Guo, Gang Wang, Anthony J. Shallop, Weidong Pan, Gengcheng Yang, Barbara L. Gaffney, Roger A. Jones, and Daniel S. Pilch pp 6469–6477 DOI: 10.1021/ja021371d

The 2-Oxocyclohexanecarboxylic Acid Keto−Enol System in Aqueous Solution J. A. Chang, A. J. Kresge, V. A. Nikolaev, and V. V. Popik pp 6478–6484 DOI: 10.1021/ja030054j Supporting Info

A m-Benzyne to o-Benzyne Conversion through a 1,2-Shift of a Phenyl Group Michael E. Blake, Kevin L. Bartlett, and Maitland Jones, Jr. pp 6485–6490 DOI: 10.1021/ja0213672 Supporting Info

Nanoparticle-Cored Dendrimers:  Synthesis and Characterization Karical R. Gopidas, James K. Whitesell, and Marye Anne Fox pp 6491–6502 DOI: 10.1021/ja029544m

Universal Iterative Strategy for the Divergent Synthesis of Dendritic Macromolecules from Conventional Monomers by a Combination of Living Radical Polymerization and Irreversible TERminator Multifunctional INItiator (TERMINI) Virgil Percec, Bogdan Barboiu, Cristian Grigoras, and Tushar K. Bera pp 6503–6516 DOI: 10.1021/ja034746j

Multivalent Drug Design. Synthesis and In Vitro Analysis of an Array of Vancomycin Dimers John H. Griffin, Martin S. Linsell, Matthew B. Nodwell, QiQi Chen, John L. Pace, Kelly L. Quast, Kevin M. Krause, Lesley Farrington, Terry X. Wu, Deborah L. Higgins, Thomas E. Jenkins, Burton G. Christensen, and J. Kevin Judice pp 6517–6531 DOI: 10.1021/ja021273s Supporting Info

Metallacarbenes from Diazoalkanes:  An Experimental and Computational Study of the Reaction Mechanism Revital Cohen, Boris Rybtchinski, Mark Gandelman, Haim Rozenberg, Jan M. L. Martin, and David Milstein pp 6532–6546 DOI: 10.1021/ja028923c Supporting Info

Spin-Forbidden Deprotonation of Aqueous Nitroxyl (HNO) Vladimir Shafirovich and Sergei V. Lymar pp 6547–6552 DOI: 10.1021/ja034378j

Multigram Scale Synthesis and Characterization of Monodisperse Tetragonal Zirconia Nanocrystals Jin Joo, Taekyung Yu, Young Woon Kim, Hyun Min Park, Fanxin Wu, Jin Z. Zhang, and Taeghwan Hyeon pp 6553–6557 DOI: 10.1021/ja034258b Supporting Info

Surface Treatment of Silicon Carbide Using TiO2(IV) Photocatalyst Yoshie Ishikawa, Yasumichi Matsumoto, Yoko Nishida, Shinichi Taniguchi, and Junji Watanabe pp 6558–6562 DOI: 10.1021/ja020359i

Using Spin Dynamics of Covalently Linked Radical Ion Pairs To Probe the Impact of Structural and Energetic Changes on Charge Recombination Shulamit Shaakov, Tamar Galili, Eli Stavitski, Haim Levanon, Aaron Lukas, and Michael R. Wasielewski pp 6563–6572 DOI: 10.1021/ja034356x

Non-Arrhenius Behavior in the Unfolding of a Short, Hydrophobic α-Helix. Complementarity of Molecular Dynamics and Lattice Model Simulations Olivier Collet and Christophe Chipot pp 6573–6580 DOI: 10.1021/ja029075o

Infrared Spectra of Group 14 Hydrides in Solid Hydrogen:  Experimental Observation of PbH4, Pb2H2, and Pb2H4 Xuefeng Wang and Lester Andrews pp 6581–6587 DOI: 10.1021/ja029862l

Characteristics of a Miniature Compartment-less Glucose−O2 Biofuel Cell and Its Operation in a Living Plant Nicolas Mano, Fei Mao, and Adam Heller pp 6588–6594 DOI: 10.1021/ja0346328

Layer-by-Layer Self-Assembled Chitosan/Poly(thiophene-3-acetic acid) and Organophosphorus Hydrolase Multilayers [J. Am. Chem. Soc. 2003, 125, 1805−1809]. Celeste A. Constantine, Sarita V. Mello, Annie Dupont, Xihui Cao, David Santos, Jr., Osvaldo N. Oliveira, Jr., Francisco T. Strixino, Ernesto C. Pereira, Vipin Rastogi, Tu-Chen Cheng, Joseph J. DeFrank, and Roger M. Leblanc p 6595 DOI: 10.1021/ja033447r

Intramolecular Cycloadditions of Cyclobutadiene with Olefins [J. Am. Chem. Soc. 2002, 124, 14748−14758]. John Limanto, John A. Tallarico, James R. Porter, Kelli S. Khuong, K. N. Houk, and Marc L. Snapper p 6595 DOI: 10.1021/ja035709v

Advances in Chemical Physics. Volume 123 Edited by I. Prigogine (University of Texas at Austin and Université Libre de Bruxelles) and Stuart A. Rice (University of Chicago). John Wiley & Sons, Inc.:  New York. 2002. x + 680 pp. $175.00. ISBN 0-471-21453-1. Mark E. Tuckerman pp 6596–6597 DOI: 10.1021/ja025297a

On-Line LC-NMR and Related Techniques Edited by Klaus Albert (Universität Tübingen). John Wiley & Sons, Inc.:  Chichester. 2002. xiv + 290 pp. $105.00. ISBN 0-471-49649-9. Bernhard Vogler p 6597 DOI: 10.1021/ja025335q

Contrast Agents II:  Optical, Ultrasound, X-ray and Radiopharmaceutical Imaging. Topics in Current Chemistry. Volume 222 Edited by Werner Krause (Schering AG, Berlin). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. x + 292 pp. $199.00. ISBN 3-540-43451-8. Vladimir P. Torchilin pp 6597–6598 DOI: 10.1021/ja025324x

Applied Homogeneous Catalysis with Organometallic Compounds:  A Comprehensive Handbook in Three Volumes. Second, Completely Revised and Enlarged Edition Edited by Boy Cornils (Hofheim, Germany) and Wolfgang A. Herrmann (Universität München). Wiley-VCH:  Weinheim. 2002. 1450 pp. $520.00. ISBN 3-527-30434-7. Richard A. Jones p 6598 DOI: 10.1021/ja0252936

Speciality Chemicals in Mineral Processing Edited by D. R. Skuse (IMERYS Minerals, Sandersville, GA). Royal Society of Chemistry:  Cambridge. 2002. viii + 144 pp. $129.00. ISBN 0-85404-831-6. p 6598 DOI: 10.1021/ja033502w

Issue 22

The Oxidation of Diamond:  The Geometry and Stretching Frequency of Carbonyl on the (100) Surface Phillip John, Neil Polwart, Clare E. Troupe, and John I. B. Wilson pp 6600–6601 DOI: 10.1021/ja029586a

Optically Active Polyelectrolyte Multilayers as Membranes for Chiral Separations Hassan H. Rmaile and Joseph B. Schlenoff pp 6602–6603 DOI: 10.1021/ja035251x Supporting Info

Oscillating Formation of 8-Oxoguanine during DNA Oxidation Blánaid White, Malcolm R. Smyth, James D. Stuart, and James F. Rusling pp 6604–6605 DOI: 10.1021/ja0343252 Supporting Info

Constraints on Supramolecular Structure in Amyloid Fibrils from Two-Dimensional Solid-State NMR Spectroscopy with Uniform Isotopic Labeling Robert Tycko and Yoshitaka Ishii pp 6606–6607 DOI: 10.1021/ja0342042 Supporting Info

Hydrogen Bonding as a Construction Element for Bidentate Donor Ligands in Homogeneous Catalysis:  Regioselective Hydroformylation of Terminal Alkenes Bernhard Breit and Wolfgang Seiche pp 6608–6609 DOI: 10.1021/ja0348997 Supporting Info

Chiral Sulfoxides as Neutral Coordinate-Organocatalysts in Asymmetric Allylation of N-Acylhydrazones Using Allyltrichlorosilanes Shū Kobayashi, Chikako Ogawa, Hideyuki Konishi, and Masaharu Sugiura pp 6610–6611 DOI: 10.1021/ja035061m Supporting Info

Dynamic Glycosylation of the Transcription Factor CREB: A Potential Role in Gene Regulation Nathan Lamarre-Vincent and Linda C. Hsieh-Wilson pp 6612–6613 DOI: 10.1021/ja028200t Supporting Info

Quantum Mechanical Models Correlating Structure with Selectivity:  Predicting the Enantioselectivity of β-Amino Alcohol Catalysts in Aldehyde Alkylation Marisa C. Kozlowski, Steven L. Dixon, Manoranjan Panda, and Giorgio Lauri pp 6614–6615 DOI: 10.1021/ja0293195 Supporting Info

Enhanced d-Amino Acid Incorporation into Protein by Modified Ribosomes Larisa M. Dedkova, Nour Eddine Fahmi, Serguei Y. Golovine, and Sidney M. Hecht pp 6616–6617 DOI: 10.1021/ja035141q

Reactivity of Chalcogenostannate Compounds:  Syntheses, Crystal Structures, and Electronic Properties of Novel Compounds Containing Discrete Ternary Anions [MII4(μ4-Se)(SnSe4)4]10- (MII = Zn, Mn) Stefanie Dehnen and Michael K. Brandmayer pp 6618–6619 DOI: 10.1021/ja029601b Supporting Info

A Novel Biaxial Smectic Liquid Crystalline Phase Formed by Rodlike Molecules with a 1,3-Diazaazulene Skeleton Akira Mori, Masahiro Yokoo, Masashi Hashimoto, Seiji Ujiie, Siegmar Diele, Ute Baumeister, and Carsten Tschierske pp 6620–6621 DOI: 10.1021/ja034569m Supporting Info

Chemical Formation of Mononuclear Univalent Zinc in a Microporous Crystalline Silicoaluminophosphate Ye Tian, Guo-Dong Li, and Jie-Sheng Chen pp 6622–6623 DOI: 10.1021/ja0343757 Supporting Info

Rhodium-Catalyzed Disulfide Exchange Reaction Mieko Arisawa and Masahiko Yamaguchi pp 6624–6625 DOI: 10.1021/ja035221u Supporting Info

Probing Hydrogen Bonding in a DNA Triple Helix Using Protium−Deuterium Fractionation Factors Daniel Coman and Irina M. Russu pp 6626–6627 DOI: 10.1021/ja034223b

Secondary Losses via γ-Lactam Formation in Hot Electron Capture Dissociation:  A Missing Link to Complete de Novo Sequencing of Proteins? Frank Kjeldsen and Roman Zubarev pp 6628–6629 DOI: 10.1021/ja035042c

Total Synthesis of the Duocarmycins Ken Yamada, Toshiki Kurokawa, Hidetoshi Tokuyama, and Tohru Fukuyama pp 6630–6631 DOI: 10.1021/ja035303i Supporting Info

Controlling the Aqueous Miscibility of Ionic Liquids:  Aqueous Biphasic Systems of Water-Miscible Ionic Liquids and Water-Structuring Salts for Recycle, Metathesis, and Separations Keith E. Gutowski, Grant A. Broker, Heather D. Willauer, Jonathan G. Huddleston, Richard P. Swatloski, John D. Holbrey, and Robin D. Rogers pp 6632–6633 DOI: 10.1021/ja0351802 Supporting Info

EDTA-Derivatized Deoxythymidine as a Tool for Rapid Determination of Protein Binding Polarity to DNA by Intermolecular Paramagnetic Relaxation Enhancement Junji Iwahara, D. Eric Anderson, Elizabeth C. Murphy, and G. Marius Clore pp 6634–6635 DOI: 10.1021/ja034488q Supporting Info

Thermodynamic Contributions of the Ordered Water Molecule in HIV-1 Protease Zheng Li and Themis Lazaridis pp 6636–6637 DOI: 10.1021/ja0299203

Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles Hiroto Yoshida, Junnai Ikadai, Miwa Shudo, Joji Ohshita, and Atsutaka Kunai pp 6638–6639 DOI: 10.1021/ja034571d Supporting Info

Rapid Radical Formation by DNA Charge Transport through Sequences Lacking Intervening Guanines Jae Yoo, Sarah Delaney, Eric D. A. Stemp, and Jacqueline K. Barton pp 6640–6641 DOI: 10.1021/ja034326u

A Colorimetric Lead Biosensor Using DNAzyme-Directed Assembly of Gold Nanoparticles Juewen Liu and Yi Lu pp 6642–6643 DOI: 10.1021/ja034775u Supporting Info

Electrochemical Resolution of 15 Oxidation States for Monolayer Protected Gold Nanoparticles Bernadette M. Quinn, Peter Liljeroth, Virginia Ruiz, Timo Laaksonen, and Kyösti Kontturi pp 6644–6645 DOI: 10.1021/ja0349305 Supporting Info

Carbon−Carbon Bond Cleavage of Diynes through the Hydroamination with Transition Metal Catalysts Tomohiro Shimada and Yoshinori Yamamoto pp 6646–6647 DOI: 10.1021/ja034105o Supporting Info

Spectroscopic Evidence for a Heme−Superoxide/Cu(I) Intermediate in a Functional Model of Cytochrome c Oxidase James P. Collman, Christopher J. Sunderland, Katja E. Berg, Michael A. Vance, and Edward I. Solomon pp 6648–6649 DOI: 10.1021/ja034382v Supporting Info

Enantioselective Total Synthesis of Briarellins E and F:  The First Total Syntheses of Briarellin Diterpenes Olivier Corminboeuf, Larry E. Overman, and Lewis D. Pennington pp 6650–6652 DOI: 10.1021/ja035445c Supporting Info

Expanding Pd-Catalyzed C−N Bond-Forming Processes:  The First Amidation of Aryl Sulfonates, Aqueous Amination, and Complementarity with Cu-Catalyzed Reactions Xiaohua Huang, Kevin W. Anderson, Danilo Zim, Lei Jiang, Artis Klapars, and Stephen L. Buchwald pp 6653–6655 DOI: 10.1021/ja035483w Supporting Info

Sequence-Selective DNA Cleavage by a Chimeric Metallopeptide Roger T. Kovacic, Joel T. Welch, and Sonya J. Franklin pp 6656–6662 DOI: 10.1021/ja0210998 Supporting Info

Investigation of Solvent Effects for the Claisen Rearrangement of Chorismate to Prephenate:  Mechanistic Interpretation via Near Attack Conformations Matthew P. Repasky, Cristiano Ruch Werneck Guimarães, Jayaraman Chandrasekhar, Julian Tirado-Rives, and William L. Jorgensen pp 6663–6672 DOI: 10.1021/ja021423z

Deoxyribozyme-Based Half-Adder Milan N. Stojanović and Darko Stefanović pp 6673–6676 DOI: 10.1021/ja0296632 Supporting Info

Efficient Macrocyclization of U-Turn Preorganized Peptidomimetics:  The Role of Intramolecular H-Bond and Solvophobic Effects Jorge Becerril, Michael Bolte, M. Isabel Burguete, Francisco Galindo, Enrique García-España, Santiago V. Luis, and Juan F. Miravet pp 6677–6686 DOI: 10.1021/ja0284759 Supporting Info

Attachment of Styrene and Phenylacetylene on Si(111)-7×7:  The Influence of Substitution Groups on the Reaction Mechanism and Formation of π-Conjugated Skeletons Feng Tao, Zhong Hai Wang, Yee Hing Lai, and Guo Qin Xu pp 6687–6696 DOI: 10.1021/ja0208759

Synthesis of Functional Olefin Copolymers with Controllable Topologies Using a Chain-Walking Catalyst Guanghui Chen, Xun S. Ma, and Zhibin Guan pp 6697–6704 DOI: 10.1021/ja028921s Supporting Info

Effect of Chromophore-Charge Distance on the Energy Transfer Properties of Water-Soluble Conjugated Oligomers Bin Liu, Brent S. Gaylord, Shu Wang, and Guillermo C. Bazan pp 6705–6714 DOI: 10.1021/ja028961w

Dissociative and Associative Mechanisms of Cope Rearrangements of Fluorinated 1,5-Hexadienes and 2,2‘-Bis-methylenecyclopentanes Kersey A. Black, Sarah Wilsey, and K. N. Houk pp 6715–6724 DOI: 10.1021/ja021330h

Measuring Molecular Weight by Atomic Force Microscopy Sergei S. Sheiko, Marcelo da Silva, David Shirvaniants, Isaac LaRue, Svetlana Prokhorova, Martin Moeller, Kathryn Beers, and Krzysztof Matyjaszewski pp 6725–6728 DOI: 10.1021/ja0346779

Characterization of a Stable Ruthenium Complex with an Oxyl Radical Katsuaki Kobayashi, Hideki Ohtsu, Tohru Wada, Tatsuhisa Kato, and Koji Tanaka pp 6729–6739 DOI: 10.1021/ja0211510 Supporting Info

Size-Tunable Emission from 1,3-Diphenyl-5-(2-anthryl)-2-pyrazoline Nanoparticles Debao Xiao, Lu Xi, Wensheng Yang, Hongbing Fu, Zhigang Shuai, Yan Fang, and Jiannian Yao pp 6740–6745 DOI: 10.1021/ja028674s Supporting Info

Towards Graphite:  Magnetic Properties of Large Polybenzenoid Hydrocarbons Damian Moran, Frank Stahl, Holger F. Bettinger, Henry F. Schaefer III, and Paul v. R. Schleyer pp 6746–6752 DOI: 10.1021/ja034497z Supporting Info

Stereoselective Association of Binuclear Metallacycles in Coordination Polymers Andrei N. Khlobystov, Matthew T. Brett, Alexander J. Blake, Neil R. Champness, Peter M. W. Gill, Darragh P. O'Neill, Simon J. Teat, Claire Wilson, and Martin Schröder pp 6753–6761 DOI: 10.1021/ja029048y Supporting Info

Atomistic Molecular Dynamics Simulations of Chemical Force Microscopy David L. Patrick, John F. Flanagan, IV, Patrick Kohl, and Ruth M. Lynden-Bell pp 6762–6773 DOI: 10.1021/ja0345367

Symmetry and Bonding in Metalloporphyrins. A Modern Implementation for the Bonding Analyses of Five- and Six-Coordinate High-Spin Iron(III)−Porphyrin Complexes through Density Functional Calculation and NMR Spectroscopy Ru-Jen Cheng, Ping-Yu Chen, Timothy Lovell, Tiqing Liu, Louis Noodleman, and David A. Case pp 6774–6783 DOI: 10.1021/ja021344n Supporting Info

Ion Atmosphere Relaxation and Percolative Electron Transfer in Co Bipyridine DNA Molten Salts Anthony M. Leone, Jennifer D. Tibodeau, Steven H. Bull, Stephen W. Feldberg, H. Holden Thorp, and Royce W. Murray pp 6784–6790 DOI: 10.1021/ja0348795 Supporting Info

Theoretical Study of the Magnetic Behavior of Hexanuclear Cu(II) and Ni(II) Polysiloxanolato Complexes Eliseo Ruiz, Joan Cano, Santiago Alvarez, Andrea Caneschi, and Dante Gatteschi pp 6791–6794 DOI: 10.1021/ja027966q

Relationships between Temperature, Magnetic Moment, and Continuous Symmetry Measures in Spin Crossover Complexes Santiago Alvarez pp 6795–6802 DOI: 10.1021/ja0283450 Supporting Info

A Biofuel Cell with Electrochemically Switchable and Tunable Power Output Eugenii Katz and Itamar Willner pp 6803–6813 DOI: 10.1021/ja034008v

Photodetachment of Zwitterions:  Probing Intramolecular Coulomb Repulsion and Attraction in the Gas Phase Using Mono-decarboxylated Pyridinium Dicarboxylates. Implications on the Mechanism of Orotidine 5‘-Monophosphate Decarboxylase Xue-Bin Wang, Jelena E. Dacres, Xin Yang, Lev Lis, Victoria M. Bedell, Lai-Sheng Wang, and Steven R. Kass pp 6814–6826 DOI: 10.1021/ja0290835 Supporting Info

Measurement of Multiple ψ Torsion Angles in Uniformly 13C,15N-Labeled α-Spectrin SH3 Domain Using 3D 15N−13C−13C−15N MAS Dipolar-Chemical Shift Correlation Spectroscopy Vladimir Ladizhansky, Christopher P. Jaroniec, Annette Diehl, Hartmut Oschkinat, and Robert G. Griffin pp 6827–6833 DOI: 10.1021/ja029082c

High Performance Non-Oxide Ceramics I Edited by Martin Jansen (Max-Planck-Institut für Festkorperforschung, Stuttgart). Springer-Verlag:  Berlin, Heidelberg, New York. 2002. xvi + 198 pp. $149.00. ISBN 3-540-43131-4. Jan A. Puszynski p 6834 DOI: 10.1021/ja025306f

Advances in DNA Sequence Specific Agents. Volume 4. Series Edited by Graham B. Jones (Northeastern University). Volume Edited by Brant J. Chapman (Montclair State University). Elsevier:  Amsterdam. 2002. x + 152 pp. $95.00. ISBN 0-444-51096-06. John J. Scocca p 6834 DOI: 10.1021/ja0253282

Encyclopedia of Electrochemistry. Volume 9. Bioelectrochemistry Edited by George S. Wilson (University of Kansas). Series Edited by Allen J. Bard (University of Texas) and Martin Stratmann (Max-Planck-Institut für Eisenforschung). Wiley-VCH:  Weinheim. 2002. x + 662 pp. $320.00. ISBN 3-527-30401-0. Michael V. Mirkin pp 6834–6835 DOI: 10.1021/ja025329u

Annual Reports on NMR Spectroscopy, Volume 45 Edited by G. A. Webb (Royal Society of Chemistry, London). Academic Press:  San Diego, London. 2002. x + 256 pp. $134.95. ISBN 0-12-505445-9. Thomas Schleich pp 6835–6836 DOI: 10.1021/ja025319t

Reviews in Computational Chemistry. Volume 18 Edited by Kenny B. Lipkowitz and Donald B. Boyd (Indiana University-Purdue University). Wiley-VCH:  Hoboken. 2002. xxxii + 350 pp. $150.00. ISBN 0-471-21576-7. René Fournier p 6836 DOI: 10.1021/ja025334y

NMR Spectroscopy of Polymers in Solution and in the Solid State Edited by H. N. Cheng (Hercules Incorporated Research Center) and Alan D. English (DuPont Central Research and Development). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2003. xiv + 448 pp. $150.00. ISBN 0-8412-3808-1. p 6836 DOI: 10.1021/ja0335115

Chemical Solution Deposition of Semiconductor Films By Gary Hodes (Weizmann Institute). Marcel Dekker, Inc.:  New York and Basel. 2003. xii + 376 pp. $150.00. ISBN 0-8247-0851-2. Mark T. Spitler pp 6836–6837 DOI: 10.1021/ja0253336

Medicinal Chemistry:  Principles and Practice. Second Edition Edited by Frank D. King (GlaxoSmithKline, UK). Royal Society of Chemistry:  Cambridge. 2002. xxvii + 448 pp. $79.95. ISBN 0-85404-631-3 (Softcover). Sean Michael Kerwin pp 6837–6838 DOI: 10.1021/ja025346j

Atomic and Molecular Photoabsorption:  Absolute Total Cross Sections By Joseph Berkowitz (Argonne National Laboratory). Academic Press:  San Diego, London. 2002. viii + 350 pp. $99.95. ISBN 0-12-091841-2. Peter W. Langhoff pp 6838–6839 DOI: 10.1021/ja025321k

Zeolites for Cleaner Technologies Edited by Michel Guisnet (Université de Poitiers) and Jean-Pierre Gilson (Université de Caen). Catalytic Science Series, Volume 3. Series Edited by Graham J. Hutchings (Cardiff University). Imperial College Press:  London. 2002. x + 378 pp. $78.00. ISBN 1-86094-329-2. p 6839 DOI: 10.1021/ja033503o

Characterization of Materials, Two Volume Set Edited by Elton Kaufmann (Argonne National Laboratory). J. Wiley & Sons, Inc.:  Hoboken. 2003. 1392 pp. $400.00. ISBN 0-471-26882-8. p 6839 DOI: 10.1021/ja033512x

Encyclopedia of Electrochemistry. Volume 1. Thermodynamics and Electrified Interfaces Edited by Eliezer Gileadi and Michael Urbakh (Tel Aviv University, Israel). Series Edited by Allen J. Bard and Martin Stratmann. Wiley-VCH:  Weinheim. 2002. x + 610 pp. $365.00. ISBN 3-527-30393-6. Antonella Badia pp 6839–6840 DOI: 10.1021/ja025330t

Issue 23

Kinetics of Weak Distance-Dependent Hole Transfer in DNA by Adenine-Hopping Mechanism Kiyohiko Kawai, Tadao Takada, Sachiko Tojo, and Tetsuro Majima pp 6842–6843 DOI: 10.1021/ja034953j

Osmium Replica of Mesoporous Silicate MCM-48:  Efficient and Reusable Catalyst for Oxidative Cleavage and Dihydroxylation Reactions Kwangyeol Lee, Yong-Ho Kim, Soo Bong Han, Hongkyu Kang, Soyoung Park, Won Seok Seo, Joon T. Park, Bongsoo Kim, and Sukbok Chang pp 6844–6845 DOI: 10.1021/ja034137b Supporting Info

A Concise Approach to Structurally Diverse β-Amino Acids Aaron R. Minter, Amelia A. Fuller, and Anna K. Mapp pp 6846–6847 DOI: 10.1021/ja0298747 Supporting Info

Fabrication of Assembled Virus Nanostructures on Templates of Chemoselective Linkers Formed by Scanning Probe Nanolithography Chin Li Cheung, Julio A. Camarero, Bruce W. Woods, Tianwei Lin, John E. Johnson, and Jim J. De Yoreo pp 6848–6849 DOI: 10.1021/ja034479h Supporting Info

Different Binding Orientations for the Same Agonist at Homologous Receptors:  A Lock and Key or a Simple Wedge? Ting-Wei Mu, Henry A. Lester, and Dennis A. Dougherty pp 6850–6851 DOI: 10.1021/ja0348086 Supporting Info

Novel Selective Inhibitors of the Interaction of Individual Nuclear Hormone Receptors with a Mutually Shared Steroid Receptor Coactivator 2 Timothy R. Geistlinger and R. Kiplin Guy pp 6852–6853 DOI: 10.1021/ja0348391 Supporting Info

Manipulating Supramolecular Self-Assembly via Tailoring Pendant Group Size of Linear Vinyl Polymers Xiao-Ying Yin, Chun Ye, Xun Ma, Er-Qiang Chen, Xiao-Ying Qi, Xiao-Feng Duan, Xin-Hua Wan, Stephen Z. D. Cheng, and Qi-Feng Zhou pp 6854–6855 DOI: 10.1021/ja034462z Supporting Info

General Approach for the Synthesis of Chiral Perylenequinones via Catalytic Enantioselective Oxidative Biaryl Coupling Carol A. Mulrooney, Xiaolin Li, Evan S. DiVirgilio, and Marisa C. Kozlowski pp 6856–6857 DOI: 10.1021/ja027745k Supporting Info

Detection of Short-Lived Transient Protein−Protein Interactions by Intermolecular Nuclear Paramagnetic Relaxation:  Plastocyanin from Anabaena variabilis D. Flemming Hansen, Mathias A. S. Hass, Hans M. Christensen, Jens Ulstrup, and Jens J. Led pp 6858–6859 DOI: 10.1021/ja034013z

Enantioselective Cyclization of Racemic Supramolecular Polymers A. Tessa ten Cate, Patricia Y. W. Dankers, Huub Kooijman, Anthony L. Spek, Rint P. Sijbesma, and E. W. Meijer pp 6860–6861 DOI: 10.1021/ja034273g Supporting Info

Photoinduced Polarization Inversion in a Ferroelectric Liquid Crystal Using an Ambidextrous Chiral Thioindigo Dopant Jason Z. Vlahakis, Michael D. Wand, and Robert P. Lemieux pp 6862–6863 DOI: 10.1021/ja0353309

Enantioselective Total Synthesis of Ustiloxin D Hiroko Tanaka, Andrew M. Sawayama, and Thomas J. Wandless pp 6864–6865 DOI: 10.1021/ja035429f Supporting Info

Kinetics and Thermodynamics of Copper(II) Binding to Apoazurin Cheryl A. Blasie and Jeremy M. Berg pp 6866–6867 DOI: 10.1021/ja035333l

Probing the Rhodopsin Cavity with Reduced Retinal Models at the CASPT2//CASSCF/AMBER Level of Theory Nicolas Ferré and Massimo Olivucci pp 6868–6869 DOI: 10.1021/ja035087d Supporting Info

Defining Space around Conducting Polymers:  Reversible Protonic Doping of a Canopied Polypyrrole Dongwhan Lee and Timothy M. Swager pp 6870–6871 DOI: 10.1021/ja034894+ Supporting Info

Formation and Properties of Cyclo[6]pyrrole and Cyclo[7]pyrrole Thomas Köhler, Daniel Seidel, Vincent Lynch, Forrest O. Arp, Zhongping Ou, Karl M. Kadish, and Jonathan L. Sessler pp 6872–6873 DOI: 10.1021/ja035089y Supporting Info

Cytosol-Mimetic Chemistry:  Kinetics of the Trypsin-Catalyzed Hydrolysis of p-Nitrophenyl Acetate upon Addition of Polyethylene Glycol and N-tert-Butyl Acetoacetamide Nabil Asaad and Jan B. F. N. Engberts pp 6874–6875 DOI: 10.1021/ja034298f Supporting Info

A Gate to Organokrypton Chemistry:  HKrCCH Leonid Khriachtchev, Hanna Tanskanen, Arik Cohen, R. Benny Gerber, Jan Lundell, Mika Pettersson, Harri Kiljunen, and Markku Räsänen pp 6876–6877 DOI: 10.1021/ja0355269

Novel Binding and Efficient Cellular Uptake of Guanidine-Based Peptide Nucleic Acids (GPNA) Peng Zhou, Miaomiao Wang, Lei Du, Gregory W. Fisher, Alan Waggoner, and Danith H. Ly pp 6878–6879 DOI: 10.1021/ja029665m Supporting Info

Deoxyribozymes That Synthesize Branched and Lariat RNA Yangming Wang and Scott K. Silverman pp 6880–6881 DOI: 10.1021/ja035150z Supporting Info

A Novel, Highly Electrical Conducting, Single-Component Molecular Material:  [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) Shao-Liang Zheng, Jie-Peng Zhang, Wing-Tak Wong, and Xiao-Ming Chen pp 6882–6883 DOI: 10.1021/ja029097a Supporting Info

Site-Selective Iodine−Magnesium Exchange Reaction of 1,4-Diiodo-1,3-Alkadienes by an Organomagnesium Ate Complex, and Its Application to Synthesis of Polysubstituted Styrenes and Phenols Kohki Fukuhara, Yuuki Takayama, and Fumie Sato pp 6884–6885 DOI: 10.1021/ja0353513 Supporting Info

Chrysanthemyl Diphosphate Synthase. The Relationship among Chain Elongation, Branching, and Cyclopropanation Reactions in the Isoprenoid Biosynthetic Pathway Hans K. Erickson and C. Dale Poulter pp 6886–6888 DOI: 10.1021/ja034520g Supporting Info

Temperature-Dependent Transitions between Normal and Inverse Equilibrium Isotope Effects for Coordination and Oxidative Addition of C−H and H−H Bonds to a Transition Metal Center Kevin E. Janak and Gerard Parkin pp 6889–6891 DOI: 10.1021/ja034559l Supporting Info

Contributions of Conformational Compression and Preferential Transition State Stabilization to the Rate Enhancement by Chorismate Mutase Cristiano Ruch Werneck Guimarães, Matthew P. Repasky, Jayaraman Chandrasekhar, Julian Tirado-Rives, and William L. Jorgensen pp 6892–6899 DOI: 10.1021/ja021424r

Incorporation of Trifluoroisoleucine into Proteins in Vivo Pin Wang, Yi Tang, and David A. Tirrell pp 6900–6906 DOI: 10.1021/ja0298287

Shape-Persistant Macrocycles with Terpyridine Units:  Synthesis, Characterization, and Structure in the Crystal Christian Grave, Dieter Lentz, Andreas Schäfer, Paolo Samorì, Jürgen P. Rabe, Peter Franke, and A. Dieter Schlüter pp 6907–6918 DOI: 10.1021/ja034029p Supporting Info

Light-Driven Decarboxylation of Wild-Type Green Fluorescent Protein Alasdair F. Bell, Deborah Stoner-Ma, Rebekka M. Wachter, and Peter J. Tonge pp 6919–6926 DOI: 10.1021/ja034588w

Direct Determination of the Complete Set of Iron Normal Modes in a Porphyrin-Imidazole Model for Carbonmonoxy-heme Proteins:  [Fe(TPP)(CO)(1-MeIm)] Brajesh K. Rai, Stephen M. Durbin, Earl W. Prohofsky, J. Timothy Sage, Mary K. Ellison, Arne Roth, W. Robert Scheidt, Wolfgang Sturhahn, and E. Ercan Alp pp 6927–6936 DOI: 10.1021/ja028219w

Approaching Real-Time Molecular Diagnostics:  Single-Pair Fluorescence Resonance Energy Transfer (spFRET) Detection for the Analysis of Low Abundant Point Mutations in K-ras Oncogenes Musundi B. Wabuyele, Hannah Farquar, Wieslaw Stryjewski, Robert P. Hammer, Steven A. Soper, Yu-Wei Cheng, and Francis Barany pp 6937–6945 DOI: 10.1021/ja034716g

EPR Spin-Trapping Evidence for the Direct, One-Electron Reduction of tert-Butylhydroperoxide to the tert-Butoxyl Radical by Copper(II):  Paradigm for a Previously Overlooked Reaction in the Initiation of Lipid Peroxidation Clare M. Jones and Mark J. Burkitt pp 6946–6954 DOI: 10.1021/ja034416z

Characterization of Supramolecular (H2O)18 Water Morphology and Water-Methanol (H2O)15(CH3OH)3 Clusters in a Novel Phosphorus Functionalized Trimeric Amino Acid Host Kannan Raghuraman, Kavita K. Katti, Leonard J. Barbour, Nagavarakishore Pillarsetty, Charles L. Barnes, and Kattesh V. Katti pp 6955–6961 DOI: 10.1021/ja034682c Supporting Info

Theoretical Study of the Amazing Firefly Bioluminescence:  The Formation and Structures of the Light Emitters Galina Orlova, John D. Goddard, and Lioubov Yu. Brovko pp 6962–6971 DOI: 10.1021/ja021255a Supporting Info

Nitroxyl Disulfides, Novel Intermediates in Transnitrosation Reactions K. N. Houk, Bruce N. Hietbrink, Michael D. Bartberger, Patrick R. McCarren, Bo Yoon Choi, Robert D. Voyksner, Jonathan S. Stamler, and Eric J. Toone pp 6972–6976 DOI: 10.1021/ja029655l Supporting Info

Fluorescence Resonance Energy Transfer (FRET) as a High-Throughput Assay for Coupling Reactions. Arylation of Amines as a Case Study Shaun R. Stauffer and John F. Hartwig pp 6977–6985 DOI: 10.1021/ja034161p Supporting Info

Stereoblock Copolymers and Tacticity Control in Controlled/Living Radical Polymerization Jean-François Lutz, Dorota Neugebauer, and Krzysztof Matyjaszewski pp 6986–6993 DOI: 10.1021/ja029517w Supporting Info

Modeling the Reaction Mechanisms of the Amide Hydrolysis in an N-(o-Carboxybenzoyl)-l-amino Acid Zhijian Wu, Fuqiang Ban, and Russell J. Boyd pp 6994–7000 DOI: 10.1021/ja021329i

Ion Pairing and Host−Guest Complexation in Low Dielectric Constant Solvents Jason W. Jones and Harry W. Gibson pp 7001–7004 DOI: 10.1021/ja034442x Supporting Info

Mechanistic Investigations of the Palladium-Catalyzed Aerobic Oxidative Kinetic Resolution of Secondary Alcohols Using (−)-Sparteine Jaime A. Mueller and Matthew S. Sigman pp 7005–7013 DOI: 10.1021/ja034262n Supporting Info

Metal Ion-Promoted Intramolecular Electron Transfer in a Ferrocene-Naphthoquinone Linked Dyad. Continuous Change in Driving Force and Reorganization Energy with Metal Ion Concentration Ken Okamoto, Hiroshi Imahori, and Shunichi Fukuzumi pp 7014–7021 DOI: 10.1021/ja034831r Supporting Info

MLCT State Structure and Dynamics of a Copper(I) Diimine Complex Characterized by Pump−Probe X-ray and Laser Spectroscopies and DFT Calculations Lin X. Chen, George B. Shaw, Irina Novozhilova, Tao Liu, Guy Jennings, Klaus Attenkofer, Gerald J. Meyer, and Philip Coppens pp 7022–7034 DOI: 10.1021/ja0294663

Intermolecular Activation of Hydrocarbon C−H Bonds under Ambient Conditions by 16-Electron Neopentylidene and Benzyne Complexes of Molybdenum Kenji Wada, Craig B. Pamplin, Peter Legzdins, Brian O. Patrick, Irina Tsyba, and Robert Bau pp 7035–7048 DOI: 10.1021/ja0349094 Supporting Info

From 1D Chain to 3D Network:  Tuning Hybrid II-VI Nanostructures and Their Optical Properties Xiaoying Huang, Jing Li, Yong Zhang, and Angelo Mascarenhas pp 7049–7055 DOI: 10.1021/ja0343611 Supporting Info

Substrate Binding to NO−Ferro−Naphthalene 1,2-Dioxygenase Studied by High-Resolution Q-Band Pulsed 2H-ENDOR Spectroscopy Tran Chin Yang, Matt D. Wolfe, Matthew B. Neibergall, Yasmina Mekmouche, John D. Lipscomb, and Brian M. Hoffman pp 7056–7066 DOI: 10.1021/ja0214126 Supporting Info

Spectroscopy and Electronic Structure of Electron Deficient Zinc Phthalocyanines Steven P. Keizer, John Mack, Barbara A. Bench, Sergiu M. Gorun, and Martin J. Stillman pp 7067–7085 DOI: 10.1021/ja0299710

Peroxide Electroreduction on Bi-Modified Au Surfaces:  Vibrational Spectroscopy and Density Functional Calculations Xiao Li and Andrew A. Gewirth pp 7086–7099 DOI: 10.1021/ja034125q Supporting Info

Alloyed Semiconductor Quantum Dots:  Tuning the Optical Properties without Changing the Particle Size Robert E. Bailey and Shuming Nie pp 7100–7106 DOI: 10.1021/ja035000o

Role of Cluster Size in Catalysis:  Spectroscopic Investigation of γ-Al2O3-Supported Ir4 and Ir6 during Ethene Hydrogenation Andrew M. Argo, Josip F. Odzak, and Bruce C. Gates pp 7107–7115 DOI: 10.1021/ja027741f Supporting Info

Diffusion Anomaly as a Function of Molecular Length of Linear Molecules:  Levitation Effect Pradip Kr. Ghorai, Subramanian Yashonath, Pierfranco Demontis, and Giuseppe B. Suffritti pp 7116–7123 DOI: 10.1021/ja028534i

Imaging Structured Water and Bound Polysaccharide on Mica Surface at Ambient Temperature Chiara Spagnoli, Katja Loos, Abraham Ulman, and Mary K. Cowman pp 7124–7128 DOI: 10.1021/ja029721j

Theoretical Study of the Conversion of Sulfonyl Precursors into Chains of Poly(p-phenylene vinylene) L. Claes, J.-P. François, and M. S. Deleuze pp 7129–7138 DOI: 10.1021/ja021295e

Modulation of the Reduction Potentials of Fullerene Derivatives Maurizio Carano, Tatiana Da Ros, Marianna Fanti, Konstantinos Kordatos, Massimo Marcaccio, Francesco Paolucci, Maurizio Prato, Sergio Roffia, and Francesco Zerbetto pp 7139–7144 DOI: 10.1021/ja034795w

Issue 24

Self-Assembly Combining Two Bioactive Peptide-Amphiphile Molecules into Nanofibers by Electrostatic Attraction Krista L. Niece, Jeffrey D. Hartgerink, Jack J. J. M. Donners, and Samuel I. Stupp pp 7146–7147 DOI: 10.1021/ja028215r Supporting Info

Catalytic Activity of Supported Au Nanoparticles Deposited from Block Copolymer Micelles Thomas F. Jaramillo, Sung-Hyeon Baeck, Beatriz Roldan Cuenya, and Eric W. McFarland pp 7148–7149 DOI: 10.1021/ja029800v

Amphicatalytic Polymerization:  Synthesis of Stereomultiblock Poly(methyl methacrylate) with Diastereospecific Ion Pairs Eugene Y.-X. Chen and Megan J. Cooney pp 7150–7151 DOI: 10.1021/ja035261y Supporting Info

100% Encapsulation of a Hydrogen Molecule into an Open-Cage Fullerene Derivative and Gas-Phase Generation of H2@C60 Yasujiro Murata, Michihisa Murata, and Koichi Komatsu pp 7152–7153 DOI: 10.1021/ja0354162 Supporting Info

Multivalency and the Mode of Action of Bacterial Sialidases Smita Thobhani, Brian Ember, Aloysius Siriwardena, and Geert-Jan Boons pp 7154–7155 DOI: 10.1021/ja029759w Supporting Info

Gold Electrodes Wired for Coupling with the Deeply Buried Active Site of Arthrobacter globiformis Amine Oxidase Corinna R. Hess, Gregory A. Juda, David M. Dooley, Ricky N. Amii, Michael G. Hill, Jay R. Winkler, and Harry B. Gray pp 7156–7157 DOI: 10.1021/ja029538q Supporting Info

Regio- and Enantiospecific Rhodium-Catalyzed Arylation of Unsymmetrical Fluorinated Acyclic Allylic Carbonates:  Inversion of Absolute Configuration P. Andrew Evans and Daisuke Uraguchi pp 7158–7159 DOI: 10.1021/ja035216q Supporting Info

Chemoenzymatic Route to Macrocyclic Hybrid Peptide/Polyketide-like Molecules Rahul M. Kohli, Martin D. Burke, Junhua Tao, and Christopher T. Walsh pp 7160–7161 DOI: 10.1021/ja0352202 Supporting Info

Transfer-Printing of Highly Aligned DNA Nanowires Hidenobu Nakao, Muhammed Gad, Shigeru Sugiyama, Kazunori Otobe, and Toshio Ohtani pp 7162–7163 DOI: 10.1021/ja034185w

A New Strategy for Improved Nicotine Vaccines Using Conformationally Constrained Haptens Michael M. Meijler, Masayuki Matsushita, Laurence J. Altobell, III, Peter Wirsching, and Kim D. Janda pp 7164–7165 DOI: 10.1021/ja034805t Supporting Info

Efficient Electroluminescence from a New Terbium Complex Hao Xin, Fu You Li, Mei Shi, Zu Qiang Bian, and Chun Hui Huang pp 7166–7167 DOI: 10.1021/ja034087a Supporting Info

Bioconjugated Nanoparticles for DNA Protection from Cleavage Xiao-xiao He, Kemin Wang, Weihong Tan, Bin Liu, Xia Lin, Chunmei He, Du Li, Shasheng Huang, and Jun Li pp 7168–7169 DOI: 10.1021/ja034450d

A Metal-Centered Hydrophobic Pocket Recognizing Pyridine over Piperidine Ki-Hyun Kim, Rita Song, and Kwan Mook Kim pp 7170–7171 DOI: 10.1021/ja035126l Supporting Info

Origin of the Regiochemistry of Propene Insertion at Octahedral Column 4 Polymerization Catalysts:  Design or Serendipity? Giovanni Talarico, Vincenzo Busico, and Luigi Cavallo pp 7172–7173 DOI: 10.1021/ja029604o Supporting Info

Light-Induced Modulation of Self-Assembly on Spiropyran-Capped Gold Nanoparticles:  A Potential System for the Controlled Release of Amino Acid Derivatives Binil Itty Ipe, S. Mahima, and K. George Thomas pp 7174–7175 DOI: 10.1021/ja0341182 Supporting Info

Accurate Ionization Potentials for UO and UO2:  A Rigorous Test of Relativistic Quantum Chemistry Calculations Jiande Han, Leonid A. Kaledin, Vasiliy Goncharov, Anatoly V. Komissarov, and Michael C. Heaven pp 7176–7177 DOI: 10.1021/ja035543y

Hybrid QM/MM Study of Thio Effects in Transphosphorylation Reactions Brent A. Gregersen, Xabier Lopez, and Darrin M. York pp 7178–7179 DOI: 10.1021/ja035167h Supporting Info

Protein Semi-Synthesis in Living Cells Izabela Giriat and Tom W. Muir pp 7180–7181 DOI: 10.1021/ja034736i Supporting Info

Direct Detection of Potassium Cations Bound to G-Quadruplex Structures by Solid-State 39K NMR at 19.6 T Gang Wu, Alan Wong, Zhehong Gan, and Jeffery T. Davis pp 7182–7183 DOI: 10.1021/ja0340634

Mechanisms of Allene Stereoinversion by Imidozirconium Complexes Forrest E. Michael, Andrew P. Duncan, Zachary K. Sweeney, and Robert G. Bergman pp 7184–7185 DOI: 10.1021/ja0348389 Supporting Info

Helix−Turn−Helix Motifs in Unsolvated Peptides David T. Kaleta and Martin F. Jarrold pp 7186–7187 DOI: 10.1021/ja0353006

Diamond-Type Lipid Cubic Phase with Large Water Channels Borislav Angelov, Angelina Angelova, Michel Ollivon, Claudie Bourgaux, and Andrew Campitelli pp 7188–7189 DOI: 10.1021/ja034578v Supporting Info

Linking Atomistic and Mesoscale Simulations of Water-Soluble Polymers Massimo G. Noro, Prem K. C. Paul, and Patrick B. Warren pp 7190–7191 DOI: 10.1021/ja0343914 Supporting Info

Observation of Quantum Coherence for Recurrence Motion of Exciton in Anthracene Dimers in Solution Iwao Yamazaki, Naoki Aratani, Seiji Akimoto, Tomoko Yamazaki, and Atsuhiro Osuka pp 7192–7193 DOI: 10.1021/ja029318c Supporting Info

Diastereoselective Photochromism of a Bisbenzothienylethene Governed by Steric as Well as Electronic Interactions Yasushi Yokoyama, Hidenori Shiraishi, Yutaka Tani, Yayoi Yokoyama, and Yoshitaka Yamaguchi pp 7194–7195 DOI: 10.1021/ja029535d Supporting Info

Spectroscopic Evidence for Hydrogen Diffusion through a Several-Nanometers-Thick Titanium Carbonitride Layer on Silicon Semyon Bocharov and Andrew V. Teplyakov pp 7196–7197 DOI: 10.1021/ja035026f

Catalytic Enantioselective Hydroboration of Cyclopropenes Marina Rubina, Michael Rubin, and Vladimir Gevorgyan pp 7198–7199 DOI: 10.1021/ja034210y Supporting Info

A Strategy for the NMR Characterization of Type II Copper(II) Proteins:  the Case of the Copper Trafficking Protein CopC from Pseudomonas Syringae Fabio Arnesano, Lucia Banci, Ivano Bertini, Isabella C. Felli, Claudio Luchinat, and Andrew R. Thompsett pp 7200–7208 DOI: 10.1021/ja034112c Supporting Info

FTIR Detection of Protonation/Deprotonation of Key Carboxyl Side Chains Caused by Redox Change of the CuA-Heme a Moiety and Ligand Dissociation from the Heme a3-CuB Center of Bovine Heart Cytochrome c Oxidase Daichi Okuno, Tadashi Iwase, Kyoko Shinzawa-Itoh, Shinya Yoshikawa, and Teizo Kitagawa pp 7209–7218 DOI: 10.1021/ja021302z Supporting Info

Hydration Changes Accompanying Nucleic Acid Intercalation Reactions:Volumetric Characterizations Feixue Han and Tigran V. Chalikian pp 7219–7229 DOI: 10.1021/ja030068p

Structure Determination of a Peptide Model of the Repeated Helical Domain in Samia cynthia ricini Silk Fibroin before Spinning by a Combination of Advanced Solid-State NMR Methods Yasumoto Nakazawa and Tetsuo Asakura pp 7230–7237 DOI: 10.1021/ja0300721

Formation and Characterization of Protein−Protein Complexes in Vacuo J. Mitchell Wells, Paul A. Chrisman, and Scott A. McLuckey pp 7238–7249 DOI: 10.1021/ja035051l

Construction of Giant Dendrimers Using a Tripodal Building Block Jaime Ruiz, Gustavo Lafuente, Sylvia Marcen, Catia Ornelas, Sylvain Lazare, Eric Cloutet, Jean-Claude Blais, and Didier Astruc pp 7250–7257 DOI: 10.1021/ja021147o Supporting Info

A Unique Autocatalytic Process and Evidence for a Concerted-Stepwise Mechanism Transition in the Dissociative Electron-Transfer Reduction of Aryl Thiocyanates Abdelaziz Houmam, Emad M. Hamed, and Ian W. J. Still pp 7258–7265 DOI: 10.1021/ja028542z Supporting Info

The First Azacyclopentenyl Carbinyl Radical Isomerizations (ACCRI):  Independent Use of Steric and Electronic (Polarization) Effects as Gating Elements Rajesh Viswanathan, Daniel Mutnick, and Jeffrey N. Johnston pp 7266–7271 DOI: 10.1021/ja029426z Supporting Info

Triplex Selective 2-(2-Naphthyl)quinoline Compounds:  Origins of Affinity and New Design Principles Jonathan B. Chaires, Jinsong Ren, Maged Henary, Oliwia Zegrocka, G. Reid Bishop, and Lucjan Strekowski pp 7272–7283 DOI: 10.1021/ja034181r Supporting Info

Synthesis of [l-Ala-1]RA-VII, [d-Ala-2]RA-VII, and [d-Ala-4]RA-VII by Epimerization of RA-VII, an Antitumor Bicyclic Hexapeptide from Rubia Plants, through Oxazoles Yukio Hitotsuyanagi, Shin-ichi Sasaki, Yuji Matsumoto, Kentaro Yamaguchi, Hideji Itokawa, and Koichi Takeya pp 7284–7290 DOI: 10.1021/ja021131y Supporting Info

Michael Addition of Stannyl Ketone Enolate to α,β-Unsaturated Esters Catalyzed by Tetrabutylammonium Bromide and an ab Initio Theoretical Study of the Reaction Course Makoto Yasuda, Kouji Chiba, Noriyuki Ohigashi, Yasuhiro Katoh, and Akio Baba pp 7291–7300 DOI: 10.1021/ja028853+ Supporting Info

Single Side Strapping:  A New Approach to Fine Tuning the Anion Recognition Properties of Calix[4]pyrroles Chang-Hee Lee, Hee-Kyung Na, Dae-Wi Yoon, Dong-Hoon Won, Won-Seob Cho, Vincent M. Lynch, Sergey V. Shevchuk, and Jonathan L. Sessler pp 7301–7306 DOI: 10.1021/ja029175u Supporting Info

Mechanism of Electrophilic Chlorination:  Experimental Determination of a Geometrical Requirement for Chlorine Transfer by the Endocyclic Restriction Test Suk Joong Lee, Michael S. Terrazas, Daniel J. Pippel, and Peter Beak pp 7307–7312 DOI: 10.1021/ja0300463 Supporting Info

Chiral Conflict. The Effect of Temperature on the Helical Sense of a Polymer Controlled by the Competition between Structurally Different Enantiomers:  From Dilute Solution to the Lyotropic Liquid Crystal State Kai Tang, Mark M. Green, Kap Soo Cheon, Jonathan V. Selinger, and Bruce A. Garetz pp 7313–7323 DOI: 10.1021/ja030065c Supporting Info

Synthesis, Structure, and Dynamic Behavior of Cyclopentadienyl-Lithium, -Sodium, and -Potassium Annelated with Bicyclo[2.2.2]octene Units:  A Systematic Study on Site Exchange of Alkali Metals on a Cyclopentadienyl Ring in Tetrahydrofuran Tohru Nishinaga, Daisuke Yamazaki, Helmut Stahr, Atsushi Wakamiya, and Koichi Komatsu pp 7324–7335 DOI: 10.1021/ja0346431 Supporting Info

Two-Step FRET as a Structural Tool Heather M. Watrob, Chia-Pin Pan, and Mary D. Barkley pp 7336–7343 DOI: 10.1021/ja034564p

Spectroscopic Study of [Fe2O2(5-Et3-TPA)2]3+:  Nature of the Fe2O2 Diamond Core and Its Possible Relevance to High-Valent Binuclear Non-Heme Enzyme Intermediates Andrew J. Skulan, Melissa A. Hanson, Hua-fen Hsu, Lawrence Que, Jr., and Edward I. Solomon pp 7344–7356 DOI: 10.1021/ja021137n Supporting Info

Additivity and the Physical Basis of Multivalency Effects:  A Thermodynamic Investigation of the Calcium EDTA Interaction Trine Christensen, David M. Gooden, Joyce E. Kung, and Eric J. Toone pp 7357–7366 DOI: 10.1021/ja021240c Supporting Info

Controlled Aggregation of ME8n- Binary Anions (M = Cr, Mo; E = As, Sb) into One-Dimensional Arrays:  Structures, Magnetism and Spectroscopy Banu Kesanli, James Fettinger, and Bryan Eichhorn pp 7367–7376 DOI: 10.1021/ja034207e Supporting Info

Synthesis and Characterization of Facial and Meridional Tris-cyclometalated Iridium(III) Complexes Arnold B. Tamayo, Bert D. Alleyne, Peter I. Djurovich, Sergey Lamansky, Irina Tsyba, Nam N. Ho, Robert Bau, and Mark E. Thompson pp 7377–7387 DOI: 10.1021/ja034537z Supporting Info

Molecular Dynamics of a Dendrimer−Dye Guest−Host System Gilberto Teobaldi and Francesco Zerbetto pp 7388–7393 DOI: 10.1021/ja027905s

A Study of Homonuclear Dipolar Recoupling Pulse Sequences in Solid-State Nuclear Magnetic Resonance T. Karlsson, J. M. Popham, J. R. Long, N. Oyler, and G. P. Drobny pp 7394–7407 DOI: 10.1021/ja0294360

Immobilization of Histidine-Tagged Proteins on Nickel by Electrochemical Dip Pen Nanolithography Gunjan Agarwal, Rajesh R. Naik, and Morley O. Stone pp 7408–7412 DOI: 10.1021/ja029856p Supporting Info

A Proton-Shuttle Mechanism Mediated by the Porphyrin in Benzene Hydroxylation by Cytochrome P450 Enzymes Sam P. de Visser and Sason Shaik pp 7413–7424 DOI: 10.1021/ja034142f Supporting Info

n-Pentane and Isopentane in One-Dimensional Channels Shreyas Y. Bhide and S. Yashonath pp 7425–7434 DOI: 10.1021/ja0285868

Three-Coordinate Aluminum in Zeolites Observed with In situ X-ray Absorption Near-Edge Spectroscopy at the Al K-Edge:  Flexibility of Aluminum Coordinations in Zeolites Jeroen A. van Bokhoven, Ad M. J. van der Eerden, and Diek C. Koningsberger pp 7435–7442 DOI: 10.1021/ja0292905

In Situ FTIR Studies of Primary Intermediates of Photocatalytic Reactions on Nanocrystalline TiO2 Films in Contact with Aqueous Solutions Ryuhei Nakamura, Akihito Imanishi, Kei Murakoshi, and Yoshihiro Nakato pp 7443–7450 DOI: 10.1021/ja029503q

Solid State Separated-Local-Field NMR Spectroscopy on Half-Integer Quadrupolar Nuclei:  Principles and Applications to Borane Analysis Julia Grinshtein and Lucio Frydman pp 7451–7460 DOI: 10.1021/ja0214025

Gas Phase Dissociation Energies of Saturated AHn·+ Radical Cations and AHn Neutrals (A = Li−F, Na−Cl):  Dehydrogenation, Deprotonation, and Formation of AHn-2·+   − H2 Complexes Adrià Gil, Joan Bertran, and Mariona Sodupe pp 7461–7469 DOI: 10.1021/ja0295927

The Theory of Electron Transfer Reactions:  What May Be Missing? David W. Small, Dmitry V. Matyushov, and Gregory A. Voth pp 7470–7478 DOI: 10.1021/ja029595j

Advances in Atomic Spectroscopy, Volume 7 Edited by Joseph Sneddon (McNeese State University). Elsevier Scientific B. V.:  Amsterdam and New York. 2002. xxxii + 406 pp. $250.00. ISBN 0-444-51033-8. Alexander Scheeline p 7479 DOI: 10.1021/ja033509d

Capillary Electrophoresis of Carbohydrates. Methods in Molecular Biology, Volume 213 Edited by Pierre Thibault (Caprion Pharmaceuticals, Montréal, Canada) and Susumu Honda (Kinki University, Higashi-osaka, Japan). Humana Press:  Totowa, NJ. 2003. xiv + 318 pp. $99.50. ISBN 0-89603-826-2. p 7479 DOI: 10.1021/ja033515+

Structural Chemistry of Glasses By K. J. Rao (Indian Institute of Science, Bangalore). Elsevier:  Amsterdam. 2002. xvi + 568 pp. $120.00. ISBN 0-08-043958-6. Richard K. Brow pp 7479–7480 DOI: 10.1021/ja025315o

Ionic Liquids:  Industrial Applications to Green Chemistry Edited by Robin D. Rogers (The University of Alabama) and Kenneth R. Seddon (The Queen's University of Belfast). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2002. xiv + 474 pp. $150.00. ISBN 0-8412-3789-1. p 7480 DOI: 10.1021/ja0335162

Biophysical Chemistry:  Membranes and Proteins Edited by Richard H. Templer and Robin Leatherbarrow (Imperial College of Science and Technology, London). Royal Society of Chemistry:  Cambridge. 2002. x + 280 pp. $179.00. ISBN 0-85404-851-0. p 7480 DOI: 10.1021/ja033517u

Seminars in Organic Synthesis:  XXVII Summer School “A. Corbella” June 17−21, 2002, Palazzo Feltrinelli (Università degli Studi Milano, Gargnano (BS)). Società Chimica Italiana. 2002. 350 pp. $79.95. ISBN 88-86208-20-0. p 7480 DOI: 10.1021/ja033518m

Issue 25

A Rh(I)-Catalyzed Cycloisomerization of Homo- and Bis-homopropargylic Alcohols Barry M. Trost and Young Ho Rhee pp 7482–7483 DOI: 10.1021/ja0344258 Supporting Info

The First Total Synthesis of Nakadomarin A Toshiaki Nagata, Masako Nakagawa, and Atsushi Nishida pp 7484–7485 DOI: 10.1021/ja034464j Supporting Info

σσ* Transition in anti,cisoid Alternating Oligosilanes:  Clear-Cut Evidence for Suppression of Conjugation Effect by a cisoid Turn Hayato Tsuji, Masayoshi Terada, Akio Toshimitsu, and Kohei Tamao pp 7486–7487 DOI: 10.1021/ja034500e Supporting Info

Dynamics of a Surface Phase Transition As Monitored by in Situ Second Harmonic Generation Boguslaw Pozniak and Daniel A. Scherson pp 7488–7489 DOI: 10.1021/ja0351185

Is It Possible To Estimate the Enantioselectivity of a Chiral Catalyst from Its Racemic Mixture? Franz Lagasse, Masaki Tsukamoto, Christopher J. Welch, and Henri B. Kagan pp 7490–7491 DOI: 10.1021/ja0300315 Supporting Info

Bovine Serum Albumin-Mediated Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate Takehiko Wada, Masaki Nishijima, Tai Fujisawa, Norimitsu Sugahara, Tadashi Mori, Asao Nakamura, and Yoshihisa Inoue pp 7492–7493 DOI: 10.1021/ja034641g Supporting Info

Nanocoatings onto Arteries via Layer-by-Layer Deposition:  Toward the in Vivo Repair of Damaged Blood Vessels Benjamin Thierry, Françoise M. Winnik, Yahye Merhi, and Maryam Tabrizian pp 7494–7495 DOI: 10.1021/ja034321x Supporting Info

Direct Observation of the Protonation State of an Imino Sugar Glycosidase Inhibitor upon Binding Annabelle Varrot, Chris A. Tarling, James M. Macdonald, Robert V. Stick, David L. Zechel, Stephen G. Withers, and Gideon J. Davies pp 7496–7497 DOI: 10.1021/ja034917k Supporting Info

Modification of Silicon AFM Cantilever Tips with an Oligo(ethylene glycol) Derivative for Resisting Proteins and Maintaining a Small Tip Size for High-Resolution Imaging Chi-Ming Yam, Zhongdang Xiao, Jianhua Gu, Sabine Boutet, and Chengzhi Cai pp 7498–7499 DOI: 10.1021/ja0350435

Protein Prosthesis:  A Nonnatural Residue Accelerates Folding and Increases Stability Ulrich Arnold, Matthew P. Hinderaker, Jens Köditz, Ralph Golbik, Renate Ulbrich-Hofmann, and Ronald T. Raines pp 7500–7501 DOI: 10.1021/ja0351239 Supporting Info

Cobalt-Substituted Zinc Finger 3 of Transcription Factor IIIA:  Interactions with Cognate DNA Detected by 31P ENDOR Spectroscopy Charles J. Walsby, Dmitriy Krepkiy, David H. Petering, and Brian M. Hoffman pp 7502–7503 DOI: 10.1021/ja034589o Supporting Info

When Does Gold Behave as a Halogen? Predicted Uranium Tetraauride and Other MAu4 Tetrahedral Species, (M = Ti, Zr, Hf, Th) Laura Gagliardi pp 7504–7505 DOI: 10.1021/ja035385a

Addition of Arenes to Ethylene and Propene Catalyzed by Ruthenium Marty Lail, Benjamin N. Arrowood, and T. Brent Gunnoe pp 7506–7507 DOI: 10.1021/ja035076k Supporting Info

Enantioselective Michael Reaction Catalyzed by Well-Defined Chiral Ru Amido Complexes:  Isolation and Characterization of the Catalyst Intermediate, Ru Malonato Complex Having a Metal−Carbon Bond Masahito Watanabe, Kunihiko Murata, and Takao Ikariya pp 7508–7509 DOI: 10.1021/ja035435b Supporting Info

Determining Dihedral Angles and Local Structure in Silk Peptide by 13C−2H REDOR Terry Gullion, Raghuvansh Kishore, and Tetsuo Asakura pp 7510–7511 DOI: 10.1021/ja0342345

Breaking the Degeneracy of the Genetic Code Inchan Kwon, Kent Kirshenbaum, and David A. Tirrell pp 7512–7513 DOI: 10.1021/ja0350076 Supporting Info

Formation of Highly Ordered Organic Monolayers by Dative Bonding:  Pyridine on Ge(100) Young Eun Cho, Jae Yeol Maeng, and Sehun KimSuklyun Hong pp 7514–7515 DOI: 10.1021/ja0344617 Supporting Info

Discovery of a Potent, Non-peptide Bradykinin B1 Receptor Antagonist Dai-Shi Su, M. Kristine Markowitz, Robert M. DiPardo, Kathy L. Murphy, C. Meacham Harrell, Stacy S. O'Malley, Richard W. Ransom, Raymond S. L. Chang, Sookhee Ha, Fred J. Hess, Douglas J. Pettibone, Glenn S. Mason, Susan Boyce, Roger M. Freidinger, and Mark G. Bock pp 7516–7517 DOI: 10.1021/ja0353457 Supporting Info

Design and Characterization of a Homodimeric Antiparallel Coiled Coil Daniel G. Gurnon, Jennifer A. Whitaker, and Martha G. Oakley pp 7518–7519 DOI: 10.1021/ja0357590 Supporting Info

A Reversible Valence Equilibrium in a Heavier Main Group Compound Andrew D. Phillips, Shirley Hino, and Philip P. Power pp 7520–7521 DOI: 10.1021/ja0347843 Supporting Info

Building Blocks for the Molecular Expression of Quantum Cellular Automata. Isolation and Characterization of a Covalently Bonded Square Array of Two Ferrocenium and Two Ferrocene Complexes Jieying Jiao, Gary J. Long, Fernande Grandjean, Alicia M. Beatty, and Thomas P. Fehlner pp 7522–7523 DOI: 10.1021/ja035077c Supporting Info

XANES Determination of the Platinum Oxidation State Distribution in Cancer Cells Treated with Platinum(IV) Anticancer Agents Matthew D. Hall, Garry J. Foran, Mei Zhang, Philip J. Beale, and Trevor W. Hambley pp 7524–7525 DOI: 10.1021/ja0354770

Operational Control of Stereoselectivity during the Enzymatic Hydrolysis of Racemic Organophosphorus Compounds Yingchun Li, Sarah D. Aubert, and Frank M. Raushel pp 7526–7527 DOI: 10.1021/ja035625m Supporting Info

High-Yield Solvothermal Formation of Magnetic CoPt Alloy Nanowires Zongtao Zhang, Douglas A. Blom, Zheng Gai, James R. Thompson, Jian Shen, and Sheng Dai pp 7528–7529 DOI: 10.1021/ja035185z Supporting Info

Photolytic Control of Peptide Self-Assembly Carlos J. Bosques and Barbara Imperiali pp 7530–7531 DOI: 10.1021/ja035360b Supporting Info

Trypanosoma cruzi Trans-sialidase Operates through a Covalent Sialyl−Enzyme Intermediate:  Tyrosine Is the Catalytic Nucleophile Andrew G. Watts, Iben Damager, Maria L. Amaya, Alejandro Buschiazzo, Pedro Alzari, Alberto C. Frasch, and Stephen G. Withers pp 7532–7533 DOI: 10.1021/ja0344967

Alkyl Complexes of Strontium and Barium:  Synthesis and Structural Characterization of {(Me3Si)2(MeOMe2Si)C}2Sr(THF) and {(Me3Si)2(MeOMe2Si)C}2Ba(MeOCH2CH2OMe) Keith Izod, Stephen T. Liddle, and William Clegg pp 7534–7535 DOI: 10.1021/ja0352404 Supporting Info

Redox-Active Tyrosine Residues:  Role for the Peptide Bond in Electron Transfer Idelisa Pujols-Ayala, Colette A. Sacksteder, and Bridgette A. Barry pp 7536–7538 DOI: 10.1021/ja035005l Supporting Info

Assemblage of Signaling DNA Enzymes with Intriguing Metal-Ion Specificities and pH Dependences Zhongjie Liu, Shirley H. J. Mei, John D. Brennan, and Yingfu Li pp 7539–7545 DOI: 10.1021/ja035208+ Supporting Info

Comparisons of Phosphorothioate with Phosphate Transfer Reactions for a Monoester, Diester, and Triester:  Isotope Effect Studies Irina E. Catrina and Alvan C. Hengge pp 7546–7552 DOI: 10.1021/ja0340026 Supporting Info

Computational Study of Ketosteroid Isomerase:  Insights from Molecular Dynamics Simulation of Enzyme Bound Substrate and Intermediate Devleena Mazumder, Kalju Kahn, and Thomas C. Bruice pp 7553–7561 DOI: 10.1021/ja030138s Supporting Info

Optical Spectroscopic Investigations of Model β-Sheet Hairpins in Aqueous Solution Jovencio Hilario, Jan Kubelka, and Timothy A. Keiderling pp 7562–7574 DOI: 10.1021/ja030039e

A Bifunctional Molecule That Displays Context-Dependent Cellular Activity Patrick D. Braun, Katherine T. Barglow, Yun-Ming Lin, Thomas Akompong, Roger Briesewitz, Gregory T. Ray, Kasturi Haldar, and Thomas J. Wandless pp 7575–7580 DOI: 10.1021/ja035176q

A Photochromic, Electrochromic, Thermochromic Ru Complexed Benzannulene:  an Organometallic Example of the Dimethyldihydropyrene−Metacyclophanediene Valence Isomerization Reginald H. Mitchell, Zinka Brkic, Vittorio A. Sauro, and David J. Berg pp 7581–7585 DOI: 10.1021/ja034807d Supporting Info

Comparative Kinetic Studies of the Copolymerization of Cyclohexene Oxide and Propylene Oxide with Carbon Dioxide in the Presence of Chromium Salen Derivatives. In Situ FTIR Measurements of Copolymer vs Cyclic Carbonate Production Donald. J. Darensbourg, Jason C. Yarbrough, Cesar Ortiz, and Cindy C. Fang pp 7586–7591 DOI: 10.1021/ja034863e Supporting Info

Enantioselective Total Synthesis of (+)-Obtusenyne Michael T. Crimmins and Mark T. Powell pp 7592–7595 DOI: 10.1021/ja029956v Supporting Info

New Insights in the Mechanism of Amine Catalyzed Epoxidation:  Dual Role of Protonated Ammonium Salts as Both Phase Transfer Catalysts and Activators of Oxone Varinder K. Aggarwal, Chrystel Lopin, and Franck Sandrinelli pp 7596–7601 DOI: 10.1021/ja0289088 Supporting Info

Billion-fold Acceleration of the Methanolysis of Paraoxon Promoted by La(OTf)3 in Methanol Josephine S. Tsang, Alexei A. Neverov, and R. S. Brown pp 7602–7607 DOI: 10.1021/ja034979a Supporting Info

Synthesis-Based Approach toward Direct Sandwich Immunoassay for Ciguatoxin CTX3C Hiroki Oguri, Masahiro Hirama, Takeshi Tsumuraya, Ikuo Fujii, Megumi Maruyama, Hisatoshi Uehara, and Yoko Nagumo pp 7608–7612 DOI: 10.1021/ja034990a Supporting Info

Theoretical Analysis of the Porphyrin−Porphyrin Exciton Interaction in Circular Dichroism Spectra of Dimeric Tetraarylporphyrins Gennaro Pescitelli, Sven Gabriel, Yuekui Wang, Jörg Fleischhauer, Robert W. Woody, and Nina Berova pp 7613–7628 DOI: 10.1021/ja030047v Supporting Info

Bis(μ-oxo)dicopper in Cu-ZSM-5 and Its Role in the Decomposition of NO:  A Combined in Situ XAFS, UV−Vis−Near-IR, and Kinetic Study Marijke H. Groothaert, Jeroen A. van Bokhoven, Andrea A. Battiston, Bert M. Weckhuysen, and Robert A. Schoonheydt pp 7629–7640 DOI: 10.1021/ja029684w Supporting Info

Zirconocene-Catalyzed Propene Polymerization:  A Quenched-Flow Kinetic Study Fuquan Song, Roderick D. Cannon, and Manfred Bochmann pp 7641–7653 DOI: 10.1021/ja029150v

Iron Chelation Properties of an Extracellular Siderophore Exochelin MN Suraj Dhungana, Marvin J. Miller, Li Dong, Colin Ratledge, and Alvin L. Crumbliss pp 7654–7663 DOI: 10.1021/ja029578u

Magnetic Properties of Cationic Tungsten(IV) Half Sandwich Compounds:  Experimental and Theoretical Study of a Solvent and Ligand Stabilized Singlet Ground State Leading to a Thermally Induced Singlet−Triplet Spin State Interconversion Christian Cremer and Peter Burger pp 7664–7677 DOI: 10.1021/ja028313c Supporting Info

Correlated ab Initio Study of Nucleic Acid Bases and Their Tautomers in the Gas Phase, in a Microhydrated Environment and in Aqueous Solution. Guanine:  Surprising Stabilization of Rare Tautomers in Aqueous Solution Michal Hanus, Filip Ryjáek, Martin Kabelá, Tomáš Kubař, Tetyana V. Bogdan, Semen A. Trygubenko, and Pavel Hobza pp 7678–7688 DOI: 10.1021/ja034245y

2D-NMR Strategy Dedicated to the Analysis of Weakly Ordered, Fully Deuterated Enantiomers in Chiral Liquid Crystals Philippe Lesot, Muriel Sarfati, Denis Merlet, Bernard Ancian, James W. Emsley, and Bakir A. Timimi pp 7689–7695 DOI: 10.1021/ja021277x Supporting Info

Fluorine-NMR Experiments for High-Throughput Screening:  Theoretical Aspects, Practical Considerations, and Range of Applicability Claudio Dalvit, Paul E. Fagerness, Daneen T. A. Hadden, Ronald W. Sarver, and Brian J. Stockman pp 7696–7703 DOI: 10.1021/ja034646d

Charge-Transfer Mechanism for Cytochrome c Adsorbed on Nanometer Thick Films. Distinguishing Frictional Control from Conformational Gating Dimitri E. Khoshtariya, Jianjun Wei, Haiying Liu, Hongjun Yue, and David H. Waldeck pp 7704–7714 DOI: 10.1021/ja034719t Supporting Info

Influence of Media and Homoconjugate Pairing on Transition Metal Hydride Protonation. An IR and DFT Study on Proton Transfer to CpRuH(CO)(PCy3) Natalia V. Belkova, Maria Besora, Lina M. Epstein, Agustí Lledós, Feliu Maseras, and Elena S. Shubina pp 7715–7725 DOI: 10.1021/ja029712a Supporting Info

Theoretical Modeling of Enzyme Catalytic Power:  Analysis of “Cratic” and Electrostatic Factors in Catechol O-Methyltransferase Maite Roca, Sergio Martí, Juan Andrés, Vicent Moliner, Iñaki Tuñón, Juan Bertrán, and Ian H. Williams pp 7726–7737 DOI: 10.1021/ja0299497

Electro-oxidation of Carbon Monoxide on Well-Ordered Pt(111)/Sn Surface Alloys Brian E. Hayden, Michael E. Rendall, and Oliver South pp 7738–7742 DOI: 10.1021/ja0214781

Nucleation of Hexagonal Ice (Ih) in Liquid Water Ravi Radhakrishnan and Bernhardt L. Trout pp 7743–7747 DOI: 10.1021/ja0211252

Broadband Dielectric Spectroscopy Edited by Friedrich Kremer (University of Leipzig) and Andreas Schönhals (BAM Federal Institute for Materials Testing and Research, Berlin). Springer-Verlag:  Berlin, Heidleberg, and New York. 2003. xxii + 730 pp. $229.00. ISBN 3-540-43407-0. C. M. Roland p 7748 DOI: 10.1021/ja0335014

Carbohydrate Synthons in Natural Products Chemistry:  Synthesis, Functionalization, and Applications Edited by Zbigniew J. Witczak (Wilkes University) and Kuniaki Tatsuta (Waseda University). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2003. xiv + 210 pp. $135.00. ISBN 0-8412-3740-9. p 7748 DOI: 10.1021/ja033524i

Organic Synthesis Based on Name Reactions:  2nd Edition. Tetrahedron Organic Chemistry Series, Volume 22 By A. Hassner and C. Stumer (Bar-Ilan University). Series Edited by J. E. Baldwin (University of Oxford) and R. M. Williams (Colorado State University). Pergamon (An Imprint of Elsevier Science, Ltd.):  Oxford. 2002. x + 444 pp. $45.00. ISBN 0-08-043259-X. pp 7748–7749 DOI: 10.1021/ja033525a

Unusual Structures and Physical Properties in Organometallic Chemistry. Physical Organometallic Chemistry. Volume 3 Edited by Marcel Gielen and Rudolph Willem (Free University of Brussels), and Bernd Wrackmeyer (Universität Bayreuth). John Wiley & Sons, Ltd.:  Chichester, UK. 2002. xx + 425 pp. $275.00. ISBN 0-471-49635-9. Lou Messerle p 7749 DOI: 10.1021/ja025340u

Advances in Photochemistry. Volume 27 Edited by Douglas C. Neckers (Bowling Green State University), Günther Von Bünau (Universität Siegen), and William S. Jenks (Iowa State University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2002. xiv + 182 pp. $135.00. ISBN 0-471-21451-5. Thomas Huser pp 7749–7750 DOI: 10.1021/ja025337a

Encyclopedia of Polymer Science and Technology, Third Edition, Part 1, Volumes 1−4 Founding Editor Herman F. Mark. Current Volumes Edited by Jacqueline Kroschwitz (J. Wiley & Sons, Inc.). John Wiley & Sons, Inc.:  Hoboken. 2003. 3005 pp. $1400.00. ISBN 0-471-28824-1. p 7750 DOI: 10.1021/ja033513p

Issue 26

An Azophenol-based Chromogenic Pyrophosphate Sensor in Water Dong Hoon Lee, Ja Hyun Im, Seung Uk Son, Young Keun Chung, and Jong-In Hong pp 7752–7753 DOI: 10.1021/ja034689u Supporting Info

The Reaction of Thio Acids with Azides:  A New Mechanism and New Synthetic Applications Ning Shangguan, Sreenivas Katukojvala, Rachel Greenberg, and Lawrence J. Williams pp 7754–7755 DOI: 10.1021/ja0294919 Supporting Info

Two Ion/Ion Charge Inversion Steps To Form a Doubly Protonated Peptide from a Singly Protonated Peptide in the Gas Phase Min He and Scott A. McLuckey pp 7756–7757 DOI: 10.1021/ja0354521

Catalytic Enone Cycloallylation via Concomitant Activation of Latent Nucleophilic and Electrophilic Partners:  Merging Organic and Transition Metal Catalysis Bradley G. Jellerichs, Jong-Rock Kong, and Michael J. Krische pp 7758–7759 DOI: 10.1021/ja0301469 Supporting Info

A Novel Carbohydrate-Derived Side-Chain Polyether with Excellent Protein Resistance Mark Metzke, Jane Z. Bai, and Zhibin Guan pp 7760–7761 DOI: 10.1021/ja0349507 Supporting Info

Oxidative Addition of C−H Bonds to RhCl(PMe3)3:  Relevant to the Catalytic Transformation of Hydrocarbons Jun-Chul Choi and Toshiyasu Sakakura pp 7762–7763 DOI: 10.1021/ja021375i Supporting Info

Combining Second-Order Jahn−Teller Distorted Cations to Create Highly Efficient SHG Materials:  Synthesis, Characterization, and NLO Properties of BaTeM2O9 (M = Mo6+ or W6+) Hyun-Seup Ra, Kang Min Ok, and P. Shiv Halasyamani pp 7764–7765 DOI: 10.1021/ja035314b Supporting Info

Synthesis and Characterization of a Macrocyclic Near-Infrared Optical Scaffold Yunpeng Ye, Wen Ping Li, Carolyn J. Anderson, Jeffery Kao, Gregory V. Nikiforovich, and Samuel Achilefu pp 7766–7767 DOI: 10.1021/ja034186o Supporting Info

1H NMR Titrations of Hydroxy Protons in Aqueous Solution as a Method of Investigation of Intramolecular Hydrogen-Bonding in Phosphorylated Compounds: Examples of myo-Inositol 2-Phosphate and myo-Inositol 1,2,6-Tris(phosphates) Marc Felemez and Bernard Spiess pp 7768–7769 DOI: 10.1021/ja021265b Supporting Info

Mechanism of Alkane Transfer-Dehydrogenation Catalyzed by a Pincer-Ligated Iridium Complex Kenton B. Renkema, Yury V. Kissin, and Alan S. Goldman pp 7770–7771 DOI: 10.1021/ja0289200 Supporting Info

Nanoporous Metals with Controlled Multimodal Pore Size Distribution Yi Ding and Jonah Erlebacher pp 7772–7773 DOI: 10.1021/ja035318g

A Weak, Short Metal−Metal Bond in a Chromium(II) Amidinate Complex Azwana R. Sadique, Mary Jane Heeg, and Charles H. Winter pp 7774–7775 DOI: 10.1021/ja035082g Supporting Info

Synthetic Catalytic Pores Naomi Sakai, Nathalie Sordé, and Stefan Matile pp 7776–7777 DOI: 10.1021/ja029845w Supporting Info

Luminescence Tribochromism and Bright Emission in Gold(I) Thiouracilate Complexes Young-A Lee and Richard Eisenberg pp 7778–7779 DOI: 10.1021/ja034560k Supporting Info

High Quantum Yield Blue Emission from Water-Soluble Au8 Nanodots Jie Zheng, Jeffrey T. Petty, and Robert M. Dickson pp 7780–7781 DOI: 10.1021/ja035473v

Structure of a Missing-Caged Metallofullerene:  La2@C72 Haruhito Kato, Atsushi Taninaka, Toshiki Sugai, and Hisanori Shinohara pp 7782–7783 DOI: 10.1021/ja0353255 Supporting Info

Rhodium-Catalyzed [2 + 2 + 2] Cyclotrimerization in an Aqueous−Organic Biphasic System Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima pp 7784–7785 DOI: 10.1021/ja035438o Supporting Info

Synthesis of Triazoles from Nonactivated Terminal Alkynes via the Three-Component Coupling Reaction Using a Pd(0)−Cu(I) Bimetallic Catalyst Shin Kamijo, Tienan Jin, Zhibao Huo, and Yoshinori Yamamoto pp 7786–7787 DOI: 10.1021/ja034191s Supporting Info

1H Detection in MAS Solid-State NMR Spectroscopy of Biomacromolecules Employing Pulsed Field Gradients for Residual Solvent Suppression Veniamin Chevelkov, Barth J. van Rossum, Federica Castellani, Kristina Rehbein, Anne Diehl, Morten Hohwy, Stefan Steuernagel, Frank Engelke, Hartmut Oschkinat, and Bernd Reif pp 7788–7789 DOI: 10.1021/ja029354b Supporting Info

Ethylene Glycol Monolayer Protected Nanoparticles for Eliminating Nonspecific Binding with Biological Molecules Ming Zheng, Fredric Davidson, and Xueying Huang pp 7790–7791 DOI: 10.1021/ja0350278 Supporting Info

C−H Activation/Borylation/Oxidation:  A One-Pot Unified Route To Meta-Substituted Phenols Bearing Ortho-/Para-Directing Groups Robert E. Maleczka, Jr., Feng Shi, Daniel Holmes, and Milton R. Smith, III pp 7792–7793 DOI: 10.1021/ja0349857 Supporting Info

Lu8Te and Lu7Te. Novel Substitutional Derivatives of Lutetium Metal Ling Chen and John D. Corbett pp 7794–7795 DOI: 10.1021/ja035392z Supporting Info

Phosphorescence Quenching by Conjugated Polymers Madhusoodhanan Sudhakar, Peter I. Djurovich, Thieo E. Hogen-Esch, and Mark E. Thompson pp 7796–7797 DOI: 10.1021/ja0343297 Supporting Info

Sensitive Quantitative Nucleic Acid Detection Using Oligonucleotide Microarrays Arnold Vainrub and B. Montgomery Pettitt pp 7798–7799 DOI: 10.1021/ja035020q

Lewis Base Activation of Lewis Acids. Vinylogous Aldol Reactions Scott E. Denmark and Gregory L. Beutner pp 7800–7801 DOI: 10.1021/ja035448p Supporting Info

A Trinuclear Heterobimetallic Ru(II)/Pt(II) Complex as a Chemodosimeter Selective for Sulfhydryl-Containing Amino Acids and Peptides Cheuk-Fai Chow, Brenda K. W. Chiu, Michael H. W. Lam, and Wai-Yeung Wong pp 7802–7803 DOI: 10.1021/ja034891x Supporting Info

Dynamic Combinatorial Optimization of a Neutral Receptor That Binds Inorganic Anions in Aqueous Solution Sijbren Otto and Stefan Kubik pp 7804–7805 DOI: 10.1021/ja0351589 Supporting Info

Electron and Hole Injection in PbSe Quantum Dot Films Brian L. Wehrenberg and Philippe Guyot-Sionnest pp 7806–7807 DOI: 10.1021/ja035369d

Chemistry between Magnesium and Multiple Molecules in Tris(8-hydroxyquinoline) Aluminum Films Simone Meloni, Amedeo Palma, Jeffrey Schwartz, Antoine Kahn, and Roberto Car pp 7808–7809 DOI: 10.1021/ja029090t

Covalent and Selective Immobilization of Fusion Proteins Maik Kindermann, Nathalie George, Nils Johnsson, and Kai Johnsson pp 7810–7811 DOI: 10.1021/ja034145s Supporting Info

A GaCl3-Catalyzed [4+1] Cycloaddition of α,β-Unsaturated Carbonyl Compounds and Isocyanides Leading to Unsaturated γ-Lactone Derivatives Naoto Chatani, Masayuki Oshita, Mamoru Tobisu, Yutaka Ishii, and Shinji Murai pp 7812–7813 DOI: 10.1021/ja035014u Supporting Info

Prussian Blue Nanoparticles Protected by Poly(vinylpyrrolidone) Takashi Uemura and Susumu Kitagawa pp 7814–7815 DOI: 10.1021/ja0356582 Supporting Info

A Dicoordinate Palladium(0) Complex with an Unusual Intramolecular η1-Arene Coordination Steven M. Reid, Robert C. Boyle, Joel T. Mague, and Mark J. Fink pp 7816–7817 DOI: 10.1021/ja0361493 Supporting Info

The Complete Gene Cluster of the Antitumor Agent Gilvocarcin V and Its Implication for the Biosynthesis of the Gilvocarcins Carsten Fischer, Fredilyn Lipata, and Jürgen Rohr pp 7818–7819 DOI: 10.1021/ja034781q Supporting Info

Synthesis of a New Zeolite Structure ITQ-24, with Intersecting 10- and 12-Membered Ring Pores Rafael Castañeda, Avelino Corma, Vicente Fornés, Fernando Rey, and Jordi Rius pp 7820–7821 DOI: 10.1021/ja035534p Supporting Info

A Convergent Total Synthesis of Hemibrevetoxin B Armen Zakarian, Alexandre Batch, and Robert A. Holton pp 7822–7824 DOI: 10.1021/ja029225v Supporting Info

The First Catalytic, Asymmetric α-Additions of Isocyanides. Lewis-Base-Catalyzed, Enantioselective Passerini-Type Reactions Scott E. Denmark and Yu Fan pp 7825–7827 DOI: 10.1021/ja035410c Supporting Info

Oxygen Activation by Nonheme Iron(II) Complexes: α-Keto Carboxylate versus Carboxylate Mark P. Mehn, Kiyoshi Fujisawa, Eric L. Hegg, and Lawrence Que, Jr. pp 7828–7842 DOI: 10.1021/ja028867f Supporting Info

Sequence Selective Recognition in the Minor Groove of dsDNA by Pyrrole, Imidazole-Substituted Bis-benzimidazole Conjugates Putta Mallikarjuna Reddy, Peter T. Jindra, Alexander L. Satz, and Thomas C. Bruice pp 7843–7848 DOI: 10.1021/ja035116k

Titration in Silico of Reversible B ↔ A Transitions in DNA Alexey K. Mazur pp 7849–7859 DOI: 10.1021/ja034550j

Ceramic-Based Nanoparticles Entrapping Water-Insoluble Photosensitizing Anticancer Drugs:  A Novel Drug−Carrier System for Photodynamic Therapy Indrajit Roy, Tymish Y. Ohulchanskyy, Haridas E. Pudavar, Earl J. Bergey, Allan R. Oseroff, Janet Morgan, Thomas J. Dougherty, and Paras N. Prasad pp 7860–7865 DOI: 10.1021/ja0343095

Small Change in a G-Rich Sequence, a Dramatic Change in Topology:  New Dimeric G-Quadruplex Folding Motif with Unique Loop Orientations Martin Črnugelj, Primož Šket, and Janez Plavec pp 7866–7871 DOI: 10.1021/ja0348694 Supporting Info

Isotope Effect-Mapping of the Ionization of Glucose Demonstrates Unusual Charge Sharing Brett E. Lewis and Vern L. Schramm pp 7872–7877 DOI: 10.1021/ja034983m Supporting Info

Control of Chiral Ordering in Aggregated Poly{3-(S)-[2-methylbutyl]thiophene} by a Doping-Dedoping Process Zhong-Biao Zhang, Michiya Fujiki, Masao Motonaga, and Charles E. McKenna pp 7878–7881 DOI: 10.1021/ja029220y Supporting Info

Hydrogen Bonding in Redox-Modulated Molecular Recognition. An Experimental and Theoretical Investigation Mark Gray, Alejandro O. Cuello, Graeme Cooke, and Vincent M. Rotello pp 7882–7888 DOI: 10.1021/ja035228b Supporting Info

Lobatamide C:  Total Synthesis, Stereochemical Assignment, Preparation of Simplified Analogues, and V-ATPase Inhibition Studies Ruichao Shen, Cheng Ting Lin, Emma Jean Bowman, Barry J. Bowman, and John A. Porco, Jr. pp 7889–7901 DOI: 10.1021/ja0352350 Supporting Info

Thermodynamic Rearrangement Synthesis and NMR Structures of C1, C3, and T Isomers of C60H36 Andrei A. Gakh, Andrew Yu. Romanovich, and Ad Bax pp 7902–7906 DOI: 10.1021/ja035332t Supporting Info

Design and Application of Basic Amino Acids Displaying Enhanced Hydrophobicity Juliana K. Kretsinger and Joel P. Schneider pp 7907–7913 DOI: 10.1021/ja029892o Supporting Info

Asymmetric Schmidt Reaction of Hydroxyalkyl Azides with Ketones Kiran Sahasrabudhe, Vijaya Gracias, Kelly Furness, Brenton T. Smith, Christopher E. Katz, D. Srinivasa Reddy, and Jeffrey Aubé pp 7914–7922 DOI: 10.1021/ja0348896 Supporting Info

Diradical Mechanisms for the Cycloaddition Reactions of 1,3-Butadiene, Benzene, Thiophene, Ethylene, and Acetylene on a Si(111)-7×7 Surface Xin Lu, Xinlan Wang, Qinghong Yuan, and Qianer Zhang pp 7923–7929 DOI: 10.1021/ja035329+

Counterion Effects on Propylene Polymerization Using Two-State ansa-Metallocene Complexes Muqtar Mohammed, Marcio Nele, Abdulaziz Al-Humydi, Shixuan Xin, Russell A. Stapleton, and Scott Collins pp 7930–7941 DOI: 10.1021/ja0207706 Supporting Info

Tandem Polar/Radical Crossover Sequences for the Formation of Fused and Bridged Bicyclic Nitrogen Heterocycles Involving Radical Ionic Chain Reactions, and Alkene Radical Cation Intermediates, Performed under Reducing Conditions:  Scope and Limitations David Crich, Krishnakumar Ranganathan, Santhosh Neelamkavil, and Xianhai Huang pp 7942–7947 DOI: 10.1021/ja035639s Supporting Info

Self-Assembly of Gears at a Fluid/Air Interface Jessamine M. K. Ng, Michael J. Fuerstman, Bartosz A. Grzybowski, Howard A. Stone, and George M. Whitesides pp 7948–7958 DOI: 10.1021/ja0347235

On the Interactions of Free Radicals with Gold Nanoparticles Zhenyuan Zhang, Alexander Berg, Haim Levanon, Richard W. Fessenden, and Dan Meisel pp 7959–7963 DOI: 10.1021/ja034830z

Cluster Size-Dependent Mechanisms of the CO + NO Reaction on Small Pdn (n ≤ 30) Clusters on Oxide Surfaces Anke S. Wörz, Ken Judai, Stéphane Abbet, and Ulrich Heiz pp 7964–7970 DOI: 10.1021/ja0352247 Supporting Info

Homogeneous Catalysis with Methane. A Strategy for the Hydromethylation of Olefins Based on the Nondegenerate Exchange of Alkyl Groups and σ-Bond Metathesis at Scandium Aaron D. Sadow and T. Don Tilley pp 7971–7977 DOI: 10.1021/ja021341a Supporting Info

Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten−Ruthenium Dinuclear Complexes Yasuhiro Ohki, Nobuo Matsuura, Tadashi Marumoto, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 7978–7988 DOI: 10.1021/ja029941x Supporting Info

Quantum Dynamics Simulations of Interfacial Electron Transfer in Sensitized TiO2 Semiconductors Luis G. C. Rego and Victor S. Batista pp 7989–7997 DOI: 10.1021/ja0346330

Using Switched Angle Spinning to Simplify NMR Spectra of Strongly Oriented Samples Robert H. Havlin, Gregory H. J. Park, Tanya Mazur, and Alexander Pines pp 7998–8006 DOI: 10.1021/ja0342244

The Structure and Dynamics of DNA in the Gas Phase Manuel Rueda, Susana G. Kalko, F. Javier Luque, and Modesto Orozco pp 8007–8014 DOI: 10.1021/ja0300564 Supporting Info

Protein-Conjugated Nanoparticles from Rapid Expansion of Supercritical Fluid Solution into Aqueous Solution Mohammed J. Meziani and Ya-Ping Sun pp 8015–8018 DOI: 10.1021/ja030104k

Description of Molecular Dynamics in Intense Laser Fields by the Time-Dependent Adiabatic State Approach:  Application to Simultaneous Two-Bond Dissociation of CO2 and Its Control Yukio Sato, Hirohiko Kono, Shiro Koseki, and Yuichi Fujimura pp 8019–8031 DOI: 10.1021/ja0344819

Formation, Structure, and Structural Properties of a New Filamentary Tubular Form:  Hollow Conical-Helix of Graphitic Boron Nitride Fang-Fang Xu, Yoshio Bando, Renzhi Ma, Dmitri Golberg, Yubao Li, and Masanori Mitome pp 8032–8038 DOI: 10.1021/ja030003m

Detection of C−Si Covalent Bond in CH3 Adsorbate Formed by Chemical Reaction of CH3MgBr and H:Si(111) Taro Yamada, Tomoyuki Inoue, Keiko Yamada, Nao Takano, Tetsuya Osaka, Hiroshi Harada, Katsuhiko Nishiyama, and Isao Taniguchi pp 8039–8042 DOI: 10.1021/ja034457v

Synthesis and Reactivity of Silyl Ruthenium Complexes:  The Importance of Trans Effects in C−H Activation, Si−C Bond Formation, and Dehydrogenative Coupling of Silanes Vladimir K. Dioumaev, Leo J. Procopio, Patrick J. Carroll, and Donald H. Berry pp 8043–8058 DOI: 10.1021/ja035131p Supporting Info

Molecular Level Study of the Formation and the Spread of MoO3 on Au (111) by Scanning Tunneling Microscopy and X-ray Photoelectron Spectroscopy Zhen Song, Tanhong Cai, Zhipeng Chang, Gang Liu, Jose A. Rodriguez, and Jan Hrbek pp 8059–8066 DOI: 10.1021/ja034862m

Advances in Quantitative Structure−Property Relationships, Volume 3 Edited by Marvin Charton (Pratt Institute) and Barbara I. Charton (New York University Library). JAI Press (an Imprint of Elsevier Science B.V.):  Amsterdam. 2002. xi + 228 pp. $160.00. ISBN 0-444-51112-1. Alan R. Katritzky p 8067 DOI: 10.1021/ja033510c

Surface and Thin Film Analysis. A Compendium of Principles, Instrumentation, and Applications Edited by Henning Bubert and Holger Jenett (Institute of Spectrochemistry and Applied Spectroscopy, Dortmund, Germany). Wiley-VCH: Weinheim, Germany. 2002. xviii + 336 pp. $84.95. ISBN 3-527-30458-4. Michael Trenary pp 8067–8068 DOI: 10.1021/ja025292d

Issue 27

Combining the Best in Triplex Recognition:  Synthesis and Nucleic Acid Binding of a BQQ−Neomycin Conjugate Dev P. Arya, Liang Xue, and Paul Tennant pp 8070–8071 DOI: 10.1021/ja034241t Supporting Info

Dipolar Couplings in Multiple Alignments Suggest α Helical Motion in Ubiquitin Jens Meiler, Wolfgang Peti, and Christian Griesinger pp 8072–8073 DOI: 10.1021/ja029816l Supporting Info

Light Activated Patterning of Dye-Labeled Molecules on Surfaces Matthew A. Holden and Paul S. Cremer pp 8074–8075 DOI: 10.1021/ja035390e Supporting Info

Nickel-Catalyzed Reductive Coupling of Alkynes and Epoxides Carmela Molinaro and Timothy F. Jamison pp 8076–8077 DOI: 10.1021/ja0361401 Supporting Info

Parallel Kinetic Resolution of 4-Alkynals Catalyzed by Rh(I)/Tol-BINAP:  Synthesis of Enantioenriched Cyclobutanones and Cyclopentenones Ken Tanaka and Gregory C. Fu pp 8078–8079 DOI: 10.1021/ja035489l Supporting Info

Solution 1H NMR Characterization of Equilibrium Heme Orientational Disorder with Functional Consequences in Mouse Neuroglobin Weihong Du, Ray Syvitski, Sylvia Dewilde, Luc Moens, and Gerd N. La Mar pp 8080–8081 DOI: 10.1021/ja034584r Supporting Info

A New Strategy for Deprotonative Functionalization of Aromatics:  Transformations with Excellent Chemoselectivity and Unique Regioselectivities Using t-Bu-P4 Base Tatsushi Imahori and Yoshinori Kondo pp 8082–8083 DOI: 10.1021/ja0342300 Supporting Info

Self-Assembly of Chiral Molecular Polygons Hua Jiang and Wenbin Lin pp 8084–8085 DOI: 10.1021/ja034402t Supporting Info

Large Stabilization of a DNA Duplex by the Deoxyadenosine Derivatives Tethering an Aromatic Hydrocarbon Group Shu-ichi Nakano, Yuuki Uotani, Shoji Nakashima, Yosuke Anno, Masayuki Fujii, and Naoki Sugimoto pp 8086–8087 DOI: 10.1021/ja034465b Supporting Info

Large-Scale Synthesis of Carbon Nanotubes by an Ethanol Thermal Reduction Process Jianwei Liu, Mingwang Shao, Xiangying Chen, Weichao Yu, Xianming Liu, and Yitai Qian pp 8088–8089 DOI: 10.1021/ja035763b

The Puromycin Route to Assess Stereo- and Regiochemical Constraints on Peptide Bond Formation in Eukaryotic Ribosomes Shelley R. Starck, Xin Qi, Brett N. Olsen, and Richard W. Roberts pp 8090–8091 DOI: 10.1021/ja034817e Supporting Info

The Pentapeptide GGAGG Has PII Conformation Liang Ding, Kang Chen, Paul A. Santini, Zhengshuang Shi, and Neville R. Kallenbach pp 8092–8093 DOI: 10.1021/ja035551e

The Gluing of a Langmuir−Blodgett Bilayer Xun Yan, Vaclav Janout, James T. Hsu, and Steven L. Regen pp 8094–8095 DOI: 10.1021/ja035453t Supporting Info

Intramolecular Nucleophile-Induced Photorearrangements and Silene Formation from an o-(Methoxymethyl)phenylsilacyclobutane William J. Leigh and Xiaojing Li pp 8096–8097 DOI: 10.1021/ja035283k Supporting Info

Mechanism and Dynamics of Azobenzene Photoisomerization Thomas Schultz, Jason Quenneville, Benjamin Levine, Alessandro Toniolo, Todd J. Martínez, Stefan Lochbrunner, Michael Schmitt, James P. Shaffer, Marek Z. Zgierski, and Albert Stolow pp 8098–8099 DOI: 10.1021/ja021363x Supporting Info

Catalytic Construction and Reconstruction of Guanidines:  Ti-Mediated Guanylation of Amines and Transamination of Guanidines Tiow-Gan Ong, Glenn P. A. Yap, and Darrin S. Richeson pp 8100–8101 DOI: 10.1021/ja035716j Supporting Info

Rapid Aggregation of Gold Nanoparticles Induced by Non-Cross-Linking DNA Hybridization Kae Sato, Kazuo Hosokawa, and Mizuo Maeda pp 8102–8103 DOI: 10.1021/ja034876s Supporting Info

Novel Triarylamine Dendrimers as a Hole-Transport Material with a Controlled Metal-Assembling Function Norifusa Satoh, Jun-Sang Cho, Masayoshi Higuchi, and Kimihisa Yamamoto pp 8104–8105 DOI: 10.1021/ja034811p Supporting Info

Binding of meso-Tetrakis(N-methylpyridium-4-yl)porphyrin to Triplex Oligonucleotides:  Evidence for the Porphyrin Stacking in the Major Groove Young-Ae Lee, Jin-Ok Kim, Tae-Sub Cho, Rita Song, and Seog K. Kim pp 8106–8107 DOI: 10.1021/ja034499j

Ultrafast Internal Conversion of Excited Cytosine via the Lowest ππ* Electronic Singlet State Manuela Merchán and Luis Serrano-Andrés pp 8108–8109 DOI: 10.1021/ja0351600 Supporting Info

Synthesis of a Zirconium Sandwich Complex and Crystallographic Characterization of Its Adduct with Tetrahydrofuran Christopher A. Bradley, Emil Lobkovsky, and Paul J. Chirik pp 8110–8111 DOI: 10.1021/ja035594v Supporting Info

Stereocontrolled Total Synthesis of (−)-Ephedradine A (Orantine) Wataru Kurosawa, Toshiyuki Kan, and Tohru Fukuyama pp 8112–8113 DOI: 10.1021/ja036011k Supporting Info

Bis[bis(trimethylsilyl)amino]silylene, an Unstable Divalent Silicon Compound Gyu-Hwan Lee, Robert West, and Thomas Müller pp 8114–8115 DOI: 10.1021/ja035374h Supporting Info

Conductivity and Field Effect Transistor of La2@C80 Metallofullerene Shin-ichiro Kobayashi, Satoshi Mori, Satoru Iida, Hiroaki Ando, Taishi Takenobu, Yasujiro Taguchi, Akihiko Fujiwara, Atsushi Taninaka, Hisanori Shinohara, and Yoshihiro Iwasa pp 8116–8117 DOI: 10.1021/ja034944a

From Azides to Nitro Compounds in a Few Seconds Using HOF·CH3CN Shlomo Rozen and Mira Carmeli pp 8118–8119 DOI: 10.1021/ja035616d

Rapid Synthesis of Polyamide Dendrimers from Unprotected AB2 Building Blocks Masaki Okazaki, Isao Washio, Yuji Shibasaki, and Mitsuru Ueda pp 8120–8121 DOI: 10.1021/ja034665n Supporting Info

Formal [3 + 2] Cycloadditions of Donor−Acceptor Cyclopropanes and Nitriles Ming Yu and Brian L. Pagenkopf pp 8122–8123 DOI: 10.1021/ja029716f Supporting Info

H-Bonding Cooperativity and Energetics of α-Helix Formation of Five 17-Amino Acid Peptides Robert Wieczorek and J. J. Dannenberg pp 8124–8129 DOI: 10.1021/ja035302q Supporting Info

Reactivity of Functional Groups on the Protein Surface:  Development of Epoxide Probes for Protein Labeling Gong Chen, Alexander Heim, Doris Riether, Dominic Yee, Yelena Milgrom, Mary Ann Gawinowicz, and Dalibor Sames pp 8130–8133 DOI: 10.1021/ja034287m Supporting Info

A Novel System of Self-Reproducing Giant Vesicles Katsuto Takakura, Taro Toyota, and Tadashi Sugawara pp 8134–8140 DOI: 10.1021/ja029379a Supporting Info

In Silico Studies of the Mechanism of Methanol Oxidation by Quinoprotein Methanol Dehydrogenase Swarnalatha Y. Reddy and Thomas C. Bruice pp 8141–8150 DOI: 10.1021/ja034406y Supporting Info

Mechanism for the Noncovalent Chiral Domino Effect:  New Paradigm for the Chiral Role of the N-Terminal Segment in a 310-Helix Yoshihito Inai, Naoki Ousaka, and Takahiro Okabe pp 8151–8162 DOI: 10.1021/ja035040s Supporting Info

Computer Simulation of the Chemical Catalysis of DNA Polymerases:  Discriminating between Alternative Nucleotide Insertion Mechanisms for T7 DNA Polymerase Jan Florián, Myron F. Goodman, and Arieh Warshel pp 8163–8177 DOI: 10.1021/ja028997o Supporting Info

Stable Conformations of Tripeptides in Aqueous Solution Studied by UV Circular Dichroism Spectroscopy Fatma Eker, Kai Griebenow, and Reinhard Schweitzer-Stenner pp 8178–8185 DOI: 10.1021/ja034625j

Photoisomerization and Proton Transfer in Photoactive Yellow Protein Michael J. Thompson, Donald Bashford, Louis Noodleman, and Elizabeth D. Getzoff pp 8186–8194 DOI: 10.1021/ja0294461

Facilitated Phosphatidylserine (PS) Flip-Flop and Thrombin Activation Using A Synthetic PS Scramblase J. Middleton Boon, Timothy N. Lambert, Adam L. Sisson, Anthony P. Davis, and Bradley D. Smith pp 8195–8201 DOI: 10.1021/ja029670q Supporting Info

Sequence- and Regioselectivity in the Montmorillonite-Catalyzed Synthesis of RNA Shin Miyakawa and James P. Ferris pp 8202–8208 DOI: 10.1021/ja034328e

Stereospecific Biocatalytic Epoxidation:  The First Example of Direct Regeneration of a FAD-Dependent Monooxygenase for Catalysis Frank Hollmann, Po-Chi Lin, Bernard Witholt, and Andreas Schmid pp 8209–8217 DOI: 10.1021/ja034119u

Solid-Phase Synthesis of Bleomycin Group Antibiotics. Construction of a 108-Member Deglycobleomycin Library Christopher J. Leitheiser, Kenneth L. Smith, Michael J. Rishel, Shigeki Hashimoto, Kazuhide Konishi, Craig J. Thomas, Chunhong Li, Michael M. McCormick, and Sidney M. Hecht pp 8218–8227 DOI: 10.1021/ja021388w Supporting Info

Tremorgenic Indole Alkaloids. The Total Synthesis of (−)-Penitrem D Amos B. Smith, III, Naoki Kanoh, Haruaki Ishiyama, Noriaki Minakawa, Jon D. Rainier, Richard A. Hartz, Young Shin Cho, Haifeng Cui, and William H. Moser pp 8228–8237 DOI: 10.1021/ja034842k Supporting Info

Total Synthesis of an Antitumor Antibiotic, Fostriecin (CI-920) Kazuyuki Miyashita, Masahiro Ikejiri, Hitomi Kawasaki, Satoko Maemura, and Takeshi Imanishi pp 8238–8243 DOI: 10.1021/ja030133v Supporting Info

Phase-Selective Solubility of Poly(N-alkylacrylamide)s David E. Bergbreiter, Reagan Hughes, Jacqueline Besinaiz, Chunmei Li, and Philip L. Osburn pp 8244–8249 DOI: 10.1021/ja0349498 Supporting Info

Structural Effects on Encapsulation As Probed in Redox-Active Core Dendrimer Isomers Tyson L. Chasse, Rakesh Sachdeva, Qun Li, Zemin Li, Randall J. Petrie, and Christopher B. Gorman pp 8250–8254 DOI: 10.1021/ja035515f Supporting Info

π-Face-Selective Diels−Alder Reactions of 3,4-Di-tert-butylthiophene 1-Oxide and 1-Imide and Formation of 1,2-Thiazetidines Takashi Otani, Jun Takayama, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama pp 8255–8263 DOI: 10.1021/ja029867i Supporting Info

Synthesis, Self-Assembly, and Switching of One-Dimensional Nanostructures from New Crowded Aromatics Mark L. Bushey, Thuc-Quyen Nguyen, and Colin Nuckolls pp 8264–8269 DOI: 10.1021/ja034783a Supporting Info

Guanidinium Receptors as Enantioselective Amino Acid Membrane Carriers Perla Breccia, Michiel Van Gool, Ruth Pérez-Fernández, Sonsoles Martín-Santamaría, Federico Gago, Pilar Prados, and Javier de Mendoza pp 8270–8284 DOI: 10.1021/ja026860s Supporting Info

Spontaneous Formation of Nanoparticle Vesicles from Homopolymer Polyelectrolytes Jennifer N. Cha, Henrik Birkedal, Larken E. Euliss, Michael H. Bartl, Michael S. Wong, Timothy J. Deming, and Galen D. Stucky pp 8285–8289 DOI: 10.1021/ja0279601

Host−[2]Rotaxanes as Cellular Transport Agents Vadims Dvornikovs, Brian E. House, Marcia Kaetzel, John R. Dedman, and David B. Smithrud pp 8290–8301 DOI: 10.1021/ja034918c

Reversible Chemical Patterning on Stimuli-Responsive Polymer Film:  Environment-Responsive Lithography Leonid Ionov, Sergiy Minko, Manfred Stamm, Jean-François Gohy, Robert Jérôme, and Andreas Scholl pp 8302–8306 DOI: 10.1021/ja035560n

An Oxazaphospholidine Approach for the Stereocontrolled Synthesis of Oligonucleoside Phosphorothioates Natsuhisa Oka, Takeshi Wada, and Kazuhiko Saigo pp 8307–8317 DOI: 10.1021/ja034502z Supporting Info

Hydrogen-Bonding Effects on the Properties of Phenoxyl Radicals. An EPR, Kinetic, and Computational Study Marco Lucarini, Veronica Mugnaini, Gian Franco Pedulli, and Maurizio Guerra pp 8318–8329 DOI: 10.1021/ja034963k Supporting Info

A Cornucopia of Cycloadducts:  Theoretical Predictions of the Mechanisms and Products of the Reactions of Cyclopentadiene with Cycloheptatriene Andrew G. Leach, E. Goldstein, and K. N. Houk pp 8330–8339 DOI: 10.1021/ja029694x Supporting Info

Effect of Catalysis on the Stability of Metallic Nanoparticles:  Suzuki Reaction Catalyzed by PVP-Palladium Nanoparticles Radha Narayanan and Mostafa A. El-Sayed pp 8340–8347 DOI: 10.1021/ja035044x

Spectroscopic and Computational Study of a Non-Heme Iron {Fe−NO}7 System:  Exploring the Geometric and Electronic Structures of the Nitrosyl Adduct of Iron Superoxide Dismutase Timothy A. Jackson, Emine Yikilmaz, Anne-Frances Miller, and Thomas C. Brunold pp 8348–8363 DOI: 10.1021/ja029523s Supporting Info

Reaction of Cyclic Nitroxides with Nitrogen Dioxide:  The Intermediacy of the Oxoammonium Cations Sara Goldstein, Amram Samuni, and Angelo Russo pp 8364–8370 DOI: 10.1021/ja035286x

XMCD for Monitoring Exchange Interactions. The Role of the Gd 4f and 5d Orbitals in Metal-Nitronyl Nitroxide Magnetic Chains Guillaume Champion, Nikolia Lalioti, Vassilis Tangoulis, Marie-Anne Arrio, Philippe Sainctavit, Françoise Villain, Andrea Caneschi, Dante Gatteschi, Christine Giorgetti, François Baudelet, Michel Verdaguer, and Christophe Cartier dit Moulin pp 8371–8376 DOI: 10.1021/ja034608u

Structural, Spectroscopic, and Redox Consequences of a Central Ligand in the FeMoco of Nitrogenase:  A Density Functional Theoretical Study Timothy Lovell, Tiqing Liu, David A. Case, and L. Noodleman pp 8377–8383 DOI: 10.1021/ja0301572

Hydroxide Ion Adsorption on Self-Assembled Monolayers H. Jürgen Kreuzer, Richard L. C. Wang, and Michael Grunze pp 8384–8389 DOI: 10.1021/ja0350839 Supporting Info

Computational Study of the Halogen Atom−Benzene Complexes Meng-Lin Tsao, Christopher M. Hadad, and Matthew S. Platz pp 8390–8399 DOI: 10.1021/ja035095u Supporting Info

Beyond the Decoupling Approximation in the Model Free Approach for the Interpretation of NMR Relaxation of Macromolecules in Solution Liliya Vugmeyster, Daniel P. Raleigh, Arthur G. Palmer, III, and Boris E. Vugmeister pp 8400–8404 DOI: 10.1021/ja029480f

Spin Transition Molecular Materials: Intelligent Contrast Agents for Magnetic Resonance Imaging Robert N. Muller, Luce Vander Elst, and Sophie Laurent pp 8405–8407 DOI: 10.1021/ja0349599

Oxygen Adsorption on Hydrated Gold Cluster Anions:  Experiment and Theory William T. Wallace, Richard B. Wyrwas, Robert L. Whetten, Roland Mitrić, and Vlasta Bonaić-Koutecký pp 8408–8414 DOI: 10.1021/ja034905z

Interfacial Catalysis Edited by Alexander G. Volkov (Oakwood College, Huntsville, AL). Marcel Dekker, Inc.:  New York, Basel. 2003. x + 674 pp. $225.00. ISBN 0-8247-0839-3. p 8415 DOI: 10.1021/ja025365t

Burger's Medicinal Chemistry & Drug Discovery, Sixth Edition, Volumes 1−6 Edited by Donald J. Abraham (Virginia Commonwealth University). John Wiley & Sons, Inc.:  Hoboken. 2003. 5568 pp. $2100.00. ISBN 0-471-37032-0. p 8415 DOI: 10.1021/ja033519e

Group 13 Chemistry:  From Fundamentals to Applications Edited by Pamela J. Shapiro (University of Idaho) and David A. Atwood (University of Kentucky). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2002. xii + 300 pp. $135.00. ISBN 0-8412-3785-9. p 8415 DOI: 10.1021/ja033520d

Drug Design:  Cutting Edge Approaches Edited by Darren R. Flower (The Edward Jenner Institute for Vaccine Research, Newbury, U.K.). Royal Society of Chemistry:  Cambridge. 2002. x + 192 pp. $109.00. ISBN 0-85404-816-2. p 8415 DOI: 10.1021/ja0335216

Mass Spectrometry in Cancer Research By John Roboz (The Mount Sinai School of Medicine, New York). CRC Press LLC:  Boca Raton, FL. 2002. xxii + 554 pp. $159.95. ISBN 0-8493-0167-X. Douglas J. Beussman pp 8415–8416 DOI: 10.1021/ja025272b

Clathrochelates:  Synthesis, Structure and Properties By Yan Z. Voloshin (Karpov Institute of Physical Chemistry), Nina A. Kostromina (Vernadskii Institute of General and Inorganic Chemistry), and Roland Krämer (Ruprecht-Karls-Universität). Elsevier:  Amsterdam. 2002. xxi + 420 pp. $185.00. ISBN 0-444-51223-3. Joseph Grzybowski p 8416 DOI: 10.1021/ja033523q

Modern Arene Chemistry:  Concepts, Synthesis, and Applications Edited by Didier Astruc (Université Bordeaux I). Wiley-VCH:  Weinheim. 2002. xviii + 618 pp. $135.00. ISBN 3-527-30489-4. Thomas W. Bell pp 8416–8417 DOI: 10.1021/ja0253641

Annual Reports on NMR Spectroscopy. Volume 43 Edited by G. A. Webb (University of Surrey). Academic Press:  San Diego, London. 2001. x + 182 pp. $119.95. ISBN 0-12-505343-6. William P. Power pp 8417–8418 DOI: 10.1021/ja0253179

Issue 28

Discovery of an Inhibitor of a Transcription Factor Using Small Molecule Microarrays and Diversity-Oriented Synthesis Angela N. Koehler, Alykhan F. Shamji, and Stuart L. Schreiber pp 8420–8421 DOI: 10.1021/ja0352698 Supporting Info

Integrated Computational and Experimental Approach for Lead Optimization and Design of Compstatin Variants with Improved Activity John L. Klepeis, Christodoulos A. Floudas, Dimitrios Morikis, C. G. Tsokos, E. Argyropoulos, L. Spruce, and John D. Lambris pp 8422–8423 DOI: 10.1021/ja034846p Supporting Info

Synthesis of Cyclic Polybutadiene via Ring-Opening Metathesis Polymerization:  The Importance of Removing Trace Linear Contaminants Christopher W. Bielawski, Diego Benitez, and Robert H. Grubbs pp 8424–8425 DOI: 10.1021/ja034524l Supporting Info

Four-Coordinate, Planar Ru(II). A Triplet State as a Response to a 14-Valence Electron Configuration Lori A. Watson, Oleg V. Ozerov, Maren Pink, and Kenneth G. Caulton pp 8426–8427 DOI: 10.1021/ja035166p Supporting Info

An Elongated Dihydrogen Complex of Iridium Vincent Pons and D. Michael Heinekey pp 8428–8429 DOI: 10.1021/ja035555j Supporting Info

Identification of Histidine Tautomers in Proteins by 2D 1H/13Cδ2 One-Bond Correlated NMR James L. Sudmeier, Elizabeth M. Bradshaw, Kristin E. Coffman Haddad, Regina M. Day, Craig J. Thalhauser, Peter A. Bullock, and William W. Bachovchin pp 8430–8431 DOI: 10.1021/ja034072c Supporting Info

Catalytic Intramolecular Crossed Aldehyde−Ketone Benzoin Reactions:  A Novel Synthesis of Functionalized Preanthraquinones Yoshifumi Hachisu, Jeffrey W. Bode, and Keisuke Suzuki pp 8432–8433 DOI: 10.1021/ja035308f Supporting Info

Substrate-Supported Lipid Nanotube Arrays Alex I. Smirnov and Oleg G. Poluektov pp 8434–8435 DOI: 10.1021/ja0349406 Supporting Info

Perylene−Tetrapalladium Sandwich Complexes Tetsuro Murahashi, Tomohito Uemura, and Hideo Kurosawa pp 8436–8437 DOI: 10.1021/ja0358246 Supporting Info

Spatially Resolved Measurement of Inhomogeneous Electrocoloration/Insertion in Polycrystalline Molybdenum Oxide Thin Films via Chronoabsorptometric Imaging Todd M. McEvoy and Keith J. Stevenson pp 8438–8439 DOI: 10.1021/ja035370c Supporting Info

Keggin Ions as UV-Switchable Reducing Agents in the Synthesis of Au Core−Ag Shell Nanoparticles Saikat Mandal, PR. Selvakannan, Renu Pasricha, and Murali Sastry pp 8440–8441 DOI: 10.1021/ja034972t Supporting Info

A Nanofluidic Switching Device Roger Karlsson, Anders Karlsson, and Owe Orwar pp 8442–8443 DOI: 10.1021/ja0348748

On-Chip Integration of Enzyme and Immunoassays:  Simultaneous Measurements of Insulin and Glucose Joseph Wang, Alfredo Ibáñez, and Madhu Prakash Chatrathi pp 8444–8445 DOI: 10.1021/ja036067e Supporting Info

Single-Molecule Surface Enhanced Resonance Raman Spectroscopy of the Enhanced Green Fluorescent Protein Satoshi Habuchi, Mircea Cotlet, Roel Gronheid, Gunter Dirix, Jan Michiels, Jos Vanderleyden, Frans C. De Schryver, and Johan Hofkens pp 8446–8447 DOI: 10.1021/ja0353311 Supporting Info

The First Synthesis of Pb1-xMnxSe Nanocrystals Tianhao Ji, Wen-Bin Jian, and Jiye Fang pp 8448–8449 DOI: 10.1021/ja0351746 Supporting Info

Design of Highly Active Iron-Based Catalysts for Atom Transfer Radical Polymerization:  Tridentate Salicylaldiminato Ligands Affording near Ideal Nernstian Behavior Rachel K. O'Reilly, Vernon C. Gibson, Andrew J. P. White, and David J. Williams pp 8450–8451 DOI: 10.1021/ja035458q Supporting Info

First Examples of AuI−X−AgI Halonium Cations (X = Cl and Br) Ke Zhang, Janardhana Prabhavathy, John H. K. Yip, Lip Lin Koh, Geok Kheng Tan, and Jagadese J. Vittal pp 8452–8453 DOI: 10.1021/ja035064z Supporting Info

The Surface Chelate Effect Ryan C. Major and X.-Y. Zhu pp 8454–8455 DOI: 10.1021/ja035544q

Crystal Engineering of Novel Cocrystals of a Triazole Drug with 1,4-Dicarboxylic Acids Julius F. Remenar, Sherry L. Morissette, Matthew L. Peterson, Brian Moulton, J. Michael MacPhee, Héctor R. Guzmán, and Örn Almarsson pp 8456–8457 DOI: 10.1021/ja035776p Supporting Info

Sequential Hydration of Small Protonated Peptides Dengfeng Liu, Thomas Wyttenbach, Perdita E. Barran, and Michael T. Bowers pp 8458–8464 DOI: 10.1021/ja034638x

Remarkably Size-Regulated Cell Invasion by Artificial Viruses. Saccharide-Dependent Self-Aggregation of Glycoviruses and Its Consequences in Glycoviral Gene Delivery Takashi Nakai, Takuya Kanamori, Shinsuke Sando, and Yasuhiro Aoyama pp 8465–8475 DOI: 10.1021/ja035636f

Allosteric Inhibition of Protein−DNA Complexes by Polyamide−Intercalator Conjugates Eric J. Fechter and Peter B. Dervan pp 8476–8485 DOI: 10.1021/ja030125e Supporting Info

Carbapenem Biosynthesis:  Confirmation of Stereochemical Assignments and the Role of CarC in the Ring Stereoinversion Process from l-Proline Anthony Stapon, Rongfeng Li, and Craig A. Townsend pp 8486–8493 DOI: 10.1021/ja034248a

Solution NMR Characterization of the Electronic Structure and Magnetic Properties of High-Spin Ferrous Heme in Deoxy Myoglobin from Aplysia limacina Dejian Ma, Raffaella Musto, Kevin M. Smith, and Gerd N. La Mar pp 8494–8504 DOI: 10.1021/ja035256u Supporting Info

Enzyme Electrokinetics:  Electrochemical Studies of the Anaerobic Interconversions between Active and Inactive States of Allochromatium vinosum [NiFe]-hydrogenase Anne K. Jones, Sophie E. Lamle, Harsh R. Pershad, Kylie A. Vincent, Simon P. J. Albracht, and Fraser A. Armstrong pp 8505–8514 DOI: 10.1021/ja035296y

Direct Synthesis of Soluble, End-Functionalized Polyenes and Polyacetylene Block Copolymers Oren A. Scherman, Isaac M. Rutenberg, and Robert H. Grubbs pp 8515–8522 DOI: 10.1021/ja0301166

Fluorescent Detection of Carbon−Carbon Bond Formation Fujie Tanaka, Rajeswari Thayumanavan, and Carlos F. Barbas III pp 8523–8528 DOI: 10.1021/ja034069t Supporting Info

The Stereochemistry of the Thermal Cheletropic Decarbonylation of 3-Cyclopentenone As Determined by Multiphoton Infrared Photolysis/Thermolysis Gregory R. Unruh and David M. Birney pp 8529–8533 DOI: 10.1021/ja0353661 Supporting Info

X-ray Crystallography and Magnetic Studies of a Stable Macrocyclic Tetranitroxide. Intramolecular Dimer of Nitroxides in a Constrained Geometry of the Upper Rim of Calix[4]arene Andrzej Rajca, Maren Pink, Teerapat Rojsajjakul, Kan Lu, Hua Wang, and Suchada Rajca pp 8534–8538 DOI: 10.1021/ja034115p Supporting Info

Accommodation of α-Substituted Residues in the β-Peptide 12-Helix:  Expanding the Range of Substitution Patterns Available to a Foldamer Scaffold Jin-Seong Park, Hee-Seung Lee, Jonathan R. Lai, Byeong Moon Kim, and Samuel H. Gellman pp 8539–8545 DOI: 10.1021/ja034180z

Photolytic Cleavage of 1-(2-Nitrophenyl)ethyl Ethers Involves Two Parallel Pathways and Product Release Is Rate-Limited by Decomposition of a Common Hemiacetal Intermediate John E. T. Corrie, Andreas Barth, V. Ranjit N. Munasinghe, David R. Trentham, and Michael C. Hutter pp 8546–8554 DOI: 10.1021/ja034354c Supporting Info

Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Cross-Linked Polystyrene-Supported (R,S)-BINAPHOS−Rh(I) Complex Fumitoshi Shibahara, Kyoko Nozaki, and Tamejiro Hiyama pp 8555–8560 DOI: 10.1021/ja034447u Supporting Info

Asymmetric Synthesis of (2S,3R)-Capreomycidine and the Total Synthesis of Capreomycin IB Duane E. DeMong and Robert M. Williams pp 8561–8565 DOI: 10.1021/ja0351241 Supporting Info

Functionalization of Single-Walled Carbon Nanotubes with (R-)Oxycarbonyl Nitrenes Michael Holzinger, Juergen Abraham, Paul Whelan, Ralf Graupner, Lothar Ley, Frank Hennrich, Manfred Kappes, and Andreas Hirsch pp 8566–8580 DOI: 10.1021/ja029931w Supporting Info

Encapsulated Oxide Nanoparticles:  The Influence of the Microstructure on Associated Impurities within a Material Dean C. Sayle and Stephen C. Parker pp 8581–8588 DOI: 10.1021/ja030119i

Composition-Tunable ZnxCd1-xSe Nanocrystals with High Luminescence and Stability Xinhua Zhong, Mingyong Han, Zhili Dong, Timothy J. White, and Wolfgang Knoll pp 8589–8594 DOI: 10.1021/ja035096m Supporting Info

Ligand-Directed Molecular Architectures:  Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms Cheng-Yong Su, Yue-Peng Cai, Chun-Long Chen, Mark D. Smith, Wolfgang Kaim, and Hans-Conrad zur Loye pp 8595–8613 DOI: 10.1021/ja034267k Supporting Info

Reductive Elimination/Oxidative Addition of Carbon−Hydrogen Bonds at Pt(IV)/Pt(II) Centers:  Mechanistic Studies of the Solution Thermolyses of TpMe2Pt(CH3)2H Michael P. Jensen, Douglas D. Wick, Stefan Reinartz, Peter S. White, Joseph L. Templeton, and Karen I. Goldberg pp 8614–8624 DOI: 10.1021/ja028477t Supporting Info

Alternating Oligo(p-phenylene vinylene)−Perylene Bisimide Copolymers:  Synthesis, Photophysics, and Photovoltaic Properties of a New Class of Donor−Acceptor Materials Edda E. Neuteboom, Stefan C. J. Meskers, Paul A. van Hal, Jeroen K. J. van Duren, E. W. Meijer, René A. J. Janssen, Hélène Dupin, Geoffrey Pourtois, Jérôme Cornil, Roberto Lazzaroni, Jean-Luc Brédas, and David Beljonne pp 8625–8638 DOI: 10.1021/ja034926t Supporting Info

Temperature Dependence of Anisotropic Protein Backbone Dynamics Tianzhi Wang, Sheng Cai, and Erik R. P. Zuiderweg pp 8639–8643 DOI: 10.1021/ja034077+ Supporting Info

Electrochemically Switchable Hydrogen-Bonded Molecular Shuttles Alessio Altieri, Francesco G. Gatti, Euan R. Kay, David A. Leigh, David Martel, Francesco Paolucci, Alexandra M. Z. Slawin, and Jenny K. Y. Wong pp 8644–8654 DOI: 10.1021/ja0352552 Supporting Info

Scavenging with TEMPO• To Identify Peptide- and Protein-Based Radicals by Mass Spectrometry:  Advantages of Spin Scavenging over Spin Trapping P. John Wright and Ann M. English pp 8655–8665 DOI: 10.1021/ja0291888

Rational Design Principle for Modulating Fluorescence Properties of Fluorescein-Based Probes by Photoinduced Electron Transfer Tetsuo Miura, Yasuteru Urano, Kumi Tanaka, Tetsuo Nagano, Kei Ohkubo, and Shunichi Fukuzumi pp 8666–8671 DOI: 10.1021/ja035282s

A DNA Aptamer as a New Target-Specific Chiral Selector for HPLC Mickael Michaud, Eric Jourdan, Annick Villet, Anne Ravel, Catherine Grosset, and Eric Peyrin pp 8672–8679 DOI: 10.1021/ja034483t

Reversible Sequence of Intramolecular Associative and Dissociative Electron-Transfer Reactions in Hydrotris(Pyrazolylborate) Complexes of Rhodium William E. Geiger, Nicole Camire Ohrenberg, Brett Yeomans, Neil G. Connelly, and David J. H. Emslie pp 8680–8688 DOI: 10.1021/ja0302073

Topics in Stereochemistry, Volume 22 Edited by Scott E. Denmark (University of Illinois). J. Wiley & Sons, Inc.:  Hoboken. 1999. xvi + 314 pp. $110.00. ISBN 0-471-25316-2. Lawrence T. Scott pp 8689–8690 DOI: 10.1021/ja025359x

Topics in Stereochemistry, Volume 23 Edited by Scott E. Denmark (University of Illinois). J. Wiley & Sons, Inc.:  Hoboken. 2003. xvi + 364 pp. $150.00. ISBN 0-471-17622-2. Lawrence T. Scott pp 8690–8691 DOI: 10.1021/ja033543s

Handbook of Surface and Colloid Chemistry. Second Edition Edited by K. S. Birdi (Consultant, Charlottenlund, Denmark). CRC Press LLC:  Boca Raton. 2003. xiv + 766 pp. $279.95. ISBN 0-8493-1079-2. L. Andrew Lyon pp 8691–8692 DOI: 10.1021/ja033508l

Issue 29

Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level Naoto Ishikawa, Miki Sugita, Tadahiko Ishikawa, Shin-ya Koshihara, and Youkoh Kaizu pp 8694–8695 DOI: 10.1021/ja029629n

Phosphine-Catalyzed Hydration and Hydroalkoxylation of Activated Olefins:  Use of a Strong Nucleophile to Generate a Strong Base Ian C. Stewart, Robert G. Bergman, and F. Dean Toste pp 8696–8697 DOI: 10.1021/ja035232n Supporting Info

Can a Single Oxidant with Two Spin States Masquerade as Two Different Oxidants? A Study of the Sulfoxidation Mechanism by Cytochrome P450 Pankaz K. Sharma, Samuël P. de Visser, and Sason Shaik pp 8698–8699 DOI: 10.1021/ja035135u Supporting Info

Structural Analogues of the Bimetallic Reaction Center in Acetyl CoA Synthase:  A Ni−Ni Model with Bound CO Rachel C. Linck, Cameron W. Spahn, Thomas B. Rauchfuss, and Scott R. Wilson pp 8700–8701 DOI: 10.1021/ja035606c Supporting Info

Rhodium-Catalyzed Enantioselective Diboration of Simple Alkenes Jeremy B. Morgan, Steven P. Miller, and James P. Morken pp 8702–8703 DOI: 10.1021/ja035851w Supporting Info

Oxidative Addition of Aryl Tosylates to Palladium(0) and Coupling of Unactivated Aryl Tosylates at Room Temperature Amy H. Roy and John F. Hartwig pp 8704–8705 DOI: 10.1021/ja035835z Supporting Info

Ni(II) Bis(oxazoline)-Catalyzed Enantioselective Syn Aldol Reactions of N-Propionylthiazolidinethiones in the Presence of Silyl Triflates David A. Evans, C. Wade Downey, and Jed L. Hubbs pp 8706–8707 DOI: 10.1021/ja035509j Supporting Info

Formation of Low-Symmetric 2D Superlattices of Gold Nanoparticles through Surface Modification by Acid−Base Interaction Masayuki Kanehara, Yasunori Oumi, Tsuneji Sano, and Toshiharu Teranishi pp 8708–8709 DOI: 10.1021/ja035187j Supporting Info

DNA-Templated Nanotube Localization Huijun Xin and Adam T. Woolley pp 8710–8711 DOI: 10.1021/ja035902p

Synthesis, Structure, and Evaluation of the Effect of Multiple Stacking on the Electron-Donor Properties of π-Stacked Polyfluorenes Rajendra Rathore, Sameh H. Abdelwahed, and Ilia A. Guzei pp 8712–8713 DOI: 10.1021/ja035518s Supporting Info

De Novo Asymmetric Bio- and Chemocatalytic Synthesis of Saccharides − Stereoselective Formal O-Glycoside Bond Formation Using Palladium Catalysis Alex C. Comely, Rienk Eelkema, Adriaan J. Minnaard, and Ben L. Feringa pp 8714–8715 DOI: 10.1021/ja0347538 Supporting Info

Intramolecular Charge Transfer and Biomimetic Reaction Kinetics in Galactose Oxidase Model Complexes Russell C. Pratt and T. Daniel P. Stack pp 8716–8717 DOI: 10.1021/ja035837j Supporting Info

How Dihydrofolate Reductase Facilitates Protonation of Dihydrofolate Thomas H. Rod and Charles L. Brooks, III pp 8718–8719 DOI: 10.1021/ja035272r Supporting Info

Mechanism-Based Invention of High-Speed Living Radical Polymerization Using Organotellurium Compounds and Azo-Initiators Atsushi Goto, Yungwan Kwak, Takeshi Fukuda, Shigeru Yamago, Kazunori Iida, Mitsuru Nakajima, and Jun-ichi Yoshida pp 8720–8721 DOI: 10.1021/ja035464m Supporting Info

Functionalization of Single-Walled Carbon Nanotubes via the Bingel Reaction Karl S. Coleman, Sam R. Bailey, Siân Fogden, and Malcolm L. H. Green pp 8722–8723 DOI: 10.1021/ja0355675 Supporting Info

A Comparison of Electron-Transfer Rates of Ferrocenoyl-Linked DNA Yi-Tao Long, Chen-Zhong Li, Todd C. Sutherland, M'hamed Chahma, Jeremy S. Lee, and Heinz-Bernhard Kraatz pp 8724–8725 DOI: 10.1021/ja034684x Supporting Info

NMR-Spectroscopic Mapping of an Engineered Cavity in the I14A Mutant of HPr from Staphylococcus carnosus Using Xenon Christian Gröger, Andreas Möglich, Miguel Pons, Brigitte Koch, Wolfgang Hengstenberg, Hans Robert Kalbitzer, and Eike Brunner pp 8726–8727 DOI: 10.1021/ja030113t Supporting Info

An Oligopeptide Containing the C-Terminal Sequence of RNase A Has a Potent RNase A Binding Property Shu-ichi Nakano and Naoki Sugimoto pp 8728–8729 DOI: 10.1021/ja034659r Supporting Info

Probing the Structure and Function of the Escherichia coli DNA Alkylation Repair AlkB Protein through Chemical Cross-Linking Yukiko Mishina and Chuan He pp 8730–8731 DOI: 10.1021/ja034636c Supporting Info

Long-Range Electron Transfer over 4 nm Governed by an Inelastic Hopping Mechanism in Self-Assembled Monolayers of Helical Peptides Tomoyuki Morita and Shunsaku Kimura pp 8732–8733 DOI: 10.1021/ja034872n Supporting Info

Total Synthesis of Apratoxin A Jiehao Chen and Craig J. Forsyth pp 8734–8735 DOI: 10.1021/ja036050w Supporting Info

Ramoplanin Inhibits Bacterial Transglycosylases by Binding as a Dimer to Lipid II Yanan Hu, Jeremiah S. Helm, Lan Chen, Xiang-Yang Ye, and Suzanne Walker pp 8736–8737 DOI: 10.1021/ja035217i Supporting Info

Inactivation of Nitroalkane Oxidase upon Mutation of the Active Site Base and Rescue with a Deprotonated Substrate Michael P. Valley and Paul F. Fitzpatrick pp 8738–8739 DOI: 10.1021/ja036045s

d-Ala-d-Lac Binding Is Not Required for the High Activity of Vancomycin Dimers against Vancomycin Resistant Enterococci Rishi K. Jain, Joaquim Trias, and Jonathan A. Ellman pp 8740–8741 DOI: 10.1021/ja0359761 Supporting Info

Understanding the Hofmeister Effect in Interactions between Chaotropic Anions and Lipid Bilayers:  Molecular Dynamics Simulations Jonathan N. Sachs and Thomas B. Woolf pp 8742–8743 DOI: 10.1021/ja0355729

Migratory Hydroamination:  A Facile Enantioselective Synthesis of Benzomorphans Barry M. Trost and Weiping Tang pp 8744–8745 DOI: 10.1021/ja0360539 Supporting Info

A Case for Asymmetric Hydrozirconation Yonghui Zhang, Richard J. Keaton, and Lawrence R. Sita pp 8746–8747 DOI: 10.1021/ja0349453 Supporting Info

Mechanistic Implications for the Formation of the Diiron Cluster in Ribonucleotide Reductase Provided by Quantitative EPR Spectroscopy Brad S. Pierce, Timothy E. Elgren, and Michael P. Hendrich pp 8748–8759 DOI: 10.1021/ja021290h Supporting Info

Probing the Role of Axial Methionine in the Blue Copper Center of Azurin with Unnatural Amino Acids Steven M. Berry, Martina Ralle, Donald W. Low, Ninian J. Blackburn, and Yi Lu pp 8760–8768 DOI: 10.1021/ja029699u Supporting Info

Synthesis, Electronic Structure, and Electron Transfer Dynamics of (Aryl)ethynyl-Bridged Donor−Acceptor Systems Naomi P. Redmore, Igor V. Rubtsov, and Michael J. Therien pp 8769–8778 DOI: 10.1021/ja021278p Supporting Info

Asymmetric Hydrosilylation of Aryl Ketones Catalyzed by Copper Hydride Complexed by Nonracemic Biphenyl Bis-phosphine Ligands Bruce H. Lipshutz, Kevin Noson, Will Chrisman, and Asher Lower pp 8779–8789 DOI: 10.1021/ja021391f

Highly Phosphorescence Iridium Complexes and Their Application in Organic Light-Emitting Devices Md. K. Nazeeruddin, R. Humphry-Baker, D. Berner, S. Rivier, L. Zuppiroli, and M. Graetzel pp 8790–8797 DOI: 10.1021/ja021413y

First Asymmetric Total Synthesis of Tetrodotoxin Norio Ohyabu, Toshio Nishikawa, and Minoru Isobe pp 8798–8805 DOI: 10.1021/ja0342998 Supporting Info

Activated Decay Pathways for Planar vs Twisted Singlet Phenylalkenes Frederick D. Lewis and Xiaobing Zuo pp 8806–8813 DOI: 10.1021/ja035066j Supporting Info

Substituent Effects on Carbocation Stability:  The pKR for p-Quinone Methide Maria M. Toteva, Michael Moran, Tina L. Amyes, and John P. Richard pp 8814–8819 DOI: 10.1021/ja029588v Supporting Info

Altering the Strength of Lectin Binding Interactions and Controlling the Amount of Lectin Clustering Using Mannose/Hydroxyl-Functionalized Dendrimers Eric K. Woller, Eric D. Walter, Joel R. Morgan, David J. Singel, and Mary J. Cloninger pp 8820–8826 DOI: 10.1021/ja0352496 Supporting Info

Molecular Compasses and Gyroscopes with Polar Rotors:  Synthesis and Characterization of Crystalline Forms Zaira Dominguez, Tinh-A. V. Khuong, Hung Dang, Carlos N. Sanrame, Jose E. Nuñez, and Miguel A. Garcia-Garibay pp 8827–8837 DOI: 10.1021/ja035274b Supporting Info

Submicron Polyethylene Particles from Catalytic Emulsion Polymerization Florian M. Bauers, Ralf Thomann, and Stefan Mecking pp 8838–8840 DOI: 10.1021/ja034504j Supporting Info

Incorporation of Unprotected Heterocyclic Side Chains into Peptoid Oligomers via Solid-Phase Submonomer Synthesis Timothy S. Burkoth, Aaron T. Fafarman, Deborah H. Charych, Michael D. Connolly, and Ronald N. Zuckermann pp 8841–8845 DOI: 10.1021/ja0352101 Supporting Info

Anomeric Effects versus Steric Hindrance to Ionic Solvation in Protonated Glucosylanilines and Cyclohexylanilines Charles L. Perrin and Joshua Kuperman pp 8846–8851 DOI: 10.1021/ja035782l

Control of Redox Transitions and Oxygen Species Binding in Mn Centers by Biologically Significant Ligands; Model Studies with [Mn]-bacteriochlorophyll a Idan Ashur, Alex Brandis, Moshe Greenwald, Yahel Vakrat-Haglili, Varda Rosenbach-Belkin, Hugo Scheer, and Avigdor Scherz pp 8852–8861 DOI: 10.1021/ja030170m

Palladium-Catalyzed Asymmetric Arylation, Vinylation, and Allenylation of tert-Cyclobutanols via Enantioselective C−C Bond Cleavage Satoshi Matsumura, Yasunari Maeda, Takahiro Nishimura, and Sakae Uemura pp 8862–8869 DOI: 10.1021/ja035293l Supporting Info

Zwitterionic and Cationic Bis(phosphine) Platinum(II) Complexes:  Structural, Electronic, and Mechanistic Comparisons Relevant to Ligand Exchange and Benzene C−H Activation Processes J. Christopher Thomas and Jonas C. Peters pp 8870–8888 DOI: 10.1021/ja0296071 Supporting Info

Structural Tuning of Charge, Orbital, and Spin Ordering in Double-Cell Perovskite Series between NdBaFe2O5 and HoBaFe2O5 Patrick M. Woodward, Emmanuelle Suard, and Pavel Karen pp 8889–8899 DOI: 10.1021/ja034813+ Supporting Info

Cyclic Polyamidato Dianions as Bridges between Mo24+ Units:  Synthesis, Crystal Structures, Electrochemistry, Absorption Spectra, and Electronic Structures F. A. Cotton, James P. Donahue, Carlos A. Murillo, Lisa M. Pérez, and Rongmin Yu pp 8900–8910 DOI: 10.1021/ja0358044 Supporting Info

Orientation Modulation of a Synthetic Polypeptide in Self-Assembled Monolayers:  A TOF-SIMS Study Kirsten Leufgen, Manfred Mutter, Horst Vogel, and Wilfried Szymczak pp 8911–8915 DOI: 10.1021/ja0210749 Supporting Info

DFT Investigation of Dehalogenation of Adenine−Halouracil Base Pairs upon Low-Energy Electron Attachment Xifeng Li, Michael D. Sevilla, and Léon Sanche pp 8916–8920 DOI: 10.1021/ja034286u Supporting Info

Influence of Backbone Conformations of Human Carbonic Anhydrase II on Carbon Dioxide Hydration:  Hydration Pathways and Binding of Bicarbonate Markus J. Loferer, Christofer S. Tautermann, Hannes H. Loeffler, and Klaus R. Liedl pp 8921–8927 DOI: 10.1021/ja035072f

Dipolar Waves Map the Structure and Topology of Helices in Membrane Proteins Michael F. Mesleh, Sangwon Lee, Gianluigi Veglia, David S. Thiriot, Francesca M. Marassi, and Stanley J. Opella pp 8928–8935 DOI: 10.1021/ja034211q

Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe3)3Ru(SiR3)2(H)2:  Model Compounds and Real Intermediates in a Dehydrogenative C−Si Bond Forming Reaction Vladimir K. Dioumaev, Bok R. Yoo, Leo J. Procopio, Patrick J. Carroll, and Donald H. Berry pp 8936–8948 DOI: 10.1021/ja035916v Supporting Info

Electron Capture Dissociation Initiates a Free Radical Reaction Cascade Nancy Leymarie, Catherine E. Costello, and Peter B. O'Connor pp 8949–8958 DOI: 10.1021/ja028831n

Insights into the Mobility of Methyl-Bearing Side Chains in Proteins from 3JCC and 3JCN Couplings James J. Chou, David A. Case, and Ad Bax pp 8959–8966 DOI: 10.1021/ja029972s Supporting Info

Issue 30

Mapping Chemical Exchange in Proteins with MW > 50 kD Chunyu Wang, Mark Rance, and Arthur G. Palmer, III pp 8968–8969 DOI: 10.1021/ja035139z

The Dual-Site Alternating Cyclocopolymerization of 1,3-Butadiene with Ethylene Tong Neo Choo and Robert M. Waymouth pp 8970–8971 DOI: 10.1021/ja034603x Supporting Info

Affinity Labeling of a Single Guanine Bulge Kazuhiko Nakatani, Souta Horie, and Isao Saito pp 8972–8973 DOI: 10.1021/ja0350740 Supporting Info

Regioselective and Enantiospecific Rhodium-Catalyzed Allylic Alkylation Reactions Using Copper(I) Enolates:  Synthesis of (−)-Sugiresinol Dimethyl Ether P. Andrew Evans and David K. Leahy pp 8974–8975 DOI: 10.1021/ja035983p Supporting Info

Colorimetric Reversibility of Polydiacetylene Supramolecules Having Enhanced Hydrogen-Bonding under Thermal and pH Stimuli Dong June Ahn, Eun-Hyuk Chae, Gil Sun Lee, Hee-Yong Shim, Tae-Eun Chang, Kwang-Duk Ahn, and Jong-Man Kim pp 8976–8977 DOI: 10.1021/ja0299001 Supporting Info

Kinetic Evidence for a Tetrameric Transition State in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes Frederic G. Buono and Donna G. Blackmond pp 8978–8979 DOI: 10.1021/ja034705n

The First Examples of a Meta-Benzannulation from the Reaction of Fischer Carbene Complexes with Alkynes Huan Wang, Jie Huang, William D. Wulff, and Arnold L. Rheingold pp 8980–8981 DOI: 10.1021/ja035428n Supporting Info

Use of Abasic Site-Containing DNA Strands for Nucleobase Recognition in Water Keitaro Yoshimoto, Seiichi Nishizawa, Masakazu Minagawa, and Norio Teramae pp 8982–8983 DOI: 10.1021/ja029786m Supporting Info

Synthesis of a First-Row Transition Metal Parent Amido Complex and Carbon Monoxide Insertion into the Amide N−H Bond Daniel J. Fox and Robert G. Bergman pp 8984–8985 DOI: 10.1021/ja035707a Supporting Info

C−H Activation of Ethers and Alkanes by Germylene−Aryl Halide Complexes Karla A. Miller, Jeffrey M. Bartolin, Rory M. O'Neill, Ryan D. Sweeder, Thomas M. Owens, Jeff W. Kampf, Mark M. Banaszak Holl, and Norman J. Wells pp 8986–8987 DOI: 10.1021/ja0357285 Supporting Info

An Unusual Isotope Effect on Substrate Inhibition in the Oxidation of Arachidonic Acid by Lipoxygenase Sheng Peng and Wilfred A. van der Donk pp 8988–8989 DOI: 10.1021/ja035977t Supporting Info

Enhanced Degradation of Chemical Warfare Agents through Molecular Engineering of the Phosphotriesterase Active Site Craig M. Hill, Wen-Shan Li, James B. Thoden, Hazel M. Holden, and Frank M. Raushel pp 8990–8991 DOI: 10.1021/ja0358798

Nuclear Quantum Effects and Hydrogen Bonding in Liquids Simone Raugei and Michael L. Klein pp 8992–8993 DOI: 10.1021/ja0351995

Detection of Unusual Lipid Mixing in Cholesterol-Rich Phospholipid Bilayers:  The Long and the Short of It Nobuya Tokutake, Bingwen Jing, and Steven L. Regen pp 8994–8995 DOI: 10.1021/ja0359355 Supporting Info

Direct Probing of Zwitterion Formation in Unsolvated Peptides Rodolphe Antoine, Michel Broyer, Philippe Dugourd, Gary Breaux, Frederick C. Hagemeister, David Pippen, Robert R. Hudgins, and Martin F. Jarrold pp 8996–8997 DOI: 10.1021/ja035912q

Water−Nucleobase “Stacking”:  H−π and Lone Pair−π Interactions in the Atomic Resolution Crystal Structure of an RNA Pseudoknot Sanjay Sarkhel, Alexander Rich, and Martin Egli pp 8998–8999 DOI: 10.1021/ja0357801

A New Chromo-chemodosimeter Selective for Sulfide Anion Diego Jiménez, Ramón Martínez-Máñez, Félix Sancenón, José V. Ros-Lis, A. Benito, and Juan Soto pp 9000–9001 DOI: 10.1021/ja0347336 Supporting Info

Enzymatic Synthesis of an Indole Diterpene by an Oxidosqualene Cyclase:  Mechanistic, Biosynthetic, and Phylogenetic Implications Quanbo Xiong, Xiuwen Zhu, William K. Wilson, A. Ganesan, and Seiichi P. T. Matsuda pp 9002–9003 DOI: 10.1021/ja036322v Supporting Info

Correlation between 2H NMR Side-Chain Order Parameters and Sequence Conservation in Globular Proteins Anthony Mittermaier, Alan R. Davidson, and Lewis E. Kay pp 9004–9005 DOI: 10.1021/ja034856q Supporting Info

Protein Electrochemistry Using Aligned Carbon Nanotube Arrays J. Justin Gooding, Rahmat Wibowo, Jingquan Liu, Wenrong Yang, Dusan Losic, Shannon Orbons, Freya J. Mearns, Joe G. Shapter, and D. Brynn Hibbert pp 9006–9007 DOI: 10.1021/ja035722f Supporting Info

Zinc Is an Essential Cofactor for Type I Isopentenyl Diphosphate:Dimethylallyl Diphosphate Isomerase Christina N. Carrigan and C. Dale Poulter pp 9008–9009 DOI: 10.1021/ja0350381

Two-Component Dendritic Gels:  Easily Tunable Materials Andrew R. Hirst, David K. Smith, Martin C. Feiters, Huub P. M. Geurts, and Andrew C. Wright pp 9010–9011 DOI: 10.1021/ja036111q Supporting Info

Shape Amphiphiles:  Mixing Rods and Disks in Liquid Crystals Richard W. Date and Duncan W. Bruce pp 9012–9013 DOI: 10.1021/ja0357947

Base-Dependent Competitive Adsorption of Single-Stranded DNA on Gold Hiromi Kimura-Suda, Dmitri Y. Petrovykh, Michael J. Tarlov, and Lloyd J. Whitman pp 9014–9015 DOI: 10.1021/ja035756n Supporting Info

Substantial 2H-Magnetic Isotope Effects on the Diastereoselectivity of Triplet Photocycloaddition Reactions Axel G. Griesbeck, Samir Bondock, and Peter Cygon pp 9016–9017 DOI: 10.1021/ja0356232 Supporting Info

Fomenting Proton Anisochronicity in the CH2D Group Benjamin D. Allen and Daniel J. O'Leary pp 9018–9019 DOI: 10.1021/ja034242l

Synthesis, Structure, and Reactivity of a η3-1-Hydroxyallyl Complex:  Protonation of an α,β-Unsaturated Carbonyl Compound Bound to Palladium(0) and Platinum(0) Sensuke Ogoshi, Masaki Morita, and Hideo Kurosawa pp 9020–9021 DOI: 10.1021/ja0361042 Supporting Info

Highly Enantioselective Michael Addition of Silyl Nitronates to α,β-Unsaturated Aldehydes Catalyzed by Designer Chiral Ammonium Bifluorides:  Efficient Access to Optically Active γ-Nitro Aldehydes and Their Enol Silyl Ethers Takashi Ooi, Kanae Doda, and Keiji Maruoka pp 9022–9023 DOI: 10.1021/ja0352810 Supporting Info

The Thiosulfinyl Group Serves as a Stereogenic Center and Shows Diamagnetic Anisotropy Similar to That of the Sulfinyl Group Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama pp 9024–9025 DOI: 10.1021/ja035892s Supporting Info

η3-Pyranyl and η3-Pyridinyl Molybdenum π-Complexes as Chiral Scaffolds for the Enantioselective Construction of Substituted Oxa- and Aza[3.3.1]bicyclics:  First Enantio- and Regiocontrolled [5+3] Cycloaddition Reactions Ramón Gómez Arrayás and Lanny S. Liebeskind pp 9026–9027 DOI: 10.1021/ja035424i Supporting Info

Cyclization of Carbonyl Groups onto Alkynes upon Reaction with IPy2BF4 and Their Trapping with Nucleophiles:  A Versatile Trigger for Assembling Oxygen Heterocycles José Barluenga, Henar Vázquez-Villa, Alfredo Ballesteros, and José M. González pp 9028–9029 DOI: 10.1021/ja0355372 Supporting Info

Artificial Metalloenzymes for Enantioselective Catalysis Based on Biotin−Avidin Jérôme Collot, Julieta Gradinaru, Nicolas Humbert, Myriem Skander, Andrea Zocchi, and Thomas R. Ward pp 9030–9031 DOI: 10.1021/ja035545i Supporting Info

Total Synthesis of Anti-HIV Agent Chloropeptin I Hongbo Deng, Jae-Kyung Jung, Tao Liu, Kevin W. Kuntz, Marc L. Snapper, and Amir H. Hoveyda pp 9032–9034 DOI: 10.1021/ja030249r Supporting Info

Secondary Structural Preferences of 2,2-Disubstituted Pyrrolidine-4-carboxylic Acid Oligomers:  β-Peptide Foldamers that Cannot Form Internal Hydrogen Bonds Bayard R. Huck, John D. Fisk, Ilia A. Guzei, Heather A. Carlson, and Samuel H. Gellman pp 9035–9037 DOI: 10.1021/ja034561c Supporting Info

Stabilization of β-Hairpin Peptides by Salt Bridges:  Role of Preorganization in the Energetic Contribution of Weak Interactions Barbara Ciani, Muriel Jourdan, and Mark S. Searle pp 9038–9047 DOI: 10.1021/ja030074l

Fluorophobic Effect Promotes Partitioning of Organics into Macroporous Organic Polymers:  A Method for Achieving High Local Concentrations Shannon M. Leeder and Michel R. Gagné pp 9048–9054 DOI: 10.1021/ja0353558 Supporting Info

Thin Film Construction and Characterization and Gas-Sensing Performances of a Tailored Phenylene−Thienylene Copolymer Francesco Naso, Francesco Babudri, Donato Colangiuli, Gianluca M. Farinola, Fabio Quaranta, Roberto Rella, Raffaele Tafuro, and Ludovico Valli pp 9055–9061 DOI: 10.1021/ja035490k Supporting Info

Degenerative Transfer Living Ziegler−Natta Polymerization:  Application to the Synthesis of Monomodal Stereoblock Polyolefins of Narrow Polydispersity and Tunable Block Length Yonghui Zhang, Richard J. Keaton, and Lawrence R. Sita pp 9062–9069 DOI: 10.1021/ja029780x Supporting Info

Singlet Hydrocarbon Carbenes with High Barriers Toward Isomerization:  A Computational Investigation Athanassios Nicolaides pp 9070–9073 DOI: 10.1021/ja0299699 Supporting Info

Mechanisms of Hydrogen-, Oxygen-, and Electron-Transfer Reactions of Cumylperoxyl Radical Shunichi Fukuzumi, Kanji Shimoosako, Tomoyoshi Suenobu, and Yoshihito Watanabe pp 9074–9082 DOI: 10.1021/ja035156o Supporting Info

3-Pyridylcarbene and 3-Pyridylnitrene:  Ring Opening to Nitrile Ylides Pawel Bednarek and Curt Wentrup pp 9083–9089 DOI: 10.1021/ja035632a Supporting Info

Study of Nucleation and Growth in the Organometallic Synthesis of Magnetic Alloy Nanocrystals:  The Role of Nucleation Rate in Size Control of CoPt3 Nanocrystals Elena V. Shevchenko, Dmitri V. Talapin, Heimo Schnablegger, Andreas Kornowski, Örjan Festin, Peter Svedlindh, Markus Haase, and Horst Weller pp 9090–9101 DOI: 10.1021/ja029937l Supporting Info

Order−Disorder in the Super-Sodalite Zn3Al6(PO4)12, 4tren, 17H2O (MIL-74):  A Combined XRD−NMR Assessment Lionel Beitone, Clarisse Huguenard, Axel Gansmüller, Marc Henry, Francis Taulelle, Thierry Loiseau, and Gérard Férey pp 9102–9110 DOI: 10.1021/ja0294818 Supporting Info

Experimental Confirmation of the Importance of Orientation in the Anomalous Chiral Sensitivity of Second Harmonic Generation Brian J. Burke, Andrew J. Moad, Mark A. Polizzi, and Garth J. Simpson pp 9111–9115 DOI: 10.1021/ja0298500 Supporting Info

Molecular and Electronic Structures of Bis-(o-diiminobenzosemiquinonato)metal(II) Complexes (Ni, Pd, Pt), Their Monocations and -Anions, and of Dimeric Dications Containing Weak Metal−Metal Bonds Diran Herebian, Eberhard Bothe, Frank Neese, Thomas Weyhermüller, and Karl Wieghardt pp 9116–9128 DOI: 10.1021/ja030123u Supporting Info

Photovoltaic Properties of Self-Assembled Monolayers of Porphyrins and Porphyrin−Fullerene Dyads on ITO and Gold Surfaces Hiroko Yamada, Hiroshi Imahori, Yoshinobu Nishimura, Iwao Yamazaki, Tae Kyu Ahn, Seong Keun Kim, Dongho Kim, and Shunichi Fukuzumi pp 9129–9139 DOI: 10.1021/ja034913f Supporting Info

17O Quadrupole Coupling and Chemical Shielding Tensors in an H-bonded Carboxyl Group:  α-Oxalic Acid Qianwen Zhang, Eduard Y. Chekmenev, and Richard J. Wittebort pp 9140–9146 DOI: 10.1021/ja034495e Supporting Info

Spectroscopic and Calorimetric Studies on the Mechanism of Methylenecyclopropane Rearrangements Triggered by Photoinduced Electron Transfer Hiroshi Ikeda, Kimio Akiyama, Yasutake Takahashi, Tatsuo Nakamura, Satoshi Ishizaki, Yukio Shiratori, Hitoshi Ohaku, Joshua L. Goodman, Abdelaziz Houmam, Danial D. M. Wayner, Shozo Tero-Kubota, and Tsutomu Miyashi pp 9147–9157 DOI: 10.1021/ja0277982 Supporting Info

Description of the Ground State Wave Functions of Ni Dithiolenes Using Sulfur K-edge X-ray Absorption Spectroscopy Robert K. Szilagyi, Booyong S. Lim, Thorsten Glaser, Richard H. Holm, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 9158–9169 DOI: 10.1021/ja029806k Supporting Info

Role of Water Mediated Interactions in Protein−Protein Recognition Landscapes Garegin A. Papoian, Johan Ulander, and Peter G. Wolynes pp 9170–9178 DOI: 10.1021/ja034729u Supporting Info

Evaluation of Backbone Proton Positions and Dynamics in a Small Protein by Liquid Crystal NMR Spectroscopy Tobias S. Ulmer, Benjamin E. Ramirez, Frank Delaglio, and Ad Bax pp 9179–9191 DOI: 10.1021/ja0350684 Supporting Info

Quantitative Analysis of Catalysis and Inhibition at Horseradish Peroxidase Monolayers Immobilized on an Electrode Surface Benoît Limoges, Jean-Michel Savéant, and Dounia Yazidi pp 9192–9203 DOI: 10.1021/ja0354263 Supporting Info

Principles and Features of Single-Scan Two-Dimensional NMR Spectroscopy Lucio Frydman, Adonis Lupulescu, and Tali Scherf pp 9204–9217 DOI: 10.1021/ja030055b

Infrared Spectra of Aluminum Hydrides in Solid Hydrogen:  Al2H4 and Al2H6 Xuefeng Wang, Lester Andrews, Simon Tam, Michelle E. DeRose, and Mario E. Fajardo pp 9218–9228 DOI: 10.1021/ja0353560

Elucidation of Fragmentation Mechanisms of Protonated Peptide Ions and Their Products:  A Case Study on Glycylglycylglycine Using Density Functional Theory and Threshold Collision-Induced Dissociation Houssain El Aribi, Christopher F. Rodriquez, David R. P. Almeida, Yun Ling, William W.-N. Mak, Alan C. Hopkinson, and K. W. Michael Siu pp 9229–9236 DOI: 10.1021/ja0207293 Supporting Info

Progress in Inorganic Chemistry, Volume 51 Edited by Kenneth Karlin (Johns Hopkins University). John Wiley & Sons, Inc.:  Hoboken. 2003. viii + 640 pp. $150.00. ISBN 0-471-26534-9. Joseph E. Earley, Sr. p 9237 DOI: 10.1021/ja025362g

Annual Reports on NMR Spectroscopy:  Appli-cations of NMR to Materials Science. Volume 44 Edited by G. A. Webb (University of Surrey) and I. Ando (Tokyo Institute of Technology). Academic Press:  San Diego, London. 2001. x + 146 pp. $124.95. ISBN 0-12-505344-4. Ian D. Gay pp 9237–9238 DOI: 10.1021/ja0253181

Issue 31

Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate Yoichi Arimoto, Shin-ichi Ohkoshi, Zhuang Jin Zhong, Hidetake Seino, Yasushi Mizobe, and Kazuhito Hashimoto pp 9240–9241 DOI: 10.1021/ja030130i Supporting Info

Chain Elongations by Three Carbon Atoms at a Time in the Boron-Catalyzed Polymerization of Methallyltriphenylarsonium Ylide Jean-Philippe Goddard, Patricia Lixon, Thierry Le Gall, and Charles Mioskowski pp 9242–9243 DOI: 10.1021/ja035792m

The First Triple Thiol-thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers Takumi Konno, Kazuyuki Haneishi, Masakazu Hirotsu, Tadashi Yamaguchi, Tasuku Ito, and Takashi Yoshimura pp 9244–9245 DOI: 10.1021/ja0302331 Supporting Info

Bulky Aluminum Alkyl Scavengers in Olefin Polymerization with Group 4 Catalysts Russell A. Stapleton, Brandon R. Galan, Scott Collins, Richard S. Simons, Jered C. Garrison, and Wiley J. Youngs pp 9246–9247 DOI: 10.1021/ja030121+ Supporting Info

An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids Nicolas Audic, Hervé Clavier, Marc Mauduit, and Jean-Claude Guillemin pp 9248–9249 DOI: 10.1021/ja021484x Supporting Info

Tin-Centered Radical and Cation:  Stable and Free Akira Sekiguchi, Tomohide Fukawa, Vladimir Ya. Lee, and Masaaki Nakamoto pp 9250–9251 DOI: 10.1021/ja030156+ Supporting Info

Purely Site-Specific Chemisorption and Conformation of Trimethylamine on Si(100)c(4 × 2) Md. Zakir Hossain, Shin-ichi Machida, Yoshiyuki Yamashita, Kozo Mukai, and Jun Yoshinobu pp 9252–9253 DOI: 10.1021/ja034413m

First Examples of Organophosphorus-Containing Materials for Light-Emitting Diodes Claire Fave, Ting-Yi Cho, Muriel Hissler, Chieh-Wei Chen, Tien-Yau Luh, Chung-Chih Wu, and Régis Réau pp 9254–9255 DOI: 10.1021/ja035155w Supporting Info

Solventless Polymerization:  Spatial Migration of a Catalyst To Form Polymeric Thin Films in Microchannels Hongwei Gu, Chenjie Xu, Lu-Tao Weng, and Bing Xu pp 9256–9257 DOI: 10.1021/ja029954a Supporting Info

Single-Step in Situ Synthesis of Polymer-Grafted Single-Wall Nanotube Composites Gunaranjan Viswanathan, Nirupama Chakrapani, Hoichang Yang, Bingqing Wei, Hyunsoo Chung, Kilwon Cho, Chang Y. Ryu, and Pulickel M. Ajayan pp 9258–9259 DOI: 10.1021/ja0354418 Supporting Info

A Cationic Guest in a 24+ Cationic Host Jean-Pascal Bourgeois, Makoto Fujita, Masaki Kawano, Shigeru Sakamoto, and Kentaro Yamaguchi pp 9260–9261 DOI: 10.1021/ja0349002 Supporting Info

Stereoelectronic Effects on Collagen Stability:  The Dichotomy of 4-Fluoroproline Diastereomers Jonathan A. Hodges and Ronald T. Raines pp 9262–9263 DOI: 10.1021/ja035881z Supporting Info

Molybdenum−Phosphorus Triple Bond Stabilization by Ancillary Alkoxide Ligation:  Synthesis and Structure of a Terminal Phosphide Tris-1-methylcyclohexanoxide Complex Frances H. Stephens, Joshua S. Figueroa, Paula L. Diaconescu, and Christopher C. Cummins pp 9264–9265 DOI: 10.1021/ja0354317 Supporting Info

Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets Wei Chen, Hong-Ming Yuan, Jia-Yu Wang, Zhao-Yue Liu, Jin-Jie Xu, Min Yang, and Jie-Sheng Chen pp 9266–9267 DOI: 10.1021/ja035388n Supporting Info

[3+3]Cycloalkyne Dimers Linked by an Azo Group:  A Stable cis-Azo Compound Forms Polymeric Aggregates by Nonplanar π−π Interactions Yuto Saiki, Hiroki Sugiura, Keiichi Nakamura, Masahiko Yamaguchi, Tomonori Hoshi, and Jun-ichi Anzai pp 9268–9269 DOI: 10.1021/ja034942q Supporting Info

Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process H. V. Rasika Dias, R. Greg Browning, Sharon A. Polach, Himashinie V. K. Diyabalanage, and Carl J. Lovely pp 9270–9271 DOI: 10.1021/ja034801o Supporting Info

A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation Feihe Huang, Frank R. Fronczek, and Harry W. Gibson pp 9272–9273 DOI: 10.1021/ja0355877 Supporting Info

TNA Synthesis by DNA Polymerases John C. Chaput and Jack W. Szostak pp 9274–9275 DOI: 10.1021/ja035917n

Unusual Effects in the Pd-Catalyzed Asymmetric Allylic Alkylations:  Synthesis of Chiral Chromans Barry M. Trost, Hong C. Shen, Li Dong, and Jean-Philippe Surivet pp 9276–9277 DOI: 10.1021/ja036052g Supporting Info

Stereospecific Photochemical Ring Expansion of Lithiated Benzamides Jonathan Clayden, Faye E. Knowles, and Christel J. Menet pp 9278–9279 DOI: 10.1021/ja035827i Supporting Info

Effect of Catenation on Protein Folding Stability Huan-Xiang Zhou pp 9280–9281 DOI: 10.1021/ja0355978 Supporting Info

Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes:  A Rapid, Practical Approach to Bicyclo[3.3.0]octenes Alejandro Delgado, J. Ramón Rodríguez, Luis Castedo, and José L. Mascareñas pp 9282–9283 DOI: 10.1021/ja0356333 Supporting Info

Cucurbit[6]uril Pseudorotaxanes:  Distinctive Gas-Phase Dissociation and Reactivity Haizhen Zhang, Eric S. Paulsen, Kevin A. Walker, Krzysztof E. Krakowiak, and David V. Dearden pp 9284–9285 DOI: 10.1021/ja035704y Supporting Info

Φ-Values beyond the Ribosomally Encoded Amino Acids:  Kinetic and Thermodynamic Consequences of Incorporating Trifluoromethyl Amino Acids in a Globular Protein Jia-Cherng Horng and Daniel P. Raleigh pp 9286–9287 DOI: 10.1021/ja0353199 Supporting Info

Meta-Conjugation and Excited-State Coupling in Phenylacetylene Dendrimers Kevin M. Gaab, Alexis L. Thompson, Jianjun Xu, Todd J. Martínez, and Christopher J. Bardeen pp 9288–9289 DOI: 10.1021/ja029489h Supporting Info

Mutasynthesis of Enterocin and Wailupemycin Analogues John A. Kalaitzis, Miho Izumikawa, Longkuan Xiang, Christian Hertweck, and Bradley S. Moore pp 9290–9291 DOI: 10.1021/ja035973o

Studying the Interaction of α-Gal Carbohydrate Antigen and Proteins by Quartz-Crystal Microbalance Yun Zhang, Vladislav Telyatnikov, Megahna Sathe, Xiangqun Zeng, and Peng George Wang pp 9292–9293 DOI: 10.1021/ja035350a Supporting Info

A New Ruthenium-Catalyzed Cleavage of a Carbon−Carbon Triple Bond:  Efficient Transformation of Ethynyl Alcohol into Alkene and Carbon Monoxide Swarup Datta, Chia-Lung Chang, Kuo-Liang Yeh, and Rai-Shung Liu pp 9294–9295 DOI: 10.1021/ja036246w Supporting Info

Design of Base-Discriminating Fluorescent Nucleoside and Its Application to T/C SNP Typing Akimitsu Okamoto, Kazuo Tanaka, Tetsuo Fukuta, and Isao Saito pp 9296–9297 DOI: 10.1021/ja035408l Supporting Info

Formation of Nanostructured Polymer Filaments in Nanochannels Chih-Yi Peng, Wook Jun Nam, Stephen J. Fonash, Bin Gu, Ayusman Sen, Kenneth Strawhecker, Sudarshan Natarajan, Henry C. Foley, and Seong H. Kim pp 9298–9299 DOI: 10.1021/ja0345423 Supporting Info

Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements Takeaki Iwamoto, Hidenori Masuda, Shintaro Ishida, Chizuko Kabuto, and Mitsuo Kira pp 9300–9301 DOI: 10.1021/ja0356784 Supporting Info

Diamond Formation by Reduction of Carbon Dioxide at Low Temperatures Zhengsong Lou, Qianwang Chen, Yufeng Zhang, Wei Wang, and Yitai Qian pp 9302–9303 DOI: 10.1021/ja035177i Supporting Info

Epicocconone, A Novel Fluorescent Compound from the Fungus Epicoccum nigrum Phillip J. L. Bell and Peter Karuso pp 9304–9305 DOI: 10.1021/ja035496+ Supporting Info

A New Class of Modular Chiral Ligands with Fluxional Groups Mukund P. Sibi, Ruzhou Zhang, and Shankar Manyem pp 9306–9307 DOI: 10.1021/ja035979d Supporting Info

3-Boronoacrolein as an Exceptional Heterodiene in the Highly Enantio- and Diastereoselective Cr(III)-Catalyzed Three-Component [4+2]/Allylboration Xuri Gao and Dennis G. Hall pp 9308–9309 DOI: 10.1021/ja036368o Supporting Info

A Stable Silicon Congener of Highly Strained Bicyclo[3.2.0]hepta-1,3,6-triene Yoshihiro Kon, Jun Ogasawara, Kenkichi Sakamoto, Chizuko Kabuto, and Mitsuo Kira pp 9310–9311 DOI: 10.1021/ja0359097 Supporting Info

Effect of Surface Pressure on the Insulator to Metal Transition of a Langmuir Polyaniline Monolayer Jie Zhang, Anna L. Barker, Daniel Mandler, and Patrick R. Unwin pp 9312–9313 DOI: 10.1021/ja036146q

Partitioning the Loss in Vancomycin Binding Affinity for d-Ala-d-Lac into Lost H-Bond and Repulsive Lone Pair Contributions Casey C. McComas, Brendan M. Crowley, and Dale L. Boger pp 9314–9315 DOI: 10.1021/ja035901x Supporting Info

Inactivation of Acetyl-CoA Synthase/Carbon Monoxide Dehydrogenase by Copper Matthew R. Bramlett, Xiangshi Tan, and Paul A. Lindahl pp 9316–9317 DOI: 10.1021/ja0352855

A Combined Experimental and Theoretical Study of Divalent Metal Ion Selectivity and Function in Proteins:  Application to E. coli Ribonuclease H1 C. Satheesan Babu, Todor Dudev, R. Casareno, J. A. Cowan, and Carmay Lim pp 9318–9328 DOI: 10.1021/ja034956w

Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity:  A View through the Prism of Marcus Theory Igor V. Alabugin, Mariappan Manoharan, Boris Breiner, and Frederick D. Lewis pp 9329–9342 DOI: 10.1021/ja035729x Supporting Info

Study of the Chemistry of ortho- and para-Biphenylnitrenes by Laser Flash Photolysis and Time-Resolved IR Experiments and by B3LYP and CASPT2 Calculations Meng-Lin Tsao, Nina Gritsan, Tammi R. James, Matthew S. Platz, David A. Hrovat, and Weston Thatcher Borden pp 9343–9358 DOI: 10.1021/ja0351591 Supporting Info

Factors that Determine the Protein Resistance of Oligoether Self-Assembled Monolayers − Internal Hydrophilicity, Terminal Hydrophilicity, and Lateral Packing Density Sascha Herrwerth, Wolfgang Eck, Sven Reinhardt, and Michael Grunze pp 9359–9366 DOI: 10.1021/ja034820y Supporting Info

First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat:  Self-Assembly and Crystal Structures Feihe Huang, Harry W. Gibson, William S. Bryant, Devdatt S. Nagvekar, and Frank R. Fronczek pp 9367–9371 DOI: 10.1021/ja034968h Supporting Info

A Heterocyclic Peptide Nanotube W. Seth Horne, C. David Stout, and M. Reza Ghadiri pp 9372–9376 DOI: 10.1021/ja034358h Supporting Info

Role of Charge-Transfer Configurations on the Addition Reaction of Aminoalkyl Radicals onto Acrylate Double Bonds Jacques Lalevée, Xavier Allonas, Sébastien Genet, and Jean-Pierre Fouassier pp 9377–9380 DOI: 10.1021/ja034750v

Resolution of the Non-Steady-State Kinetics of the Two-Step Mechanism for the Diels−Alder Reaction between Anthracene and Tetracyanoethylene in Acetonitrile Kishan L. Handoo, Yun Lu, and Vernon D. Parker pp 9381–9387 DOI: 10.1021/ja0299396

“Belt and Braces”:  A Peptide-Based Linker System of de Novo Design Maxim G. Ryadnov, Buelent Ceyhan, Christof M. Niemeyer, and Derek N. Woolfson pp 9388–9394 DOI: 10.1021/ja0352045 Supporting Info

The Role of the HOOO- Anion in the Ozonation of Alcohols:  Large Differences in the Gas-Phase and in the Solution-Phase Mechanism Anan Wu, Dieter Cremer, and Božo Plesniar pp 9395–9402 DOI: 10.1021/ja030245m Supporting Info

Design of Heterogeneous Catalysts via Multiple Active Site Positioning in Organic−Inorganic Hybrid Materials Véronique Dufaud and Mark E. Davis pp 9403–9413 DOI: 10.1021/ja034594s Supporting Info

Easily Processable Phenylene−Thiophene-Based Organic Field-Effect Transistors and Solution-Fabricated Nonvolatile Transistor Memory Elements Melissa Mushrush, Antonio Facchetti, Michael Lefenfeld, Howard E. Katz, and Tobin J. Marks pp 9414–9423 DOI: 10.1021/ja035143a

Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds:  Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Cory A. Jaska, Karen Temple, Alan J. Lough, and Ian Manners pp 9424–9434 DOI: 10.1021/ja030160l Supporting Info

Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex Elizabeth D. Blue, Amelia Davis, David Conner, T. Brent Gunnoe, Paul D. Boyle, and P. S. White pp 9435–9441 DOI: 10.1021/ja0353659 Supporting Info

Mechanisms of C−C and C−H Alkane Reductive Eliminations from Octahedral Pt(IV):  Reaction via Five-Coordinate Intermediates or Direct Elimination? Dawn M. Crumpton-Bregel and Karen I. Goldberg pp 9442–9456 DOI: 10.1021/ja029140u Supporting Info

Quantitative Measure for the “Nakedness” of Fluoride Ion Sources Karl O. Christe and H. Donald Brooke Jenkins pp 9457–9461 DOI: 10.1021/ja035675r

Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si−H and C−H Bonds Aaron D. Sadow and T. Don Tilley pp 9462–9475 DOI: 10.1021/ja030024g Supporting Info

Cationic Assembly of Metal Complex Aggregates:  Structural Diversity, Solution Stability, and Magnetic Properties Xiang Lin, Dan M. J. Doble, Alexander J. Blake, Andrew Harrison, Claire Wilson, and Martin Schröder pp 9476–9483 DOI: 10.1021/ja0341438 Supporting Info

α- and β-A2Hg3M2S8 (A = K, Rb; M = Ge, Sn):  Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response J.-H. Liao, G. M. Marking, K. F. Hsu, Y. Matsushita, M. D. Ewbank, R. Borwick, P. Cunningham, M. J. Rosker, and M. G. Kanatzidis pp 9484–9493 DOI: 10.1021/ja034121l Supporting Info

Electronic Excitation Energies of ZniOi Clusters Jon M. Matxain, Jose M. Mercero, Joseph E. Fowler, and Jesus M. Ugalde pp 9494–9499 DOI: 10.1021/ja0264504 Supporting Info

Structure and Phase Transitions of Alkyl Chains on Mica Hendrik Heinz, Hein J. Castelijns, and Ulrich W. Suter pp 9500–9510 DOI: 10.1021/ja021248m

Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M‘]n+:  Computational Analyses of the Effect of the Metal Haijun Jiao, Karine Costuas, John A. Gladysz, Jean-François Halet, Maud Guillemot, Loic Toupet, Frédéric Paul, and Claude Lapinte pp 9511–9522 DOI: 10.1021/ja034619n Supporting Info

On the Nonpolar Hydration Free Energy of Proteins:  Surface Area and Continuum Solvent Models for the Solute−Solvent Interaction Energy Ronald M. Levy, Linda Y. Zhang, Emilio Gallicchio, and Anthony K. Felts pp 9523–9530 DOI: 10.1021/ja029833a

Influence of Delocalization on the Stability of Dianions:  Study of a Systematic Series of Dianions with Growing Electronic Localization Sven Feuerbacher and Lorenz S. Cederbaum pp 9531–9537 DOI: 10.1021/ja035878f

Total Synthesis of Elisabethin A:  Intramolecular Diels−Alder Reaction under Biomimetic Conditions  [J. Am. Chem. Soc. 2003, 125, 4680−4681].  Thilo J. Heckrodt and Johann Mulzer p 9538 DOI: 10.1021/ja036029v

Self-Assembled Nanostructures By Jin Z. Zhang (University of California, Santa Cruz), Zhong-Lin Wang (Georgia Institute of Technology), Jun Liu (Sandia National Labs), Shaowei Chen (Southern Illinois University), and Gang-Yu Liu (University of California, Davis). Kluwer Academic/Plenum Publisher:  New York. 2003. xviii + 316 pp. $135.00. ISBN 0-306-47299-6. David A. Vanden Bout p 9539 DOI: 10.1021/ja0253585

Biocatalysis in Polymer Science Edited by Richard A. Gross (Polytechnic University) and H. N. Cheng (Hercules Incorporated Research Center). American Chemical Society (Distributed by Oxford University Press):  Washington, DC. 2003. xvi + 336 pp. $145.00. ISBN 0-8412-3781-6. p 9539 DOI: 10.1021/ja0335263

Chemistry and Applications of Polyphosphazenes By Harry R. Allcock (The Pennsylvania State University). John Wiley & Sons, Inc.:  Hoboken. 2003. xii + 726 pp. $325.00. ISBN 0-471-44371-9. Robert H. Neilson pp 9539–9540 DOI: 10.1021/ja0253639

Handbook of Molecular Physics and Quantum Chemistry, Volumes 1−3 Edited by Stephen Wilson (Rutherford Appleton Laboratory, Chilton, U.K.), Peter F. Bernath (University of Waterloo, Ontario, Canada), and Roy McWeeny (Università di Pisa, Italy). John Wiley & Sons, Ltd:  Chichester. 2003. 2200 pp. $895.00. ISBN 0-471-62374-1. p 9540 DOI: 10.1021/ja033538o

Issue 32

Application of Host−Guest Chemistry in Nanotube-Based Device Fabrication:  Photochemically Controlled Immobilization of Azobenzene Nanotubes on Patterned α-CD Monolayer/Au Substrates via Molecular Recognition Ipsita A. Banerjee, Lingtao Yu, and Hiroshi Matsui pp 9542–9543 DOI: 10.1021/ja0344011 Supporting Info

Asymmetric Addition of Alkylzinc Reagents to Cyclic α,β-Unsaturated Ketones and a Tandem Enantioselective Addition/Diastereoselective Epoxidation with Dioxygen Sang-Jin Jeon and Patrick J. Walsh pp 9544–9545 DOI: 10.1021/ja036302t Supporting Info

A Reversible Tube-to-Rod Transition in a Block Copolymer Micelle Jose Raez, Juan Pablo Tomba, Ian Manners, and Mitchell A. Winnik pp 9546–9547 DOI: 10.1021/ja030251i Supporting Info

A Novel Kinetic Trap for NO Release from Cytochrome c‘:  A Possible Mechanism for NO Release from Activated Soluble Guanylate Cyclase Colin R. Andrew, Kenton R. Rodgers, and Robert R. Eady pp 9548–9549 DOI: 10.1021/ja035105r

Mixed-Element Capture Agents:  A Simple Strategy for the Construction of Synthetic, High-Affinity Protein Capture Ligands Kiran Bachhawat-Sikder and Thomas Kodadek pp 9550–9551 DOI: 10.1021/ja034912n Supporting Info

Spontaneous Catalytic Generation of Nitric Oxide from S-Nitrosothiols at the Surface of Polymer Films Doped with Lipophilic Copper(II) Complex Bong Kyun Oh and Mark E. Meyerhoff pp 9552–9553 DOI: 10.1021/ja035775x Supporting Info

Biomimetic Synthesis of (±)-Pinnatal and (±)-Sterekunthal A Jeremiah P. Malerich and Dirk Trauner pp 9554–9555 DOI: 10.1021/ja036026i Supporting Info

Calculation of Dipole-Shielding Polarizabilities (σαβγI):  The Influence of Uniform Electric Field Effects on the Shielding of Backbone Nuclei in Proteins Jonathan Boyd, Carmen Domene, Christina Redfield, Marta B. Ferraro, and Paolo Lazzeretti pp 9556–9557 DOI: 10.1021/ja034855y Supporting Info

Ketonization of Incarcerated Acetophenone Enol Darren A. Makeiff, Kodumuru Vishnumurthy, and John C. Sherman pp 9558–9559 DOI: 10.1021/ja030094n Supporting Info

Chelating Bis(thiophosphinic amidate)s as Versatile Supporting Ligands for the Group 3 Metals. An Application to the Synthesis of Highly Active Catalysts for Intramolecular Alkene Hydroamination Young Kwan Kim, Tom Livinghouse, and Yoshikazu Horino pp 9560–9561 DOI: 10.1021/ja021445l Supporting Info

Ultrafast Fluorescence Investigation of Excitation Energy Transfer in Different Dendritic Core Branched Structures Ying Wang, Mahinda I. Ranasinghe, and Theodore Goodson, III pp 9562–9563 DOI: 10.1021/ja035215y Supporting Info

Hydrocarbation Chemistry Proceeding from Nickel Carbenes Hongyi Hou, Peter K. Gantzel, and Clifford P. Kubiak pp 9564–9565 DOI: 10.1021/ja030108p Supporting Info

Observation of Individual Transitions in Magnetically Equivalent Spin Systems Konstantin Pervushin and Beat Vögeli pp 9566–9567 DOI: 10.1021/ja035288h Supporting Info

Unprecedented Double C−C Bond Cleavage of a Cyclopentadienyl Ligand Zhenfeng Xi, Kimihiko Sato, Ye Gao, Jianming Lu, and Tamotsu Takahashi pp 9568–9569 DOI: 10.1021/ja027234y Supporting Info

Enantioselective Hydrogenation of Tetrasubstituted Olefins of Cyclic β-(Acylamino)acrylates Wenjun Tang, Shulin Wu, and Xumu Zhang pp 9570–9571 DOI: 10.1021/ja035777h Supporting Info

Light-Induced Aminocarbene to Imine Dyotropic Rearrangement in a Chromium(0) Center:  An Unprecedented Reaction Pathway Miguel A. Sierra, Israel Fernández, María J. Mancheño, Mar Gómez-Gallego, M. Rosario Torres, Fernando P. Cossío, Ana Arrieta, Begoña Lecea, Ana Poveda, and Jesús Jiménez-Barbero pp 9572–9573 DOI: 10.1021/ja035614t Supporting Info

β-Elimination of a Phosphonate Group from an Alkoxy Radical:  An Intramolecular Acylation Approach Using an Acylphosphonate as a Carbonyl Group Acceptor Sunggak Kim, Chang Ho Cho, and Chae Jo Lim pp 9574–9575 DOI: 10.1021/ja036499p Supporting Info

Macrolactonization via Ti(IV)-Mediated Epoxy-Acid Coupling:  A Total Synthesis of (−)-Dactylolide [and Zampanolide] Thomas R. Hoye and Min Hu pp 9576–9577 DOI: 10.1021/ja035579q Supporting Info

Catalytic C−H Bond Functionalization with Palladium(II):  Aerobic Oxidative Annulations of Indoles Eric M. Ferreira and Brian M. Stoltz pp 9578–9579 DOI: 10.1021/ja035054y Supporting Info

A Designed β-Hairpin Peptide for Molecular Recognition of ATP in Water Sara M. Butterfield and Marcey L. Waters pp 9580–9581 DOI: 10.1021/ja0359254 Supporting Info

Enyne Metathesis for the Formation of Macrocyclic 1,3-Dienes Eric C. Hansen and Daesung Lee pp 9582–9583 DOI: 10.1021/ja036374k Supporting Info

A Highly Efficient Three-Component Coupling of Aldehyde, Alkyne, and Amines via C−H Activation Catalyzed by Gold in Water Chunmei Wei and Chao-Jun Li pp 9584–9585 DOI: 10.1021/ja0359299 Supporting Info

Fast Back Electron Transfer Prevents Guanine Damage by Photoexcited Thionine Bound to DNA Chikara Dohno, Eric D. A. Stemp, and Jacqueline K. Barton pp 9586–9587 DOI: 10.1021/ja036397z

A Potent and Highly Selective Inhibitor of Human α-1,3-Fucosyltransferase via Click Chemistry Lac V. Lee, Michael L. Mitchell, Shih-Jung Huang, Valery V. Fokin, K. Barry Sharpless, and Chi-Huey Wong pp 9588–9589 DOI: 10.1021/ja0302836 Supporting Info

Identification of Glu166 as the General Base in the Acylation Reaction of Class A β-Lactamases through QM/MM Modeling Johannes C. Hermann, Lars Ridder, Adrian J. Mulholland, and Hans-Dieter Höltje pp 9590–9591 DOI: 10.1021/ja034434g

Coulomb Explosion upon Electron Attachment to a Four-Coordinate Monoanionic Metal Complex Anders Baardseth Nielsen, Preben Hvelplund, Bo Liu, Steen Brøndsted Nielsen, and Shigeo Tomita pp 9592–9593 DOI: 10.1021/ja0360182

Enolization of Acetone in Superheated Water Detected via Radical Formation Khashayar Ghandi, Brenda Addison-Jones, Jean-Claude Brodovitch, Brett M. McCollum, Iain McKenzie, and Paul W. Percival pp 9594–9595 DOI: 10.1021/ja036377x Supporting Info

Toward a Versatile Allylation Reagent:  Practical, Enantioselective Allylation of Acylhydrazones Using Strained Silacycles Richard Berger, Philippe M. A. Rabbat, and James L. Leighton pp 9596–9597 DOI: 10.1021/ja035001g Supporting Info

Surface-Enhanced Raman Scattering in the Ultraviolet Spectral Region:  UV-SERS on Rhodium and Ruthenium Electrodes Bin Ren, Xu-Feng Lin, Zhi-Lin Yang, Guo-Kun Liu, Ricardo F. Aroca, Bing-Wei Mao, and Zhong-Qun Tian pp 9598–9599 DOI: 10.1021/ja035541d Supporting Info

Observation of the Marcus Inverted Region of Electron Transfer Reactions at a Liquid/Liquid Interface Peng Sun, Fei Li, Yong Chen, Meiqin Zhang, Zhiquan Zhang, Zhao Gao, and Yuanhua Shao pp 9600–9601 DOI: 10.1021/ja0362297 Supporting Info

A Concise Route to Benzofused Macrolactones via Ynolides:  Cycloproparadicicol Zhi-Qiang Yang and Samuel J. Danishefsky pp 9602–9603 DOI: 10.1021/ja036192q Supporting Info

A π-Basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand Oleg V. Ozerov, Lori A. Watson, Maren Pink, and Kenneth G. Caulton pp 9604–9605 DOI: 10.1021/ja035165x Supporting Info

The Largest Protein Observed To Fold by Two-State Kinetic Mechanism Does Not Obey Contact-Order Correlation Kathryn Jones and Pernilla Wittung-Stafshede pp 9606–9607 DOI: 10.1021/ja0358807 Supporting Info

In Situ Functionalization of Porous Silicon during the Electrochemical Formation Process in Ethanoic Hydrofluoric Acid Solution Giorgio Mattei and Veronica Valentini pp 9608–9609 DOI: 10.1021/ja036228e Supporting Info

A New Co2(CO)8-Mediated Tandem [5 + 1]/[2 + 2 + 1]-Cycloaddition Reaction:  A One-Pot Synthesis of Tricyclic δ-Lactones from cis-Epoxy Ene-ynes Arjan Odedra, Chang-Jung Wu, Reniguntala J. Madhushaw, Su-Lein Wang, and Rai-Shung Liu pp 9610–9611 DOI: 10.1021/ja0346633 Supporting Info

Structural Aspects for Evolution of β-Lactamases from Penicillin-Binding Proteins Samy O. Meroueh, George Minasov, Wenlin Lee, Brian K. Shoichet, and Shahriar Mobashery pp 9612–9618 DOI: 10.1021/ja034861u

pH as a Trigger of Peptide β-Sheet Self-Assembly and Reversible Switching between Nematic and Isotropic Phases Amalia Aggeli, Mark Bell, Lisa M. Carrick, Colin W. G. Fishwick, Richard Harding, Peter J. Mawer, Sheena E. Radford, Andrew E. Strong, and Neville Boden pp 9619–9628 DOI: 10.1021/ja021047i

Unprecedented Monofunctional Metalation of Adenine Nucleobase in Guanine- and Thymine-Containing Dinucleotide Sequences by a Cytotoxic Platinum−Acridine Hybrid Agent Colin G. Barry, Hemanta Baruah, and Ulrich Bierbach pp 9629–9637 DOI: 10.1021/ja0351443 Supporting Info

Determinants of Unnatural Nucleobase Stability and Polymerase Recognition Allison A. Henry, Chengzhi Yu, and Floyd E. Romesberg pp 9638–9646 DOI: 10.1021/ja035398o

Coordination-Driven Self-Assembly of Supramolecular Cages:  Heteroatom-Containing and Complementary Trigonal Prisms Yury K. Kryschenko, S. Russell Seidel, David C. Muddiman, Angelito I. Nepomuceno, and Peter J. Stang pp 9647–9652 DOI: 10.1021/ja030209n Supporting Info

Asymmetric Synthesis of the Highly Potent Anti-Metastatic Prostacyclin Analogue Cicaprost and Its Isomer Isocicaprost Marco Lerm, Hans-Joachim Gais, Kejun Cheng, and Cornelia Vermeeren pp 9653–9667 DOI: 10.1021/ja030200l Supporting Info

Efficient Excitation Energy Transfer in Long Meso−Meso Linked Zn(II) Porphyrin Arrays Bearing a 5,15-Bisphenylethynylated Zn(II) Porphyrin Acceptor Naoki Aratani, Hyun Sun Cho, Tae Kyu Ahn, Sung Cho, Dongho Kim, Hitoshi Sumi, and Atsuhiro Osuka pp 9668–9681 DOI: 10.1021/ja030002u Supporting Info

Indium-Mediated β-Allylation, β-Propargylation, and β-Allenylation onto α,β-Unsaturated Ketones:  Reactions of in-Situ-Generated 3-tert-Butyldimethylsilyloxyalk-2-enylsulfonium Salts with in-Situ-Generated Organoindium Reagents Kooyeon Lee, Hyunseok Kim, Tomoya Miura, Koichi Kiyota, Hiroyuki Kusama, Sunggak Kim, Nobuharu Iwasawa, and Phil Ho Lee pp 9682–9688 DOI: 10.1021/ja035988m Supporting Info

An ab Initio Study toward Understanding the Mechanistic Photochemistry of Acetamide Xue-Bo Chen, Wei-Hai Fang, and De-Cai Fang pp 9689–9698 DOI: 10.1021/ja029005h Supporting Info

Slow Anion Exchange, Conformational Equilibria, and Fluorescent Sensing in Venus Flytrap Aminopyridinium-Based Anion Hosts Karl J. Wallace, Warwick J. Belcher, David R. Turner, Kauser F. Syed, and Jonathan W. Steed pp 9699–9715 DOI: 10.1021/ja034921w Supporting Info

Self-Assembly of Ferrocene-Functionalized Perylene Bisimide Bridging Ligands with Pt(II) Corner to Electrochemically Active Molecular Squares Chang-Cheng You and Frank Würthner pp 9716–9725 DOI: 10.1021/ja029648x Supporting Info

Dehydrophenylnitrenes:  Quartet versus Doublet States Holger F. Bettinger and Wolfram Sander pp 9726–9733 DOI: 10.1021/ja029296u Supporting Info

Ordered Architectures of a Soluble Hexa-peri-hexabenzocoronene−Pyrene Dyad:  Thermotropic Bulk Properties and Nanoscale Phase Segregation at Surfaces Natalia Tchebotareva, Xiaomin Yin, Mark D. Watson, Paolo Samorì, Jürgen P. Rabe, and Klaus Müllen pp 9734–9739 DOI: 10.1021/ja028609i Supporting Info

Structure-Based Design of a Highly Selective Catalytic Site-Directed Inhibitor of Ser/Thr Protein Phosphatase 2B (Calcineurin) Yoshiyasu Baba, Nozomu Hirukawa, Naoto Tanohira, and Mikiko Sodeoka pp 9740–9749 DOI: 10.1021/ja034694y

Mechanism of a Strongly Anisotropic MoIII−CN−MnII Spin−Spin Coupling in Molecular Magnets Based on the [Mo(CN)7]4- Heptacyanometalate:  A New Strategy for Single-Molecule Magnets with High Blocking Temperatures Vladimir S. Mironov, Liviu F. Chibotaru, and Arnout Ceulemans pp 9750–9760 DOI: 10.1021/ja029518o

Individual Single-Walled Nanotubes and Hydrogels Made by Oxidative Exfoliation of Carbon Nanotube Ropes Nina I. Kovtyukhova, Thomas E. Mallouk, Ling Pan, and Elizabeth C. Dickey pp 9761–9769 DOI: 10.1021/ja0344516 Supporting Info

Controlled Formation of Highly Organized Mesoporous Titania Thin Films:  From Mesostructured Hybrids to Mesoporous Nanoanatase TiO2 Eduardo L. Crepaldi, Galo J. de A. A. Soler-Illia, David Grosso, Florence Cagnol, François Ribot, and Clément Sanchez pp 9770–9786 DOI: 10.1021/ja030070g Supporting Info

Photoinduced Axial Ligation and Deligation Dynamics of Nonplanar Nickel Dodecaarylporphyrins Jennifer L. Retsek, Charles Michael Drain, Christine Kirmaier, Daniel J. Nurco, Craig J. Medforth, Kevin M. Smith, Igor V. Sazanovich, Vladimir S. Chirvony, Jack Fajer, and Dewey Holten pp 9787–9800 DOI: 10.1021/ja020611m

A Novel and General Synthetic Pathway to Strychnos Indole Alkaloids:  Total Syntheses of (−)-Tubifoline, (−)-Dehydrotubifoline, and (−)-Strychnine Using Palladium-Catalyzed Asymmetric Allylic Substitution Miwako Mori, Masato Nakanishi, Daisuke Kajishima, and Yoshihiro Sato pp 9801–9807 DOI: 10.1021/ja029382u Supporting Info

A Mechanistic Investigation of the Carbon−Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex Felicia L. Taw, Alexander H. Mueller, Robert G. Bergman, and Maurice Brookhart pp 9808–9813 DOI: 10.1021/ja034468o Supporting Info

Photodissociation Dynamics of Fluorobenzene Cheng-Liang Huang, Jyh-Chiang Jiang, Alexander M. Mebel, Yuan T. Lee, and Chi-Kung Ni pp 9814–9820 DOI: 10.1021/ja030185k

Ab Initio Calculation of the Vibrational and Electronic Spectra of trans- and cis-Azobenzene Heike Fliegl, Andreas Köhn, Christof Hättig, and Reinhart Ahlrichs pp 9821–9827 DOI: 10.1021/ja034433o Supporting Info

Effects of Surface Coordination Chemistry on the Magnetic Properties of MnFe2O4 Spinel Ferrite Nanoparticles Christy R. Vestal and Z. John Zhang pp 9828–9833 DOI: 10.1021/ja035474n

Multicomponent Submicron Features of Biomolecules Created by Voltage Controlled Deposition from a Nanopipet Andreas Bruckbauer, Dejian Zhou, Liming Ying, Yuri E. Korchev, Chris Abell, and David Klenerman pp 9834–9839 DOI: 10.1021/ja035755v Supporting Info

Solvent Reorganization in Electron and Ion Transfer Reactions near a Smooth Electrified Surface:  a Molecular Dynamics Study Christoph Hartnig and Marc T. M. Koper pp 9840–9845 DOI: 10.1021/ja035498u

On the Electronic Origins of Structural Isomerism in the Iron−Sulfur Cubane, [(C5H5)4Fe4S4]2+ Sushilla Z. Knottenbelt and John E. McGrady pp 9846–9852 DOI: 10.1021/ja0353053 Supporting Info

A New Angle on Heat Capacity Changes in Hydrophobic Solvation Kelly R. Gallagher and Kim A. Sharp pp 9853–9860 DOI: 10.1021/ja029796n Supporting Info

Theoretical Examination of Mg2+-Mediated Hydrolysis of a Phosphodiester Linkage as Proposed for the Hammerhead Ribozyme Rhonda A. Torres, Fahmi Himo, Thomas C. Bruice, Louis Noodleman, and Timothy Lovell pp 9861–9867 DOI: 10.1021/ja021451h

Structure of Gramicidin A in a Lipid Bilayer Environment Determined Using Molecular Dynamics Simulations and Solid-State NMR Data Toby W. Allen, Olaf S. Andersen, and Benoit Roux pp 9868–9877 DOI: 10.1021/ja029317k

Theoretical and Experimental Investigations on the Chemical Reactions of Positively Charged Phenyl Radicals with Cytosine and 1-Methylcytosine Yiqun Huang and Hilkka Kenttämaa pp 9878–9889 DOI: 10.1021/ja021263r

Bulk Microphase Segregation of an Asymmetric Organometallic−Inorganic Diblock Copolymer:  A Remarkable Example of Concentric Cylinders [J. Am. Chem. Soc. 2003, 125, 6010−6011]. Jose Raez Yuanming Zhang, Lan Cao, Srebri Petrov, Kurt Erlacher, Ulrich Wiesner, Ian Manners, and Mitchell A. Winnik p 9890 DOI: 10.1021/ja033449b

Issue 33

One-Step Fabrication of Uniform Si-Core/CdSe-Sheath Nanocables Quan Li and Chunrui Wang pp 9892–9893 DOI: 10.1021/ja035787i Supporting Info

Catalytic Propene Polymerization:  Determination of Propagation, Termination, and Epimerization Kinetics by Direct NMR Observation of the (EBI)Zr(MeB(C6F5)3)propenyl Catalyst Species Douglass R. Sillars and Clark R. Landis pp 9894–9895 DOI: 10.1021/ja036393u Supporting Info

Thermally Programmable Gas Storage and Release in Single Crystals of an Organic van der Waals Host Gary D. Enright, Konstantin A. Udachin, Igor L. Moudrakovski, and John A. Ripmeester pp 9896–9897 DOI: 10.1021/ja0351701 Supporting Info

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents Margarita Paneque, Cristina M. Posadas, Manuel L. Poveda, Nuria Rendón, Verónica Salazar, Enrique Oñate, and Kurt Mereiter pp 9898–9899 DOI: 10.1021/ja035655p Supporting Info

Catalytic Asymmetric Cyanosilylation of Ketones with Chiral Lewis Base Shi-Kai Tian, Ran Hong, and Li Deng pp 9900–9901 DOI: 10.1021/ja036222p Supporting Info

[60]Fullerene-Motivated Organogel Formation in a Porphyrin Derivative Bearing Programmed Hydrogen-Bonding Sites Michihiro Shirakawa, Norifumi Fujita, and Seiji Shinkai pp 9902–9903 DOI: 10.1021/ja035933k Supporting Info

Further Insight into the Relaxation Dynamics of Photoexcited I-(H2O)n Clusters Qadir K. Timerghazin and Gilles H. Peslherbe pp 9904–9905 DOI: 10.1021/ja035395b Supporting Info

Size-Controlled Assembly of Gold Nanoparticles Induced by a Tridentate Thioether Ligand Mathew M. Maye, Jin Luo, I-Im S. Lim, Li Han, Nancy N. Kariuki, Daniel Rabinovich, Tianbo Liu, and Chuan-Jian Zhong pp 9906–9907 DOI: 10.1021/ja0363866 Supporting Info

Noncontact Temperature Measurement in Microliter-Sized Volumes Using Fluorescent-Labeled DNA Oligomers Sangmin Jeon, Jeff Turner, and Steve Granick pp 9908–9909 DOI: 10.1021/ja036431+ Supporting Info

Versatile and Cooperative Reactivity of a Triruthenium Polyhydride Cluster. A Computational Study Dmitry V. Khoroshun, Akiko Inagaki, Hiroharu Suzuki, Sergei F. Vyboishchikov, Djamaladdin G. Musaev, and Keiji Morokuma pp 9910–9911 DOI: 10.1021/ja036027a Supporting Info

Iron-Catalyzed Olefin cis-Dihydroxylation by H2O2:  Electrophilic versus Nucleophilic Mechanisms Megumi Fujita, Miquel Costas, and Lawrence Que, Jr. pp 9912–9913 DOI: 10.1021/ja029863d Supporting Info

Detection of Amide I Signals of Interfacial Proteins in Situ Using SFG Jie Wang, Mark A. Even, Xiaoyun Chen, Alvin H. Schmaier, J. Herbert Waite, and Zhan Chen pp 9914–9915 DOI: 10.1021/ja036373s

A Novel Method for the Templated Synthesis of Homogeneous Samples of Hollow Carbon Nanospheres from Cellulose Chars Andrew M. Herring, J. Thomas McKinnon, Bryan D. McCloskey, Jonathan Filley, Keith W. Gneshin, Ryan A. Pavelka, Hans-Joachim Kleebe, and Darin J. Aldrich pp 9916–9917 DOI: 10.1021/ja035031j Supporting Info

Hairpin-Shaped Heterometallic Luminescent Lanthanide Complexes for DNA Intercalative Recognition Peter B. Glover, Peter R. Ashton, Laura J. Childs, Alison Rodger, Michael Kercher, René M. Williams, Luisa De Cola, and Zoe Pikramenou pp 9918–9919 DOI: 10.1021/ja029886s Supporting Info

A Parallel Colorimetric Method for the Rapid Discovery and Optimization of Heterogeneous Hydrodesulfurization Catalysts Chad L. Staiger, Douglas A. Loy, Gregory M. Jamison, Duane A. Schneider, and Christopher J. Cornelius pp 9920–9921 DOI: 10.1021/ja034222j Supporting Info

Characterization of Collagen Model Peptides Containing 4-Fluoroproline; (4(S)-Fluoroproline-Pro-Gly)10 Forms a Triple Helix, but (4(R)-Fluoroproline-Pro-Gly)10 Does Not Masamitsu Doi, Yoshinori Nishi, Susumu Uchiyama, Yuji Nishiuchi, Takashi Nakazawa, Tadayasu Ohkubo, and Yuji Kobayashi pp 9922–9923 DOI: 10.1021/ja035997v Supporting Info

Trapping Specific Quaternary States of the Allosteric Enzyme Aspartate Transcarbamoylase in Silica Matrix Sol−Gels Jay M. West and Evan R. Kantrowitz pp 9924–9925 DOI: 10.1021/ja0360440

The Role of the Putative Catalytic Base in the Phosphoryl Transfer Reaction in a Protein Kinase:  First-Principles Calculations Marat Valiev, R. Kawai, Joseph A. Adams, and John H. Weare pp 9926–9927 DOI: 10.1021/ja029618u

Synthesis of Template-Free Zeolite Nanocrystals by Using in Situ Thermoreversible Polymer Hydrogels Huanting Wang, Brett A. Holmberg, and Yushan Yan pp 9928–9929 DOI: 10.1021/ja036071q Supporting Info

Miniaturized Chemical Multiplexed Sensor Array Ming Su, Shuyou Li, and Vinayak P. Dravid pp 9930–9931 DOI: 10.1021/ja035727c

Duplex Foldamers from Assembly Induced Folding Xiaowu Yang, Suzana Martinovic, Richard D. Smith, and Bing Gong pp 9932–9933 DOI: 10.1021/ja0361897 Supporting Info

Microelectrochemical Logic Circuits Wei Zhan and Richard M. Crooks pp 9934–9935 DOI: 10.1021/ja0366585

Quantification of Functional Group Interactions in Transition States Christopher A. Hunter, Caroline M. R. Low, Jeremy G. Vinter, and Cristiano Zonta pp 9936–9937 DOI: 10.1021/ja034767d

A Snapshot of Enzyme Catalysis Using Electrospray Ionization Mass Spectrometry Zhili Li, Apurba K Sau, Shida Shen, Craig Whitehouse, Timor Baasov, and Karen S. Anderson pp 9938–9939 DOI: 10.1021/ja0354768 Supporting Info

In Situ Generation of the Silica Shell Layer − Key Factor to the Simple High Yield Synthesis of Silver Nanowires Chih-Hao Hsia, Ming-Yu Yen, Chu-Chun Lin, Hsin-Tien Chiu, and Chi-Young Lee pp 9940–9941 DOI: 10.1021/ja035339a Supporting Info

Polarized Photoluminescence from Poly(p-phenylene−ethynylene) via a Block Copolymer Nanotemplate Craig A. Breen, Tao Deng, Thomas Breiner, Edwin L. Thomas, and Timothy M. Swager pp 9942–9943 DOI: 10.1021/ja036024y Supporting Info

Star-Shaped Polycyclic Aromatics Based on Oligothiophene-Functionalized Truxene:  Synthesis, Properties, and Facile Emissive Wavelength Tuning Jian Pei, Jin-Liang Wang, Xiao-Yu Cao, Xing-Hua Zhou, and Wen-Bin Zhang pp 9944–9945 DOI: 10.1021/ja0361650 Supporting Info

Guest Encapsulation in a Water-Soluble Molecular Capsule Based on Ionic Interactions Francesca Corbellini, Luigi Di Costanzo, Mercedes Crego-Calama, Silvano Geremia, and David N. Reinhoudt pp 9946–9947 DOI: 10.1021/ja034535e Supporting Info

Cross-Modulation of the pKa of Nucleobases in a Single-Stranded Hexameric-RNA Due to Tandem Electrostatic Nearest-Neighbor Interactions P. Acharya, S. Acharya, P. Cheruku, N. V. Amirkhanov, A. Földesi, and J. Chattopadhyaya pp 9948–9961 DOI: 10.1021/ja034651h Supporting Info

Structural Characterization of the Zinc Site in Protein Farnesyltransferase Daniel A. Tobin, Jennifer S. Pickett, Heather L. Hartman, Carol A. Fierke, and James E. Penner-Hahn pp 9962–9969 DOI: 10.1021/ja035927o Supporting Info

New Base Pairing Motifs. The Synthesis and Thermal Stability of Oligodeoxynucleotides Containing Imidazopyridopyrimidine Nucleosides with the Ability to Form Four Hydrogen Bonds Noriaki Minakawa, Naoshi Kojima, Sadao Hikishima, Takashi Sasaki, Arihiro Kiyosue, Naoko Atsumi, Yoshihito Ueno, and Akira Matsuda pp 9970–9982 DOI: 10.1021/ja0347686 Supporting Info

Why Is Tetrazole Formation by Addition of Azide to Organic Nitriles Catalyzed by Zinc(II) Salts? Fahmi Himo, Zachary P. Demko, Louis Noodleman, and K. Barry Sharpless pp 9983–9987 DOI: 10.1021/ja030204q

Control of Stepwise Radial Complexation in Dendritic Polyphenylazomethines Masayoshi Higuchi, Masanori Tsuruta, Hiroshi Chiba, Satoshi Shiki, and Kimihisa Yamamoto pp 9988–9997 DOI: 10.1021/ja035608x

Fascinating Transformations of Donor−Acceptor Complexes of Group 13 Metal (Al, Ga, In) Derivatives with Nitriles and Isonitriles:  From Monomeric Cyanides to Rings and Cages Alexey Y. Timoshkin and Henry F. Schaefer, III pp 9998–10011 DOI: 10.1021/ja030117y Supporting Info

2‘-Mercaptonucleotide Interference Reveals Regions of Close Packing within Folded RNA Molecules Jason P. Schwans, Cecilia N. Cortez, Joe M. Olvera, and Joseph A. Piccirilli pp 10012–10018 DOI: 10.1021/ja035175y Supporting Info

A New Perspective on β-Sheet Structures Using Vibrational Raman Optical Activity:  From Poly(l-lysine) to the Prion Protein Iain H. McColl, Ewan W. Blanch, Andrew C. Gill, Alexandre G. O. Rhie, Mark A. Ritchie, Lutz Hecht, Kurt Nielsen, and Laurence D. Barron pp 10019–10026 DOI: 10.1021/ja021464v

Quantum Mechanical Study of Stereoselectivity in the Oxazaborolidine-Catalyzed Reduction of Acetophenone Giuliano Alagona, Caterina Ghio, Maurizio Persico, and Simone Tomasi pp 10027–10039 DOI: 10.1021/ja034928d

Hypoxia-Targeting Copper Bis(selenosemicarbazone) Complexes:  Comparison with Their Sulfur Analogues Thomas C. Castle, Richard I. Maurer, Frank E. Sowrey, Michael J. Went, Christopher A. Reynolds, Eric J. L. McInnes, and Philip J. Blower pp 10040–10049 DOI: 10.1021/ja035737d Supporting Info

Surface Structures of SrTiO3 (001):  A TiO2-rich Reconstruction with a c(4 × 2) Unit Cell Natasha Erdman, Oliver Warschkow, Mark Asta, Kenneth R. Poeppelmeier, Donald E. Ellis, and Laurence D. Marks pp 10050–10056 DOI: 10.1021/ja034933h

Polyyn-diyls Capped by Diruthenium Termini:  A New Family of Carbon-Rich Organometallic Compounds and Distance-Dependent Electronic Coupling Therein Guo-Lin Xu, Gang Zou, Yu-Hua Ni, Maria C. DeRosa, Robert J. Crutchley, and Tong Ren pp 10057–10065 DOI: 10.1021/ja035434j Supporting Info

Synthetic, Structural, and Mechanistic Studies on the Oxidative Addition of Aromatic Chlorides to a Palladium (N-Heterocyclic Carbene) Complex:  Relevance to Catalytic Amination Alexandra K. de K. Lewis, Stephen Caddick, F. Geoffrey N. Cloke, Norman C. Billingham, Peter B. Hitchcock, and John Leonard pp 10066–10073 DOI: 10.1021/ja035565k Supporting Info

Formation of Single-Bonded (C60-)2 and (C70-)2 Dimers in Crystalline Ionic Complexes of Fullerenes Dmitri V. Konarev, Salavat S. Khasanov, Gunzi Saito, Akihiro Otsuka, Yukihiro Yoshida, and Rimma N. Lyubovskaya pp 10074–10083 DOI: 10.1021/ja035546a Supporting Info

Structural Chemistry of “Defect” Cyanometalate Boxes:  {Cs[CpCo(CN)3]4[Cp*Ru]3} and {M[Cp*Rh(CN)3]4[Cp*Ru]3} (M = NH4, Cs) Matthew L. Kuhlman and Thomas B. Rauchfuss pp 10084–10092 DOI: 10.1021/ja035253h Supporting Info

Kinetics and Thermodynamics of H• Transfer from (η5-C5R5)Cr(CO)3H (R = Ph, Me, H) to Methyl Methacrylate and Styrene Lihao Tang, Elizabeth T. Papish, Graham P. Abramo, Jack R. Norton, Mu-Hyun Baik, Richard A. Friesner, and Anthony Rappé pp 10093–10102 DOI: 10.1021/ja034927l Supporting Info

Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis Jennifer A. Love, Melanie S. Sanford, Michael W. Day, and Robert H. Grubbs pp 10103–10109 DOI: 10.1021/ja027472t Supporting Info

Manganese(II) and Copper(II) Hexafluoroacetylacetonate 1:1 Complexes with 5-(4-[N-tert-Butyl-N-aminoxyl]phenyl)pyrimidine:  Regiochemical Parity Analysis for Exchange Behavior of Complexes between Radicals and Paramagnetic Cations Lora M. Field, Paul M. Lahti, Fernando Palacio, and Armando Paduan-Filho pp 10110–10118 DOI: 10.1021/ja0343813 Supporting Info

Evidence for Inverted Region Behavior in Proton Transfer to Carbanions Claude P. Andrieux, Jean Gamby, Philippe Hapiot, and Jean-Michel Savéant pp 10119–10124 DOI: 10.1021/ja035268f Supporting Info

The Amide Rotational Barriers in Picolinamide and Nicotinamide:  NMR and ab Initio Studies Ryan A. Olsen, Lisa Liu, Nima Ghaderi, Adam Johns, Mary E. Hatcher, and Leonard J. Mueller pp 10125–10132 DOI: 10.1021/ja028751j

Electrochemical Investigation of Photooxidation Processes Promoted by Sulfo-polyoxometalates:  Coupling of Photochemical and Electrochemical Processes into an Effective Catalytic Cycle Thomas Rüther, Victoria M. Hultgren, Brian P. Timko, Alan M. Bond, William R. Jackson, and Anthony G. Wedd pp 10133–10143 DOI: 10.1021/ja029348f Supporting Info

Relativistic Effects in Heavy-Element Chemistry and Physics Edited by Bernd A. Hess (Friedrich-Alexander-Universität, Erlangen-Nürnberg). John Wiley & Sons, Ltd.:  Chichester. 2003. xix + 307 pp. $105.00. ISBN 0-470-84138-9. Vedene H. Smith, Jr. p 10144 DOI: 10.1021/ja033504g

Industrial Dyes:  Chemistry, Properties, Applications Edited by Klaus Hunger (Kelkheim, Germany). Wiley-VCH:  Weinheim. 2003. xxiv + 600 pp. $185.00. ISBN 3-527-30426-6. p 10144 DOI: 10.1021/ja0335418

The Essence of Chromatography By Colin F. Poole (Wayne State University). Elsevier:  Amsterdam and New York. 2003. x + 926 pp. $89.00. ISBN 0-444-50199-1 (Paperback). David J. Butcher pp 10144–10145 DOI: 10.1021/ja033507t

Handbook of Detection of Enzymes on Electrophoretic Gels, Second Edition By Gennady P. Manchenko (Institute of Marine Biology, Russian Academy of Science). CRC Press LLC:  Boca Raton. 2003. xiv + 554 pp. $159.95. ISBN 0-849-31257-4. p 10145 DOI: 10.1021/ja0335420

Polymer Blends Handbook, Volumes 1−2 Edited by L. A. Utracki (National Research Council Canada). Kluwer Academic Publishers:  Dordrecht. 2002. xxxvi + 1442 pp. $583.50. ISBN 1-4020-1114-8 (Set). p 10145 DOI: 10.1021/ja0335465

Wiley Guide to Chemical Incompatibilities, Second Edition Edited by Richard P. Pohanish and Stanley A. Greene. John Wiley & Sons, Inc.:  Hoboken. 2003. xvi + 1278 pp. $125.00. ISBN 0-471-23859-7. p 10145 DOI: 10.1021/ja033549h

Progress in the Chemistry of Organic Natural Products, 85 Edited by W. Herz (The Florida State University), H. Falk (Johannes-Kepler-Universität, Austria), and G. W. Kirby (The University of Glasgow). Springer-Verlag:  Wien. 2003. x + 258 pp. $189.00. ISBN 3-211-83783-3. Timothy A. Blizzard pp 10145–10146 DOI: 10.1021/ja033522y

Issue 34

Aminoglycoside (Neomycin) Preference Is for A-Form Nucleic Acids, Not Just RNA:  Results from a Competition Dialysis Study Dev P. Arya, Liang Xue, and Bert Willis pp 10148–10149 DOI: 10.1021/ja035117c Supporting Info

Fluorescent Caged Phosphoserine Peptides as Probes to Investigate Phosphorylation-Dependent Protein Associations M. Eugenio Vázquez, Mark Nitz, Justine Stehn, Michael B. Yaffe, and Barbara Imperiali pp 10150–10151 DOI: 10.1021/ja0351847 Supporting Info

New Polyamide Cryptand for Anion Binding Sung Ok Kang, José M. Llinares, Douglas Powell, David VanderVelde, and Kristin Bowman-James pp 10152–10153 DOI: 10.1021/ja034969+ Supporting Info

Hole Trapping at N6-Cyclopropyldeoxyadenosine Suggests a Direct Contribution of Adenine Bases to Hole Transport through DNA Chikara Dohno, Atsushi Ogawa, Kazuhiko Nakatani, and Isao Saito pp 10154–10155 DOI: 10.1021/ja035887o Supporting Info

Triquinanes from Linear Alkylidene Carbenes via Trimethylenemethane Diyls Hee-Yoon Lee and Yeonjoon Kim pp 10156–10157 DOI: 10.1021/ja036263l Supporting Info

Conversion of a PLP-Dependent Racemase into an Aldolase by a Single Active Site Mutation Florian P. Seebeck and Donald Hilvert pp 10158–10159 DOI: 10.1021/ja036707d Supporting Info

Scandium-Catalyzed Allylboration of Aldehydes as a Practical Method for Highly Diastereo- and Enantioselective Construction of Homoallylic Alcohols Hugo Lachance, Xiaosong Lu, Michel Gravel, and Dennis G. Hall pp 10160–10161 DOI: 10.1021/ja036807j Supporting Info

Enantioselective Rare-Earth Catalyzed Quinone Diels−Alder Reactions David A. Evans and Jimmy Wu pp 10162–10163 DOI: 10.1021/ja0367602 Supporting Info

De Novo Determination of Bond Orientations and Order Parameters from Residual Dipolar Couplings with High Accuracy Kathryn B. Briggman and Joel R. Tolman pp 10164–10165 DOI: 10.1021/ja035904+ Supporting Info

Biosynthetic Origins of the Natural Product, Thiolactomycin:  A Unique and Selective Inhibitor of Type II Dissociated Fatty Acid Synthases Maria S. Brown, Konstantin Akopiants, Diane M. Resceck, Hamish A. I. McArthur, Ellen McCormick, and Kevin A. Reynolds pp 10166–10167 DOI: 10.1021/ja034540i Supporting Info

Safety-Catch Linker Strategies for the Production of Radiopharmaceuticals Labeled with Positron-Emitting Isotopes Derek Maclean, Jiang Zhu, Mingying Chen, Ron Hale, Nagichettiar Satymurthy, and Jorge R. Barrio pp 10168–10169 DOI: 10.1021/ja034725p Supporting Info

Four-Coordinate Phosphinidene Complexes of Titanium Prepared by α-H-Migration:  Phospha-Staudinger and Phosphaalkene-Insertion Reactions Falguni Basuli, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola pp 10170–10171 DOI: 10.1021/ja036559r Supporting Info

Hexaarylcyclotriplumbane:  A Molecule with a Homonuclear Ring System of Lead Frank Stabenow, Wolfgang Saak, Heinrich Marsmann, and Manfred Weidenbruch pp 10172–10173 DOI: 10.1021/ja036299d Supporting Info

Catalytic Asymmetric [3+2] Cycloaddition of Azomethine Ylides. Development of a Versatile Stepwise, Three-Component Reaction for Diversity-Oriented Synthesis Chuo Chen, Xiaodong Li, and Stuart L. Schreiber pp 10174–10175 DOI: 10.1021/ja036558z Supporting Info

Synthesis and Characterization of Faceted Hexagonal Aluminum Nitride Nanotubes Qiang Wu, Zheng Hu, Xizhang Wang, Yinong Lu, Xin Chen, Hua Xu, and Yi Chen pp 10176–10177 DOI: 10.1021/ja0359963 Supporting Info

Nylon/DNA:  Single-Stranded DNA with a Covalently Stitched Nylon Lining Lei Zhu, Philip S. Lukeman, James W. Canary, and Nadrian C. Seeman pp 10178–10179 DOI: 10.1021/ja035186r Supporting Info

Synthesis of Monodisperse Nanocrystals of Manganese Oxides Ming Yin and Stephen O'Brien pp 10180–10181 DOI: 10.1021/ja0362656 Supporting Info

Micellar Shape Change and Internal Segregation Induced by Chemical Modification of a Tryptych Block Copolymer Surfactant Zhilian Zhou, Zhibo Li, Yu Ren, Marc A. Hillmyer, and Timothy P. Lodge pp 10182–10183 DOI: 10.1021/ja036551h Supporting Info

Cross-Linking Strategy for Molecular Recognition and Fluorescent Sensing of a Multi-phosphorylated Peptide in Aqueous Solution Akio Ojida, Masa-aki Inoue, Yasuko Mito-oka, and Itaru Hamachi pp 10184–10185 DOI: 10.1021/ja036317r Supporting Info

Facile Synthesis of Cucurbit[n]uril Derivatives via Direct Functionalization:  Expanding Utilization of Cucurbit[n]uril Sang Yong Jon, Narayanan Selvapalam, Dong Hyun Oh, Jin-Koo Kang, Soo-Young Kim, Young Jin Jeon, Jae Wook Lee, and Kimoon Kim pp 10186–10187 DOI: 10.1021/ja036536c Supporting Info

Stereoselectivity in DNA-Templated Organic Synthesis and Its Origins Xiaoyu Li and David R. Liu pp 10188–10189 DOI: 10.1021/ja035379e Supporting Info

A One-Step Synthesis of a Poly(iptycene) through an Unusual Diels−Alder Cyclization/Dechlorination of Tetrachloropentacene Dmitrii F. Perepichka, Michael Bendikov, Hong Meng, and Fred Wudl pp 10190–10191 DOI: 10.1021/ja036193i Supporting Info

Viral-Induced Self-Assembly of Magnetic Nanoparticles Allows the Detection of Viral Particles in Biological Media J. Manuel Perez, F. Joseph Simeone, Yoshinaga Saeki, Lee Josephson, and Ralph Weissleder pp 10192–10193 DOI: 10.1021/ja036409g Supporting Info

Conformationally Constrained Analogues of Bleomycin A5 Michael J. Rishel, Craig J. Thomas, Zhi-Fu Tao, Corine Vialas, Christopher J. Leitheiser, and Sidney M. Hecht pp 10194–10205 DOI: 10.1021/ja030057w Supporting Info

Activation Enthalpies and Entropies for the Microscopic Rate Constants of Acetate-Catalyzed Isomerization of 5-Androstene-3,17-dione Wendy J. Houck and Ralph M. Pollack pp 10206–10212 DOI: 10.1021/ja035957r Supporting Info

Direct Observation of Guanine Radical Cation Deprotonation in Duplex DNA Using Pulse Radiolysis Kazuo Kobayashi and Seiichi Tagawa pp 10213–10218 DOI: 10.1021/ja036211w Supporting Info

Synthesis of Both Enantiomers of a P-Chirogenic 1,2-Bisphospholanoethane Ligand via Convergent Routes and Application to Rhodium-Catalyzed Asymmetric Hydrogenation of CI-1008 (Pregabalin) Garrett Hoge pp 10219–10227 DOI: 10.1021/ja034715o Supporting Info

Apparent NAC Effect in Chorismate Mutase Reflects Electrostatic Transition State Stabilization Marek Štrajbl, Avital Shurki, Mitsunori Kato, and Arieh Warshel pp 10228–10237 DOI: 10.1021/ja0356481 Supporting Info

Construction of Eight-Membered Ether Rings by Olefin Geometry-Dependent Internal Alkylation:  First Asymmetric Total Syntheses of (+)-3-(E)- and (+)-3-(Z)-Pinnatifidenyne Hyoungsu Kim, Won Jun Choi, Jaeyoon Jung, Sanghee Kim, and Deukjoon Kim pp 10238–10240 DOI: 10.1021/ja035538u Supporting Info

Rigid Macrocyclic Triamides as Anion Receptors:  Anion-Dependent Binding Stoichiometries and 1H Chemical Shift Changes Kihang Choi and Andrew D. Hamilton pp 10241–10249 DOI: 10.1021/ja034563x Supporting Info

Synthesis and Characterization of Thermoreversible Biopolymer Microgels Based on Hydrogen Bonded Nucleobase Pairing Rong Cao, Zhenyu Gu, Lorraine Hsu, Gary D. Patterson, and Bruce A. Armitage pp 10250–10256 DOI: 10.1021/ja035211t Supporting Info

Self-Assembly, Structure, and Dynamic Interconversion of Metallosupramolecular Architectures Generated by Pb(II) Binding-Induced Unfolding of a Helical Ligand Mihail Barboiu, Gavin Vaughan, Roland Graff, and Jean-Marie Lehn pp 10257–10265 DOI: 10.1021/ja0301929 Supporting Info

Multiscale Self-Organization of the Organic Semiconductor α-Quinquethiophene Manuela Melucci, Massimo Gazzano, Giovanna Barbarella, Massimiliano Cavallini, Fabio Biscarini, Piera Maccagnani, and Paolo Ostoja pp 10266–10274 DOI: 10.1021/ja036152m Supporting Info

N-Alkyl Perfluoroalkanamides as Low Molecular-Mass Organogelators Mathew George, Samuel L. Snyder, Pierre Terech, Charles J. Glinka, and Richard G. Weiss pp 10275–10283 DOI: 10.1021/ja0362407 Supporting Info

Synthesis, Assembly, and Thin Film Transistors of Dihydrodiazapentacene:  An Isostructural Motif for Pentacene Qian Miao, Thuc-Quyen Nguyen, Takao Someya, Graciela B. Blanchet, and Colin Nuckolls pp 10284–10287 DOI: 10.1021/ja036466+ Supporting Info

Melem (2,5,8-Triamino-tri-s-triazine), an Important Intermediate during Condensation of Melamine Rings to Graphitic Carbon Nitride:  Synthesis, Structure Determination by X-ray Powder Diffractometry, Solid-State NMR, and Theoretical Studies Barbara Jürgens, Elisabeth Irran, Jürgen Senker, Peter Kroll, Helen Müller, and Wolfgang Schnick pp 10288–10300 DOI: 10.1021/ja0357689 Supporting Info

Is It Homogeneous or Heterogeneous Catalysis? Identification of Bulk Ruthenium Metal as the True Catalyst in Benzene Hydrogenations Starting with the Monometallic Precursor, Ru(II)(η6-C6Me6)(OAc)2, Plus Kinetic Characterization of the Heterogeneous Nucleation, Then Autocatalytic Surface-Growth Mechanism of Metal Film Formation Jason A. Widegren, Martin A. Bennett, and Richard G. Finke pp 10301–10310 DOI: 10.1021/ja021436c Supporting Info

Amines Made Easily:  A Highly Selective Hydroaminomethylation of Olefins Moballigh Ahmed, Abdul Majeed Seayad, Ralf Jackstell, and Matthias Beller pp 10311–10318 DOI: 10.1021/ja030143w

Radical Cage Effects in the Photochemical Degradation of Polymers:  Effect of Radical Size and Mass on the Cage Recombination Efficiency of Radical Cage Pairs Generated Photochemically from the (CpCH2CH2N(CH3)C(O)(CH2)nCH3)2Mo2(CO)6 (n = 3, 8, 18) Complexes Erick Schutte, T. J. R. Weakley, and David R. Tyler pp 10319–10326 DOI: 10.1021/ja035030r Supporting Info

Molecular Squares with Paramagnetic Diruthenium Corners:  Synthetic and Crystallographic Challenges Panagiotis Angaridis, John F. Berry, F. Albert Cotton, Carlos A. Murillo, and Xiaoping Wang pp 10327–10334 DOI: 10.1021/ja036095x Supporting Info

Synthesis of Crystalline Skutterudite Superlattices Using the Modulated Elemental Reactant Method Joshua R. Williams, Arwyn L. E. Smalley, Heike Sellinschegg, Carrie Daniels-Hafer, Jennifer Harris, Mark B. Johnson, and David C. Johnson pp 10335–10341 DOI: 10.1021/ja020565q

In Situ Quantum Dot Growth on Multiwalled Carbon Nanotubes Sarbajit Banerjee and Stanislaus S. Wong pp 10342–10350 DOI: 10.1021/ja035980c Supporting Info

Oxidation of C−H Bonds by [(bpy)2(py)RuIVO]2+ Occurs by Hydrogen Atom Abstraction Jasmine R. Bryant and James M. Mayer pp 10351–10361 DOI: 10.1021/ja035276w Supporting Info

Metal−Metal Interactions in Heterobimetallic d8−d10 Complexes. Structures and Spectroscopic Investigation of [M‘M‘ ‘(μ-dcpm)2(CN)2]+ (M‘ = Pt, Pd; M‘ ‘ = Cu, Ag, Au) and Related Complexes by UV−vis Absorption and Resonance Raman Spectroscopy and ab Initio Calculations Bao-Hui Xia, Hong-Xing Zhang, Chi-Ming Che, King-Hung Leung, David Lee Phillips, Nianyong Zhu, and Zhong-Yuan Zhou pp 10362–10374 DOI: 10.1021/ja0355325 Supporting Info

Sulfonated Microporous Organic−Inorganic Hybrids as Strong Bronsted Acids1 Zhike Wang, Joy M. Heising, and Abraham Clearfield pp 10375–10383 DOI: 10.1021/ja030226c

Ab Initio QM/MM Study Shows There Is No General Acid in the Reaction Catalyzed by 4-Oxalocrotonate Tautomerase G. Andrés Cisneros, Haiyan Liu, Yingkai Zhang, and Weitao Yang pp 10384–10393 DOI: 10.1021/ja029672a Supporting Info

Lithium-Cation/π Complexes of Aromatic Systems. The Effect of Increasing the Number of Fused Rings Jean-François Gal, Pierre-Charles Maria, Michèle Decouzon, Otilia Mó, Manuel Yáñez, and José Luis M. Abboud pp 10394–10401 DOI: 10.1021/ja029843b

Electrochemical Property:  Structure Relationships in Monoclinic Li3-yV2(PO4)3 S.-C. Yin, H. Grondey, P. Strobel, M. Anne, and L. F. Nazar pp 10402–10411 DOI: 10.1021/ja034565h Supporting Info

DFT Computational Study of the Mechanism of Allyl Halides Carbonylation Catalyzed by Nickel Tetracarbonyl Andrea Bottoni, Gian Pietro Miscione, Juan J. Novoa, and Xavier Prat-Resina pp 10412–10419 DOI: 10.1021/ja030100f

Cross-Correlated Relaxation Enhanced 1H−13C NMR Spectroscopy of Methyl Groups in Very High Molecular Weight Proteins and Protein Complexes Vitali Tugarinov, Peter M. Hwang, Jason E. Ollerenshaw, and Lewis E. Kay pp 10420–10428 DOI: 10.1021/ja030153x Supporting Info

Proton-Coupled Electron Transfer in a Model for Tyrosine Oxidation in Photosystem II Claudio Carra, Nedialka Iordanova, and Sharon Hammes-Schiffer pp 10429–10436 DOI: 10.1021/ja035588z

Catalytic CO Oxidation by Free Au2-:  Experiment and Theory Liana D. Socaciu, Jan Hagen, Thorsten M. Bernhardt, Ludger Wöste, Ulrich Heiz, Hannu Häkkinen, and Uzi Landman pp 10437–10445 DOI: 10.1021/ja027926m

Theoretical Study of Chlorine Nitrates:  Implications for Stratospheric Chlorine Chemistry Srinivasan Parthiban, Timothy J. Lee, Sujata Guha, and Joseph S. Francisco pp 10446–10458 DOI: 10.1021/ja010297g Supporting Info

A Theoretical Exploration of the 1,3-Dipolar Cycloadditions onto the Sidewalls of (n,n) Armchair Single-Wall Carbon Nanotubes Xin Lu, Feng Tian, Xin Xu, Nanqin Wang, and Qianer Zhang pp 10459–10464 DOI: 10.1021/ja034662a

ZnS Nanomaterial Characterization by MALDI-TOF Mass Spectrometry Gregory A. Khitrov and Geoffrey F. Strouse pp 10465–10469 DOI: 10.1021/ja035508r

Synthesis of SnS2/SnS Fullerene-like Nanoparticles:  A Superlattice with Polyhedral Shape Sung You Hong, Ronit Popovitz-Biro, Yehiam Prior, and Reshef Tenne pp 10470–10474 DOI: 10.1021/ja036057d

Mechanistic Study of the Gas-Phase Decomposition of Methyl Formate Joseph S. Francisco* pp 10475–10480 DOI: 10.1021/ja0117682 Supporting Info

Migration of Methyl Groups between Aliphatic Amines in Water  [J. Am. Chem. Soc. 2003, 125, 310-311].  Brian P. Callahan and Richard Wolfenden p 10481 DOI: 10.1021/ja033448j

Prism 4 GraphPad Software, Inc. 5755 Oberlin Drive, #110, San Diego, CA 92121. www.graphpad.com. See Web Site for Pricing Information Dean R. Appling p 10482 DOI: 10.1021/ja033563u

Issue 35

A “Sea Urchin” Family of Boranes and Carboranes:  The 6m + 2n Electron Rule Zhi-Xiang Wang and Paul von Ragué Schleyer pp 10484–10485 DOI: 10.1021/ja035578y Supporting Info

A Novel Montmorillonite-Enwrapped Scandium as a Heterogeneous Catalyst for Michael Reaction Tomonori Kawabata, Tomoo Mizugaki, Kohki Ebitani, and Kiyotomi Kaneda pp 10486–10487 DOI: 10.1021/ja0302578 Supporting Info

Gold Nanoparticles as Catalysts for Polymerization of Alkylsilanes to Siloxane Nanowires, Filaments, and Tubes B. L. V. Prasad, Savka I. Stoeva, Christopher M. Sorensen, Vladimir Zaikovski, and Kenneth J. Klabunde pp 10488–10489 DOI: 10.1021/ja035046h Supporting Info

Stable, Three-Coordinate Ni(CO)2(NHC) (NHC = N-Heterocyclic Carbene) Complexes Enabling the Determination of Ni−NHC Bond Energies Reto Dorta, Edwin D. Stevens, Carl D. Hoff, and Steven P. Nolan pp 10490–10491 DOI: 10.1021/ja0362151 Supporting Info

Hexacoordination of a Dimethyl Sulfide Molecule Mitsukimi Tsunoda and François P. Gabbaï pp 10492–10493 DOI: 10.1021/ja036197n Supporting Info

Fluorotetraphenylbismuth:  A New Reagent for Efficient Regioselective α-Phenylation of Carbonyl Compounds Takashi Ooi, Ryoji Goto, and Keiji Maruoka pp 10494–10495 DOI: 10.1021/ja030150k Supporting Info

Conformational Control in Activation of an Enediyne M. F. Semmelhack, Lingyun Wu, Robert A. Pascal, Jr., and Douglas M. Ho pp 10496–10497 DOI: 10.1021/ja036763e Supporting Info

Decarbonylative Cross-Coupling of Cyclic Anhydrides:  Introducing Stereochemistry at an sp3 Carbon in the Cross-Coupling Event Erin M. O'Brien, Eric A. Bercot, and Tomislav Rovis pp 10498–10499 DOI: 10.1021/ja036290b Supporting Info

Sequence-Specific Dinucleotide Cleavage Promoted by Synergistic Interactions between Neighboring Modified Nucleotides in DNA Jia Liu Wolfe, Bing H. Wang, Tomohiko Kawate, and Vincent P. Stanton, Jr. pp 10500–10501 DOI: 10.1021/ja035646g Supporting Info

A Mechanistic Alternative for the Intramolecular Hydroboration of Homoallylic Amine and Phosphine Borane Complexes Matthew Scheideman, Peter Shapland, and Edwin Vedejs pp 10502–10503 DOI: 10.1021/ja034655m Supporting Info

An Ultra Acid Stable Reversed Stationary Phase Brian C. Trammell, Lianjia Ma, Hao Luo, Marc A. Hillmyer, and Peter W. Carr pp 10504–10505 DOI: 10.1021/ja036339d Supporting Info

2,3-Difluorotyrosine at Position 356 of Ribonucleotide Reductase R2:  A Probe of Long-Range Proton-Coupled Electron Transfer Cyril S. Yee, Michelle C.Y. Chang, Jie Ge, Daniel G. Nocera, and JoAnne Stubbe pp 10506–10507 DOI: 10.1021/ja036242r Supporting Info

A Supramolecular Approach to an Allosteric Catalyst Nathan C. Gianneschi, Paul A. Bertin, SonBinh T. Nguyen, Chad A. Mirkin, Lev N. Zakharov, and Arnold L. Rheingold pp 10508–10509 DOI: 10.1021/ja035621h Supporting Info

Nitrite Catalyzes Ferriheme Protein Reductive Nitrosylation Bernadette O. Fernandez and Peter C. Ford pp 10510–10511 DOI: 10.1021/ja036693b Supporting Info

One-Electron Oxidized Nickel(II)−(Disalicylidene)diamine Complex:  Temperature-Dependent Tautomerism between Ni(III)−Phenolate and Ni(II)−Phenoxyl Radical States Yuichi Shimazaki, Fumito Tani, Kôichi Fukui, Yoshinori Naruta, and Osamu Yamauchi pp 10512–10513 DOI: 10.1021/ja035806o Supporting Info

Nitrogen Atom Insertion into Ir−S and C−S Bonds Initiated by Photolysis of Iridium(III)−Azido-Dithiocarbamato Complexes Takayoshi Suzuki, Antonio G. DiPasquale, and James M. Mayer pp 10514–10515 DOI: 10.1021/ja0365779 Supporting Info

Dendrimer Disassembly by Benzyl Ether Depolymerization Sheng Li, Michael L. Szalai, Robert M. Kevwitch, and Dominic V. McGrath pp 10516–10517 DOI: 10.1021/ja0349960 Supporting Info

Organic−Inorganic Hybrid Liquid Crystals:  Hybridization of Calamitic Liquid-Crystalline Amines with Monodispersed Anisotropic TiO2 Nanoparticles Kiyoshi Kanie and Tadao Sugimoto pp 10518–10519 DOI: 10.1021/ja0357691 Supporting Info

Resonance Hyper-Raman Scattering from Conjugated Organic Donor−Acceptor “Push−Pull” Chromophores with Large First Hyperpolarizabilities Anne Myers Kelley, Weinan Leng, and Mireille Blanchard-Desce pp 10520–10521 DOI: 10.1021/ja036570r

Alkene Oxidation by a Platinum Oxo Complex and Isolation of a Platinaoxetane Endre Szuromi, Hui Shan, and Paul R. Sharp pp 10522–10523 DOI: 10.1021/ja036496c Supporting Info

Neutral Bishomoaromatic Semibullvalenes Hai-Shun Wu, Haijun Jiao, Zhi-Xiang Wang, and Paul v. R. Schleyer pp 10524–10525 DOI: 10.1021/ja036403r Supporting Info

Lanthanide-Sensitized Lanthanide Luminescence:  Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex Stephen Faulkner and Simon J. A. Pope pp 10526–10527 DOI: 10.1021/ja035634v Supporting Info

The First Framework Solid Composed of Vanadosilicate Clusters Akhilesh Tripathi, Timothy Hughbanks, and Abraham Clearfield pp 10528–10529 DOI: 10.1021/ja0365173 Supporting Info

Probing Motions between Equivalent RNA Domains Using Magnetic Field Induced Residual Dipolar Couplings:  Accounting for Correlations between Motions and Alignment Qi Zhang, Rachel Throolin, Stephen W. Pitt, Alexander Serganov, and Hashim M. Al-Hashimi pp 10530–10531 DOI: 10.1021/ja0363056 Supporting Info

Polymerization of Diacetylenes by Hydrogen Bond Templated Adlayer Formation David W. Mosley, Mark A. Sellmyer, Erin J. Daida, and Joseph M. Jacobson pp 10532–10533 DOI: 10.1021/ja036625p Supporting Info

Analogies between the Reactivities of an Anionic Gallium(I) Heterocycle and N-Heterocyclic Carbenes Toward Metallocenes Robert J. Baker, Cameron Jones, and Jamie A. Platts pp 10534–10535 DOI: 10.1021/ja036933n Supporting Info

Highly Enantioselective Iridium-Catalyzed Hydrogenation of Heteroaromatic Compounds, Quinolines Wen-Bo Wang, Sheng-Mei Lu, Peng-Yu Yang, Xiu-Wen Han, and Yong-Gui Zhou pp 10536–10537 DOI: 10.1021/ja0353762 Supporting Info

A Convenient Method for the Preparation of Inverted tert-Alkyl Carboxylates from Chiral tert-Alcohols by a New Type of Oxidation−Reduction Condensation Using 2,6-Dimethyl-1,4-benzoquinone Teruaki Mukaiyama, Taichi Shintou, and Kentaro Fukumoto pp 10538–10539 DOI: 10.1021/ja0303844 Supporting Info

Just a Near Attack Conformer for Catalysis (Chorismate to Prephenate Rearrangements in Water, Antibody, Enzymes, and Their Mutants) Sun Hur and Thomas C. Bruice pp 10540–10542 DOI: 10.1021/ja0357846

Chemical Genomic Profiling of Biological Networks Using Graph Theory and Combinations of Small Molecule Perturbations Stephen J. Haggarty, Paul A. Clemons, and Stuart L. Schreiber pp 10543–10545 DOI: 10.1021/ja035413p Supporting Info

Preparation, Physical Properties, On-Bead Binding Assay and Spectroscopic Reliability of 25 Barcoded Polystyrene−Poly(ethylene glycol) Graft Copolymers Hicham Fenniri, Sangki Chun, Lunhan Ding, Yegor Zyrianov, and Klaas Hallenga pp 10546–10560 DOI: 10.1021/ja035665q Supporting Info

Conditional Protein Splicing:  A New Tool to Control Protein Structure and Function in Vitro and in Vivo Henning D. Mootz, Elyse S. Blum, Amy B. Tyszkiewicz, and Tom W. Muir pp 10561–10569 DOI: 10.1021/ja0362813

Understanding Binding Affinity:  A Combined Isothermal Titration Calorimetry/Molecular Dynamics Study of the Binding of a Series of Hydrophobically Modified Benzamidinium Chloride Inhibitors to Trypsin Reinskje Talhout, Alessandra Villa, Alan E. Mark, and Jan B. F. N. Engberts pp 10570–10579 DOI: 10.1021/ja034676g Supporting Info

Diversity Synthesis via C−H Bond Functionalization:  Concept-Guided Development of New C-Arylation Methods for Imidazoles Bengü Sezen and Dalibor Sames pp 10580–10585 DOI: 10.1021/ja036157j Supporting Info

Complementary C3-Symmetric Donor−Acceptor Components:  Cocrystal Structure and Control of Mesophase Stability Lee Y. Park, Darren G. Hamilton, Edward A. McGehee, and Kathryn A. McMenimen pp 10586–10590 DOI: 10.1021/ja036540o Supporting Info

Modular and Tunable Chemosensor Scaffold for Divalent Zinc Melissa D. Shults, Dierdre A. Pearce, and Barbara Imperiali pp 10591–10597 DOI: 10.1021/ja0355980 Supporting Info

Metalloprotein Association, Self-Association, and Dynamics Governed by Hydrophobic Interactions:  Simultaneous Occurrence of Gated and True Electron-Transfer Reactions between Cytochrome f and Cytochrome c6 from Chlamydomonas reinhardtii Tijana Ž. Grove and Nenad M. Kostić pp 10598–10607 DOI: 10.1021/ja036009t Supporting Info

Conformational Restraint in Thermal Rearrangements of a Cyclobutane:  3,4-Dicyanotricyclo[4.2.2.02,5]decane W. von E. Doering and JoAnn Peters DeLuca pp 10608–10614 DOI: 10.1021/ja030050e Supporting Info

Guest-Induced Assembly of Tetracarboxyl-Cavitand and Tetra(3-pyridyl)-Cavitand into a Heterodimeric Capsule via Hydrogen Bonds and CH−Halogen and/or CH−π Interaction:  Control of the Orientation of the Encapsulated Guest Kenji Kobayashi, Kei Ishii, Shigeru Sakamoto, Toshiaki Shirasaka, and Kentaro Yamaguchi pp 10615–10624 DOI: 10.1021/ja035337q Supporting Info

Convenient Scaffold for Forming Heteroporphyrin Arrays in Aqueous Media Koji Kano, Ryuhei Nishiyabu, Tomoko Yamazaki, and Iwao Yamazaki pp 10625–10634 DOI: 10.1021/ja035055q Supporting Info

Mechanistic Study of an Improbable Reaction:  Alkene Dehydrogenation by the Δ12 Acetylenase of Crepis alpina Darwin W. Reed, Devin R. Polichuk, Peter H. Buist, Stephen J. Ambrose, Robert J. Sasata, Christopher K. Savile, Andrew R. S. Ross, and Patrick S. Covello pp 10635–10640 DOI: 10.1021/ja036489o

Mechanism of 1,3-Migration in Allylperoxyl Radicals:  Computational Evidence for the Formation of a Loosely Bound Radical−Dioxygen Complex Santiago Olivella and Albert Solé pp 10641–10650 DOI: 10.1021/ja030171e Supporting Info

Synthesis of Conformationally Stable 1,8-Diarylnaphthalenes:  Development of New Photoluminescent Sensors for Ion-Selective Recognition Christian Wolf and Xuefeng Mei pp 10651–10658 DOI: 10.1021/ja0358145 Supporting Info

Mechanism of Di-tert-Butylsilylene Transfer from a Silacyclopropane to an Alkene Tom G. Driver and K. A. Woerpel pp 10659–10663 DOI: 10.1021/ja0301370 Supporting Info

A Synthetic Strategy for the Preparation of Cyclic Peptide Mimetics Based on SET-Promoted Photocyclization Processes Ung Chan Yoon, Ying Xue Jin, Sun Wha Oh, Chan Hyo Park, Jong Hoon Park, Charles F. Campana, Xiaolu Cai, Eileen N. Duesler, and Patrick S. Mariano pp 10664–10671 DOI: 10.1021/ja030297b Supporting Info

Beyond Two-State Conical Intersections. Three-State Conical Intersections in Low Symmetry Molecules:  the Allyl Radical Spiridoula Matsika and David R. Yarkony pp 10672–10676 DOI: 10.1021/ja036201v

A Catalytic Asymmetric Method for the Synthesis of γ-Unsaturated β-Amino Acid Derivatives Alice E. Lurain and Patrick J. Walsh pp 10677–10683 DOI: 10.1021/ja035213d Supporting Info

Reduction of CuO and Cu2O with H2: H Embedding and Kinetic Effects in the Formation of Suboxides Jae Y. Kim, José A. Rodriguez, Jonathan C. Hanson, Anatoly I. Frenkel, and Peter L. Lee pp 10684–10692 DOI: 10.1021/ja0301673

Nanowells on Silica Particles in Water Containing Long-Distance Porphyrin Heterodimers Guangtao Li, Sheshanath V. Bhosale, Tianyu Wang, Steffen Hackbarth, Beate Roeder, Ulrich Siggel, and Jürgen-Hinrich Fuhrhop pp 10693–10702 DOI: 10.1021/ja035558w

Unprecedented Head-to-Head Conformers of d(GpG) Bound to the Antitumor Active Compound Tetrakis (μ-carboxylato)dirhodium(II,II) Helen T. Chifotides, Karl M. Koshlap, Lisa M. Pérez, and Kim R. Dunbar pp 10703–10713 DOI: 10.1021/ja027779s Supporting Info

Novel Binding Interactions of the DNA Fragment d(pGpG) Cross-Linked by the Antitumor Active Compound Tetrakis(μ-carboxylato)dirhodium(II,II) Helen T. Chifotides, Karl M. Koshlap, Lisa M. Pérez, and Kim R. Dunbar pp 10714–10724 DOI: 10.1021/ja0291585 Supporting Info

Hierarchical Assembly of Two-Dimensional Homochiral Nanocavity Arrays Hannes Spillmann, Alexandre Dmitriev, Nian Lin, Paolo Messina, Johannes V. Barth, and Klaus Kern pp 10725–10728 DOI: 10.1021/ja0362353

Successive Removal of Chloride Ions from Organic Polychloride Pollutants. Mechanisms of Reductive Electrochemical Elimination in Aliphatic Gem-Polychlorides, α,β-Polychloroalkenes, and α,β-Polychloroalkanes in Mildly Protic Medium Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 10729–10739 DOI: 10.1021/ja036141t Supporting Info

Probing Helix Formation in Unsolvated Peptides Gary A. Breaux and Martin F. Jarrold pp 10740–10747 DOI: 10.1021/ja0300362

Molecular Rectification and Conductance Switching in Carbon-Based Molecular Junctions by Structural Rearrangement Accompanying Electron Injection Richard McCreery, Jon Dieringer, Ali Osman Solak, Brian Snyder, Aletha M. Nowak, William R. McGovern, and Stacy DuVall pp 10748–10758 DOI: 10.1021/ja0362196 Supporting Info

Electron, Hydride, and Fluoride Affinities of Silicon-Containing Species:  Computational Studies Robert Damrauer, April J. Crowell, and Colleen F. Craig pp 10759–10766 DOI: 10.1021/ja0301875 Supporting Info

Expanding Pd-Catalyzed C−N Bond-Forming Processes:  The First Amidation of Aryl Sulfonates, Aqueous Amination, and Complementarity with Cu-Catalyzed Reactions [J. Am. Chem. Soc. 2003, 125, 6653−6655]. Xiaohua Huang, Kevin W. Anderson, Danilo Zim, Lei Jiang, Artis Klapars, and Stephen L. Buchwald p 10767 DOI: 10.1021/ja033450a

Organic Synthesis Highlights V Edited by Hans-Günther Schmalz (University of Cologne) and Thomas Wirth (Cardiff University). Wiley-VCH:  Weinheim. 2003. xii + 440 pp. $75.00. ISBN 3-527-30611-0. p 10768 DOI: 10.1021/ja033550g

Measurement Uncertainty in Chemical Analysis Edited by Paul De Bièvre (Kasterlee, Belgium) and Helmut Günzler (Weinheim, Germany). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xii + 284 pp. $89.95. ISBN 3-540-43990-0. p 10768 DOI: 10.1021/ja0335519

Magnetic Resonance in Food Science:  Latest Developments Edited by P. S. Belton (University of East Anglia), A. M. Gil (University of Aveiro), G. A. Webb (University of Surrey), and D. Rutledge (Institut National de la Recherche Agron, Paris). The Royal Society of Chemistry:  Cambridge. 2003. x + 272 pp. $150.00. ISBN 0-85404-886-3. p 10768 DOI: 10.1021/ja0335521

Ullmann's Encyclopedia of Industrial Chemistry:  Sixth, Completely Revised Edition. Volumes 1−40 Edited by Wiley-VCH. Wiley-VCH:  Weinheim. 2003. 30 000 pp. $5500. ISBN 3-527-30385-5. p 10768 DOI: 10.1021/ja0335566

Issue 36

Long-Range Magnetic Coupling through Extended π-Conjugated Aromatic Bridges in Dinuclear Copper(II) Metallacyclophanes Emilio Pardo, Juan Faus, Miguel Julve, Francesc Lloret, M. Carmen Muñoz, Joan Cano, Xavier Ottenwaelder, Yves Journaux, Rosa Carrasco, Gonzalo Blay, Isabel Fernández, and Rafael Ruiz-García pp 10770–10771 DOI: 10.1021/ja030060f Supporting Info

Total Synthesis of Merrilactone A Masayuki Inoue, Takaaki Sato, and Masahiro Hirama pp 10772–10773 DOI: 10.1021/ja036587+ Supporting Info

A Molecular Metal Ferromagnet from the Organic Donor Bis(ethylenedithio)tetraselenafulvalene and Bimetallic Oxalate Complexes Antonio Alberola, Eugenio Coronado, José R. Galán-Mascarós, Carlos Giménez-Saiz, and Carlos J. Gómez-García pp 10774–10775 DOI: 10.1021/ja035772k Supporting Info

Switching of Alcohol Oxidation Mechanism on Nickel Surfaces by Fluorine Substitution Qing Zhao and Francisco Zaera pp 10776–10777 DOI: 10.1021/ja0362858

A New Copper-Catalyzed [3 + 2] Cycloaddition:  Enantioselective Coupling of Terminal Alkynes with Azomethine Imines To Generate Five-Membered Nitrogen Heterocycles Ryo Shintani and Gregory C. Fu pp 10778–10779 DOI: 10.1021/ja036922u Supporting Info

Enantioselective Indole Friedel−Crafts Alkylations Catalyzed by Bis(oxazolinyl)pyridine−Scandium(III) Triflate Complexes David A. Evans, Karl A. Scheidt, Keith R. Fandrick, Hon Wai Lam, and Jimmy Wu pp 10780–10781 DOI: 10.1021/ja036985c Supporting Info

Dinitrogen Chemistry from Trigonally Coordinated Iron and Cobalt Platforms Theodore A. Betley and Jonas C. Peters pp 10782–10783 DOI: 10.1021/ja036687f Supporting Info

The [2 + 4] Diels−Alder Cycloadditon Product of a Probable Dialuminene, Ar‘AlAlAr‘ (Ar‘ = C6H3- 2,6-Dipp2; Dipp = C6H3-2,6-Pri2), with Toluene Robert J. Wright, Andrew D. Phillips, and Philip P. Power pp 10784–10785 DOI: 10.1021/ja034478p Supporting Info

Flattening the B6H62- Octahedron. Ab Initio Prediction of a New Family of Planar All-Boron Aromatic Molecules Anastassia N. Alexandrova, K. Alexander Birch, and Alexander I. Boldyrev pp 10786–10787 DOI: 10.1021/ja0361906 Supporting Info

Catalyst/Cocatalyst Nuclearity Effects in Single-Site Olefin Polymerization. Significantly Enhanced 1-Octene and Isobutene Comonomer Enchainment in Ethylene Polymerizations Mediated by Binuclear Catalysts and Cocatalysts Hongbo Li, Liting Li, Tobin J. Marks, Louise Liable-Sands, and Arnold L. Rheingold pp 10788–10789 DOI: 10.1021/ja036289c Supporting Info

Mono-, Di-, and Trianionic β-Diketiminato Ligands:  A Computational Study and the Synthesis and Structure of [(YbL)3(THF)], L = [{N(SiMe3)C(Ph)}2CH] Odile Eisenstein, Peter B. Hitchcock, Alexei V. Khvostov, Michael F. Lappert, Laurent Maron, Lionel Perrin, and Andrey V. Protchenko pp 10790–10791 DOI: 10.1021/ja036902s Supporting Info

Vapor Phase Synthesis of Tungsten Nanowires Sreeram Vaddiraju, Hari Chandrasekaran, and Mahendra K. Sunkara pp 10792–10793 DOI: 10.1021/ja035868e Supporting Info

Synthesis of Organic One-Dimensional Nanomaterials by Solid-Phase Reaction Huibiao Liu, Yuliang Li, Shengqiang Xiao, Haiyang Gan, Tonggang Jiu, Hongmei Li, Lei Jiang, Daoben Zhu, Dapeng Yu, Bin Xiang, and Yaofeng Chen pp 10794–10795 DOI: 10.1021/ja036697g Supporting Info

An Electron-Catalyzed Cope Cyclization. The Structure of the 2,5-Dicyano-1,5-hexadiene Radical Anion in the Gas Phase Loubna A. Hammad and Paul G. Wenthold pp 10796–10797 DOI: 10.1021/ja037143g Supporting Info

Direct Spectroscopic Evidence of the Cross-Coupling Reaction between CH2(a) and CF3(a) on Ag(111) W. X. Huang and J. M. White pp 10798–10799 DOI: 10.1021/ja0364625

Excited-State Intramolecular Proton Transfer in Five-Membered Hydrogen-Bonding Systems:  2-Pyridyl Pyrazoles Wei-Shan Yu, Chung-Chih Cheng, Yi-Ming Cheng, Pei-Chi Wu, Yi-Hwa Song, Yun Chi, and Pi-Tai Chou pp 10800–10801 DOI: 10.1021/ja035382y Supporting Info

Absolute Stereochemistry of Allylic Alcohols, Amines, and Other Ene Moieties:  A Microscale Cross Metathesis/Exciton Chirality Protocol Katsunori Tanaka, Koji Nakanishi, and Nina Berova pp 10802–10803 DOI: 10.1021/ja036847n Supporting Info

Photochemical and Thermal Reactions of a Kinetically Stabilized 9-Silaanthracene:  The First Spectroscopic Observation of a 9,10-Dewar-9-silaanthracene Isomer Akihiro Shinohara, Nobuhiro Takeda, and Norihiro Tokitoh pp 10804–10805 DOI: 10.1021/ja036106m Supporting Info

2-D Array Formation of Genetically Engineered Viral Cages on Au Surfaces and Imaging by Atomic Force Microscopy Michael T. Klem, Debbie Willits, Mark Young, and Trevor Douglas pp 10806–10807 DOI: 10.1021/ja0363718 Supporting Info

The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes Sean P. Brown, Michael P. Brochu, Christopher J. Sinz, and David W. C. MacMillan pp 10808–10809 DOI: 10.1021/ja037096s Supporting Info

Spectroscopic Studies of the Interaction of Ferrous Bleomycin with DNA Jyllian N. Kemsley, Kelly Loeb Zaleski, Marina S. Chow, Andrea Decker, Ekaterina Y. Shishova, Erik C. Wasinger, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 10810–10821 DOI: 10.1021/ja034579n Supporting Info

Conformational Analysis of Furanoid ε-Sugar Amino Acid Containing Cyclic Peptides by NMR Spectroscopy, Molecular Dynamics Simulation, and X-ray Crystallography:  Evidence for a Novel Turn Structure Renate M. van Well, Luciana Marinelli, Cornelis Altona, Kees Erkelens, Gregg Siegal, Mark van Raaij, Antonio L. Llamas-Saiz, Horst Kessler, Ettore Novellino, Antonio Lavecchia, Jacques H. van Boom, and Mark Overhand pp 10822–10829 DOI: 10.1021/ja035461+ Supporting Info

Lipophilic G-Quadruplexes Are Self-Assembled Ion Pair Receptors, and the Bound Anion Modulates the Kinetic Stability of These Complexes Xiaodong Shi, Katherine M. Mullaugh, James C. Fettinger, Yun Jiang, Steven A. Hofstadler, and Jeffery T. Davis pp 10830–10841 DOI: 10.1021/ja035267n Supporting Info

Face-to-Face and Edge-to-Face π−π Interactions in a Synthetic DNA Hairpin with a Stilbenediether Linker Martin Egli, Valentina Tereshko, Garib N. Mushudov, Ruslan Sanishvili, Xiaoyang Liu, and Frederick D. Lewis pp 10842–10849 DOI: 10.1021/ja0355527

RNA-Tethered Phenyl Azide Photocrosslinking via a Short-Lived Indiscriminant Electrophile Karen L. Buchmueller, Brian T. Hill, Matthew S. Platz, and Kevin M. Weeks pp 10850–10861 DOI: 10.1021/ja035743+

Loading Peptidyl-Coenzyme A onto Peptidyl Carrier Proteins: A Novel Approach in Characterizing Macrocyclization by Thioesterase Domains Stephan A. Sieber, Christopher T. Walsh, and Mohamed A. Marahiel pp 10862–10866 DOI: 10.1021/ja0361852 Supporting Info

Substrate Analogues for an RNA-Editing Adenosine Deaminase:  Mechanistic Investigation and Inhibitor Design Eduardo A. Véliz, LaHoma M. Easterwood, and Peter A. Beal pp 10867–10876 DOI: 10.1021/ja029742d

The First Experimental Test of the Hypothesis that Enzymes Have Evolved To Enhance Hydrogen Tunneling Kenneth M. Doll, Bruce R. Bender, and Richard G. Finke pp 10877–10884 DOI: 10.1021/ja030120h Supporting Info

Cross-Linked Bis-hemoglobins:  Connections and Oxygen Binding Nikolai Gourianov and Ronald Kluger pp 10885–10892 DOI: 10.1021/ja036596i Supporting Info

1,5-Asymmetric Induction in Boron-Mediated β-Alkoxy Methyl Ketone Aldol Addition Reactions David A. Evans, Bernard Côté, Paul J. Coleman, and Brian T. Connell pp 10893–10898 DOI: 10.1021/ja027640h Supporting Info

Synthesis of the Antifungal Macrolide Antibiotic (+)-Roxaticin David A. Evans and Brian T. Connell pp 10899–10905 DOI: 10.1021/ja027638q Supporting Info

Role of Electron-Transfer Processes in Reactions of Diarylcarbenium Ions and Related Quinone Methides with Nucleophiles Armin R. Ofial, Kei Ohkubo, Shunichi Fukuzumi, Roland Lucius, and Herbert Mayr pp 10906–10912 DOI: 10.1021/ja035191v Supporting Info

Synthesis and Characterization of High-Molecular-Weight Syndiotactic Amorphous Polypropylene Claudio De Rosa, Finizia Auriemma, Odda Ruiz de Ballesteros, Luigi Resconi, Anna Fait, Eleonora Ciaccia, and Isabella Camurati pp 10913–10920 DOI: 10.1021/ja035911y

Lewis Acid-Catalyzed Benzannulation via Unprecedented [4+2] Cycloaddition of o-Alkynyl(oxo)benzenes and Enynals with Alkynes Naoki Asao, Tsutomu Nogami, Sunyoung Lee, and Yoshinori Yamamoto pp 10921–10925 DOI: 10.1021/ja036927r Supporting Info

A New Protocol for the In Situ Generation of Aromatic, Heteroaromatic, and Unsaturated Diazo Compounds and Its Application in Catalytic and Asymmetric Epoxidation of Carbonyl Compounds. Extensive Studies To Map Out Scope and Limitations, and Rationalization of Diastereo- and Enantioselectivities Varinder K. Aggarwal, Emma Alonso, Imhyuck Bae, George Hynd, Kevin M. Lydon, Matthew J. Palmer, Mamta Patel, Marina Porcelloni, Jeffery Richardson, Rachel A. Stenson, John R. Studley, Jean-Luc Vasse, and Caroline L. Winn pp 10926–10940 DOI: 10.1021/ja034606+ Supporting Info

RAMPED-UP NMR:  Multiplexed NMR-Based Screening for Drug Discovery Edward R. Zartler, Jeffrey Hanson, Bryan E. Jones, Allen D. Kline, George Martin, Huaping Mo, Michael J. Shapiro, Rong Wang, Haiping Wu, and Jiangli Yan pp 10941–10946 DOI: 10.1021/ja0348593 Supporting Info

Computational Study on the Origin of the Stereoselectivity for the Photochemical Denitrogenation of Diazabicycloheptene Adalgisa Sinicropi, Chris S. Page, Waldemar Adam, and Massimo Olivucci pp 10947–10959 DOI: 10.1021/ja0263137 Supporting Info

Glycosidic Bond Formation in Aqueous Solution:  On the Oxocarbenium Intermediate John M. Stubbs and Dominik Marx pp 10960–10962 DOI: 10.1021/ja035600n

Studies into the Thermodynamic Origin of Negative Cooperativity in Ion-Pairing Molecular Recognition Suzanne L. Tobey and Eric V. Anslyn pp 10963–10970 DOI: 10.1021/ja030265o Supporting Info

DNA Alkylation Properties of Yatakemycin Jay P. Parrish, David B. Kastrinsky, Scott E. Wolkenberg, Yasuhiro Igarashi, and Dale L. Boger pp 10971–10976 DOI: 10.1021/ja035984h Supporting Info

Calamitic Bolaamphiphiles with (Semi)Perfluorinated Lateral Chains:  Polyphilic Block Molecules with New Liquid Crystalline Phase Structures Xiaohong Cheng, Marko Prehm, Malay Kumar Das, Jens Kain, Ute Baumeister, Siegmar Diele, Dag Leine, Alfred Blume, and Carsten Tschierske pp 10977–10996 DOI: 10.1021/ja036213g Supporting Info

Analysis and Interpretation of Metal-Radical Coupling in a Series of Square Planar Nickel Complexes:  Correlated Ab Initio and Density Functional Investigation of [Ni(LISQ)2] (LISQ=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-)) Diran Herebian, Karl E. Wieghardt, and Frank Neese pp 10997–11005 DOI: 10.1021/ja030124m Supporting Info

1,4-Dioxobenzene Compounds of Gallium:  Reversible Binding of Pyridines to [{(tBu)2Ga}2(μ-OC6H4O)]n in the Solid State Laura H. van Poppel, Simon G. Bott, and Andrew R. Barron pp 11006–11017 DOI: 10.1021/ja0208714 Supporting Info

Kinetics and Mechanism of Rhenium-Catalyzed O Atom Transfer from Epoxides Kevin P. Gable and Eric C. Brown pp 11018–11026 DOI: 10.1021/ja027971u Supporting Info

Oxidation Mechanism of Phenols by Dicopper−Dioxygen (Cu2/O2) Complexes Takao Osako, Kei Ohkubo, Masayasu Taki, Yoshimitsu Tachi, Shunichi Fukuzumi, and Shinobu Itoh pp 11027–11033 DOI: 10.1021/ja029380+ Supporting Info

Facile Fabrication of Ag−Pd Bimetallic Nanoparticles in Ultrathin TiO2-Gel Films:  Nanoparticle Morphology and Catalytic Activity Junhui He, Izumi Ichinose, Toyoki Kunitake, Aiko Nakao, Yukihide Shiraishi, and Naoki Toshima pp 11034–11040 DOI: 10.1021/ja035970b

Aromatic vs Aliphatic C−H Bond Activation by Rhodium(I) as a Function of Agostic Interactions:  Catalytic H/D Exchange between Olefins and Methanol or Water Boris Rybtchinski, Revital Cohen, Yehoshoa Ben-David, Jan M. L. Martin, and David Milstein pp 11041–11050 DOI: 10.1021/ja029197g Supporting Info

Using Effective Group Potential Methodology for Predicting Organometallic Complex Properties Fabienne Alary, Jean-Louis Heully, Romuald Poteau, Laurent Maron, Georges Trinquier, and Jean-Pierre Daudey pp 11051–11061 DOI: 10.1021/ja034534m

Electrical Conduction through Linear Porphyrin Arrays Dae Hwan Yoon, Sun Bae Lee, K.-H. Yoo, Jinhee Kim, Jong Kuk Lim, Naoki Aratani, Akihiko Tsuda, Atsuhiro Osuka, and Dongho Kim pp 11062–11064 DOI: 10.1021/ja0346429 Supporting Info

Sorptive Reconstruction of the CuAlCl4 Framework upon Reversible Ethylene Binding Roger M. Sullivan, Haiming Liu, D. Steve Smith, Jonathan C. Hanson, Derek Osterhout, Michael Ciraolo, Clare P. Grey, and James D. Martin pp 11065–11079 DOI: 10.1021/ja036172o Supporting Info

Multicolor Photochromism of Two- and Three-Component Diarylethene Crystals Masakazu Morimoto, Seiya Kobatake, and Masahiro Irie pp 11080–11087 DOI: 10.1021/ja035277o Supporting Info

Electron Density Distributions of Redox Active Mixed Valence Carboxylate Bridged Trinuclear Iron Complexes Jacob Overgaard, Finn K. Larsen, Birgit Schiøtt, and Bo B. Iversen pp 11088–11099 DOI: 10.1021/ja0346072 Supporting Info

Generalized and Facile Synthesis of Semiconducting Metal Sulfide Nanocrystals Jin Joo, Hyon Bin Na, Taekyung Yu, Jung Ho Yu, Young Woon Kim, Fanxin Wu, Jin Z. Zhang, and Taeghwan Hyeon pp 11100–11105 DOI: 10.1021/ja0357902 Supporting Info

Kinetics and Mechanism of the Proton Transfer to Cp*Fe(dppe)H:  Absence of a Direct Protonation at the Metal Site Natalia V. Belkova, Pavel O. Revin, Lina M. Epstein, Evgenii V. Vorontsov, Vladimir I. Bakhmutov, Elena S. Shubina, Edmond Collange, and Rinaldo Poli pp 11106–11115 DOI: 10.1021/ja0358450 Supporting Info

New Probes of Ligand Flexibility in Drug Design:  Transferred 13C CSA−Dipolar Cross-Correlated Relaxation at Natural Abundance Jeffrey W. Peng pp 11116–11130 DOI: 10.1021/ja030154p Supporting Info

Evidence for Cyclohexyl as a Reactive Surface Intermediate during High-Pressure Cyclohexane Catalytic Reactions on Pt(111) by Sum Frequency Generation Vibrational Spectroscopy Minchul Yang and Gabor A. Somorjai pp 11131–11135 DOI: 10.1021/ja035710u

Hypervalent Iodine Chemistry:  Modern Developments in Organic Synthesis. Topics in Current Chemistry, 224 Edited by T. Wirth (Cardiff University). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 264 pp. $189.00. ISBN 3-540-44107-7. Michael J. Krische p 11136 DOI: 10.1021/ja033530e

Issue 37

Sonochemistry and Sonoluminescence of Room-Temperature Ionic Liquids James D. Oxley, Tanya Prozorov, and Kenneth S. Suslick pp 11138–11139 DOI: 10.1021/ja029830y Supporting Info

Highly Flexible Polyelectrolyte Nanotubes Sufen Ai, Gang Lu, Qiang He, and Junbai Li pp 11140–11141 DOI: 10.1021/ja0356378 Supporting Info

Cation−π Binding of an Alkali Metal Ion by Pendant α,α-Dimethylbenzyl Groups within a Dinuclear Iron(III) Structural Unit Wolfgang Schmitt, Christopher E. Anson, Jonathan P. Hill, and Annie K. Powell pp 11142–11143 DOI: 10.1021/ja029409+ Supporting Info

The Mechanism of Vesicle Fusion as Revealed by Molecular Dynamics Simulations Siewert J. Marrink and Alan E. Mark pp 11144–11145 DOI: 10.1021/ja036138+ Supporting Info

Novel Fluorogenic Substrates for Imaging β-Lactamase Gene Expression Wenzhong Gao, Bengang Xing, Roger Y. Tsien, and Jianghong Rao pp 11146–11147 DOI: 10.1021/ja036126o Supporting Info

Expanding Organoboron Chemistry:  Epoxidation of Potassium Organotrifluoroborates Gary A. Molander and María Ribagorda pp 11148–11149 DOI: 10.1021/ja0351140 Supporting Info

Stopped-Flow Fourier Transform Infrared Spectroscopy of Nitromethane Oxidation by the Diiron(IV) Intermediate of Methane Monooxygenase Mylrajan Muthusamy, Edna A. Ambundo, Simon J. George, Stephen J. Lippard, and Roger N. F. Thorneley pp 11150–11151 DOI: 10.1021/ja036081r

Synthesis, Structure, Bridge−Terminal Exchange Kinetics, and Molecular Orbital Calculations of Pyrazolate-Bridged Digallium Complexes Containing Bridging Phenyl Groups Chatu T. Sirimanne, John E. Knox, Mary Jane Heeg, H. Bernhard Schlegel, and Charles H. Winter pp 11152–11153 DOI: 10.1021/ja036256x Supporting Info

A Comparison of Crystalline- and Graft Polymer-Based Chemosensors Steven J. Broadwater, Mary Kay Hickey, and D. Tyler McQuade pp 11154–11155 DOI: 10.1021/ja035218a Supporting Info

Synthesis and Characterization of the First Carbene Derivative of a Polyoxometalate Vincent Artero, Anna Proust, Patrick Herson, Françoise Villain, Christophe Cartier dit Moulin, and Pierre Gouzerh pp 11156–11157 DOI: 10.1021/ja036257p Supporting Info

Temperature Dependence of NMR Order Parameters and Protein Dynamics Francesca Massi and Arthur G. Palmer, III pp 11158–11159 DOI: 10.1021/ja035605k

Dynamics of Curved DNA Molecules:  Prediction and Experiment Tali E. Haran, Ilana Cohen, Alexander Spasic, Kevin Yang, and Udayan Mohanty pp 11160–11161 DOI: 10.1021/ja0303337

Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion David M. Jenkins and Jonas C. Peters pp 11162–11163 DOI: 10.1021/ja036198f Supporting Info

Cell Surface Labeling of Escherichia coli via Copper(I)-Catalyzed [3+2] Cycloaddition A. James Link and David A. Tirrell pp 11164–11165 DOI: 10.1021/ja036765z Supporting Info

Thermodynamics of Phase Transitions in Langmuir Monolayers Observed by Vibrational Sum Frequency Spectroscopy Marc C. Gurau, Edward T. Castellana, Fernando Albertorio, Sho Kataoka, Soon-Mi Lim, Richard D. Yang, and Paul S. Cremer pp 11166–11167 DOI: 10.1021/ja036735w

Identification of Active-Site Inhibitors of MurG Using a Generalizable, High-Throughput Glycosyltransferase Screen Jeremiah S. Helm, Yanan Hu, Lan Chen, Ben Gross, and Suzanne Walker pp 11168–11169 DOI: 10.1021/ja036494s Supporting Info

Screening of Protein Crystallization Conditions on a Microfluidic Chip Using Nanoliter-Size Droplets Bo Zheng, L. Spencer Roach, and Rustem F. Ismagilov pp 11170–11171 DOI: 10.1021/ja037166v

Full Miscibility of Disk- and Rod-Shaped Mesogens in the Nematic Phase Paul H. J. Kouwer and Georg H. Mehl pp 11172–11173 DOI: 10.1021/ja037075y Supporting Info

Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin'ichirou Mitani, Yoshihiko Ito, and Masahiro Murakami pp 11174–11175 DOI: 10.1021/ja0368958 Supporting Info

Palladium-Catalyzed α-Arylation of Esters and Amides under More Neutral Conditions Takuo Hama, Xiaoxiang Liu, Darcy A. Culkin, and John F. Hartwig pp 11176–11177 DOI: 10.1021/ja036792p Supporting Info

Novel Peptides Bearing Pyrene and Coumarin Units with or without β-Cyclodextrin in Their Side Chains Exhibit Intramolecular Fluorescence Resonance Energy Transfer Mohammed Akhter Hossain, Hisakazu Mihara, and Akihiko Ueno pp 11178–11179 DOI: 10.1021/ja036427y Supporting Info

Polar Phase Hydroformylation:  The Dramatic Effect of Water on Mono- and Dirhodium Catalysts David A. Aubry, Novella N. Bridges, Kerri Ezell, and George G. Stanley pp 11180–11181 DOI: 10.1021/ja035926w Supporting Info

Unexpected Hofmann Elimination in the Benzophenone−(Phenylthio)acetic Tetrabutylammonium Salt Photoredox System Andrzej Wrzyszczyński, Marek Pietrzak, Jarogniew Bartoszewicz, Halina Kozubek, Gordon L. Hug, Bronislaw Marciniak, and Jerzy Pczkowski pp 11182–11183 DOI: 10.1021/ja036196v

Vibrational Spectroscopy of CO in Gas-Phase Rhodium Cluster−CO Complexes André Fielicke, Gert von Helden, Gerard Meijer, Benoit Simard, Stéphane Dénommée, and David M. Rayner pp 11184–11185 DOI: 10.1021/ja036897s Supporting Info

Narrow (n,m)-Distribution of Single-Walled Carbon Nanotubes Grown Using a Solid Supported Catalyst Sergei M. Bachilo, Leandro Balzano, Jose E. Herrera, Francisco Pompeo, Daniel E. Resasco, and R. Bruce Weisman pp 11186–11187 DOI: 10.1021/ja036622c

Mechanism of Chromyl Chloride Epoxidation Anthony K. Rappe and Shuzhou Li pp 11188–11189 DOI: 10.1021/ja036086o Supporting Info

Extraction of Monodisperse Palladium Nanoparticles from Dendrimer Templates Joaquin C. Garcia-Martinez, Robert W. J. Scott, and Richard M. Crooks pp 11190–11191 DOI: 10.1021/ja037196y Supporting Info

Reversible Electrochemical Detection of Nonelectroactive Polyions Alexey Shvarev and Eric Bakker pp 11192–11193 DOI: 10.1021/ja037167n Supporting Info

Interatomic Distance Measurement in Solid-State NMR between a Spin-1/2 and a Spin-5/2 Using a Universal REAPDOR Curve A. Goldbourt, S. Vega, T. Gullion, and Alexander J. Vega pp 11194–11195 DOI: 10.1021/ja0360642

The First Fluoride One-Dimensional Nanostructures:  Microemulsion-Mediated Hydrothermal Synthesis of BaF2 Whiskers Minhua Cao, Changwen Hu, and Enbo Wang pp 11196–11197 DOI: 10.1021/ja036939c Supporting Info

Molecular Logic:  A Half-Subtractor Based on Tetraphenylporphyrin Steven J. Langford and Trevor Yann pp 11198–11199 DOI: 10.1021/ja036909+ Supporting Info

Rapid-Freeze-Quench Magnetic Circular Dichroism of Intermediate X in Ribonucleotide Reductase:  New Structural Insight Nataša Mitić, Lana Saleh, Gerhard Schenk, J. Martin Bollinger, Jr., and Edward I. Solomon pp 11200–11201 DOI: 10.1021/ja036556e Supporting Info

Chemical Contrasting in a Single Polymer Molecule AFM Experiment Anton Kiriy, Ganna Gorodyska, Sergiy Minko, Constantinos Tsitsilianis, Werner Jaeger, and Manfred Stamm pp 11202–11203 DOI: 10.1021/ja037262w

Enantioselective Michael Additions to α,β-Unsaturated Imides Catalyzed by a Salen−Al Complex Mark S. Taylor and Eric N. Jacobsen pp 11204–11205 DOI: 10.1021/ja037177o Supporting Info

Enantioselective Syntheses of Aeruginosin 298-A and Its Analogues Using a Catalytic Asymmetric Phase-Transfer Reaction and Epoxidation Takashi Ohshima, Vijay Gnanadesikan, Tomoyuki Shibuguchi, Yuhei Fukuta, Tetsuhiro Nemoto, and Masakatsu Shibasaki pp 11206–11207 DOI: 10.1021/ja037290e Supporting Info

Application of High Pressure Induced by Water-Freezing to the Direct Catalytic Asymmetric Three-Component List−Barbas−Mannich Reaction Yujiro Hayashi, Wataru Tsuboi, Mitsuru Shoji, and Noriyuki Suzuki pp 11208–11209 DOI: 10.1021/ja0372513 Supporting Info

A New Catalytic Conjugate Addition/Aldol Strategy That Avoids Preformed Metalated Nucleophiles Kandasamy Subburaj and John Montgomery pp 11210–11211 DOI: 10.1021/ja0362048 Supporting Info

The Cyclooctatriene-η2-ynyl Potassium Zwitterionic Radical:  Evidence for a Potassium Organometallic Steven J. Peters, Matthew R. Turk, Matthew K. Kiesewetter, Richard C. Reiter, and Cheryl D. Stevenson pp 11212–11213 DOI: 10.1021/ja0371698 Supporting Info

Spectroscopic and Electronic Structure Studies of 2,3-Dihydroxybiphenyl 1,2-Dioxygenase:  O2 Reactivity of the Non-Heme Ferrous Site in Extradiol Dioxygenases Mindy I. Davis, Erik C. Wasinger, Andrea Decker, Monita Y. M. Pau, Frédéric H. Vaillancourt, Jeffrey T. Bolin, Lindsay D. Eltis, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 11214–11227 DOI: 10.1021/ja029746i Supporting Info

Novel Functionally Grafted Pseudo-Semi-interpenetrating Networks Constructed by Reactive Linear−Dendritic Copolymers1 Ivan Gitsov and Chao Zhu pp 11228–11234 DOI: 10.1021/ja0345625 Supporting Info

The First Total Synthesis of Discorhabdin A Hirofumi Tohma, Yu Harayama, Miki Hashizume, Minako Iwata, Yorito Kiyono, Masahiro Egi, and Yasuyuki Kita pp 11235–11240 DOI: 10.1021/ja0365330 Supporting Info

Synthesis and Photophysical Studies of Bis-enediynes as Tunable Fluorophores Gil Tae Hwang, Hyung Su Son, Ja Kang Ku, and Byeang Hyean Kim pp 11241–11248 DOI: 10.1021/ja0349148 Supporting Info

Thermally Reversible Formation of Microspheres through Non-Covalent Polymer Cross-Linking Raymond J. Thibault, Peter J. Hotchkiss, Mark Gray, and Vincent M. Rotello pp 11249–11252 DOI: 10.1021/ja034868b Supporting Info

Catalytic Enantioselective Conjugate Reduction of Lactones and Lactams Gregory Hughes, Masanari Kimura, and Stephen L. Buchwald pp 11253–11258 DOI: 10.1021/ja0351692 Supporting Info

Fabrication of Nanoscale Metallic Spirals Using Phospholipid Microtubule Organizational Templates Ronald R. Price, Walter J. Dressick, and Alok Singh pp 11259–11263 DOI: 10.1021/ja036173g

Single-Electron Entrapment of [8]Annulyne, Biannulenylenes, and an Annulenoannulene Steven J. Peters, Matthew R. Turk, Matthew K. Kiesewetter, and Cheryl D. Stevenson pp 11264–11268 DOI: 10.1021/ja035062e Supporting Info

New Insight into Modeling Non-Covalently Imprinted Polymers Hyunjung Kim and David A. Spivak pp 11269–11275 DOI: 10.1021/ja0361502 Supporting Info

Development and Application of a New General Method for the Asymmetric Synthesis of syn- and anti-1,3-Amino Alcohols Takuya Kochi, Tony P. Tang, and Jonathan A. Ellman pp 11276–11282 DOI: 10.1021/ja0363462 Supporting Info

Infrared-Visible Sum Frequency Generation Spectroscopic Study of Molecular Orientation at Polystyrene/Comb-Polymer Interfaces Gary P. Harp, Hasnain Rangwalla, Mohsen S. Yeganeh, and Ali Dhinojwala pp 11283–11290 DOI: 10.1021/ja035513v Supporting Info

Controlled and Stereoselective Polymerization of Lactide:  Kinetics, Selectivity, and Microstructures Zhiyuan Zhong, Pieter J. Dijkstra, and Jan Feijen pp 11291–11298 DOI: 10.1021/ja0347585 Supporting Info

Mesoporous Polyhedral Cages and Shells Formed by Textured Self-Assembly of ZnO Nanocrystals Pu Xian Gao and Zhong Lin Wang pp 11299–11305 DOI: 10.1021/ja035569p

Epitaxial Heterostructures:  Side-to-Side Si−ZnS, Si−ZnSe Biaxial Nanowires, and Sandwichlike ZnS−Si−ZnS Triaxial Nanowires Junqing Hu, Yoshio Bando, Zongwen Liu, Takashi Sekiguchi, Dmitri Golberg, and Jinhua Zhan pp 11306–11313 DOI: 10.1021/ja030235l Supporting Info

Spectroscopic Investigation of Stellacyanin Mutants:  Axial Ligand Interactions at the Blue Copper Site Serena DeBeer George, Lipika Basumallick, Robert K. Szilagyi, David W. Randall, Michael G. Hill, Aram M. Nersissian, Joan S. Valentine, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 11314–11328 DOI: 10.1021/ja035802j Supporting Info

Single-Wall Carbon Nanotube Interaction with Gases:  Sample Contaminants and Environmental Monitoring Andrea Goldoni, Rosanna Larciprete, Luca Petaccia, and Silvano Lizzit pp 11329–11333 DOI: 10.1021/ja034898e

Nanopatterning of Alkynes on Hydrogen-Terminated Silicon Surfaces by Scanning Probe-Induced Cathodic Electrografting Patrick T. Hurley, Alexander E. Ribbe, and Jillian M. Buriak pp 11334–11339 DOI: 10.1021/ja035857l Supporting Info

How Does Huperzine A Enter and Leave the Binding Gorge of Acetylcholinesterase? Steered Molecular Dynamics Simulations Yechun Xu, Jianhua Shen, Xiaomin Luo, Israel Silman, Joel L. Sussman, Kaixian Chen, and Hualiang Jiang pp 11340–11349 DOI: 10.1021/ja029775t Supporting Info

A Highly Active Zinc Catalyst for the Controlled Polymerization of Lactide Charlotte K. Williams, Laurie E. Breyfogle, Sun Kyung Choi, Wonwoo Nam, Victor G. Young, Jr., Marc A. Hillmyer, and William B. Tolman pp 11350–11359 DOI: 10.1021/ja0359512 Supporting Info

A General Model for Selectivity in Olefin Cross Metathesis Arnab K. Chatterjee, Tae-Lim Choi, Daniel P. Sanders, and Robert H. Grubbs pp 11360–11370 DOI: 10.1021/ja0214882 Supporting Info

Reactions of B Atoms and Clusters with NO:  Experimental and Theoretical Characterization of Novel Molecules Containing B, N, and O Mingfei Zhou, Nobuko Tsumori, Qiang Xu, Gary P. Kushto, and Lester Andrews pp 11371–11378 DOI: 10.1021/ja0367187

Temperature Dependence of Domain Motions of Calmodulin Probed by NMR Relaxation at Multiple Fields Shou-Lin Chang, Attila Szabo, and Nico Tjandra pp 11379–11384 DOI: 10.1021/ja034064w Supporting Info

Single-Scan NMR Spectroscopy at Arbitrary Dimensions Yoav Shrot and Lucio Frydman pp 11385–11396 DOI: 10.1021/ja0350785 Supporting Info

Reaction of Phenyl Radicals with Acetylene:  Quantum Chemical Investigation of the Mechanism and Master Equation Analysis of the Kinetics I. V. Tokmakov and M. C. Lin pp 11397–11408 DOI: 10.1021/ja0301121 Supporting Info

Mono- and Dibridged Isomers of Si2H3 and Si2H4:  the True Ground State Global Minima. Theory and Experiment in Concert Levent Sari, M. C. McCarthy, Henry F. Schaefer III, and P. Thaddeus pp 11409–11417 DOI: 10.1021/ja0300923

Electrocatalytic Reactions Mediated by N,N,N‘,N‘-Tetraalkyl-1,4-phenylenediamine Redox Liquid Microdroplet-Modified Electrodes:  Chemical and Photochemical Reactions In, and At the Surface of, Femtoliter Droplets Jay D. Wadhawan, Andrew J. Wain, Andrew N. Kirkham, David J. Walton, Bill Wood, Robert R. France, Steven D. Bull, and Richard G. Compton pp 11418–11429 DOI: 10.1021/ja030315p Supporting Info

Catalytic Reduction of Acetone by [(bpy)Rh]+:  A Theoretical Mechanistic Investigation and Insight into Cooperativity Effects in This System Mark A. Iron, Andreas Sundermann, and Jan M. L. Martin pp 11430–11441 DOI: 10.1021/ja028489e Supporting Info

On the Viability of Small Endohedral Hydrocarbon Cage Complexes:  X@C4H4, X@C8H8, X@C8H14, X@C10H16, X@C12H12, and X@C16H16 Damian Moran, H. Lee Woodcock, Zhongfang Chen, Henry F. Schaefer III, and Paul v. R. Schleyer pp 11442–11451 DOI: 10.1021/ja0345470 Supporting Info

Construction of Hydrolytically Degradable Thin Films via Layer-by-Layer Deposition of Degradable Polyelectrolytes [J. Am. Chem. Soc. 2002, 124, 13992−13993]. Eduardo Vázquez, David M. Dewitt, and Paula T. Hammond, and David M. Lynn p 11452 DOI: 10.1021/ja033452v

New Aspects in Phosphorus Chemistry II. Topics in Current Chemistry, 223 Edited by Jean-Pierre Majoral (Laboratoire de Chimie de Coordination CNRS, Toulouse, France). Springer-Verlag:  Berlin, Heidelberg, and New York. 2003. vii + 264 pp. $189.00. ISBN 3-540-44086-0. Christopher D. Spilling p 11453 DOI: 10.1021/ja033514h

Material Research in Atomic Scale by Mössbauer Spectroscopy Edited by Miroslav Mashlan (Palacky University), Marcel Miglierini (Slovak University of Technology), and Peter Schaaf (Universität Göttingen). Kluwer Academic Publishers:  Dordrecht, Boston, London. 2003. x + 362 pp. $137.00. ISBN 1-4020-1196-2. p 11453 DOI: 10.1021/ja033569j

Block Copolymers:  Synthetic Strategies, Physical Properties, and Applications By Nikos Hadjichristidis and Stergios Pispas (University of Athens) and George Floudas (University of Ioannina). John Wiley and Sons, Inc.:  Hoboken, NJ. 2003. xx + 420 pp. $125.00. ISBN 0-471-39436-X. Adi Eisenberg pp 11453–11454 DOI: 10.1021/ja025357c

Handbook of Free Radical Initiators By E. T. Denisov, T. G. Denisova, and T. S. Pokidova (Russian Academy of Sciences, Moscow). John Wiley & Sons, Inc.:  Hoboken, NJ. xxii + 880 pp. $300.00. ISBN 0-471-20753-5. p 11454 DOI: 10.1021/ja033545c

Issue 38

Stereoselective Construction of Cyclic Ethers Using a Tandem Two-Component Etherification:  Elucidation of the Role of Bismuth Tribromide P. Andrew Evans, Jian Cui, Santosh J. Gharpure, and Robert J. Hinkle pp 11456–11457 DOI: 10.1021/ja036439j Supporting Info

A Novel Two-Fluorophore Approach to Ratiometric Sensing of Zn2+ Carolyn C. Woodroofe and Stephen J. Lippard pp 11458–11459 DOI: 10.1021/ja0364930 Supporting Info

Hydroxyapatite-Bound Cationic Ruthenium Complexes as Novel Heterogeneous Lewis Acid Catalysts for Diels−Alder and Aldol Reactions Kohsuke Mori, Takayoshi Hara, Tomoo Mizugaki, Kohki Ebitani, and Kiyotomi Kaneda pp 11460–11461 DOI: 10.1021/ja0302533 Supporting Info

Control of Alkanethiolate Monolayer Structure Using Vapor-Phase Annealing Zachary J. Donhauser, David W. Price II, James M. Tour, and Paul S. Weiss pp 11462–11463 DOI: 10.1021/ja035036g

New Routes to Transition Metal-Carbido Species:  Synthesis and Characterization of the Carbon-Centered Trigonal Prismatic Clusters [W6CCl18]n- (n = 1, 2, 3) Eric J. Welch, Nathan R. M. Crawford, Robert G. Bergman, and Jeffrey R. Long pp 11464–11465 DOI: 10.1021/ja035962v Supporting Info

Type-II Quantum Dots:  CdTe/CdSe(Core/Shell) and CdSe/ZnTe(Core/Shell) Heterostructures Sungjee Kim, Brent Fisher, Hans-Jürgen Eisler, and Moungi Bawendi pp 11466–11467 DOI: 10.1021/ja0361749 Supporting Info

1,4,5-Trigermabicyclo[2.1.0]pent-2-en-5-ylium:  The Isolable Bishomocyclopropenylium Ion Containing a Heavier Group 14 Element Yutaka Ishida, Akira Sekiguchi, and Yoshio Kabe pp 11468–11469 DOI: 10.1021/ja030327a Supporting Info

Doping γ-Fe2O3 Nanoparticles with Mn(III) Suppresses the Transition to the α-Fe2O3 Structure Jriuan Lai, Kurikka V. P. M. Shafi, Katja Loos, Abraham Ulman, Yongjae Lee, Thomas Vogt, and Claude Estournès pp 11470–11471 DOI: 10.1021/ja035409d Supporting Info

Rh-Catalyzed Kinetic Resolution of Enynes and Highly Enantioselective Formation of 4-Alkenyl-2,3-disubstituted Tetrahydrofurans Aiwen Lei, Minsheng He, and Xumu Zhang pp 11472–11473 DOI: 10.1021/ja0351950 Supporting Info

Ultrasensitive DNA Detection Using Highly Fluorescent Bioconjugated Nanoparticles Xiaojun Zhao, Rovelyn Tapec-Dytioco, and Weihong Tan pp 11474–11475 DOI: 10.1021/ja0358854 Supporting Info

Creation of a Productive, Highly Enantioselective Nitrilase through Gene Site Saturation Mutagenesis (GSSM) Grace DeSantis, Kelvin Wong, Bob Farwell, Kelly Chatman, Zoulin Zhu, Geoff Tomlinson, Hongjun Huang, Xuqiu Tan, Lisa Bibbs, Pei Chen, Keith Kretz, and Mark J. Burk pp 11476–11477 DOI: 10.1021/ja035742h Supporting Info

Chemical Activation of Cytochrome c Proteins via Crown Ether Complexation:  Cold-Active Synzymes for Enantiomer-Selective Sulfoxide Oxidation in Methanol Dharam Paul, Atsuko Suzumura, Hideki Sugimoto, Junji Teraoka, Satoshi Shinoda, and Hiroshi Tsukube pp 11478–11479 DOI: 10.1021/ja037239a

Excess Electron Transfer from an Internally Conjugated Aromatic Amine to 5-Bromo-2‘-deoxyuridine in DNA Takeo Ito and Steven E. Rokita pp 11480–11481 DOI: 10.1021/ja035952u Supporting Info

Enantioselective Synthesis of “Quaternary” 1,4-Benzodiazepin-2-one Scaffolds via Memory of Chirality Paul R. Carlier, Hongwu Zhao, Joe DeGuzman, and Polo C.-H. Lam pp 11482–11483 DOI: 10.1021/ja0365781 Supporting Info

Ambient Temperature Activation of Haloporphyrinic-Enediynes:  Electronic Contributions to Bergman Cycloaromatization Mahendra Nath, John C. Huffman, and Jeffrey M. Zaleski pp 11484–11485 DOI: 10.1021/ja0302782 Supporting Info

Racemization of an Asparagine Residue during Peptide Deamidation Bei Li, Ronald T. Borchardt, Elizabeth M. Topp, David VanderVelde, and Richard L. Schowen pp 11486–11487 DOI: 10.1021/ja0360992 Supporting Info

First Catalytic Reductive Coupling of 1,3-Diynes to Carbonyl Partners:  A New Regio- and Enantioselective C−C Bond Forming Hydrogenation Ryan R. Huddleston, Hye-Young Jang, and Michael J. Krische pp 11488–11489 DOI: 10.1021/ja030415v Supporting Info

Chiral Porous Hybrid Solids for Practical Heterogeneous Asymmetric Hydrogenation of Aromatic Ketones Aiguo Hu, Helen L. Ngo, and Wenbin Lin pp 11490–11491 DOI: 10.1021/ja0348344 Supporting Info

Oxygen Binding to Sulfur in Nitrosylated Iron−Thiolate Complexes:  Relevance to the Fe-Containing Nitrile Hydratases Chien-Ming Lee, Chung-Hung Hsieh, Amitava Dutta, Gene-Hsiang Lee, and Wen-Feng Liaw pp 11492–11493 DOI: 10.1021/ja035292t Supporting Info

(S)-Selective Dynamic Kinetic Resolution of Secondary Alcohols by the Combination of Subtilisin and an Aminocyclopentadienylruthenium Complex as the Catalysts Mahn-Joo Kim, Yong Il Chung, Yoon Kyung Choi, Han Ki Lee, Daeho Kim, and Jaiwook Park pp 11494–11495 DOI: 10.1021/ja036766r Supporting Info

Vapor Phase Self-Assembly of Electrooptic Thin Films via Triple Hydrogen Bonds Peiwang Zhu, Hu Kang, Antonio Facchetti, Guennadi Evmenenko, Pulak Dutta, and Tobin J. Marks pp 11496–11497 DOI: 10.1021/ja037164a Supporting Info

Synthesis of CdS and ZnS Nanowires Using Single-Source Molecular Precursors Carl J. Barrelet, Yue Wu, David C. Bell, and Charles M. Lieber pp 11498–11499 DOI: 10.1021/ja036990g

Triple-Helix Propensity of Hydroxyproline and Fluoroproline:  Comparison of Host−Guest and Repeating Tripeptide Collagen Models Anton V. Persikov, John A. M. Ramshaw, Alan Kirkpatrick, and Barbara Brodsky pp 11500–11501 DOI: 10.1021/ja036673+

Helical Conformational Specificity of Enzymatically Synthesized Water-Soluble Conducting Polyaniline Nanocomposites Muthiah Thiyagarajan, Lynne A. Samuelson, Jayant Kumar, and Ashok L. Cholli pp 11502–11503 DOI: 10.1021/ja035414h

Simultaneous and Accurate Determination of One-Bond 15N−13C‘ and Two-Bond 1HN−13C‘ Dipolar Couplings Keyang Ding and Angela M. Gronenborn pp 11504–11505 DOI: 10.1021/ja035954e Supporting Info

1,4-Palladium Migration via C−H Activation, Followed by Arylation:  Synthesis of Fused Polycycles Marino A. Campo, Qinhua Huang, Tuanli Yao, Qingping Tian, and Richard C. Larock pp 11506–11507 DOI: 10.1021/ja035121o Supporting Info

A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts:  Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition Tamio Hayashi, Kazuhito Ueyama, Norihito Tokunaga, and Kazuhiro Yoshida pp 11508–11509 DOI: 10.1021/ja037367z Supporting Info

A Stereoselective Synthesis of (−)-Tetrodotoxin Andrew Hinman and J. Du Bois pp 11510–11511 DOI: 10.1021/ja0368305 Supporting Info

Experimental and Theoretical Characterization of H2OOO+ Mingfei Zhou, Aihua Zeng, Yun Wang, Qingyu Kong, Zhi-Xiang Wang, and Paul van Rague Schleyer pp 11512–11513 DOI: 10.1021/ja037125z Supporting Info

Synthesis of (−)-Terpestacin via Catalytic, Stereoselective Fragment Coupling:  Siccanol Is Terpestacin, Not 11-epi-Terpestacin Johann Chan and Timothy F. Jamison pp 11514–11515 DOI: 10.1021/ja0373925 Supporting Info

A Mechanistic Dichotomy in Ruthenium-Catalyzed Propargyl Alcohol Reactivity:  A Novel Hydrative Diyne Cyclization Barry M. Trost and Michael T. Rudd pp 11516–11517 DOI: 10.1021/ja036410f Supporting Info

A Sugar Discriminating Binuclear Copper(II) Complex Susanne Striegler and Michael Dittel pp 11518–11524 DOI: 10.1021/ja035561f Supporting Info

A Novel RNA Motif Based on the Structure of Unusually Stable 2‘,5‘-Linked r(UUCG) Loops Alexei Yu. Denisov, Rami N. Hannoush, Kalle Gehring, and Masad J. Damha pp 11525–11531 DOI: 10.1021/ja036207k Supporting Info

A Novel Inhibitor for Fe-type Nitrile Hydratase:  2-Cyano-2-propyl Hydroperoxide Masanari Tsujimura, Masafumi Odaka, Hiroshi Nakayama, Naoshi Dohmae, Hiroyuki Koshino, Tadao Asami, Mikio Hoshino, Koji Takio, Shigeo Yoshida, Mizuo Maeda, and Isao Endo pp 11532–11538 DOI: 10.1021/ja035018z

Dihydrogen-Bond-Promoted Catalysis:  Catalytic Hydration of Nitriles with the Indenylruthenium Hydride Complex (η5-C9H7)Ru(dppm)H (dppm = Bis(diphenylphosphino)methane) Wai Kit Fung, Xin Huang, Man Lok Man, Siu Man Ng,Siu Man Ng, Mei Yuen Hung, Zhenyang Lin, and Chak Po Lau pp 11539–11544 DOI: 10.1021/ja034050q

A Versatile Modification of On-Column Oligodeoxynucleotides Using a Copper-Catalyzed Oxidative Acetylenic Coupling Reaction Noriaki Minakawa, Yayoi Ono, and Akira Matsuda pp 11545–11552 DOI: 10.1021/ja036055t Supporting Info

Mechanism of Formation of Hydrogen Trioxide (HOOOH) in the Ozonation of 1,2-Diphenylhydrazine and 1,2-Dimethylhydrazine:  An Experimental and Theoretical Investigation Božo Plesniar, Tell Tuttle, Janez Cerkovnik, Jože Koller, and Dieter Cremer pp 11553–11564 DOI: 10.1021/ja036801u Supporting Info

The Reactions of Imidazol-2-ylidenes with the Hydrogen Atom:  A Theoretical Study and Experimental Confirmation with Muonium Iain McKenzie, Jean-Claude Brodovitch, Paul W. Percival, Taramatee Ramnial, and Jason A. C. Clyburne pp 11565–11570 DOI: 10.1021/ja028770t Supporting Info

Highly Oriented Self-Assembled Monolayers as Templates for Epitaxial Calcite Growth A. Markus Travaille, Lotte Kaptijn, Paul Verwer, Bas Hulsken, Johannes A. A. W. Elemans, Roeland J. M. Nolte, and Herman van Kempen pp 11571–11577 DOI: 10.1021/ja034624r

A Theoretical Study on the Mechanism, Regiochemistry, and Stereochemistry of Hydrosilylation Catalyzed by Cationic Ruthenium Complexes Lung Wa Chung, Yun-Dong Wu, Barry M. Trost, and Zachary T. Ball pp 11578–11582 DOI: 10.1021/ja034833b Supporting Info

Singular Crystalline β‘-Layered Topologies Directed by Ribbons of Self-Complementary Amide···Amide Ring Motifs in [EDT-TTF-(CONH2)2]2X (X = HSO4-, ClO4-, ReO4-, AsF6-):  Coupled Activation of Ribbon Curvature, Electron Interactions, and Magnetic Susceptibility Stéphane A. Baudron, Narcis Avarvari, Patrick Batail, Claude Coulon, Rodolphe Clérac, Enric Canadell, and Pascale Auban-Senzier pp 11583–11590 DOI: 10.1021/ja0356129 Supporting Info

Electroreductive Intramolecular Coupling of Chiral α-Imino Esters:  Stereoselective Synthesis of Mixed Ketals of cis-2,4-Disubstituted Azetidine-3-ones Naoki Kise, Hiroshi Ozaki, Noriaki Moriyama, Yasuo Kitagishi, and Nasuo Ueda pp 11591–11596 DOI: 10.1021/ja036975b Supporting Info

The Charge-Transfer Motif in Crystal Engineering. Self-Assembly of Acentric (Diamondoid) Networks from Halide Salts and Carbon Tetrabromide as Electron-Donor/Acceptor Synthons Sergey V. Lindeman, Jürgen Hecht, and Jay K. Kochi pp 11597–11606 DOI: 10.1021/ja030299w Supporting Info

DNA Base Damage by the Antitumor Agent 3-Amino-1,2,4-benzotriazine 1,4-Dioxide (Tirapazamine) Mustafa Birincioglu, Pawel Jaruga, Goutam Chowdhury, Henry Rodriguez, Miral Dizdaroglu, and Kent S. Gates pp 11607–11615 DOI: 10.1021/ja0352146

Nonplanar Distortions of Bis-Base Low-Spin Iron(II)−Porphyrinates:  Absorption and Resonance Raman Investigations of Cross-Trans-Linked Iron(II)−Basket-Handle Porphyrin Complexes Thierry Picaud, Carole Le Moigne, Bernard Loock, Michel Momenteau, and Alain Desbois pp 11616–11625 DOI: 10.1021/ja034710r

Germanium and Tin Analogues of Alkynes and Their Reduction Products Lihung Pu, Andrew D. Phillips, Anne F. Richards, Matthias Stender, Richard S. Simons, Marilyn M. Olmstead, and Philip P. Power pp 11626–11636 DOI: 10.1021/ja035711m Supporting Info

Direct Measurement of the Hyperfine and g-Tensors of a Mn(III)−Mn(IV) Complex in Polycrystalline and Frozen Solution Samples by High-Field EPR Christelle Hureau, Geneviève Blondin, Michèle Cesario, and Sun Un pp 11637–11645 DOI: 10.1021/ja035153b Supporting Info

Peering into the Self-Assembly of Surfactant Templated Thin-Film Silica Mesophases Dhaval A. Doshi, Alain Gibaud, Valerie Goletto, Mengcheng Lu, Henry Gerung, Benjamin Ocko, Sang M. Han, and C. Jeffrey Brinker pp 11646–11655 DOI: 10.1021/ja0295523

Inelastic Neutron Scattering and Raman Spectroscopies and Periodic DFT Studies of Rb2PtH6 and Rb2PtD6 Stewart F. Parker, Stephen M. Bennington, Anibal. J. Ramirez-Cuesta, Gudrun Auffermann, Welf Bronger, Henryk Herman, Kenneth P. J. Williams, and Tim Smith pp 11656–11661 DOI: 10.1021/ja034323h

Novel Route to Periodic Mesoporous Aminosilicas, PMAs:  Ammonolysis of Periodic Mesoporous Organosilicas Tewodros Asefa, Michal Kruk, Neil Coombs, Hiltrud Grondey, Mark J. MacLachlan, Mietek Jaroniec, and Geoffrey A. Ozin pp 11662–11673 DOI: 10.1021/ja036080z Supporting Info

Potential-Dependent Reorientation of Thiocyanate on Au Electrodes Xiao Li and Andrew A. Gewirth pp 11674–11683 DOI: 10.1021/ja0363112 Supporting Info

Capillarity Effects on Crystallization Kinetics:  Insulin Ilya Reviakine, Dimitra K. Georgiou, and Peter G. Vekilov pp 11684–11693 DOI: 10.1021/ja030194t

Heterophase Ligand Exchange and Metal Transfer between Monolayer Protected Clusters Yang Song, Tao Huang, and Royce W. Murray pp 11694–11701 DOI: 10.1021/ja0355731

Cycloaddition Reactions of Metalloaromatic Complexes of Iridium and Rhodium:  A Mechanistic DFT Investigation Mark A. Iron, Jan M. L. Martin, and Milko E. van der Boom pp 11702–11709 DOI: 10.1021/ja036723a Supporting Info

Low-Temperature NMR Studies of the Structure and Dynamics of a Novel Series of Acid−Base Complexes of HF with Collidine Exhibiting Scalar Couplings Across Hydrogen Bonds Ilja G. Shenderovich, Peter M. Tolstoy, Nikolai S. Golubev, Sergei N. Smirnov, Gleb S. Denisov, and Hans-Heinrich Limbach pp 11710–11720 DOI: 10.1021/ja029183a Supporting Info

Mechanism for the Cyclotrimerization of Alkynes and Related Reactions Catalyzed by CpRuCl Karl Kirchner, Maria José Calhorda, Roland Schmid, and Luís F. Veiros pp 11721–11729 DOI: 10.1021/ja035137e

Identity Proton-Transfer Reactions from C−H, N−H, and O−H Acids. An ab Initio, DFT, and CPCM-B3LYP Aqueous Solvent Model Study James R. Keeffe, Scott Gronert, Michael E. Colvin, and Ngoc L. Tran pp 11730–11745 DOI: 10.1021/ja0356683 Supporting Info

Why Does Cyclopropene Have the Acidity of an Acetylene but the Bond Energy of Methane? Alireza Fattahi, Ralph E. McCarthy, Mohammad R. Ahmad, and Steven R. Kass pp 11746–11750 DOI: 10.1021/ja035725s

Infrared Spectra and Structures of the Stable CuH2-, AgH2-, AuH2-, and AuH4- Anions and the AuH2 Molecule Lester Andrews and Xuefeng Wang pp 11751–11760 DOI: 10.1021/ja036307q

Trends in Exchange Coupling for Trimethylenemethane-Type Bis(semiquinone) Biradicals and Correlation of Magnetic Exchange with Mixed Valency for Cross-Conjugated Systems David A. Shultz, Rosario M. Fico, Jr., Scot H. Bodnar, R. Krishna Kumar, Kira E. Vostrikova, Jeff W. Kampf, and Paul D. Boyle pp 11761–11771 DOI: 10.1021/ja0367849 Supporting Info

Viscosity Effects on the Thermal Decomposition of Bis(perfluoro-2-N-propoxypropionyl) Peroxide in Dense Carbon Dioxide and Fluorinated Solvents [J. Am. Chem. Soc. 2001, 123, 7199−7206]. W. Clayton Bunyard, John F. Kadla, James DeYoung, and Joseph M. DeSimone p 11772 DOI: 10.1021/ja025127y

Synthesis of a First-Row Transition Metal Parent Amido Complex and Carbon Monoxide Insertion into the Amide N−H Bond  [J. Am. Chem. Soc. 2003, 125, 8984−8985].  Daniel J. Fox and Robert G. Bergman p 11772 DOI: 10.1021/ja0334513

Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel [J. Am. Chem. Soc. 2002, 124 (48), 14416−14424]. Patrick L. Holland, Thomas R. Cundari, Lanyn L. Perez, Nathan A. Eckert, and Rene J. Lachicotte p 11772 DOI: 10.1021/ja0378411

Rational Design to Block Amino Acid Editing of a tRNA Synthetase [J. Am. Chem. Soc. 2002, 124, 7286−7287]. Richard S. Mursinna and Susan A. Martinis p 11773 DOI: 10.1021/ja033453n

Issue 39

Control of the Geometry of the Adsorbed Thin Layer by the Depletion Interaction Dongshan Zhou, Junfeng Zhang, Liang Li, and Gi Xue pp 11774–11775 DOI: 10.1021/ja035989e

Four-Component Reactions for a New Diastereoselective Synthesis of Chiral Quaternary Centers Genia Sklute, Deborah Amsallem, Amal Shabli, Jos P. Varghese, and Ilan Marek pp 11776–11777 DOI: 10.1021/ja036872t Supporting Info

Synthesis and Structure of UO2I2(OH2)2·4Et2O:  First Structurally Characterized U(VI)−I Bond and Lightest Missing Member of the UO2X2 (X = Halide) Series Margaret-Jane Crawford, Arkady Ellern, Heinrich Nöth, and Max Suter pp 11778–11779 DOI: 10.1021/ja030260r Supporting Info

Conversion of Extradiol Aromatic Ring-Cleaving Homoprotocatechuate 2,3-Dioxygenase into an Intradiol Cleaving Enzyme Stephanie L. Groce and John D. Lipscomb pp 11780–11781 DOI: 10.1021/ja0368103

Adding Amino Acids with Novel Reactivity to the Genetic Code of Saccharomyces Cerevisiae Alexander Deiters, T. Ashton Cropp, Mridul Mukherji, Jason W. Chin, J. Christopher Anderson, and Peter G. Schultz pp 11782–11783 DOI: 10.1021/ja0370037 Supporting Info

Through-Bond 13C−13C Correlation at the Natural Abundance Level:  Refining Dynamic Regions in the Crystal Structure of Vitamin-D3 with Solid-State NMR Ryan A. Olsen, Jochem Struppe, Douglas W. Elliott, Richard J. Thomas, and Leonard J. Mueller pp 11784–11785 DOI: 10.1021/ja036655s Supporting Info

Molecular Imprinting of Biomineralized CdS Nanostructures:  Crystallographic Control Using Self-Assembled DNA−Membrane Templates Hongjun Liang, Thomas E. Angelini, James Ho, Paul V. Braun, and Gerard C. L. Wong pp 11786–11787 DOI: 10.1021/ja036529o Supporting Info

Coordination and Mechanism of Reversible Cleavage of S-Adenosylmethionine by the [4Fe-4S] Center in Lysine 2,3-Aminomutase Dawei Chen, Charles Walsby, Brian M. Hoffman, and Perry A. Frey pp 11788–11789 DOI: 10.1021/ja036120z Supporting Info

Site-Specific Protein Immobilization by Staudinger Ligation Matthew B. Soellner, Kimberly A. Dickson, Bradley L. Nilsson, and Ronald T. Raines pp 11790–11791 DOI: 10.1021/ja036712h Supporting Info

Resolved Chiral 3,4-Diazaphospholanes and Their Application to Catalytic Asymmetric Allylic Alkylation Thomas P. Clark and Clark R. Landis pp 11792–11793 DOI: 10.1021/ja036359f Supporting Info

Designed Helical Peptides Inhibit an Intramembrane Protease Chittaranjan Das, Oksana Berezovska, Thekla S. Diehl, Cedric Genet, Ilya Buldyrev, Jui-Yi Tsai, Bradley T. Hyman, and Michael S. Wolfe pp 11794–11795 DOI: 10.1021/ja037131v Supporting Info

Enantioselective Synthesis of α,β-Disubstituted-β-amino Acids Mukund P. Sibi, Narayanasamy Prabagaran, Sandeep G. Ghorpade, and Craig P. Jasperse pp 11796–11797 DOI: 10.1021/ja0372309 Supporting Info

Reversible Binding of Nitric Oxide and Carbon−Carbon Bond Formation in a Meso-hydroxylated Heme Sankar Prasad Rath, Richard Koerner, Marilyn M. Olmstead, and Alan L. Balch pp 11798–11799 DOI: 10.1021/ja035032b Supporting Info

Internally Catalyzed Separation of Adhered Lipid Membranes Fredric M. Menger and Victor A. Seredyuk pp 11800–11801 DOI: 10.1021/ja030334z

Thermally Reversible Hydrogels via Intramolecular Folding and Consequent Self-Assembly of a de Novo Designed Peptide Darrin J. Pochan, Joel P. Schneider, Juliana Kretsinger, Bulent Ozbas, Karthikan Rajagopal, and Lisa Haines pp 11802–11803 DOI: 10.1021/ja0353154 Supporting Info

Facilitated Forward Chemical Genetics Using a Tagged Triazine Library and Zebrafish Embryo Screening Sonya M. Khersonsky, Da-Woon Jung, Tae-Wook Kang, Daniel P. Walsh, Ho-Sang Moon, Hakryul Jo, Eric M. Jacobson, Vivekananda Shetty, Thomas A. Neubert, and Young-Tae Chang pp 11804–11805 DOI: 10.1021/ja035334d Supporting Info

Free-Radical Reactions under Diffusional Constraints:  Orientation Does Matter in Hydrogen Transfer A. C. Buchanan, III, Michelle K. Kidder, and Phillip F. Britt pp 11806–11807 DOI: 10.1021/ja036435e

Circularly Polarized Luminescence from Bridged Triarylamine Helicenes Jason E. Field, Gilles Muller, James P. Riehl, and D. Venkataraman pp 11808–11809 DOI: 10.1021/ja035626e Supporting Info

Vibrational Coherence from the Dipyridine Complex of Bacteriochlorophyll a:  Intramolecular Modes in the 10−220-cm-1 Regime, Intermolecular Solvent Modes, and Relevance to Photosynthesis Katherine R. Shelly, Elizabeth A. Carson, and Warren F. Beck pp 11810–11811 DOI: 10.1021/ja0366890 Supporting Info

Sodium-Ion Binding to DNA:  Detection by Ultrafast Time-Resolved Stokes-Shift Spectroscopy Latha A. Gearheart, Mark M. Somoza, W. Evan Rivers, Catherine J. Murphy, Robert S. Coleman, and Mark A. Berg pp 11812–11813 DOI: 10.1021/ja0363617 Supporting Info

Mimicking Photosynthesis in a Computationally Designed Synthetic Metalloprotein Lidia Cristian, Piotr Piotrowiak, and Ramy S. Farid pp 11814–11815 DOI: 10.1021/ja0292142 Supporting Info

Resolution Enhancement in Multidimensional Solid-State NMR Spectroscopy of Proteins Using Spin-State Selection Luminita Duma, Sabine Hediger, Bernhard Brutscher, Anja Böckmann, and Lyndon Emsley pp 11816–11817 DOI: 10.1021/ja036893n

The First General Palladium Catalyst for the Suzuki−Miyaura and Carbonyl Enolate Coupling of Aryl Arenesulfonates Hanh Nho Nguyen, Xiaohua Huang, and Stephen L. Buchwald pp 11818–11819 DOI: 10.1021/ja036947t Supporting Info

Peptide Self-Replication Enhanced by a Proline Kink Xiangqun Li and Jean Chmielewski pp 11820–11821 DOI: 10.1021/ja036569s Supporting Info

Control of Cu(II) and Cu(III) States in N-Confused Porphyrin by Protonation/Deprotonation at the Peripheral Nitrogen Hiromitsu Maeda, Yuichi Ishikawa, Tomoyuki Matsuda, Atsuhiro Osuka, and Hiroyuki Furuta pp 11822–11823 DOI: 10.1021/ja0356075 Supporting Info

High-Resolution 17O NMR Spectroscopy of Wadsleyite (β-Mg2SiO4) Sharon E. Ashbrook, Andrew J. Berry, William O. Hibberson, Stefan Steuernagel, and Stephen Wimperis pp 11824–11825 DOI: 10.1021/ja036777k

Thermally-Regulated Molecular Selectivity of Organosilica Sol−Gels Mukti S. Rao and Bakul C. Dave pp 11826–11827 DOI: 10.1021/ja0352348

Solid-State NMR Spectroscopy Method for Determination of the Backbone Torsion Angle ψ in Peptides with Isolated Uniformly Labeled Residues Jerry C. C. Chan and Robert Tycko pp 11828–11829 DOI: 10.1021/ja0369820 Supporting Info

The Modulating Possibilities of Dicarbollide Clusters:  Optimizing the Kharasch Catalysts Oscar Tutusaus, Clara Viñas, Rosario Núñez, Francesc Teixidor, Albert Demonceau, Sébastien Delfosse, Alfred F. Noels, Ignasi Mata, and Elies Molins pp 11830–11831 DOI: 10.1021/ja036342x Supporting Info

Voltammetry of the Phase Transfer of Polypeptide Protamines across Polarized Liquid/Liquid Interfaces Shigeru Amemiya, Xiting Yang, and Tracy L. Wazenegger pp 11832–11833 DOI: 10.1021/ja036572b Supporting Info

Nano-Precision Replication of Natural Cellulosic Substances by Metal Oxides Jianguo Huang and Toyoki Kunitake pp 11834–11835 DOI: 10.1021/ja037419k

Dynamic Kinetic Asymmetric Cycloadditions of Isocyanates to Vinylaziridines Barry M. Trost and Daniel R. Fandrick pp 11836–11837 DOI: 10.1021/ja037450m Supporting Info

Simultaneous in Situ Total Internal Reflectance Fluorescence/Atomic Force Microscopy Studies of DPPC/dPOPC Microdomains in Supported Planar Lipid Bilayers James E. Shaw, Andrea Slade, and Christopher M. Yip pp 11838–11839 DOI: 10.1021/ja0370894

Synthesis and Self-Assembly of a Heteroarm Star Amphiphile with 12 Alternating Arms and a Well-Defined Core Jing Teng and Eugene R. Zubarev pp 11840–11841 DOI: 10.1021/ja036705t Supporting Info

The Hydroxide Complex of Pseudomonas aeruginosa Heme Oxygenase as a Model of the Low-Spin Iron(III) Hydroperoxide Intermediate in Heme Catabolism:  13C NMR Spectroscopic Studies Suggest the Active Participation of the Heme in Macrocycle Hydroxylation Gregori A. Caignan, Rahul Deshmukh, Yuhong Zeng, Angela Wilks, Richard A. Bunce, and Mario Rivera pp 11842–11852 DOI: 10.1021/ja036147i Supporting Info

Development of a Chemical Structure Comparison Method for Integrated Analysis of Chemical and Genomic Information in the Metabolic Pathways Masahiro Hattori, Yasushi Okuno, Susumu Goto, and Minoru Kanehisa pp 11853–11865 DOI: 10.1021/ja036030u Supporting Info

The Rate of O2 and CO Binding to a Copper Complex, Determined by a “Flash-and-Trap” Technique, Exceeds that for Hemes H. Christopher Fry, Donald V. Scaltrito, Kenneth D. Karlin, and Gerald J. Meyer pp 11866–11871 DOI: 10.1021/ja034911v Supporting Info

The Structure of NADH in the Enzyme dTDP-d-glucose Dehydratase (RmlB) Konstantinos Beis, Simon T. M. Allard, Adrian D. Hegeman, Garib Murshudov, Douglas Philp, and James H. Naismith pp 11872–11878 DOI: 10.1021/ja035796r Supporting Info

Determination of Initial and Long-Term Microstructure Changes in Ultrahigh Molecular Weight Polyethylene Induced by Drawing Neat and Pyrenyl Modified Films Chuping Luo, Teresa D. Z. Atvars, Pavla Meakin, Anita J. Hill, and Richard G. Weiss pp 11879–11892 DOI: 10.1021/ja0362205 Supporting Info

Convergent Total Syntheses of Gambierol and 16-epi-Gambierol and Their Biological Activities Isao Kadota, Hiroyoshi Takamura, Kumi Sato, Akio Ohno, Kumiko Matsuda, Masayuki Satake, and Yoshinori Yamamoto pp 11893–11899 DOI: 10.1021/ja036984k Supporting Info

Molecular Dynamics Simulation of an Electric Field Driven Dipolar Molecular Rotor Attached to a Quartz Glass Surface Dominik Horinek and Josef Michl pp 11900–11910 DOI: 10.1021/ja0348851 Supporting Info

Mechanism of the Alternating Copolymerization of Epoxides and CO2 Using β-Diiminate Zinc Catalysts:  Evidence for a Bimetallic Epoxide Enchainment David R. Moore, Ming Cheng, Emil B. Lobkovsky, and Geoffrey W. Coates pp 11911–11924 DOI: 10.1021/ja030085e Supporting Info

Organometallic Gold(III) Compounds as Catalysts for the Addition of Water and Methanol to Terminal Alkynes Raquel Casado, María Contel, Mariano Laguna, Pilar Romero, and Sergio Sanz pp 11925–11935 DOI: 10.1021/ja036049x Supporting Info

Ketene Formation in Benzdiyne Chemistry:  Ring Cleavage versus Wolff Rearrangement Tadatake Sato, Hiroyuki Niino, and Akira Yabe pp 11936–11941 DOI: 10.1021/ja035826q Supporting Info

Highly Diastereoselective Hydrogenations Leading to β-Hydroxy δ-Lactones in Hydroxy-Protected Form. A Modified View of δ-Lactone Conformations Svante Brandänge, Magnus Färnbäck, Hans Leijonmarck, and Anders Sundin pp 11942–11955 DOI: 10.1021/ja036002b Supporting Info

Use of Group 4 Bis(sulfonamido) Complexes in the Intramolecular Hydroamination of Alkynes and Allenes Lutz Ackermann, Robert G. Bergman, and Rebecca N. Loy pp 11956–11963 DOI: 10.1021/ja0361547 Supporting Info

Biscarbene−Ruthenium Complexes in Catalysis: Novel Stereoselective Synthesis of (1E,3E)-1,4-Disubstituted-1,3-dienes via Head-to-Head Coupling of Terminal Alkynes and Addition of Carboxylic Acids Jacques Le Paih, Florian Monnier, Sylvie Dérien, Pierre H. Dixneuf, Eric Clot, and Odile Eisenstein pp 11964–11975 DOI: 10.1021/ja0349554 Supporting Info

Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO2 Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands:  Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO)3S (dmb = 4,4‘-Dimethyl-2,2‘-bipyridine, S = Solvent) Yukiko Hayashi, Shouichi Kita, Bruce S. Brunschwig, and Etsuko Fujita pp 11976–11987 DOI: 10.1021/ja035960a Supporting Info

Probing Residual Interactions in Unfolded Protein States Using NMR Spin Relaxation Techniques:  An Application to Δ131Δ Wing-Yiu Choy and Lewis E. Kay pp 11988–11992 DOI: 10.1021/ja035705q Supporting Info

Interfacial Solubilization of Model Amphiphilic Molecules in Block Copolymer Micelles Amira Choucair and Adi Eisenberg pp 11993–12000 DOI: 10.1021/ja036667d Supporting Info

Gas-Phase Ion Mobilities and Structures of Benzene Cluster Cations (C6H6)n+, n = 2−6 Mark J. Rusyniak, Yehia M. Ibrahim, Douglas L. Wright, Shiv N. Khanna, and M. Samy El-Shall pp 12001–12013 DOI: 10.1021/ja035504m

Photochemistry of Ortho, Ortho‘ Dialkyl Phenyl Azides Meng-Lin Tsao and Matthew S. Platz pp 12014–12025 DOI: 10.1021/ja035833e Supporting Info

Quantitative Evaluation of Experimental NMR Restraints Sander B. Nabuurs, Chris A. E. M. Spronk, Elmar Krieger, Hans Maassen, Gert Vriend, and Geerten W. Vuister pp 12026–12034 DOI: 10.1021/ja035440f

Theoretical Perspectives on the Reaction Mechanism of Serine Proteases:  The Reaction Free Energy Profiles of the Acylation Process Toyokazu Ishida and Shigeki Kato pp 12035–12048 DOI: 10.1021/ja021369m

Addition of Organometallic Compounds to Tin-Containing Cyclic Ketones. Remote Stereocontrol Induced by the Stannyl Group Asunción Barbero, Francisco J. Pulido, and Juan A. Rincón pp 12049–12056 DOI: 10.1021/ja036340c Supporting Info

Organolithiums:  Selectivity for Synthesis By Jonathan Clayden (University of Manchester). Pergamon (An Imprint of Elsevier Science, Ltd.):  Oxford. 2002. xvi + 384 pp. $45.00. ISBN 0-08-043261. Paul R. Carlier p 12057 DOI: 10.1021/ja033527v

Photoacoustic Infrared Spectroscopy By Kirk H. Michaelian (National Resources Canada). From the Series:  Chemical Analysis, Volume 159. Edited by J. D. Winefordner. John Wiley and Sons, Inc.:  Hoboken, NJ. 2003. xii + 336 pp. $125.00. ISBN 0-471-13477-5. Richard A. Palmer pp 12057–12058 DOI: 10.1021/ja033534j

Solvent-Free Organic Synthesis By Koichi Tanaka (Ehime University, Japan). Wiley-VCH GmbH & Co. KGaA:  Weinheim. 2003. x + 434 pp. $135.00. ISBN 3-527-30612-9. p 12058 DOI: 10.1021/ja0335667

Vacuum Technology:  Calculations in Chemistry By D. J. Hucknall (Leybold Vacuum, London) and A. Morris (University of Southampton, UK). Royal Society of Chemistry:  Cambridge. 2003. x + 234 pp. $89.95. ISBN 0-85404-651-8. p 12058 DOI: 10.1021/ja033570i

Glow Discharge Plasmas in Analytical Spectroscopy Edited by R. Kenneth Marcus (Clemson University) and José A. C. Broekaert (Universität Hamburg). John Wiley & Sons, Ltd.:  Chichester. 2003. xvi + 482 pp. $165.00. ISBN 0-471-60699-5. Lucia M. Babcock pp 12058–12059 DOI: 10.1021/ja033535b

Adsorbents:  Fundamentals and Applications By Ralph T. Yang (University of Michigan). Wiley-Interscience:  Hoboken, NJ. 2003. xii + 410 pp. $89.95. ISBN 0-471-29741-0. Mietek Jaroniec p 12059 DOI: 10.1021/ja033554l

Ionic Liquids in Synthesis Edited by Peter Wasserscheid (Institute for Technical and Macromolecular Chemistry, Aachen) and Thomas Welton (Imperial College of Science, London). Wiley-VCH:  Weinheim. 2003. xvi + 364 pp. $175.00. ISBN 3-527-30515-7. Richard A. Bartsch pp 12059–12060 DOI: 10.1021/ja033540f

Quantum Medicinal Chemistry Edited by Paolo Carloni (International School for Advanced Studies, Trieste) and Frank Alber (Rockefeller University). From the Series:  Methods and Principles in Medicinal Chemistry, Volume 17. Edited by Raimund Mannhold, Hugo Kubinyi, and Gerd Folkers. Wiley-VCH Verlag GmbH & Co.:  Weinheim. 2003. xviii + 281 pp. ISBN 3-527-30456-8. William A. Seitz p 12060 DOI: 10.1021/ja033548p

Issue 40

pH Responsive Eu(III)−Phenanthroline Supramolecular Conjugate:  Novel “Off−On−Off” Luminescent Signaling in the Physiological pH Range Thorfinnur Gunnlaugsson, Joseph P. Leonard, Katell Sénéchal, and Andrew J. Harte pp 12062–12063 DOI: 10.1021/ja035425a Supporting Info

Off-Resonance TROSY (R1ρ − R1) for Quantitation of Fast Exchange Processes in Large Proteins James G. Kempf, Ju-yeon Jung, Nicole S. Sampson, and J. Patrick Loria pp 12064–12065 DOI: 10.1021/ja037101s

What Should Be Impossible:  Resolution of the Mononuclear Gallium Coordination Complex, Tris(benzohydroxamato)gallium(III)1 Julia L. Brumaghim and Kenneth N. Raymond pp 12066–12067 DOI: 10.1021/ja0360283

Rational Design of Cavitand Receptors for Mass Sensors Michele Suman, Micol Freddi, Chiara Massera, Franco Ugozzoli, and Enrico Dalcanale pp 12068–12069 DOI: 10.1021/ja0355271 Supporting Info

Novel Polymer Capsules from Amphiphilic Graft Copolymers and Cross-Metathesis Kurt Breitenkamp and Todd Emrick pp 12070–12071 DOI: 10.1021/ja036561i Supporting Info

Bright Phosphorescence of a Trinuclear Copper(I) Complex:  Luminescence Thermochromism, Solvatochromism, and “Concentration Luminochromism” H. V. Rasika Dias, Himashinie V. K. Diyabalanage, Manal A. Rawashdeh-Omary, Matthew A. Franzman, and Mohammad A. Omary pp 12072–12073 DOI: 10.1021/ja036736o

A Selective Irreversible Inhibitor Targeting a PDZ Protein Interaction Domain Naoaki Fujii, Jose J. Haresco, Kathleen A. P. Novak, David Stokoe, Irwin D. Kuntz, and R. Kiplin Guy pp 12074–12075 DOI: 10.1021/ja035540l Supporting Info

Divergent Function in the Crotonase Superfamily:  An Anhydride Intermediate in the Reaction Catalyzed by 3-Hydroxyisobutyryl-CoA Hydrolase Brian J. Wong and John A. Gerlt pp 12076–12077 DOI: 10.1021/ja037652i

Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C−H Bonds with the Copper-Homoscorpionate Catalyst TpBr3Cu(NCMe) M. Mar Díaz-Requejo, Tomás R. Belderraín, M. Carmen Nicasio, Swiatoslaw Trofimenko, and Pedro J. Pérez pp 12078–12079 DOI: 10.1021/ja037072l

Identification of a Novel Michael Acceptor Group for the Reversible Addition of Oxygen- and Sulfur-Based Nucleophiles. Synthesis and Reactivity of the 3-Alkylidene-3H-indole 1-Oxide Function of Avrainvillamide Andrew G. Myers and Seth B. Herzon pp 12080–12081 DOI: 10.1021/ja0372006 Supporting Info

Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking:  Remarkable Thermal Behavior in a Solid Hidemitsu Uno, Akane Masumoto, and Noboru Ono pp 12082–12083 DOI: 10.1021/ja036203f Supporting Info

Synthesis of Substituted Oxindoles from α-Chloroacetanilides via Palladium-Catalyzed C−H Functionalization Edward J. Hennessy and Stephen L. Buchwald pp 12084–12085 DOI: 10.1021/ja037546g Supporting Info

A Selective Biomimetic Tweezer for Noradrenaline O. Molt, D. Rübeling, and T. Schrader pp 12086–12087 DOI: 10.1021/ja035212l Supporting Info

An Atypical Linear Cu(I)−S2 Center Constitutes the High-Affinity Metal-Sensing Site in the CueR Metalloregulatory Protein Kui Chen, Saodat Yuldasheva, James E. Penner-Hahn, and Thomas V. O'Halloran pp 12088–12089 DOI: 10.1021/ja036070y Supporting Info

Highly Self-Organized Electron Transfer from an Iridium Complex to p-Benzoquinone Due to Formation of a π-Dimer Radical Anion Complex Triply Bridged by Scandium Ions Junpei Yuasa, Tomoyoshi Suenobu, and Shunichi Fukuzumi pp 12090–12091 DOI: 10.1021/ja037098c Supporting Info

Helical Peptoid Mimics of Magainin-2 Amide James A. Patch and Annelise E. Barron pp 12092–12093 DOI: 10.1021/ja037320d Supporting Info

Asymmetric Morita−Baylis−Hillman Reactions Catalyzed by Chiral Brønsted Acids Nolan T. McDougal and Scott E. Schaus pp 12094–12095 DOI: 10.1021/ja037705w Supporting Info

Dip-Pen Nanolithography of Reactive Alkoxysilanes on Glass Hyungil Jung, Rajan Kulkarni, and C. Patrick Collier pp 12096–12097 DOI: 10.1021/ja0363720 Supporting Info

Single-Crystal Structures of Polymer Electrolytes Wesley A. Henderson, Neil R. Brooks, and Victor G. Young, Jr. pp 12098–12099 DOI: 10.1021/ja036535k Supporting Info

Determination of Long-Range Distances and Dynamic Order Parameters by Dipolar Recoupling in High-Resolution Magic-Angle Spinning NMR Spectroscopy Karena Thieme and Ingo Schnell pp 12100–12101 DOI: 10.1021/ja037374n Supporting Info

Stereoselective cis-Addition of Aromatic C−H Bonds to Alkynes Catalyzed by Dinuclear Palladium Complexes Naofumi Tsukada, Tomohiro Mitsuboshi, Hiroyuki Setoguchi, and Yoshio Inoue pp 12102–12103 DOI: 10.1021/ja0375075 Supporting Info

Palladium-Catalyzed Nucleophilic Benzylic Substitutions of Benzylic Esters Ryoichi Kuwano, Yutaka Kondo, and Yosuke Matsuyama pp 12104–12105 DOI: 10.1021/ja037735z Supporting Info

A Stereodivergent Approach to Chiral Nonracemic N-Protected α,α-Dialkylated Amino Acids Claude Spino and Cédrickx Gobdout pp 12106–12107 DOI: 10.1021/ja037078a Supporting Info

The Intramolecular Carboxyarylation Approach to Podophyllotoxin Aaron J. Reynolds, Andrew J. Scott, Craig I. Turner, and Michael S. Sherburn pp 12108–12109 DOI: 10.1021/ja0376588 Supporting Info

Dendrimeric Pyridoxamine Enzyme Mimics Lei Liu and Ronald Breslow pp 12110–12111 DOI: 10.1021/ja0374473 Supporting Info

Resonance Raman Imaging of the NADPH Oxidase Subunit Cytochrome b558 in Single Neutrophilic Granulocytes Henk-Jan van Manen, Natallia Uzunbajakava, Robin van Bruggen, Dirk Roos, and Cees Otto pp 12112–12113 DOI: 10.1021/ja036973r

Synthesis and Characterization of Aliphatic α-Dithiones, Di(1-adamantyl)- and Di-tert-butylethanedithiones Yutaka Ono, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama pp 12114–12115 DOI: 10.1021/ja0371496 Supporting Info

Electrophilic Aromatic Chlorination and Haloperoxidation of Chloride Catalyzed by Polyfluorinated Alcohols:  A New Manifestation of Template Catalysis Revital Ben-Daniel, Samuël P. de Visser, Sason Shaik, and Ronny Neumann pp 12116–12117 DOI: 10.1021/ja0364524 Supporting Info

Ternary Copper Complexes for Photocleavage of DNA by Red Light:  Direct Evidence for Sulfur-to-Copper Charge Transfer and d−d Band Involvement Shanta Dhar, Dulal Senapati, Puspendu K. Das, Pabitra Chattopadhyay, Munirathinam Nethaji, and Akhil R. Chakravarty pp 12118–12124 DOI: 10.1021/ja036681q Supporting Info

Synthesis and Properties of RNA Analogues Having Amides as Interuridine Linkages at Selected Positions Eriks Rozners, Dace Katkevica, Erika Bizdena, and Roger Strömberg pp 12125–12136 DOI: 10.1021/ja0360900 Supporting Info

Molecular Assembly of C2-Symmetric Bis-(2S)-2-methyldodecanoylamides of α,ω-Alkylidenediamines into Coiled Coil and Twisted Ribbon Aggregates Takaaki Sumiyoshi, Katsumi Nishimura, Minoru Nakano, Tetsuro Handa, Yoshihisa Miwa, and Kiyoshi Tomioka pp 12137–12142 DOI: 10.1021/ja035085t Supporting Info

Ruthenium(II)-Catalyzed Selective Intramolecular [2 + 2 + 2] Alkyne Cyclotrimerizations Yoshihiko Yamamoto, Takayasu Arakawa, Ryuji Ogawa, and Kenji Itoh pp 12143–12160 DOI: 10.1021/ja0358697 Supporting Info

Stable (Long-Bonded) Dimers via the Quantitative Self-Association of Different Cationic, Anionic, and Uncharged π-Radicals:  Structures, Energetics, and Optical Transitions Jian-Ming Lü, Sergiy V. Rosokha, and Jay K. Kochi pp 12161–12171 DOI: 10.1021/ja0364928 Supporting Info

Asymmetric, Stereocontrolled Total Synthesis of Paraherquamide A Robert M. Williams, Jianhua Cao, Hidekazu Tsujishima, and Rhona J. Cox pp 12172–12178 DOI: 10.1021/ja036713+ Supporting Info

The Polyhomologation of 1-Boraadamantane:  Mapping the Migration Pathways of a Propagating Macrotricyclic Trialkylborane Carl E. Wagner, Jang-Seob Kim, and Kenneth J. Shea pp 12179–12195 DOI: 10.1021/ja0361291 Supporting Info

Syntheses, Conformations, and Basicities of Bicyclic Triamines Thomas W. Bell, Heung-Jin Choi, William Harte, and Michael G. B. Drew pp 12196–12210 DOI: 10.1021/ja030236d Supporting Info

Ordered Reactive Nanomembranes/Nanotemplates from Thin Films of Block Copolymer Supramolecular Assembly Alexander Sidorenko, Igor Tokarev, Sergiy Minko, and Manfred Stamm pp 12211–12216 DOI: 10.1021/ja036085w

Slow Hydrogen Atom Self-Exchange between Os(IV) Anilide and Os(III) Aniline Complexes:  Relationships with Electron and Proton Transfer Self-Exchange Jake D. Soper and James M. Mayer pp 12217–12229 DOI: 10.1021/ja036328k Supporting Info

Thermodynamic Hydride Donor Abilities of [HW(CO)4L]- Complexes (L = PPh3, P(OMe)3, CO) and Their Reactions with [C5Me5Re(PMe3)(NO)(CO)]+ William W. Ellis, Rebecca Ciancanelli, Susie M. Miller, James W. Raebiger, M. Rakowski DuBois, and Daniel L. DuBois pp 12230–12236 DOI: 10.1021/ja036524r Supporting Info

Copper Complexes of Nitrogen-Anchored Tripodal N-Heterocyclic Carbene Ligands Xile Hu, Ingrid Castro-Rodriguez, and Karsten Meyer pp 12237–12245 DOI: 10.1021/ja036880+ Supporting Info

A 6π + 6π Potentially Antiaromatic Zwitterion Preferred to a Quinoidal Structure:  Its Reactivity Toward Organic and Inorganic Reagents Pierre Braunstein, Olivier Siri, Jean-philippe Taquet, Marie-Madeleine Rohmer, Marc Bénard, and Richard Welter pp 12246–12256 DOI: 10.1021/ja0354622 Supporting Info

Tuning the Valence of the Cerium Center in (Na)phthalocyaninato and Porphyrinato Cerium Double-Deckers by Changing the Nature of the Tetrapyrrole Ligands Yongzhong Bian, Jianzhuang Jiang, Ye Tao, Michael T. M. Choi, Renjie Li, Anthony C. H. Ng, Peihua Zhu, Na Pan, Xuan Sun, Dennis P. Arnold, Zhong-Yuan Zhou, Hung-Wing Li, Thomas C. W. Mak, and Dennis K. P. Ng pp 12257–12267 DOI: 10.1021/ja036017+ Supporting Info

Combined Experimental/Theoretical Refinement of Indole Ring Geometry Using Deuterium Magnetic Resonance and ab Initio Calculations Roger E. Koeppe, II, Haiyan Sun, Patrick C. A. van der Wel, Erin M. Scherer, Peter Pulay, and Denise V. Greathouse pp 12268–12276 DOI: 10.1021/ja035052d Supporting Info

Solid-State Supramolecular Organization, Established Directly from Powder Diffraction Data, and Photoluminescence Efficiency of Rigid-Core Oligothiophene-S,S-dioxides Emilio Tedesco, Fabio Della Sala, Laura Favaretto, Giovanna Barbarella, David Albesa-Jové, Dario Pisignano, Giuseppe Gigli, Roberto Cingolani, and Kenneth D. M. Harris pp 12277–12283 DOI: 10.1021/ja035570o

Synthesis, Photophysical and Nonlinear Optical Properties of Macromolecular Architectures Featuring Octupolar Tris(bipyridine) Ruthenium(II) Moieties:  Evidence for a Supramolecular Self-Ordering in a Dentritic Structure Thomas Le Bouder, Olivier Maury, Arnaud Bondon, Karine Costuas, Edmond Amouyal, Isabelle Ledoux, Joseph Zyss, and Hubert Le Bozec pp 12284–12299 DOI: 10.1021/ja030296j Supporting Info

Donor−Acceptor Phthalocyanine Nanoaggregates Andrés de la Escosura, M. Victoria Martínez-Díaz, Pall Thordarson, Alan E. Rowan, Roeland J. M. Nolte, and Tomás Torres pp 12300–12308 DOI: 10.1021/ja030038m Supporting Info

Dynamic Equilibrium of a Supramolecular Dimeric Rhomboid and Trimeric Hexagon and Determination of Its Thermodynamic Constants Takuya Yamamoto, Atta M. Arif, and Peter J. Stang pp 12309–12317 DOI: 10.1021/ja0302984 Supporting Info

Computational Evidence for Methyl-Donated Hydrogen Bonds and Hydrogen-Bond Networking in 1,2-Ethanediol−Dimethyl Sulfoxide Robert A. Vergenz, Ibrahim Yazji, Christi Whittington, Jaimee Daw, and King Tu Tran pp 12318–12327 DOI: 10.1021/ja036516a Supporting Info

Reactions That Generate Aromatic Molecules:  Is Aromatic Stabilization Less or More Advanced than Bond Changes at the Transition State? Kinetic and Thermodynamic Acidities of Rhenium Carbene Complexes Claude F. Bernasconi, Mark L. Ragains, and Santanu Bhattacharya pp 12328–12336 DOI: 10.1021/ja030229p Supporting Info

A High-Frequency and High-Field EPR Study of New Azide and Fluoride Mononuclear Mn(III) Complexes Claire Mantel, Alia K. Hassan, Jacques Pécaut, Alain Deronzier, Marie-Noëlle Collomb, and Carole Duboc-Toia pp 12337–12344 DOI: 10.1021/ja034652+ Supporting Info

Adiabatic Single Scan Two-Dimensional NMR Spectrocopy Philippe Pelupessy pp 12345–12350 DOI: 10.1021/ja034958g Supporting Info

Unusual Chemistry of the Complex Mg•+(2-Fluoropyridine) Activated by the Photoexcitation of Mg•+ Hai-Chuan Liu, Shihe Yang, Xin-Hao Zhang, and Yun-Dong Wu pp 12351–12357 DOI: 10.1021/ja036476a Supporting Info

C−H- - -O Hydrogen Bonds in β-Sheetlike Networks:  Combined X-ray Crystallography and High-Pressure Infrared Study Kwang Ming Lee, Hai-Chou Chang, Jyh-Chiang Jiang, Jack C. C. Chen, Hsiang-En Kao, Sheng Hsien Lin, and Ivan J. B. Lin pp 12358–12364 DOI: 10.1021/ja036719z Supporting Info

Issue 41

Noncyclic [10-S-5] Sulfuranide Dioxide Salts with Three S−C Bonds:  A New Class of Stable Hypervalent Compounds Dmitri V. Sevenard, Alexander A. Kolomeitsev, Berthold Hoge, Enno Lork, and Gerd-Volker Röschenthaler pp 12366–12367 DOI: 10.1021/ja030155h Supporting Info

Inter- and Intramolecular Activation of Aromatic C−H Bonds by Diphosphine and Hydrido-Bridged Dinuclear Iridium Complexes Ken-ichi Fujita, Hirohide Nakaguma, Taro Hamada, and Ryohei Yamaguchi pp 12368–12369 DOI: 10.1021/ja036929b Supporting Info

Fluorogenic Resolution of Ligand Binding by a Nucleic Acid Aptamer Edward J. Merino and Kevin M. Weeks pp 12370–12371 DOI: 10.1021/ja035299a Supporting Info

Highly Sensitive in Vitro Selections for DNA-Linked Synthetic Small Molecules with Protein Binding Affinity and Specificity Jeffrey B. Doyon, Thomas M. Snyder, and David R. Liu pp 12372–12373 DOI: 10.1021/ja036065u Supporting Info

Cellular Uptake of Aminoglycosides, Guanidinoglycosides, and Poly-arginine Nathan W. Luedtke, Peter Carmichael, and Yitzhak Tor pp 12374–12375 DOI: 10.1021/ja0360135 Supporting Info

A New Fluoride Selective Fluorescent as Well as Chromogenic Chemosensor Containing a Naphthalene Urea Derivative Eun Jin Cho, Jung Wha Moon, Seung Whan Ko, Jin Yong Lee, Sook Kyung Kim, Juyoung Yoon, and Kye Chun Nam pp 12376–12377 DOI: 10.1021/ja036248g Supporting Info

Understanding the Mechanism of H+-Induced Demetalation as a Design Strategy for Robust Iron(III) Peroxide-Activating Catalysts Anindya Ghosh, Alexander D. Ryabov, Sherry M. Mayer, David C. Horner, Duane E. Prasuhn, Jr., Sayam Sen Gupta, Leonard Vuocolo, Caleb Culver, Michael P. Hendrich, Cliffton E. F. Rickard, Richard E. Norman, Colin P. Horwitz, and Terrence J. Collins pp 12378–12379 DOI: 10.1021/ja0367344 Supporting Info

Stereospecific Radical Polymerization of N-Triphenylmethylmethacrylamides Leading to Highly Isotactic Helical Polymers Naohiro Hoshikawa, Yuji Hotta, and Yoshio Okamoto pp 12380–12381 DOI: 10.1021/ja035871y Supporting Info

Structure of Antibacterial Peptide Microcin J25:  A 21-Residue Lariat Protoknot Marvin J. Bayro, Jayanta Mukhopadhyay, G. V. T. Swapna, Janet Y. Huang, Li-Chung Ma, Elena Sineva, Philip E. Dawson, Gaetano T. Montelione, and Richard H. Ebright pp 12382–12383 DOI: 10.1021/ja036677e Supporting Info

Large Oriented Arrays and Continuous Films of TiO2-Based Nanotubes Zhengrong R. Tian, James A. Voigt, Jun Liu, Bonnie Mckenzie, and Huifang Xu pp 12384–12385 DOI: 10.1021/ja0369461

2,3,4- or 2,3,5-Trisubstituted Furans:  Catalyst-Controlled Highly Regioselective Ring-Opening Cycloisomerization Reaction of Cyclopropenyl Ketones Shengming Ma and Junliang Zhang pp 12386–12387 DOI: 10.1021/ja036616g Supporting Info

Heteroepitaxial Growth of a Zeolite Film with a Patterned Surface-Texture Toru Wakihara, Shigehiro Yamakita, Kumiko Iezumi, and Tatsuya Okubo pp 12388–12389 DOI: 10.1021/ja0363765 Supporting Info

Targeting the Transcriptional Machinery with Unique Artificial Transcriptional Activators Zhiqian Wu, Garrette Belanger, Brian B. Brennan, Jenifer K. Lum, Aaron R. Minter, Steven P. Rowe, Annette Plachetka, Chinmay Y. Majmudar, and Anna K. Mapp pp 12390–12391 DOI: 10.1021/ja036685v Supporting Info

Synthesis of Monodisperse Polymers from Proteins Jerry Yang, Irina Gitlin, Vijay M. Krishnamurthy, Jenny A. Vazquez, Catherine E. Costello, and George M. Whitesides pp 12392–12393 DOI: 10.1021/ja035978l Supporting Info

Amine-Catalyzed Coupling of Allenic Esters to α,β-Unsaturated Carbonyls Catherine A. Evans and Scott J. Miller pp 12394–12395 DOI: 10.1021/ja0377798 Supporting Info

Photoinduced Magnetization of the Cyano-Bridged 3d−4f Heterobimetallic Assembly Nd(DMF)4(H2O)3(μ-CN)Fe(CN)5·H2O (DMF = N,N-Dimethylformamide) Guangming Li, Takashiro Akitsu, Osamu Sato, and Yasuaki Einaga pp 12396–12397 DOI: 10.1021/ja037183k Supporting Info

Reaching into the Major Groove of B-DNA:  Synthesis and Nucleic Acid Binding of a Neomycin−Hoechst 33258 Conjugate Dev P. Arya and Bert Willis pp 12398–12399 DOI: 10.1021/ja036742k Supporting Info

Single-Crystal-to-Single-Crystal Topochemical Polymerizations of a Terminal Diacetylene:  Two Remarkable Transformations Give the Same Conjugated Polymer Xi Ouyang, Frank W. Fowler, and Joseph W. Lauher pp 12400–12401 DOI: 10.1021/ja037557+ Supporting Info

Improving the Performance of Methylalumoxane:  A Facile and Efficient Method to Trap “Free” Trimethylaluminum Vincenzo Busico, Roberta Cipullo, Francesco Cutillo, Nic. Friederichs, Sara Ronca, and Bing Wang pp 12402–12403 DOI: 10.1021/ja0372412 Supporting Info

Gas-Phase Peptide/Protein Cationizing Agent Switching via Ion/Ion Reactions Kelly A. Newton and Scott A. McLuckey pp 12404–12405 DOI: 10.1021/ja036924e

A Palladium-Catalyzed Glycosylation Reaction:  The de Novo Synthesis of Natural and Unnatural Glycosides Ravula Satheesh Babu and George A. O'Doherty pp 12406–12407 DOI: 10.1021/ja037097k Supporting Info

Structure of Colloidal Bismuth Subcitrate (CBS) in Dilute HCl:  Unique Assembly of Bismuth Citrate Dinuclear Units ([Bi(cit)2Bi]2-) Wei Li, Lan Jin, Nianyong Zhu, Xuemei Hou, Feng Deng, and Hongzhe Sun pp 12408–12409 DOI: 10.1021/ja037019x Supporting Info

DNA-Templated Metal Catalysis Jens Brunner, Andriy Mokhir, and Roland Kraemer pp 12410–12411 DOI: 10.1021/ja0365429 Supporting Info

Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity Carolyn E. Anderson and Larry E. Overman pp 12412–12413 DOI: 10.1021/ja037086r Supporting Info

Active-Site Coating for Molecular Discrimination in Heterogeneous Catalysis Paul Collier, Stan Golunski, Chan Malde, John Breen, and Robbie Burch pp 12414–12415 DOI: 10.1021/ja037136s Supporting Info

Self-Promoted Electron Transfer from Cobalt(II) Porphyrin to p-Fluoranil To Produce a Dimer Radical Anion-Cobalt(III) Porphyrin Complex Ken Okamoto and Shunichi Fukuzumi pp 12416–12417 DOI: 10.1021/ja036747h Supporting Info

Laser Flash Photolysis Formation and Direct Kinetic Studies of Manganese(V)-Oxo Porphyrin Intermediates Rui Zhang and Martin Newcomb pp 12418–12419 DOI: 10.1021/ja0377448 Supporting Info

Synthesis of Poly(biphenylene ruthenacyclopentatrienylene), a New Organometallic Conducting Polymer with Ferromagnetic Interaction in Its Reduced State Masashi Kurashina, Masaki Murata, Tokuko Watanabe, and Hiroshi Nishihara pp 12420–12421 DOI: 10.1021/ja036934f Supporting Info

Methyl/Ethyl Differentiation in Diastereoselective Hydride Addition to [Tp‘W(CO)(PhCCMe)(NHCMeEt)][BAr‘4] Neil J. Vogeley, Peter S. White, and Joseph L. Templeton pp 12422–12423 DOI: 10.1021/ja035467z Supporting Info

Rapid Two-Step Synthesis of Mitrin from Heparosan:  A Replacement for Heparin Balagurunathan Kuberan, David L. Beeler, Roger Lawrence, Miroslaw Lech, and Robert D. Rosenberg pp 12424–12425 DOI: 10.1021/ja036737g Supporting Info

Nickel-Catalyzed Highly Regio- and Stereoselective Three-Component Assembly of Allenes, Aryl Iodides, and Alkenylzirconium Reagents Ming-Si Wu, Dinesh Kumar Rayabarapu, and Chien-Hong Cheng pp 12426–12427 DOI: 10.1021/ja037718+ Supporting Info

Conical Intersections of Three Electronic States Affect the Ground State of Radical Species with Little or No Symmetry:  Pyrazolyl Spiridoula Matsika and David R. Yarkony pp 12428–12429 DOI: 10.1021/ja037925+

Extended π-Conjugated Dendrimers Based on Truxene Xiao-Yu Cao, Wen-Bin Zhang, Jin-Liang Wang, Xing-Hua Zhou, Hua Lu, and Jian Pei pp 12430–12431 DOI: 10.1021/ja037723d Supporting Info

Probing the Kinetic Landscape of Transient Peptide−Protein Interactions by Use of Peptide 15N NMR Relaxation Dispersion Spectroscopy:  Binding of an Antithrombin Peptide to Human Prothrombin Dmitri Tolkatchev, Ping Xu, and Feng Ni pp 12432–12442 DOI: 10.1021/ja021238l

The Kinetics of Helix Unfolding of an Azobenzene Cross-Linked Peptide Probed by Nanosecond Time-Resolved Optical Rotatory Dispersion Eefei Chen, Janet R. Kumita, G. Andrew Woolley, and David S. Kliger pp 12443–12449 DOI: 10.1021/ja030277+

Nanosecond Photoreduction of Cytochrome P450cam by Channel-Specific Ru-diimine Electron Tunneling Wires Alexander R. Dunn, Ivan J. Dmochowski, Jay R. Winkler, and Harry B. Gray pp 12450–12456 DOI: 10.1021/ja0294111 Supporting Info

Electron Transfer Reactions of Redox Cofactors in Spinach Photosystem I Reaction Center Protein in Lipid Films on Electrodes Bernard Munge, Somes K. Das, Robielyn Ilagan, Zeus Pendon, Jing Yang, Harry A. Frank, and James F. Rusling pp 12457–12463 DOI: 10.1021/ja036671p

Microcin J25 Has a Threaded Sidechain-to-Backbone Ring Structure and Not a Head-to-Tail Cyclized Backbone K. Johan Rosengren, Richard J. Clark, Norelle L. Daly, Ulf Göransson, Alun Jones, and David J. Craik pp 12464–12474 DOI: 10.1021/ja0367703 Supporting Info

Structure of Microcin J25, a Peptide Inhibitor of Bacterial RNA Polymerase, is a Lassoed Tail Kelly-Anne Wilson, Markus Kalkum, Jennifer Ottesen, Julia Yuzenkova, Brian T. Chait, Robert Landick, Tom Muir, Konstantin Severinov, and Seth A. Darst pp 12475–12483 DOI: 10.1021/ja036756q Supporting Info

Rapid Sample-Mixing Technique for Transient NMR and Photo-CIDNP Spectroscopy:  Applications to Real-Time Protein Folding K. Hun Mok, Toshio Nagashima, Iain J. Day, Jonathan A. Jones, Charles J. V. Jones, Christopher M. Dobson, and P. J. Hore pp 12484–12492 DOI: 10.1021/ja036357v

Intervalence Near-IR Spectra of Delocalized Dinitroaromatic Radical Anions Stephen F. Nelsen, Asgeir E. Konradsson, Michael N. Weaver, and João P. Telo pp 12493–12501 DOI: 10.1021/ja036066m Supporting Info

Chiral Ru-Based Complexes for Asymmetric Olefin Metathesis:  Enhancement of Catalyst Activity through Steric and Electronic Modifications Joshua J. Van Veldhuizen, Dennis G. Gillingham, Steven B. Garber, Osamu Kataoka, and Amir H. Hoveyda pp 12502–12508 DOI: 10.1021/ja0302228 Supporting Info

Excited-State Singlet Manifold and Oscillatory Features of a Nonatetraeniminium Retinal Chromophore Model Alessandro Cembran, Fernando Bernardi, Massimo Olivucci, and Marco Garavelli pp 12509–12519 DOI: 10.1021/ja030215j Supporting Info

Theoretical Analysis of Residual Dipolar Coupling Patterns in Regular Secondary Structures of Proteins Alessandro Mascioni and Gianluigi Veglia pp 12520–12526 DOI: 10.1021/ja0354824

Palladium-Catalyzed Negishi Cross-Coupling Reactions of Unactivated Alkyl Iodides, Bromides, Chlorides, and Tosylates Jianrong Zhou and Gregory C. Fu pp 12527–12530 DOI: 10.1021/ja0363258 Supporting Info

Nanocrystals Modified with Peptide Nucleic Acids (PNAs) for Selective Self-Assembly and DNA Detection Raj Chakrabarti and Alexander M. Klibanov pp 12531–12540 DOI: 10.1021/ja035399g Supporting Info

Nonenzymatic Breakdown of the Tetrahedral (α-Carboxyketal Phosphate) Intermediates of MurA and AroA, Two Carboxyvinyl Transferases. Protonation of Different Functional Groups Controls the Rate and Fate of Breakdown Bartosz Byczynski, Shehadeh Mizyed, and Paul J. Berti pp 12541–12550 DOI: 10.1021/ja0349655

Substrate Recognition and Channeling of Monomodules from the Pikromycin Polyketide Synthase Brian J. Beck, Courtney C. Aldrich, Robert A. Fecik, Kevin A. Reynolds, and David H. Sherman pp 12551–12557 DOI: 10.1021/ja034841s Supporting Info

Dendrimeric Organochalcogen Catalysts for the Activation of Hydrogen Peroxide:  Origins of the “Dendrimer Effect” with Catalysts Terminating in Phenylseleno Groups Michael D. Drake, Frank V. Bright, and Michael R. Detty pp 12558–12566 DOI: 10.1021/ja0367593 Supporting Info

Large-Scale Synthesis of Nearly Monodisperse CdSe/CdS Core/Shell Nanocrystals Using Air-Stable Reagents via Successive Ion Layer Adsorption and Reaction J. Jack Li, Y. Andrew Wang, Wenzhuo Guo, Joel C. Keay, Tetsuya D. Mishima, Matthew B. Johnson, and Xiaogang Peng pp 12567–12575 DOI: 10.1021/ja0363563

Highly Regio- and Stereoselective Acylboration, Acylsilation, and Acylstannation of Allenes Catalyzed by Phosphine-Free Palladium Complexes:  An Efficient Route to a New Class of 2-Acylallylmetal Reagents Feng-Yu Yang, Muthian Shanmugasundaram, Shih-Yih Chuang, Po-Jen Ku, Ming-Yuan Wu, and Chien-Hong Cheng pp 12576–12583 DOI: 10.1021/ja036021l Supporting Info

Organolathanide-Catalyzed Regioselective Intermolecular Hydroamination of Alkenes, Alkynes, Vinylarenes, Di- and Trivinylarenes, and Methylenecyclopropanes. Scope and Mechanistic Comparison to Intramolecular Cyclohydroaminations Jae-Sang Ryu, George Yanwu Li, and Tobin J. Marks pp 12584–12605 DOI: 10.1021/ja035867m

Crystal Environments Probed by EPR Spectroscopy. Variations in the EPR Spectra of CoII(octaethylporphyrin) Doped in Crystalline Diamagnetic Hosts and a Reassessment of the Electronic Structure of Four-Coordinate Cobalt(II) Andrew Ozarowski, Hon Man Lee, and Alan L. Balch pp 12606–12614 DOI: 10.1021/ja030221f Supporting Info

Electronic Structure of Linear Thiophenolate-Bridged Heteronuclear Complexes [LFeMFeL]n+ (M = Cr, Co, Fe; n = 1−3):  A Combination of Kinetic Exchange Interaction and Electron Delocalization Liviu F. Chibotaru, Jean-Jacques Girerd, Geneviève Blondin, Thorsten Glaser, and Karl Wieghardt pp 12615–12630 DOI: 10.1021/ja030027t Supporting Info

Synthesis, Cyclic Voltammetric Studies, and Electrogenerated Chemiluminescence of a New Phenylquinoline-Biphenothiazine Donor−Acceptor Molecule Rebecca Y. Lai, Xiangxing Kong, Samson A. Jenekhe, and Allen J. Bard pp 12631–12639 DOI: 10.1021/ja036600q Supporting Info

Analysis of Proton−Proton Transfer Dynamics in Rotating Solids and Their Use for 3D Structure Determination Adam Lange, Karsten Seidel, Laurent Verdier, Sorin Luca, and Marc Baldus pp 12640–12648 DOI: 10.1021/ja034555g Supporting Info

Single-Molecule Spectroscopy of Interfacial Electron Transfer Michael W. Holman, Ruchuan Liu, and David M. Adams pp 12649–12654 DOI: 10.1021/ja0343104 Supporting Info

Oxidation Mechanism of Aromatic Peroxy and Bicyclic Radicals from OH−Toluene Reactions Inseon Suh, Renyi Zhang, Luisa T. Molina, and Mario J. Molina pp 12655–12665 DOI: 10.1021/ja0350280 Supporting Info

A Recyclable Chiral Ru Catalyst for Enantioselective Olefin Metathesis. Efficient Catalytic Asymmetric Ring-Opening/Cross Metathesis in Air [J. Am. Chem. Soc. 2002, 124, 4954−4955]. Joshua J. Van Veldhuizen, Steven B. Garber, Jason S. Kingsbury, and Amir H. Hoveyda p 12666 DOI: 10.1021/ja033454f

Enantioselective Total Synthesis of Borrelidin  [J. Am. Chem. Soc. 2003, 125, 1458−1459].  Matthew O. Duffey, Arnaud LeTiran, and James P. Morken p 12666 DOI: 10.1021/ja0334560

“@-Tides”:  The 1,2-Dihydro-3(6H)-pyridinone Unit as a β-Strand Mimic [J. Am. Chem. Soc. 2002, 124, 58−66]. Scott T. Phillips, Miroslav Rezac, Ulrich Abel, Michael Kossenjans, and Paul A. Bartlett p 12666 DOI: 10.1021/ja033457s

Issue 42

Protein Surface Recognition by Rational Design:  Nanomolar Ligands for Potassium Channels Stefan N. Gradl, John P. Felix, Ehud Y. Isacoff, Maria L. Garcia, and Dirk Trauner pp 12668–12669 DOI: 10.1021/ja036155z Supporting Info

Distinguishing Rate-Limiting Electron versus H-Atom Transfers in Cu2(O2)-Mediated Oxidative N-Dealkylations:  Application of Inter- versus Intramolecular Kinetic Isotope Effects Jason Shearer, Christiana Xin Zhang, Lanying Q. Hatcher, and Kenneth D. Karlin pp 12670–12671 DOI: 10.1021/ja0359409 Supporting Info

Enantioselective Michael Reaction of Malonates to Nitroolefins Catalyzed by Bifunctional Organocatalysts Tomotaka Okino, Yasutaka Hoashi, and Yoshiji Takemoto pp 12672–12673 DOI: 10.1021/ja036972z Supporting Info

C−H Bond Activation by Unsymmetrical 2-(N-Arylimino)pyrrolide Pt Complexes:  Geometric Effects on Reactivity Carl N. Iverson, Charles A. G. Carter, R. Tom Baker, John D. Scollard, Jay A. Labinger, and John E. Bercaw pp 12674–12675 DOI: 10.1021/ja036511d Supporting Info

Regioselective Bond Cleavage in the Dissociative Electron Transfer to Benzyl Thiocyanates Abdelaziz Houmam, Emad M. Hamed, Philippe Hapiot, John M. Motto, and Adrian L. Schwan pp 12676–12677 DOI: 10.1021/ja036710x Supporting Info

Formation and Isolation of an Iron-Tripyrrole Complex from Heme Degradation Sankar Prasad Rath, Marilyn M. Olmstead, Lechoslaw Latos-Grażyński, and Alan L. Balch pp 12678–12679 DOI: 10.1021/ja036656k Supporting Info

Aqueous Self-Assembly of Unsymmetric Peptide Bolaamphiphiles into Nanofibers with Hydrophilic Cores and Surfaces Randal C. Claussen, Bryan M. Rabatic, and Samuel I. Stupp pp 12680–12681 DOI: 10.1021/ja035882r Supporting Info

Assembly of a Supramolecular Cube, [(Cp*WS3Cu3)8Cl8(CN)12Li4] from a Preformed Incomplete Cubane-like Compound [PPh4][Cp*WS3(CuCN)3] Jian-Ping Lang, Qing-Feng Xu, Zhong-Ning Chen, and Brendan F. Abrahams pp 12682–12683 DOI: 10.1021/ja036995d Supporting Info

Tetrahedranyllithium:  Synthesis, Characterization, and Reactivity Akira Sekiguchi and Masanobu Tanaka pp 12684–12685 DOI: 10.1021/ja030476t Supporting Info

Shell Cross-Linked Cylinders of Polyisoprene-b-ferrocenyldimethylsilane:  Formation of Magnetic Ceramic Replicas and Microfluidic Channel Alignment and Patterning Xiao-Song Wang, André Arsenault, Geoffrey A. Ozin, Mitchell A. Winnik, and Ian Manners pp 12686–12687 DOI: 10.1021/ja037521h Supporting Info

[(Th2F5)(NC7H5O4)2(H2O)][NO3]:  An Actinide−Organic Open Framework Jong-Young Kim, Alexander J. Norquist, and Dermot O'Hare pp 12688–12689 DOI: 10.1021/ja036832p Supporting Info

Ultrathin Cross-Linked Nanoparticle Membranes Yao Lin, Habib Skaff, Alexander Böker, A. D. Dinsmore, Todd Emrick, and Thomas P. Russell pp 12690–12691 DOI: 10.1021/ja036919a

A New Copper Acetate-Bis(oxazoline)-Catalyzed, Enantioselective Henry Reaction David A. Evans, Daniel Seidel, Magnus Rueping, Hon Wai Lam, Jared T. Shaw, and C. Wade Downey pp 12692–12693 DOI: 10.1021/ja0373871 Supporting Info

Stereoselective Intramolecular [4 + 3] Cycloadditions of Nitrogen-Stabilized Chiral Oxyallyl Cations via Epoxidation of N-Tethered Allenamides Hui Xiong, Jian Huang, Sunil K. Ghosh, and Richard P. Hsung pp 12694–12695 DOI: 10.1021/ja030416n Supporting Info

Three-Dimensional Self-Assembly of Metallic Rods with Submicron Diameters Using Magnetic Interactions J. Christopher Love, Adam R. Urbach, Mara G. Prentiss, and George M. Whitesides pp 12696–12697 DOI: 10.1021/ja037642h Supporting Info

New Insights into the Reaction of Zinc Alkyls with Dioxygen Janusz Lewiński, Wojciech Marciniak, Janusz Lipkowski, and Iwona Justyniak pp 12698–12699 DOI: 10.1021/ja036020t Supporting Info

Cine-Substitution in the Stille Coupling:  Evidence for the Carbenoid Reactivity of sp3-gem-Organodimetallic Iodopalladio-trialkylstannylalkane Intermediates Eric Fillion and Nicholas J. Taylor pp 12700–12701 DOI: 10.1021/ja037409j Supporting Info

Mechanistic Studies of the Addition of Carbonyl Compounds to Tetramesityldigermene Mini S. Samuel and Kim M. Baines pp 12702–12703 DOI: 10.1021/ja036848f Supporting Info

Sub-100 nm Confinement of Magnetic Nanoparticles Using Localized Magnetic Field Gradients Adam R. Urbach, J. Christopher Love, Mara G. Prentiss, and George M. Whitesides pp 12704–12705 DOI: 10.1021/ja0378308 Supporting Info

An Experimental Look into Subelectron Charge Flow Roie Yerushalmi, Kim K. Baldridge, and Avigdor Scherz pp 12706–12707 DOI: 10.1021/ja035946y Supporting Info

Polyketide Chain Length Control by Chain Length Factor Yi Tang, Shiou-Chuan Tsai, and Chaitan Khosla pp 12708–12709 DOI: 10.1021/ja0378759 Supporting Info

Ab Initio Excited-State Dynamics of the Photoactive Yellow Protein Chromophore Chaehyuk Ko, Benjamin Levine, A. Toniolo, Leslie Manohar, Seth Olsen, Hans-Joachim Werner, and Todd J. Martínez pp 12710–12711 DOI: 10.1021/ja0365025 Supporting Info

Naphtho[2,3-a]pyrene Forms Chiral Domains on Au(111) C. Brian France and B. A. Parkinson pp 12712–12713 DOI: 10.1021/ja037056o

Nonspecificity Induces Chiral Specificity in the Folding Transition of Giant DNA Michiko Ito, Akira Sakakura, Naomi Miyazawa, Shizuaki Murata, and Kenichi Yoshikawa pp 12714–12715 DOI: 10.1021/ja036745x Supporting Info

Bis(carbene)pyridine Complexes of Cr(III):  Exceptionally Active Catalysts for the Oligomerization of Ethylene David S. McGuinness, Vernon C. Gibson, Duncan F. Wass, and Jonathan W. Steed pp 12716–12717 DOI: 10.1021/ja037217o Supporting Info

Hydrophobically Directed Selective Reduction of Ketones Mark R. Biscoe and Ronald Breslow pp 12718–12719 DOI: 10.1021/ja0379924 Supporting Info

Synthesis of Furanophane Derivatives through [8+2]-Cycloaddition of Dienylisobenzofurans and Alkynes Yumei Luo, James W. Herndon, and Francisco Cervantes-Lee pp 12720–12721 DOI: 10.1021/ja037500n Supporting Info

Biomolecular Stress-Sensitive Gauges:  Surface-Mediated Immobilization of Mechanosensitive Membrane Protein Maryna Ornatska, Sharon E. Jones, Rajesh R. Naik, Morley O. Stone, and Vladimir V. Tsukruk pp 12722–12723 DOI: 10.1021/ja037686q Supporting Info

Asymmetric Dimers Can Be Formed by Dewetting Half-Shells of Gold Deposited on the Surfaces of Spherical Oxide Colloids Yu Lu, Hui Xiong, Xuchuan Jiang, and Younan XiaMara Prentiss and George M. Whitesides pp 12724–12725 DOI: 10.1021/ja0373014 Supporting Info

Covalent Adlayer Growth on a Diamond Thin Film Surface Paweł Krysiński, Yoshiuki Show, Jason Stotter, and G. J. Blanchard pp 12726–12728 DOI: 10.1021/ja036077f

Stepwise Evolution of the Structure and Electronic Properties of DNA Frederick D. Lewis, Xiaoyang Liu, Yansheng Wu, and Xiaobing Zuo pp 12729–12731 DOI: 10.1021/ja036449k Supporting Info

Dual Catalytic Apparatus of the Thiamin Diphosphate Coenzyme:  Acid−Base via the 1‘,4‘-Iminopyrimidine Tautomer along with Its Electrophilic Role Frank Jordan, Natalia S. Nemeria, Sheng Zhang, Yan Yan, Palaniappa Arjunan, and William Furey pp 12732–12738 DOI: 10.1021/ja0346126

NMR and Quantum Chemical Study on the OH···π and CH···O Interactions between Trehalose and Unsaturated Fatty Acids:  Implication for the Mechanism of Antioxidant Function of Trehalose Kazuyuki Oku, Hikaru Watanabe, Michio Kubota, Shigeharu Fukuda, Masashi Kurimoto, Yoshio Tsujisaka, Masashi Komori, Yoshio Inoue, and Minoru Sakurai pp 12739–12748 DOI: 10.1021/ja034777e

Synthesis and Biological Activity of Photoactivatable N-Ras Peptides and Proteins Martin Völkert, Koji Uwai, Andreas Tebbe, Boriana Popkirova, Melanie Wagner, Jürgen Kuhlmann, and Herbert Waldmann pp 12749–12758 DOI: 10.1021/ja036178d Supporting Info

5-Enolpyruvylshikimate 3-Phosphate Synthase:  Chemical Synthesis of the Tetrahedral Intermediate and Assignment of the Stereochemical Course of the Enzymatic Reaction Ming An, Uday Maitra, Ulf Neidlein, and Paul A. Bartlett pp 12759–12767 DOI: 10.1021/ja036627+ Supporting Info

Balancing Kinetic and Thermodynamic Control:  the Mechanism of Carbocation Cyclization by Squalene Cyclase Ramkumar Rajamani and Jiali Gao pp 12768–12781 DOI: 10.1021/ja0371799 Supporting Info

The Vroman Effect:  A Molecular Level Description of Fibrinogen Displacement Seung-Yong Jung, Soon-Mi Lim, Fernando Albertorio, Gibum Kim, Marc C. Gurau, Richard D. Yang, Matthew A. Holden, and Paul S. Cremer pp 12782–12786 DOI: 10.1021/ja037263o Supporting Info

Atomic Resolution Density Maps Reveal Secondary Structure Dependent Differences in Electronic Distribution Paula I. Lario and Alice Vrielink pp 12787–12794 DOI: 10.1021/ja0289954

Independent Generation of 5-(2‘-Deoxycytidinyl)methyl Radical and the Formation of a Novel Cross-Link Lesion between 5-Methylcytosine and Guanine Qibin Zhang and Yinsheng Wang pp 12795–12802 DOI: 10.1021/ja034866r Supporting Info

Active Oxygen Species Generated from Photoexcited Fullerene (C60) as Potential Medicines:  O2-• versus 1O2 Yoko Yamakoshi, Naoki Umezawa, Akemi Ryu, Kumi Arakane, Naoki Miyata, Yukihiro Goda, Toshiki Masumizu, and Tetsuo Nagano pp 12803–12809 DOI: 10.1021/ja0355574

Side-Chain Dynamics of an α-Helical Polypeptide Monitored by Fluorescence Jean Duhamel, Sabesh Kanagalingam, Thomas J. O'Brien, and Mark W. Ingratta pp 12810–12822 DOI: 10.1021/ja035947q

DFT Calculations on the Effects of Para Substituents on the Energy Differences between Singlet and Triplet States of 2,2-Difluoro-1,3-diphenylcyclopentane-1,3-diyls Daisy Y. Zhang, David A. Hrovat, Manabu Abe, and Weston Thatcher Borden pp 12823–12828 DOI: 10.1021/ja0355067 Supporting Info

Biphenalenylidene:  The Forgotten Bistricyclic Aromatic Ene. A Theoretical Study Sergey Pogodin and Israel Agranat pp 12829–12835 DOI: 10.1021/ja035968k Supporting Info

A Second-Generation Synthesis of the C1−C28 Portion of the Altohyrtins (Spongistatins) Jed L. Hubbs and Clayton H. Heathcock pp 12836–12843 DOI: 10.1021/ja030316h Supporting Info

Multigram Synthesis of the C29−C51 Subunit and Completion of the Total Synthesis of Altohyrtin C (Spongistatin 2) Clayton H. Heathcock, Mark McLaughlin, Jesus Medina, Jed L. Hubbs, Grier A. Wallace, Robert Scott, Michele M. Claffey, Christopher J. Hayes, and Gregory R. Ott pp 12844–12849 DOI: 10.1021/ja030317+ Supporting Info

Selective Oxygenation of Ring-Substituted Toluenes with Electron-Donating and -Withdrawing Substituents by Molecular Oxygen via Photoinduced Electron Transfer Kei Ohkubo, Kyou Suga, Kohei Morikawa, and Shunichi Fukuzumi pp 12850–12859 DOI: 10.1021/ja036645r Supporting Info

Synthesis of α-Amino Acids via Asymmetric Phase Transfer-Catalyzed Alkylation of Achiral Nickel(II) Complexes of Glycine-Derived Schiff Bases Yuri N. Belokon, Natalia B. Bespalova, Tatiana D. Churkina, Ivana Císařová, Marina G. Ezernitskaya, Syuzanna R. Harutyunyan, Radim Hrdina, Henri B. Kagan, Pavel Koovský, Konstantin A. Kochetkov, Oleg V. Larionov, Konstantin A. Lyssenko, Michael North, Miroslav Polášek, Alexander S. Peregudov, Vladimir V. Prisyazhnyuk, and Štěpán Vyskoil pp 12860–12871 DOI: 10.1021/ja035465e Supporting Info

Photoreactions of 3-Diazo-3H-benzofuran-2-one; Dimerization and Hydrolysis of Its Primary Photoproduct, A Quinonoid Cumulenone:  A Study by Time-Resolved Optical and Infrared Spectroscopy Yvonne Chiang, Martin Gaplovsky, A. Jerry Kresge, King Hung Leung, Christian Ley, Marek Mac, Gabriele Persy, David L. Phillips, Vladimir V. Popik, Christoph Rödig, Jakob Wirz, and Yu Zhu pp 12872–12880 DOI: 10.1021/ja0365476 Supporting Info

Stoichiometric Compounds of Magnesium Dichloride with Ethanol for the Supported Ziegler−Natta Catalysis:  First Recognition and Multidimensional MAS NMR Study Piero Sozzani, Silvia Bracco, Angiolina Comotti, Roberto Simonutti, and Isabella Camurati pp 12881–12893 DOI: 10.1021/ja034630n Supporting Info

L-edge X-ray Absorption Spectroscopy of Non-Heme Iron Sites:  Experimental Determination of Differential Orbital Covalency Erik C. Wasinger, Frank M. F. de Groot, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 12894–12906 DOI: 10.1021/ja034634s Supporting Info

Novel Halogen and Interhalogen Adducts of Nanoscale Magnesium Oxide Peter K. Stoimenov, Vladimir Zaikovski, and Kenneth J. Klabunde pp 12907–12913 DOI: 10.1021/ja030195l

Magnesium Tetraarylporphyrin Tweezer:  a CD-Sensitive Host for Absolute Configurational Assignments of α-Chiral Carboxylic Acids Gloria Proni, Gennaro Pescitelli, Xuefei Huang, Koji Nakanishi, and Nina Berova pp 12914–12927 DOI: 10.1021/ja036294g Supporting Info

Size- and Support-Dependent Electronic and Catalytic Properties of Au0/Au3+ Nanoparticles Synthesized from Block Copolymer Micelles B. Roldan Cuenya, Sung-Hyeon Baeck, Thomas F. Jaramillo, and Eric W. McFarland pp 12928–12934 DOI: 10.1021/ja036468u

Toward Binary Nitrosyls:  Distinctly Bent Fe−N−O Linkages in Base-Stabilized Fe(NO)3+ Complexes Trevor W. Hayton, W. Stephen McNeil, Brian O. Patrick, and Peter Legzdins pp 12935–12944 DOI: 10.1021/ja036887r Supporting Info

Fully Localized Mixed-Valence Oxidation Products of Molecules Containing Two Linked Dimolybdenum Units:  An Effective Structural Criterion F. Albert Cotton, Naresh S. Dalal, Chun Y. Liu, Carlos A. Murillo, J. Micah North, and Xiaoping Wang pp 12945–12952 DOI: 10.1021/ja036920+ Supporting Info

Highly Emissive Supramolecular Oligo(p-phenylene vinylene) Dendrimers F. S. Precup-Blaga, J. C. Garcia-Martinez, A. P. H. J. Schenning, and E. W. Meijer pp 12953–12960 DOI: 10.1021/ja0211050

Photohydration and Photosolvolysis of Biphenyl Alkenes and Alcohols via Biphenyl Quinone Methide-type Intermediates and Diarylmethyl Carbocations Darryl W. Brousmiche, Musheng Xu, Matthew Lukeman, and Peter Wan pp 12961–12970 DOI: 10.1021/ja036808b Supporting Info

Homoleptic Cyclometalated Iridium Complexes with Highly Efficient Red Phosphorescence and Application to Organic Light-Emitting Diode Akira Tsuboyama, Hironobu Iwawaki, Manabu Furugori, Taihei Mukaide, Jun Kamatani, Satoshi Igawa, Takashi Moriyama, Seishi Miura, Takao Takiguchi, Shinjiro Okada, Mikio Hoshino, and Kazunori Ueno pp 12971–12979 DOI: 10.1021/ja034732d Supporting Info

Nucleophilic Reactivities of Carbanions in Water:  The Unique Behavior of the Malodinitrile Anion Thorsten Bug and Herbert Mayr pp 12980–12986 DOI: 10.1021/ja036838e Supporting Info

Issue 43

Molding of Three-Dimensional Microstructures of Gels Min D. Tang, Andrew P. Golden, and Joe Tien pp 12988–12989 DOI: 10.1021/ja037677h

Stereoselective Iodocyclopropanation of Terminal Alkenes with Iodoform, Chromium(II) Chloride, and N,N,N‘,N‘-Tetraethylethylenediamine Kazuhiko Takai, Shota Toshikawa, Atsushi Inoue, and Ryo Kokumai pp 12990–12991 DOI: 10.1021/ja0373061 Supporting Info

Radical Polymerization Initiated by Bergman Cyclization Joseph D. Rule, Scott R. Wilson, and Jeffrey S. Moore pp 12992–12993 DOI: 10.1021/ja0359198 Supporting Info

Regioselective Synthesis of Unsymmetrical C-Aryl Glycosides Using Silicon Tethers as Disposable Linkers David E. Kaelin, Jr., Steven M. Sparks, Hilary R. Plake, and Stephen F. Martin pp 12994–12995 DOI: 10.1021/ja0375582 Supporting Info

Dioxygen-Coupled Oxidative Amination of Styrene Vitaliy I. Timokhin, Natia R. Anastasi, and Shannon S. Stahl pp 12996–12997 DOI: 10.1021/ja0362149 Supporting Info

Microbial Synthesis of the Energetic Material Precursor 1,2,4-Butanetriol Wei Niu, Mapitso N. Molefe, and J. W. Frost pp 12998–12999 DOI: 10.1021/ja036391+ Supporting Info

Catalyzed Olefin Isomerization Leading to Highly Stereoselective Claisen Rearrangements of Aliphatic Allyl Vinyl Ethers Scott G. Nelson, Christopher J. Bungard, and Kan Wang pp 13000–13001 DOI: 10.1021/ja037655v Supporting Info

Indium-Catalyzed Addition of Active Methylene Compounds to 1-Alkynes Masaharu Nakamura, Kohei Endo, and Eiichi Nakamura pp 13002–13003 DOI: 10.1021/ja038006m Supporting Info

Facile Synthesis of a Fullerene-Barbituric Acid Derivative and Supramolecular Catalysis of Its Photoinduced Dimerization Nathan D. McClenaghan, Christelle Absalon, and Dario M. Bassani pp 13004–13005 DOI: 10.1021/ja0372098 Supporting Info

Isolation, Characterization, and Reaction of Activated Iodosylbenzene Monomer Hydroxy(phenyl)iodonium Ion with Hypervalent Bonding:  Supramolecular Complex PhI+OH·18-Crown-6 with Secondary I···O Interactions Masahito Ochiai, Kazunori Miyamoto, Motoo Shiro, Tomoyuki Ozawa, and Kentaro Yamaguchi pp 13006–13007 DOI: 10.1021/ja0377899 Supporting Info

Evidence for Hydrogen Abstraction from C1 of Taurine by the High-Spin Fe(IV) Intermediate Detected during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase (TauD) John C. Price, Eric W. Barr, Timothy E. Glass, Carsten Krebs, and J. Martin Bollinger, Jr. pp 13008–13009 DOI: 10.1021/ja037400h Supporting Info

Multinuclear Oxo-Bridged Manganese Complexes with a Bulky Substituted Benzoate Ligand:  Novel Species Obtained by Using Steric Control Sumitra Mukhopadhyay and William H. Armstrong pp 13010–13011 DOI: 10.1021/ja036490n Supporting Info

Asymmetric Cyclization via Memory of Chirality:  A Concise Access to Cyclic Amino Acids with a Quaternary Stereocenter Takeo Kawabata, Shimpei Kawakami, and Swapan Majumdar pp 13012–13013 DOI: 10.1021/ja0378299 Supporting Info

Electroless Deposition of Palladium at Bare and Templated Liquid/Liquid Interfaces Robert A. W. Dryfe, Andrew O. Simm, and Brett Kralj pp 13014–13015 DOI: 10.1021/ja037599y Supporting Info

Supramolecular Design for Multivalent Interaction:  Maltose Mobility along Polyrotaxane Enhanced Binding with Concanavalin A Tooru Ooya, Masaru Eguchi, and Nobuhiko Yui pp 13016–13017 DOI: 10.1021/ja034583z Supporting Info

A New Strategy to Induce γ-Turns:  Peptides Composed of Alternating α-Aminoxy Acids and α-Amino Acids Dan Yang, Wei Li, Jin Qu, Shi-Wei Luo, and Yun-Dong Wu pp 13018–13019 DOI: 10.1021/ja036136p Supporting Info

Metallabenzene versus Cp Complex Formation:  A DFT Investigation Mark A. Iron, Jan M. L. Martin, and Milko E. van der Boom pp 13020–13021 DOI: 10.1021/ja037983v Supporting Info

A General Strategy to Elisabethane Diterpenes:  Stereocontrolled Synthesis of Elisapterosin B via Oxidative Cyclization of an Elisabethin Precursor Nobuaki Waizumi, Ana R. Stankovic, and Viresh H. Rawal pp 13022–13023 DOI: 10.1021/ja035898h Supporting Info

How Does Product Isotope Effect Prove the Operation of a Two-State “Rebound” Mechanism in C−H Hydroxylation by Cytochrome P450? Devesh Kumar, Samuël P. de Visser, and Sason Shaik pp 13024–13025 DOI: 10.1021/ja036906x Supporting Info

Electrokinetic Trapping and Concentration Enrichment of DNA in a Microfluidic Channel Jinhua Dai, Takashi Ito, Li Sun, and Richard M. Crooks pp 13026–13027 DOI: 10.1021/ja0374776 Supporting Info

Formation of the Intermediate-Spin Iron(III) Porphyrin Complexes with (dxz, dyz)3(dxy)1(dz2)1 Electron Configuration Takanori Sakai, Yoshiki Ohgo, Takahisa Ikeue, Masashi Takahashi, Masuo Takeda, and Mikio Nakamura pp 13028–13029 DOI: 10.1021/ja030448a Supporting Info

Controllable Diastereoselective Cyclopropanation. Enantioselective Synthesis of Vinylcyclopropanes via Chiral Telluronium Ylides Wei-Wei Liao, Kai Li, and Yong Tang pp 13030–13031 DOI: 10.1021/ja036254c Supporting Info

Remarkable Effect of Pore Size on the Catalytic Activity of Mesoporous Silica for the Acetalization of Cyclohexanone with Methanol Masakazu Iwamoto, Yasuhiro Tanaka, Naoki Sawamura, and Seitaro Namba pp 13032–13033 DOI: 10.1021/ja0375129 Supporting Info

Kinetic Evaluation of Phenolase Activity of Tyrosinase Using Simplified Catalytic Reaction System Shin-ichi Yamazaki and Shinobu Itoh pp 13034–13035 DOI: 10.1021/ja036425d Supporting Info

34S Isotope Effect on Sulfate Ester Hydrolysis:  Mechanistic Implications Benjamin T. Burlingham, Lisa M. Pratt, Ernest R. Davidson, Vernon J. Shiner, Jr., Jon Fong, and Theodore S. Widlanski pp 13036–13037 DOI: 10.1021/ja0279747 Supporting Info

Identification of Surface Molecular Hydrates on Solid Sulfuric Acid Films Suzanne B. Couling, Karen L. Nash, John Fletcher, Alex Henderson, John C. Vickerman, and Andrew B. Horn pp 13038–13039 DOI: 10.1021/ja036384l

Selective Association of Cholesterol with Long-Chain Phospholipids in Liquid-Ordered Bilayers:  Support for the Existence of Lipid Rafts Michihiro Sugahara, Maki Uragami, and Steven L. Regen pp 13040–13041 DOI: 10.1021/ja038102n

Indium-Mediated Reaction of Trialkylsilyl Propargyl Bromide with Aldehydes:  Highly Regioselective Synthesis of Allenic and Homopropargylic Alcohols Man-Jing Lin and Teck-Peng Loh pp 13042–13043 DOI: 10.1021/ja037410i Supporting Info

Ten-Electron Coordination and Reactivity of an Arylphosphinidene Ligand M. Esther García, Víctor Riera, Miguel A. Ruiz, David Sáez, Hayrullo Hamidov, John C. Jeffery, and Thomas Riis-Johannessen pp 13044–13045 DOI: 10.1021/ja037293r Supporting Info

Sequential and Specific Exchange of Multiple Coiled-Coil Components Nathan A. Schnarr and Alan J. Kennan pp 13046–13051 DOI: 10.1021/ja035666i Supporting Info

Design of Amino Acid Sulfonamides as Transition-State Analogue Inhibitors of Arginase Evis Cama, Hyunshun Shin, and David W. Christianson pp 13052–13057 DOI: 10.1021/ja036365b

Large-Scale Millisecond Intersubunit Dynamics in the B Subunit Homopentamer of the Toxin Derived from Escherichia coli O157 Anna Yung, W. Bruce Turnbull, Arnout P. Kalverda, Gary S. Thompson, Steve W. Homans, Pavel Kitov, and David R. Bundle pp 13058–13062 DOI: 10.1021/ja0367288

Optical Spectra of Synechocystis and Spinach Photosystem II Preparations at 1.7 K:  Identification of the D1-Pheophytin Energies and Stark Shifts Sindra Peterson Årsköld, Vanessa M. Masters, Barry J. Prince, Paul J. Smith, Ron J. Pace, and Elmars Krausz pp 13063–13074 DOI: 10.1021/ja034548s Supporting Info

Direct Detection of a Hydrogen Ligand in the [NiFe] Center of the Regulatory H2-Sensing Hydrogenase from Ralstonia eutropha in Its Reduced State by HYSCORE and ENDOR Spectroscopy Marc Brecht, Maurice van Gastel, Thorsten Buhrke, Bärbel Friedrich, and Wolfgang Lubitz pp 13075–13083 DOI: 10.1021/ja036624x

The Plumber's Nightmare:1 A New Morphology in Block Copolymer−Ceramic Nanocomposites and Mesoporous Aluminosilicates Adam C. Finnefrock, Ralph Ulrich, Gilman E. S. Toombes, Sol M. Gruner, and Ulrich Wiesner pp 13084–13093 DOI: 10.1021/ja0355170 Supporting Info

Biosynthesis of Vitamin B1 in Yeast. Derivation of the Pyrimidine Unit from Pyridoxine and Histidine. Intermediacy of Urocanic Acid Johannes Zeidler, Brian G. Sayer, and Ian D. Spenser pp 13094–13105 DOI: 10.1021/ja030261j

Transition State Differences in Hydrolysis Reactions of Alkyl versus Aryl Phosphate Monoester Monoanions Piotr K. Grzyska, Przemyslaw G. Czyryca, Jamie Purcell, and Alvan C. Hengge pp 13106–13111 DOI: 10.1021/ja036571j Supporting Info

2,3-Anhydrosugars in Glycoside Bond Synthesis. NMR and Computational Investigations into the Mechanism of Glycosylations with 2,3-Anhydrofuranosyl Glycosyl Sulfoxides Christopher S. Callam, Rajendrakumar Reddy Gadikota, Douglas M. Krein, and Todd L. Lowary pp 13112–13119 DOI: 10.1021/ja0349610 Supporting Info

Direct Determination of the Number of Electrons Needed To Reduce Coenzyme F430 Pentamethyl Ester to the Ni(I) Species Exhibiting the Electron Paramagnetic Resonance and Ultraviolet−Visible Spectra Characteristic for the MCRred1 State of Methyl-coenzyme M Reductase Rafal Piskorski and Bernhard Jaun pp 13120–13125 DOI: 10.1021/ja037862v Supporting Info

Hydroformylation Reactions with Recyclable Rhodium-Complexed Dendrimers on a Resin Shui-Ming Lu and Howard Alper pp 13126–13131 DOI: 10.1021/ja0303384 Supporting Info

Structure Assignment, Total Synthesis, and Antiviral Evaluation of Cycloviracin B1 Alois Fürstner, Martin Albert, Jacek Mlynarski, Maribel Matheu, and Erik DeClercq pp 13132–13142 DOI: 10.1021/ja036521e Supporting Info

New Concepts in Thermoplastic Elastomers:  The Case of Syndiotactic Polypropylene, an Unconventional Elastomer with High Crystallinity and Large Modulus Finizia Auriemma and Claudio De Rosa pp 13143–13147 DOI: 10.1021/ja036282v

Highly Cooperative Formation of Bis-Urea Based Supramolecular Polymers Vesna Simic, Laurent Bouteiller, and Matthieu Jalabert pp 13148–13154 DOI: 10.1021/ja037589x Supporting Info

Total Syntheses of Furaquinocin A, B, and E Barry M. Trost, Oliver R. Thiel, and Hon-Chung Tsui pp 13155–13164 DOI: 10.1021/ja0364118 Supporting Info

Simultaneous Light Emission from a Mixture of Dendrimer Encapsulated Chromophores:  A Model for Single-Layer Multichromophoric Organic Light-Emitting Diodes Paul Furuta, Jason Brooks, Mark E. Thompson, and Jean M. J. Fréchet pp 13165–13172 DOI: 10.1021/ja0371348 Supporting Info

Controlling Solubility and Modulating Peripheral Function in Dendrimer Encapsulated Dyes Paul Furuta and Jean M. J. Fréchet pp 13173–13181 DOI: 10.1021/ja037133f Supporting Info

Homolytic vs Heterolytic Paths in the Photochemistry of Haloanilines Mauro Freccero, Maurizio Fagnoni, and Angelo Albini pp 13182–13190 DOI: 10.1021/ja036000r Supporting Info

Dramatic Steric Behavior in Electron Transfer from Various Donors to CF3Br Peter W. Harland and Philip R. Brooks pp 13191–13197 DOI: 10.1021/ja036451b

Direct Observation of Triplet State Emission of Single Molecules:  Single Molecule Phosphorescence Quenching of Metalloporphyrin and Organometallic Complexes by Molecular Oxygen and Their Quenching Rate Distributions Erwen Mei, Sergei Vinogradov, and Robin M. Hochstrasser pp 13198–13204 DOI: 10.1021/ja030271k

Magnetic Quantum Dots:  Synthesis, Spectroscopy, and Magnetism of Co2+- and Ni2+-Doped ZnO Nanocrystals Dana A. Schwartz, Nick S. Norberg, Quyen P. Nguyen, Jason M. Parker, and Daniel R. Gamelin pp 13205–13218 DOI: 10.1021/ja036811v Supporting Info

Experimental Evidence for a Temperature Dependent Transition between Normal and Inverse Equilibrium Isotope Effects for Oxidative Addition of H2 to Ir(PMe2Ph)2(CO)Cl Kevin E. Janak and Gerard Parkin pp 13219–13224 DOI: 10.1021/ja0362611 Supporting Info

Absorption and Emission Spectra of Ce3+ in Elpasolite Lattices Peter A. Tanner, Chris S. K. Mak, Norman M. Edelstein, Keith M. Murdoch, Guokiu Liu, Jin Huang, Luis Seijo, and Zoila Barandiarán pp 13225–13233 DOI: 10.1021/ja036659x

Monomeric MnIII/II and FeIII/II Complexes with Terminal Hydroxo and Oxo Ligands:  Probing Reactivity via O−H Bond Dissociation Energies Rajeev Gupta and A. S. Borovik pp 13234–13242 DOI: 10.1021/ja030149l Supporting Info

Asymmetric Synthesis of Unsaturated, Fused Bicyclic Proline Analogues through Amino Alkylation of Cyclic Bis(allylsulfoximine)titanium Complexes and Migratory Cyclization of δ-Amino Alkenyl Aminosulfoxonium Salts Stefan Koep, Hans-Joachim Gais, and Gerhard Raabe pp 13243–13251 DOI: 10.1021/ja030324y Supporting Info

Insight into the Partial Oxidation of Propene:  The Reactions of 2-Propen-1-ol on Clean and O-Covered Mo(110) L. J. Deiner, J. G. Serafin, C. M. Friend, S. G. Weller, J. A. Levinson, and R. E. Palmer pp 13252–13257 DOI: 10.1021/ja030250q

Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C−H Bond Activation-Elimination Sequence Nicka Chinkov, Swapan Majumdar, and Ilan Marek pp 13258–13264 DOI: 10.1021/ja036751t Supporting Info

Theoretical Studies on the Hydrolysis of Mono-Phosphate and Tri-Phosphate in Gas Phase and Aqueous Solution Yan-Ni Wang, Igor A. Topol, Jack R. Collins, and Stanley K. Burt pp 13265–13273 DOI: 10.1021/ja0279794 Supporting Info

A Seemingly Well Understood Light-Induced Peroxide Decarboxylation Reaction Reinvestigated with Femtosecond Time Resolution Bernd Abel, Michael Buback, Matthias Kling, Stefan Schmatz, and Jörg Schroeder pp 13274–13278 DOI: 10.1021/ja036304d

NanoCell Electronic Memories James M. Tour, Long Cheng, David P. Nackashi, Yuxing Yao, Austen K. Flatt, Sarah K. St. Angelo, Thomas E. Mallouk, and Paul D. Franzon pp 13279–13283 DOI: 10.1021/ja036369g

Supramolecular Assembly of Dendritic Polymers Elucidated by 1H and 13C Solid-State MAS NMR Spectroscopy Almut Rapp, Ingo Schnell, Daniel Sebastiani, Steven P. Brown, Virgil Percec, and Hans Wolfgang Spiess pp 13284–13297 DOI: 10.1021/ja035127d

In Situ NMR Spectroscopy of Combustion Satyanarayana Anala, Galina E. Pavlovskaya, Prakash Pichumani, Todd J. Dieken, Michael D. Olsen, and Thomas Meersmann pp 13298–13302 DOI: 10.1021/ja035838b

Explorations in Organic Chemistry Leading to the Total Synthesis of (±)-Gelsemine [J. Am. Chem. Soc. 2002, 124, 9812−9824]. Fay W. Ng, Hong Lin, Pauline Chiu, and Samuel J. Danishefsky p 13303 DOI: 10.1021/ja0334558

Relativistic Electronic Structure Theory:  Part 1, Fundamentals Edited by Peter Schwerdtfeger (University of Auckland).  Theoretical and Computational Chemistry, Volume 11. Series Edited by P. Politzer (University of New Orleans) and Z. B. Maksic (Rudjer Boskovic Institute). Elsevier Science B. V.:  Amsterdam. 2002. xx + 926 pp. $340.00. ISBN 0-444-51249-7. Russell M. Pitzer p 13304 DOI: 10.1021/ja033529f

Perspectives in Organometallic Chemistry Edited By C. G. Screttas and B. R. Steele (National Hellenic Research Foundation, Athens). Royal Society of Chemistry:  Cambridge. 2003. x + 322 pp. $199.00. ISBN 0-85404-876-6. p 13304 DOI: 10.1021/ja033568r

Issue 44

Shape-Adaptable Water-Soluble Conjugated Polymers Bin Liu, Shu Wang, Guillermo C. Bazan, and Alexander Mikhailovsky pp 13306–13307 DOI: 10.1021/ja0365072 Supporting Info

Measurement and ab Initio Calculation of CSA/Dipole−Dipole Cross-Correlated Relaxation Provide Insight into the Mechanism of a H2-Forming Dehydrogenase Stefan Bartoschek, Gerrit Buurman, Bernhard H. Geierstanger, Jon Lapham, and Christian Griesinger pp 13308–13309 DOI: 10.1021/ja029953i Supporting Info

Self-Assembly Approach toward Magnetic Silica-Type Nanoparticles of Different Shapes from Reverse Block Copolymer Mesophases Carlos B. W. Garcia, Yuanming Zhang, Surbhi Mahajan, Francis DiSalvo, and Ulrich Wiesner pp 13310–13311 DOI: 10.1021/ja037116q

Water Molecules in the Schiff Base Region of Bacteriorhodopsin Mikihiro Shibata, Taro Tanimoto, and Hideki Kandori pp 13312–13313 DOI: 10.1021/ja037343s

Constructing a Stable Carbene with a Novel Topology and Electronic Framework Patrick Bazinet, Glenn P. A. Yap, and Darrin S. Richeson pp 13314–13315 DOI: 10.1021/ja0372661 Supporting Info

Dealkylation of Organotin Compounds by Biological Dithiols:  Toward the Chemistry of Organotin Toxicity Bethany Buck, Alessandro Mascioni, Lawrence Que, Jr., and Gianluigi Veglia pp 13316–13317 DOI: 10.1021/ja0354723 Supporting Info

Possible Lowest-Energy Geometry of Silicon Clusters Si21 and Si25 Soohaeng Yoo, Xiao Cheng Zeng, Xiaolei Zhu, and Jaeil Bai pp 13318–13319 DOI: 10.1021/ja0365678 Supporting Info

Self-Sustaining Peristaltic Motion on the Surface of a Porous Gel Yukikazu Takeoka, Masayoshi Watanabe, and Ryo Yoshida pp 13320–13321 DOI: 10.1021/ja036904c Supporting Info

Toward Artificial Developmental Regulators Hans-Dieter Arndt, Karl E. Hauschild, David P. Sullivan, Kara Lake, Peter B. Dervan, and Aseem Z. Ansari pp 13322–13323 DOI: 10.1021/ja0371395 Supporting Info

Stable Lanthanide Luminescence Agents Highly Emissive in Aqueous Solution:  Multidentate 2-Hydroxyisophthalamide Complexes of Sm3+, Eu3+, Tb3+, Dy3+ Stéphane Petoud, Seth M. Cohen, Jean-Claude G. Bünzli, and Kenneth N. Raymond pp 13324–13325 DOI: 10.1021/ja0379363 Supporting Info

A Convenient One-Pot Procedure to Afford Bicyclic Molecules by Stereospecific Iron Carbonyl Mediated [6 + 2] Ene-Type Cyclization:  A Possible Approach to Gelsemine Anthony J. Pearson and Xiaolong Wang pp 13326–13327 DOI: 10.1021/ja030407e Supporting Info

Tetrasilatetrahedranide:  A Silicon Cage Anion Masaaki Ichinohe, Masafumi Toyoshima, Rei Kinjo, and Akira Sekiguchi pp 13328–13329 DOI: 10.1021/ja0305050 Supporting Info

Contact Ion Pair between Na+ and PtCl62- Favored in Methanol Kevin J. Naidoo, Anton S. Lopis, Arjan N. Westra, David J. Robinson, and Klaus R. Koch pp 13330–13331 DOI: 10.1021/ja035326x Supporting Info

Dicopper-[18]ane-N6 Complex as the Platform for Phosphate Monoester Binding Julia E. Barker, Yu Liu, Nicole D. Martin, and Tong Ren pp 13332–13333 DOI: 10.1021/ja036407w Supporting Info

Spin Crossover of Spiro-Biphenalenyl Neutral Radical Molecular Conductors Jingsong Huang and Miklos Kertesz pp 13334–13335 DOI: 10.1021/ja038038+ Supporting Info

Water−Protein Interactions in Microcrystalline Crh Measured by 1H−13C Solid-State NMR Spectroscopy Anne Lesage and Anja Böckmann pp 13336–13337 DOI: 10.1021/ja036720y

Protein Alignment by a Coexpressed Lanthanide-Binding Tag for the Measurement of Residual Dipolar Couplings Jens Wöhnert, Katherine J. Franz, Mark Nitz, Barbara Imperiali, and Harald Schwalbe pp 13338–13339 DOI: 10.1021/ja036022d Supporting Info

A Catalytic Reaction of Alkynes via Multiple-Site Functionalization Subramanian Karur, S. R. S. Saibabu Kotti, Xin Xu, John F. Cannon, Allan Headley, and Guigen Li pp 13340–13341 DOI: 10.1021/ja0304188 Supporting Info

Interaction between Ketopantolactone and Chirally Modified Pt Investigated by Attenuated Total Reflection IR Concentration Modulation Spectroscopy Norberto Bonalumi, Thomas Bürgi, and Alfons Baiker pp 13342–13343 DOI: 10.1021/ja037371a Supporting Info

Dioxygen Activation by an Osmium-dihydride:  Preparation and Characterization of a d4 Square-Planar Complex Miguel A. Esteruelas, Francisco J. Modrego, Enrique Oñate, and Eva Royo pp 13344–13345 DOI: 10.1021/ja037484u Supporting Info

Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Oxastibetane Yosuke Uchiyama, Naokazu Kano, and Takayuki Kawashima pp 13346–13347 DOI: 10.1021/ja037586k Supporting Info

[Cr(N)Cl4]2-:  A Simple Nitrido Complex Synthesized by Nitrogen-Atom Transfer Jesper Bendix pp 13348–13349 DOI: 10.1021/ja0371000 Supporting Info

Group Transfer from Nickel Imido, Phosphinidene, and Carbene Complexes to Ethylene with Formation of Aziridine, Phosphirane, and Cyclopropane Products Rory Waterman and Gregory L. Hillhouse pp 13350–13351 DOI: 10.1021/ja0381914 Supporting Info

Protein Charge-State Distributions in Electrospray-Ionization Mass Spectrometry Do Not Appear To Be Limited by the Surface Tension of the Solvent Maria Šamalikova and Rita Grandori pp 13352–13353 DOI: 10.1021/ja037000u

Alumina Nanotubes Containing Lithium of High Ion Mobility Hae Jin Kim, Hyun Chul Lee, Chang Houn Rhee, Soo Hyun Chung, Hee Cheon Lee, Kyung Hee Lee, and Jae Sung Lee pp 13354–13355 DOI: 10.1021/ja0374269 Supporting Info

Strong Two-Photon Absorption of Self-Assembled Butadiyne-Linked Bisporphyrin Kazuya Ogawa, Atsushi Ohashi, Yoshiaki Kobuke, Kenji Kamada, and Koji Ohta pp 13356–13357 DOI: 10.1021/ja035056i Supporting Info

A Light-Activated Probe of Intracellular Protein Kinase Activity Willem F. Veldhuyzen, Quan Nguyen, Gary McMaster, and David S. Lawrence pp 13358–13359 DOI: 10.1021/ja037801x Supporting Info

Chiroptical Switching in a Bistable Molecular Shuttle Giovanni Bottari, David A. Leigh, and Emilio M. Pérez pp 13360–13361 DOI: 10.1021/ja036665t Supporting Info

Glycine on a Wet Pyrite Surface at Extreme Conditions Christian Boehme and Dominik Marx pp 13362–13363 DOI: 10.1021/ja0359714

Hollow Nanostructures of Platinum with Controllable Dimensions Can Be Synthesized by Templating Against Selenium Nanowires and Colloids Brian Mayers, Xuchuan Jiang, David Sunderland, Bryan Cattle, and Younan Xia pp 13364–13365 DOI: 10.1021/ja0379722 Supporting Info

Nanoporous Materials with Spherical and Gyroid Cavities Created by Quantitative Etching of Polydimethylsiloxane in Polystyrene−Polydimethylsiloxane Block Copolymers Sokol Ndoni, Martin E. Vigild, and Rolf H. Berg pp 13366–13367 DOI: 10.1021/ja0360034 Supporting Info

Development of Chiral Nucleophilic Pyridine Catalysts:  Applications in Asymmetric Quaternary Carbon Synthesis Scott A. Shaw, Pedro Aleman, and Edwin Vedejs pp 13368–13369 DOI: 10.1021/ja037223k Supporting Info

Catalytic Benzene Alkylation over Mesoporous Zeolite Single Crystals:  Improving Activity and Selectivity with a New Family of Porous Materials Christina Hviid Christensen, Kim Johannsen, Iver Schmidt, and Claus Hviid Christensen pp 13370–13371 DOI: 10.1021/ja037063c

Evidence for Environmentally Coupled Hydrogen Tunneling during Dihydrofolate Reductase Catalysis Giovanni Maglia and Rudolf K. Allemann pp 13372–13373 DOI: 10.1021/ja035692g Supporting Info

MAS NMR Structure of a Microcrystalline Cd-Bacteriochlorophyll d Analogue Ido de Boer, Jörg Matysik, Masaaki Amakawa, Shiki Yagai, Hitoshi Tamiaki, Alfred R. Holzwarth, and Huub J. M. de Groot pp 13374–13375 DOI: 10.1021/ja0367492 Supporting Info

Tandem Lesions Are the Major Products Resulting from a Pyrimidine Nucleobase Radical K. Nolan Carter and Marc M. Greenberg pp 13376–13378 DOI: 10.1021/ja036629u Supporting Info

Catalytic Mechanism of S-Ribosylhomocysteinase (LuxS):  Direct Observation of Ketone Intermediates by 13C NMR Spectroscopy Jinge Zhu, Xubo Hu, Eric Dizin, and Dehua Pei pp 13379–13381 DOI: 10.1021/ja0369663 Supporting Info

Manadomanzamines A and B:  A Novel Alkaloid Ring System with Potent Activity against Mycobacteria and HIV-1 Jiangnan Peng, Jin-Feng Hu, Abul B. Kazi, Ze Li, Mitchell Avery, Olivier Peraud, Russell T. Hill, Scott G. Franzblau, Fangqiu Zhang, Raymond F. Schinazi, Susan S. Wirtz, Phillip Tharnish, Michelle Kelly, Subagus Wahyuono, and Mark T. Hamann pp 13382–13386 DOI: 10.1021/ja030087z Supporting Info

Reversible “Irreversible” Inhibition of Chymotrypsin Using Nanoparticle Receptors Nicholas O. Fischer, Ayush Verma, Catherine M. Goodman, Joseph M. Simard, and Vincent M. Rotello pp 13387–13391 DOI: 10.1021/ja0352505 Supporting Info

Solution 1H, 15N NMR Spectroscopic Characterization of Substrate-Bound, Cyanide-Inhibited Human Heme Oxygenase:  Water Occupation of the Distal Cavity Yiming Li, Ray T. Syvitski, Karine Auclair, Paul Ortiz de Montellano, and Gerd N. La Mar pp 13392–13403 DOI: 10.1021/ja036176t Supporting Info

Synthesis and Characterization of Potent Bivalent Amyloidosis Inhibitors That Bind Prior to Transthyretin Tetramerization Nora S. Green, Satheesh K. Palaninathan, James C. Sacchettini, and Jeffery W. Kelly pp 13404–13414 DOI: 10.1021/ja030294z Supporting Info

SUBPOL:  A Novel Sucrose-Based Polymer Support for Solid-Phase Peptide Synthesis and Affinity Chromatography Applications Alexander Poschalko, Thomas Rohr, Heinrich Gruber, Alberto Bianco, Gilles Guichard, Jean-Paul Briand, Viktoria Weber, and Dieter Falkenhagen pp 13415–13426 DOI: 10.1021/ja035874a Supporting Info

Solid-Phase Oligodeoxynucleotide Synthesis:  A Two-Step Cycle Using Peroxy Anion Deprotection Agnieszka B. Sierzchala, Douglas J. Dellinger, Jason R. Betley, Tadeusz K. Wyrzykiewicz, Christina M. Yamada, and Marvin H. Caruthers pp 13427–13441 DOI: 10.1021/ja030376n

Regio- and Enantioselective Alkane Hydroxylation with Engineered Cytochromes P450 BM-3 Matthew W. Peters, Peter Meinhold, Anton Glieder, and Frances H. Arnold pp 13442–13450 DOI: 10.1021/ja0303790

Using DNA-Binding Proteins as an Analytical Tool Maxim Berezovski and Sergey N. Krylov pp 13451–13454 DOI: 10.1021/ja037186x

Diselenides and Allyl Selenides as Glutathione Peroxidase Mimetics. Remarkable Activity of Cyclic Seleninates Produced in Situ by the Oxidation of Allyl ω-Hydroxyalkyl Selenides Thomas G. Back and Ziad Moussa pp 13455–13460 DOI: 10.1021/ja0357588 Supporting Info

Comparison of Excited-State Energy Transfer in Arrays of Hydroporphyrins (Chlorins, Oxochlorins) versus Porphyrins:  Rates, Mechanisms, and Design Criteria Masahiko Taniguchi, Doyoung Ra, Christine Kirmaier, Eve Hindin, Jennifer K. Schwartz, James R. Diers, Robert S. Knox, David F. Bocian, Jonathan S. Lindsey, and Dewey Holten pp 13461–13470 DOI: 10.1021/ja035987u Supporting Info

Spectroscopic Consequences of a Mixed Valence Excited State:  Quantitative Treatment of a Dihydrazine Diradical Dication Jenny V. Lockard, Jeffrey I. Zink, Asgeir E. Konradsson, Michael N. Weaver, and Stephen F. Nelsen pp 13471–13480 DOI: 10.1021/ja036046k

Cascade Cyclizations and Couplings Involving Nickel Enolates Gireesh M. Mahandru, Andy R. L. Skauge, Sanjoy K. Chowdhury, Kande K. D. Amarasinghe, Mary Jane Heeg, and John Montgomery pp 13481–13485 DOI: 10.1021/ja037423w Supporting Info

First Enantiospecific Total Synthesis of the Antitubercular Marine Natural Product Pseudopteroxazole. Revision of Assigned Stereochemistry James P. Davidson and E. J. Corey pp 13486–13489 DOI: 10.1021/ja0378916 Supporting Info

Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine−Ruthenium(II) Complexes Christian A. Sandoval, Takeshi Ohkuma, Kilian Muñiz, and Ryoji Noyori pp 13490–13503 DOI: 10.1021/ja030272c Supporting Info

Molecular Imprinting Inside Dendrimers Steven C. Zimmerman, Ilya Zharov, Michael S. Wendland, Neal A. Rakow, and Kenneth S. Suslick pp 13504–13518 DOI: 10.1021/ja0357240

8-Methylguanosine:  A Powerful Z-DNA Stabilizer Yan Xu, Reiko Ikeda, and Hiroshi Sugiyama pp 13519–13524 DOI: 10.1021/ja036233i Supporting Info

Structural and Spectroscopic Studies of Peptoid Oligomers with α-Chiral Aliphatic Side Chains Cindy W. Wu, Kent Kirshenbaum, Tracy J. Sanborn, James A. Patch, Kai Huang, Ken A. Dill, Ronald N. Zuckermann, and Annelise E. Barron pp 13525–13530 DOI: 10.1021/ja037540r Supporting Info

A Cycloaddition Cascade Approach to the Total Synthesis of (−)-FR182877 David A. Evans and Jeremy T. Starr pp 13531–13540 DOI: 10.1021/ja037643+ Supporting Info

Real-Time Multicolor DNA Detection with Chemoresponsive Diffraction Gratings and Nanoparticle Probes Ryan C. Bailey, Jwa-Min Nam, Chad A. Mirkin, and Joseph T. Hupp pp 13541–13547 DOI: 10.1021/ja035479k

New n-Type Organic Semiconductors:  Synthesis, Single Crystal Structures, Cyclic Voltammetry, Photophysics, Electron Transport, and Electroluminescence of a Series of Diphenylanthrazolines Christopher J. Tonzola, Maksudul M. Alam, Werner Kaminsky, and Samson A. Jenekhe pp 13548–13558 DOI: 10.1021/ja036314e Supporting Info

Alloyed ZnxCd1-xS Nanocrystals with Highly Narrow Luminescence Spectral Width Xinhua Zhong, Yaoyu Feng, Wolfgang Knoll, and Mingyong Han pp 13559–13563 DOI: 10.1021/ja036683a Supporting Info

Modifying Electronic Communication in Dimolybdenum Units by Linkage Isomers of Bridged Oxamidate Dianions F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, Dino Villagrán, and Xiaoping Wang pp 13564–13575 DOI: 10.1021/ja036884e Supporting Info

Binding Energies of Water to Sodiated Valine and Structural Isomers in the Gas Phase:  The Effect of Proton Affinity on Zwitterion Stability Andrew S. Lemoff, Matthew F. Bush, and Evan R. Williams pp 13576–13584 DOI: 10.1021/ja034544n

A Theoretical Study of the NMR Spin−Spin Coupling Constants of the Complexes [(NC)5Pt−Tl(CN)n]n- (n = 0−3) and [(NC)5Pt−Tl−Pt(CN)5]3-:  A Lesson on Environmental Effects Jochen Autschbach and Boris Le Guennic pp 13585–13593 DOI: 10.1021/ja0368047

Ultrafast Excited-State Dynamics of Adenine and Monomethylated Adenines in Solution:  Implications for the Nonradiative Decay Mechanism Boiko Cohen, Patrick M. Hare, and Bern Kohler pp 13594–13601 DOI: 10.1021/ja035628z

Synergistic Effects in Multicomponent Electrocatalysts:  The Pb−Ir−O System Conor Mullens, Michael Pikulski, Sabri Agachan, and Waldemar Gorski pp 13602–13608 DOI: 10.1021/ja0366843

Intramolecular Directional Förster Resonance Energy Transfer at the Single-Molecule Level in a Dendritic System Mircea Cotlet, Roel Gronheid, Satoshi Habuchi, Alina Stefan, Arianna Barbafina, Klaus Müllen, Johan Hofkens, and Frans C. De Schryver pp 13609–13617 DOI: 10.1021/ja036858g

The First Total Synthesis of Nakadomarin A [J. Am. Chem. Soc. 2003, 125, 7484−7485]. Toshiaki Nagata, Masako Nakagawa, and Atsushi Nishida p 13618 DOI: 10.1021/ja033459c Supporting Info

Fundamentals of Molecular Catalysis. Current Methods in Inorganic Chemistry. Volume 3 Edited by Hideo Kurosawa (Osaka University) and Akio Yamamoto (Waseda University). Elsevier:  Amsterdam. 2003. xiv + 522 pp. $220.00. ISBN 0-444-50921-6. David Tellers p 13619 DOI: 10.1021/ja033574n

Handbook of Aqueous Solubility Data By Samuel H. Yalkowsky and Yan He (University of Arizona). CRC Press LLC:  Boca Raton FL. 2003. xii + 1496 pp. $299.95. ISBN 0-8493-1532-8. p 13619 DOI: 10.1021/ja033578s

Hydrocarbon Chemistry, Second Edition By George A. Olah (Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles) and Árpád Molnár (University of Szeged, Hungary). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2003. xxiv + 871 pp. $150.00. ISBN 0-471-41782-3. Jay K. Kochi pp 13619–13620 DOI: 10.1021/ja033567z

Interfacial Supramolecular Assemblies By Johannes G. Vos, Robert J. Forster (Dublin University), and Tia E. Keyes (Dublin Institute of Technology). John Wiley & Sons, Ltd.:  Chichester. 2003. xi + 317 pp. $195.00. ISBN 0-471-49071-7. Rajendra Rathore p 13620 DOI: 10.1021/ja033539g

Synthetic Methods in Step-Growth Polymers Edited by Martin E. Rogers (Luna Innovations, Blacksburg, VA) and Timothy E. Long (Virginia Tech). J. Wiley and Sons, Inc.:  Hoboken. 2003. xii + 606 pp. $129.95. ISBN 0-471-38769-X. Eli M. Pearce p 13620 DOI: 10.1021/ja033557y

The Chemistry of Organic Germanium, Tin and Lead Compounds, Volume 2. Parts 1−2 Edited by Zvi Rappoport (The Hebrew University, Jerusalem). John Wiley & Sons, Ltd.:  Chichester. 2002. xl + 1912 pp. $1510.00. ISBN 0-471-49738-X. Peter P. Gaspar pp 13620–13622 DOI: 10.1021/ja033558q

Issue 45

The Development of a Facile Tandem Wolff/Cope Rearrangement for the Synthesis of Fused Carbocyclic Skeletons Richmond Sarpong, Julius T. Su, and Brian M. Stoltz pp 13624–13625 DOI: 10.1021/ja037587c Supporting Info

High-Frequency Dynamic Nuclear Polarization in MAS Spectra of Membrane and Soluble Proteins Melanie Rosay, Jonathan C. Lansing, Kristin C. Haddad, William W. Bachovchin, Judith Herzfeld, Richard J. Temkin, and Robert G. Griffin pp 13626–13627 DOI: 10.1021/ja036898k

Luotonin A. A Naturally Occurring Human DNA Topoisomerase I Poison Ali Cagir, Shannon H. Jones, Rong Gao, Brian M. Eisenhauer, and Sidney M. Hecht pp 13628–13629 DOI: 10.1021/ja0368857

Bioactive Recognition Sites May Not Be Energetically Preferred in Protein−Carbohydrate Complexes in the Gas Phase Weijie Wang, Elena N. Kitova, and John S. Klassen pp 13630–13631 DOI: 10.1021/ja036998q Supporting Info

Asymmetric Simmons−Smith Cyclopropanation of Unfunctionalized Olefins Jiang Long, Yi Yuan, and Yian Shi pp 13632–13633 DOI: 10.1021/ja030488e Supporting Info

Synthesis of the Elusive (R3P)2MF2 (M = Pd, Pt) Complexes Anette Yahav, Israel Goldberg, and Arkadi Vigalok pp 13634–13635 DOI: 10.1021/ja0377753 Supporting Info

Clean Inversion of Configuration in the Pd-Catalyzed Cross-Coupling of 2-Bromo-1,3-dienes Xingzhong Zeng, Qian Hu, Mingxing Qian, and Ei-ichi Negishi pp 13636–13637 DOI: 10.1021/ja0304392 Supporting Info

Selective Complexation of Li+ in Water at Neutral pH Using a Self-Assembled Ionophore Zacharias Grote, Marie-Line Lehaire, Rosario Scopelliti, and Kay Severin pp 13638–13639 DOI: 10.1021/ja036621k Supporting Info

Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism Paul B. Glaser and T. Don Tilley pp 13640–13641 DOI: 10.1021/ja037620v Supporting Info

The First Applications of Carbene Ligands in Cross-Couplings of Alkyl Electrophiles:  Sonogashira Reactions of Unactivated Alkyl Bromides and Iodides Matthias Eckhardt and Gregory C. Fu pp 13642–13643 DOI: 10.1021/ja038177r Supporting Info

Distinct Thermodynamics for the Formation and Cleavage of N−H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex Mira Kanzelberger, Xiawei Zhang, Thomas J. Emge, Alan S. Goldman, Jing Zhao, Christopher Incarvito, and John F. Hartwig pp 13644–13645 DOI: 10.1021/ja037363u Supporting Info

Calix[2]bipyrrole[2]furan and Calix[2]bipyrrole[2]thiophene:  New Pyrrolic Receptors Exhibiting a Preference for Carboxylate Anions Jonathan L. Sessler, Deqiang An, Won-Seob Cho, and Vincent Lynch pp 13646–13647 DOI: 10.1021/ja038264j Supporting Info

[60]Fullerene-Containing Polyurethane Films with Large Ultrafast Nonresonant Third-Order Nonlinearity at Telecommunication Wavelengths Li Kuang, Qiying Chen, Edward H. Sargent, and Zhi Yuan Wang pp 13648–13649 DOI: 10.1021/ja0376240 Supporting Info

Relationship between Redox Function and Protein Stability of Cytochromes c Norifumi Terui, Naoki Tachiiri, Hitomi Matsuo, Jun Hasegawa, Susumu Uchiyama, Yuji Kobayashi, Yasuo Igarashi, Yoshihiro Sambongi, and Yasuhiko Yamamoto pp 13650–13651 DOI: 10.1021/ja035682f Supporting Info

One-Step Water-Assisted Synthesis of High-Quality Carbon Nanotubes Directly from Graphite Zhenhui Kang, Enbo Wang, Lei Gao, Suoyuan Lian, Min Jiang, Changwen Hu, and Lin Xu pp 13652–13653 DOI: 10.1021/ja037399m

Control of A Double Helix DNA Assembly by Use of Cross-Linked Oligonucleotides Masayuki Endo and Tetsuro Majima pp 13654–13655 DOI: 10.1021/ja036752l Supporting Info

High Electron Mobility in Ladder Polymer Field-Effect Transistors Amit Babel and Samson A. Jenekhe pp 13656–13657 DOI: 10.1021/ja0371810 Supporting Info

Mapping the Sites for Selective Oxidation of Guanines in DNA K. Senthilkumar, F. C. Grozema, C. Fonseca Guerra, F. M. Bickelhaupt, and L. D. A. Siebbeles pp 13658–13659 DOI: 10.1021/ja037027d Supporting Info

The Glass Transition Time Scale and Configurational Entropy in Polymers:  An Experimental Molecular View J. E. Wolak, X. Jia, and Jeffery L. White pp 13660–13661 DOI: 10.1021/ja037738b

Bis-Silicon-Bridged Stilbene Homologues Synthesized by New Intramolecular Reductive Double Cyclization Shigehiro Yamaguchi, Caihong Xu, and Kohei Tamao pp 13662–13663 DOI: 10.1021/ja038487+ Supporting Info

A Switch for the Transfer of Substrate between Nonribosomal Peptide and Polyketide Modules of the Rifamycin Synthetase Assembly Line Suzanne J. Admiraal, Chaitan Khosla, and Christopher T. Walsh pp 13664–13665 DOI: 10.1021/ja0379060 Supporting Info

Discovery of the Archaeal Chemical Link between Glycogen (Starch) Synthase Families Using a New Mass Spectrometry Assay Corbin J. Zea, Stephen W. MacDonell, and Nicola L. Pohl pp 13666–13667 DOI: 10.1021/ja037298o Supporting Info

Density Functional Theory Studies of Electron Interaction with DNA:  Can Zero eV Electrons Induce Strand Breaks? Xifeng Li, Michael D. Sevilla, and Léon Sanche pp 13668–13669 DOI: 10.1021/ja036509m Supporting Info

Robust Mixed 10/12 Helices Promoted by “Alternating Chirality” in a New Family of C-Linked Carbo-β-peptides Gangavaram V. M. Sharma, K. Ravinder Reddy, Palakodety Radha Krishna, A. Ravi Sankar, K. Narsimulu, S. Kiran Kumar, P. Jayaprakash, B. Jagannadh, and A. C. Kunwar pp 13670–13671 DOI: 10.1021/ja035752i Supporting Info

The Crystal Structures of the Chiral Alkyllithium Bases [n-BuLi·(−)-Sparteine]2 and [Et2O·(i-PrLi)2·(−)-Sparteine] Carsten Strohmann, Katja Strohfeldt, and Daniel Schildbach pp 13672–13673 DOI: 10.1021/ja0374372 Supporting Info

The Organization and Assembly of a β-Sheet Formed by a Prion Peptide in Solution:  An Isotope-Edited FTIR Study R. A. Gangani D. Silva, Wendy Barber-Armstrong, and Sean M. Decatur pp 13674–13675 DOI: 10.1021/ja036725v Supporting Info

Magnetic Properties of Tetrakis[4-(α-diazobenzyl)pyridine]bis(thiocyanato-N)cobalt(II) in Frozen Solution after Irradiation. Formation of a Single-Molecule Magnet in Frozen Solution Satoru Karasawa, Guangyuan Zhou, Hiroshi Morikawa, and Noboru Koga pp 13676–13677 DOI: 10.1021/ja035478s Supporting Info

A Novel Mechanism of Proton Transfer in Protonated Peptides Petr Kulhánek, Edward W. Schlag, and Jaroslav Koa pp 13678–13679 DOI: 10.1021/ja035800z Supporting Info

Supramolecular Hydrogels Respond to Ligand−Receptor Interaction Yan Zhang, Hongwei Gu, Zhimou Yang, and Bing Xu pp 13680–13681 DOI: 10.1021/ja036817k Supporting Info

Substrate-Induced Pairing in 2,3,6,7,10,11-Hexakis-undecalkoxy-triphenylene Self-Assembled Monolayers on Au(111) Nathalie Katsonis, Alexandr Marchenko, and Denis Fichou pp 13682–13683 DOI: 10.1021/ja0375737

Tunable Photochromism of Spirooxazines via Metal Coordination Roni A. Kopelman, Sean M. Snyder, and Natia L. Frank pp 13684–13685 DOI: 10.1021/ja036306y Supporting Info

Electrocatalytic Investigation of Light-Induced Electron Transfer between Cytochrome c6 and Photosystem I Vanessa Proux-Delrouyre, Christophe Demaille, Winfried Leibl, Pierre Sétif, Hervé Bottin, and Christian Bourdillon pp 13686–13692 DOI: 10.1021/ja0363819

Competitive Reactions in Solutions of Poly-l-histidine, Calf Thymus DNA, and Synthetic Polyanions:  Determining the Binding Constants of Polyelectrolytes Alexander N. Zelikin, Elizabeth S. Trukhanova, David Putnam, Vladimir A. Izumrudov, and Andrey A. Litmanovich pp 13693–13699 DOI: 10.1021/ja036387y

Free Radical Reactions of Methionine in Peptides:  Mechanisms Relevant to β-Amyloid Oxidation and Alzheimer's Disease Christian Schöneich, Dariusz Pogocki, Gordon L. Hug, and Krzysztof Bobrowski pp 13700–13713 DOI: 10.1021/ja036733b Supporting Info

Resonance Raman Spectroscopic Studies of Hydroperoxo-Myoglobin at Cryogenic Temperatures Mohammed Ibrahim, Ilia G. Denisov, Thomas M. Makris, James R. Kincaid, and Stephen G. Sligar pp 13714–13718 DOI: 10.1021/ja036949d Supporting Info

Hypochlorite-Mediated Fragmentation of Hyaluronan, Chondroitin Sulfates, and Related N-Acetyl Glycosamines:  Evidence for Chloramide Intermediates, Free Radical Transfer Reactions, and Site-Specific Fragmentation Martin D. Rees, Clare L. Hawkins, and Michael J. Davies pp 13719–13733 DOI: 10.1021/ja0370591 Supporting Info

Eutectic Phase Polymerization of Activated Ribonucleotide Mixtures Yields Quasi-Equimolar Incorporation of Purine and Pyrimidine Nucleobases Pierre-Alain Monnard, Anastassia Kanavarioti, and David W. Deamer pp 13734–13740 DOI: 10.1021/ja036465h

Impressive Structural Diversity and Polymorphism in the Modular Compounds ABi3Q5 (A = Rb, Cs; Q = S, Se, Te) Lykourgos Iordanidis, Daniel Bilc, Subhendra D. Mahanti, and Mercouri G. Kanatzidis pp 13741–13752 DOI: 10.1021/ja034196p Supporting Info

Combinatorial Decoding:  An Approach for Universal DNA Array Fabrication Jason R. Epstein, Jane A. Ferguson, Kyong-Hoon Lee, and David R. Walt pp 13753–13759 DOI: 10.1021/ja0365577

Ground-State Conformational Equilibrium and Photochemical Behavior of Syn and Anti N,N‘-Dimethyl-N,N‘-di-1-naphthylurea Protophanes Todd L. Kurth and Frederick D. Lewis pp 13760–13767 DOI: 10.1021/ja034311w Supporting Info

The Effect of the Initial Water of Hydration on the Energetics, Structures, and H/D Exchange Mechanism of a Family of Pentapeptides:  An Experimental and Theoretical Study Thomas Wyttenbach, Béla Paizs, Perdita Barran, Linda Breci, Dengfeng Liu, Sándor Suhai, Vicki H. Wysocki, and Michael T. Bowers pp 13768–13775 DOI: 10.1021/ja037204a

“Electromers” of the Tetramethyleneethane Radical Cation and Their Nonexistence in the Octamethyl Derivative:  Interplay of Experiment and Theory Beat Müller, Thomas Bally, Fabian Gerson, Armin de Meijere, and Malte von Seebach pp 13776–13783 DOI: 10.1021/ja037252v Supporting Info

Application of Conformation Design in Acyclic Stereoselection:  Total Synthesis of Borrelidin as the Crystalline Benzene Solvate Stephen Hanessian, Yang Yang, Simon Giroux, Vincent Mascitti, Jianguo Ma, and Franck Raeppel pp 13784–13792 DOI: 10.1021/ja030139k Supporting Info

Novel “Potentially Antiaromatic”, Acidichromic Quinonediimines with Tunable Delocalization of Their 6π-Electron Subunits Olivier Siri, Pierre Braunstein, Marie-Madeleine Rohmer, Marc Bénard, and Richard Welter pp 13793–13803 DOI: 10.1021/ja035463u Supporting Info

Myoglobin-CO Substate Structures and Dynamics:  Multidimensional Vibrational Echoes and Molecular Dynamics Simulations Kusai A. Merchant, W. G. Noid, Ryo Akiyama, Ilya J. Finkelstein, Alexei Goun, Brian L. McClain, Roger F. Loring, and M. D. Fayer pp 13804–13818 DOI: 10.1021/ja035654x Supporting Info

Crucial Role of Three-Center Hydrogen Bonding in a Challenging Chiral Molecular Recognition Sung-Gon Kim, Kyung-Hyun Kim, Young Kook Kim, Seung Koo Shin, and Kyo Han Ahn pp 13819–13824 DOI: 10.1021/ja037031p Supporting Info

Intramolecular 1,3-Dipolar Ene Reactions of Nitrile Oxides Occur by Stepwise 1,1-Cycloaddition/Retro-Ene Mechanisms Zhi-Xiang Yu and K. N. Houk pp 13825–13830 DOI: 10.1021/ja0376487 Supporting Info

Comparative Reactivity of Sterically Crowded nf3 (C5Me5)3Nd and (C5Me5)3U Complexes with CO:  Formation of a Nonclassical Carbonium Ion versus an f Element Metal Carbonyl Complex William J. Evans, Stosh A. Kozimor, Gregory W. Nyce, and Joseph W. Ziller pp 13831–13835 DOI: 10.1021/ja036631l Supporting Info

Deuterium Isotope Effects on Hydrophobic Interactions:  The Importance of Dispersion Interactions in the Hydrophobic Phase Maciej Turowski, Naoki Yamakawa, Jaroslaw Meller, Kazuhiro Kimata, Tohru Ikegami, Ken Hosoya, Nobuo Tanaka, and Edward R. Thornton pp 13836–13849 DOI: 10.1021/ja036006g Supporting Info

Influence of a Polar Near-Neighbor on Incipient Proton Transfer in a Strongly Hydrogen Bonded Complex Sherri W. Hunt, Kelly J. Higgins, Matthew B. Craddock, Carolyn S. Brauer, and Kenneth R. Leopold pp 13850–13860 DOI: 10.1021/ja030435x Supporting Info

The Electronic Structure of the Photoexcited Triplet State of Free-Base (Tetraphenyl)porphyrin by Time-Resolved Electron−Nuclear Double Resonance and Density Functional Theory Christopher W. M. Kay pp 13861–13867 DOI: 10.1021/ja036278j

Ile, Leu, and Val Methyl Assignments of the 723-Residue Malate Synthase G Using a New Labeling Strategy and Novel NMR Methods Vitali Tugarinov and Lewis E. Kay pp 13868–13878 DOI: 10.1021/ja030345s Supporting Info

Insights into the Structure and Reactivity of Acylperoxo Complexes in the Kochi−Jacobsen−Katsuki Catalytic System. A Density Functional Study Ilja V. Khavrutskii, Djamaladdin G. Musaev, and Keiji Morokuma pp 13879–13889 DOI: 10.1021/ja0343656 Supporting Info

Functional Dynamics of Ion Channels:  Modulation of Proton Movement by Conformational Switches Ching-Hsing Yu and Régis Pomès pp 13890–13894 DOI: 10.1021/ja0353208

Selective Binding of Monovalent Cations to the Stacking G-Quartet Structure Formed by Guanosine 5‘-Monophosphate:  A Solid-State NMR Study Alan Wong and Gang Wu pp 13895–13905 DOI: 10.1021/ja0302174 Supporting Info

Principles of the Quantum Control of Molecular Processes By Moshe Shapiro (Weizmann Institute of Science) and Paul Brumer (University of Toronto). John Wiley & Sons, Inc.:  Hoboken. 2003. xiv + 354 pp. $79.95. ISBN 0-471-24184-9. Robert J. Levis p 13906 DOI: 10.1021/ja033533r

Physical Chemistry of Polymer Rheology By Junji Furukawa (Kyoto University). Springer Series in Chemical Physics, No. 72. Edited by F. P. Schäfer, J. P. Toennies, and W. Zingth. Kodansha, Ltd.:  Tokyo, and Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xvi + 278 pp. $99.00. ISBN 4-06-209664-1 (Kodansha) and 3-540-00053-4 (Springer-Verlag). G. C. Berry pp 13906–13907 DOI: 10.1021/ja0335723

Advances in Controlled/Living Radical Polymerization Edited by Krzysztof Matyjaszewski (Carnegie Mellon University). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2003. xvi + 688 pp. $175.00. ISBN 0-8412-3854-5. p 13907 DOI: 10.1021/ja033575f

Handbook of Thermoluminescence By Claudio Furetta (Rome University “La Sapienza”). World Scientific:  Singapore, River Edge, NJ, London. 2003. xviii + 462 pp. $84.00. ISBN 981-238-240-2. p 13907 DOI: 10.1021/ja033585g

Beyond Metallocenes:  Next-Generation Polymerization Catalysts Edited by Abhimanyu O. Patil (ExxonMobil Research and Engineering Company) and Gregory G. Hlatky (Equistar Chemical LP). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2003. xiv + 250 pp. $130.00. ISBN 0-8412-3838-3. p 13907 DOI: 10.1021/ja0335871

Oligosaccharides in Food and Agriculture Edited by Gillian Eggleston and Gregory L. Côté (U.S. Department of Agriculture). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2003. xiv + 250 pp. $125.00. ISBN 0-8412-3826-X. pp 13907–13908 DOI: 10.1021/ja0335768

Group 13 Chemistry III:  Industrial Applications Edited by Herbert W. Roesky (University of Göttingen, Germany) and David A. Atwood (University of Kentucky, Lexington). From the Series, Structure & Bonding, 105. Edited by D. M. P. Mingos. Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 208 pp. $169.00. ISBN 3-540-44105-0. Guy Bertrand p 13908 DOI: 10.1021/ja033573v

Issue 46

Experimental Evidence for Intramolecular Blue-Shifting C−H···O Hydrogen Bonding by Matrix-Isolation Infrared Spectroscopy Hiroatsu Matsuura, Hiroshi Yoshida, Munenori Hieda, Shin-ya Yamanaka, Takanori Harada, Kei Shin-ya, and Keiichi Ohno pp 13910–13911 DOI: 10.1021/ja030538f Supporting Info

Intervalence Involvement of Bridging Ligand Vibrations in Hexaruthenium Mixed-Valence Clusters Probed by Resonance Raman Spectroscopy Casey H. Londergan, Reginaldo C. Rocha, Mac G. Brown, Andrew P. Shreve, and Clifford P. Kubiak pp 13912–13913 DOI: 10.1021/ja036127g Supporting Info

Preferential End-to-End Assembly of Gold Nanorods by Biotin−Streptavidin Connectors K. K. Caswell, James N. Wilson, Uwe H. F. Bunz, and Catherine J. Murphy pp 13914–13915 DOI: 10.1021/ja037969i Supporting Info

Covalently Attached Saccharides on Silicon Surfaces Louis C. P. M. de Smet, Gerrit A. Stork, Geert H. F. Hurenkamp, Qiao-Yu Sun, Hüseyin Topal, Patrick J. E. Vronen, Alex B. Sieval, Andrew Wright, Gerben M. Visser, Han Zuilhof, and Ernst J. R. Sudhölter pp 13916–13917 DOI: 10.1021/ja037445i

Lighting-Up the Dynamics of Telomerization and DNA Replication by CdSe−ZnS Quantum Dots Fernando Patolsky, Ron Gill, Yossi Weizmann, Taleb Mokari, Uri Banin, and Itamar Willner pp 13918–13919 DOI: 10.1021/ja035848c Supporting Info

Two Metal Centers Bridging Two C60 Cages as a Wide Passage for Efficient Interfullerene Electronic Interaction Gaehang Lee, Youn-Jaung Cho, Bo Keun Park, Kwangyeol Lee, and Joon T. Park pp 13920–13921 DOI: 10.1021/ja037106p Supporting Info

Multistimuli, Multiresponsive Metallo-Supramolecular Polymers J. Benjamin Beck and Stuart J. Rowan pp 13922–13923 DOI: 10.1021/ja038521k Supporting Info

Efficient and Sequence-Specific DNA-Templated Polymerization of Peptide Nucleic Acid Aldehydes Daniel M. Rosenbaum and David R. Liu pp 13924–13925 DOI: 10.1021/ja038058b Supporting Info

Formation of 13C-, 15N-, and 18O-Labeled Guanidinohydantoin from Guanosine Oxidation with Singlet Oxygen. Implications for Structure and Mechanism Yu Ye, James G. Muller, Wenchen Luo, Charles L. Mayne, Anthony J. Shallop, Roger A. Jones, and Cynthia J. Burrows pp 13926–13927 DOI: 10.1021/ja0378660 Supporting Info

Helical Sexithiophenes:  An Experimental and Theoretical Study Implicating the Alternating 2,2‘:3,3‘ Regioisomer as a Reliable Helical Motif Michael J. Marsella, Kunsang Yoon, Adah Almutairi, Sheraz K. Butt, and Fook S. Tham pp 13928–13929 DOI: 10.1021/ja038260e Supporting Info

Do All-Metal Antiaromatic Clusters Exist? Zhongfang Chen, Clémence Corminboeuf, Thomas Heine, Jon Bohmann, and Paul von Ragué Schleyer pp 13930–13931 DOI: 10.1021/ja0361392 Supporting Info

Membrane Mimetic Environments Alter the Conformation of the Outer Membrane Protein BtuB Gail E. Fanucci, Jae Y. Lee, and David S. Cafiso pp 13932–13933 DOI: 10.1021/ja0376442 Supporting Info

Supramolecular Peapods Composed of a Metalloporphyrin Nanotube and Fullerenes Tatsuya Yamaguchi, Noriyuki Ishii, Kentaro Tashiro, and Takuzo Aida pp 13934–13935 DOI: 10.1021/ja038178j Supporting Info

Molecular Recognition and Conductance in Crown Ethers Chris Liu, Derek Walter, and Daniel NeuhauserRoi Baer pp 13936–13937 DOI: 10.1021/ja029085p

Transverse Dephasing Optimized Solid-State NMR Spectroscopy G. De Paëpe, N. Giraud, A. Lesage, P. Hodgkinson, A. Böckmann, and L. Emsley pp 13938–13939 DOI: 10.1021/ja037213j Supporting Info

Completely “Green” Synthesis and Stabilization of Metal Nanoparticles Poovathinthodiyil Raveendran, Jie Fu, and Scott L. Wallen pp 13940–13941 DOI: 10.1021/ja029267j Supporting Info

α‘-Hydroxy Enones as Achiral Templates for Lewis Acid-Catalyzed Enantioselective Diels−Alder Reactions Claudio Palomo, Mikel Oiarbide, Jesús M. García, Alberto González, and Elena Arceo pp 13942–13943 DOI: 10.1021/ja0368002 Supporting Info

Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes Amy H. Roy and John F. Hartwig pp 13944–13945 DOI: 10.1021/ja037959h Supporting Info

Tuning Chirality of Single-Wall Carbon Nanotubes by Selective Etching with Carbon Dioxide Kwanyong Seo, Changwook Kim, Yong Soo Choi, Kyung Ah Park, Young Hee Lee, and Bongsoo Kim pp 13946–13947 DOI: 10.1021/ja035262q Supporting Info

Unusual Tethering Effects in the Schmidt Reaction of Hydroxyalkyl Azides with Ketones:  Cation−π and Steric Stabilization of a Pseudoaxial Phenyl Group Christopher E. Katz and Jeffrey Aubé pp 13948–13949 DOI: 10.1021/ja0382361 Supporting Info

Facile Self-Assembly of Predesigned Neutral 2D Pt-Macrocycles via a New Class of Rigid Oxygen Donor Linkers Neeladri Das, Partha Sarathi Mukherjee, Atta M. Arif, and Peter J. Stang pp 13950–13951 DOI: 10.1021/ja037788g Supporting Info

Lipase-Catalyzed Kinetic Resolution on Solid-Phase via a “Capture and Release” Strategy Cara E. Humphrey, Nicholas J. Turner, Morag A. M. Easson, Sabine L. Flitsch, and Rein V. Ulijn pp 13952–13953 DOI: 10.1021/ja037922x Supporting Info

An X- (X = I, Br)-Triggered Ring-Opening Coupling Reaction of Cyclopropenes with Organic Halides Shengming Ma, Junliang Zhang, Yangjun Cai, and Lianghua Lu pp 13954–13955 DOI: 10.1021/ja038131y Supporting Info

Mechanism of Chromyl Chloride Alkane Oxidation Anthony K. Rappe and Maria Jaworska pp 13956–13957 DOI: 10.1021/ja036362z Supporting Info

Projection−Reconstruction of Three-Dimensional NMR Spectra Ēriks Kupe and Ray Freeman pp 13958–13959 DOI: 10.1021/ja038297z Supporting Info

Synthesis of MnP Nanocrystals by Treatment of Metal Carbonyl Complexes with Phosphines:  A New, Versatile Route to Nanoscale Transition Metal Phosphides Susanthri C. Perera, Georgy Tsoi, Lowell E. Wenger, and Stephanie L. Brock pp 13960–13961 DOI: 10.1021/ja038037h Supporting Info

Computational Studies on the A Cluster of Acetyl-Coenzyme A Synthase:  Geometric and Electronic Properties of the NiFeC Species and Mechanistic Implications Ralph P. Schenker and Thomas C. Brunold pp 13962–13963 DOI: 10.1021/ja037893q Supporting Info

Trimethylsilylation of Framework Brønsted Acid Sites in Microporous Zeolites and Silico-Aluminophosphates Weiguo Song, David M. Marcus, Saifudin M. Abubakar, Emma Jani, and James F. Haw pp 13964–13965 DOI: 10.1021/ja034541a

Structure-Selective Synthesis of Mesostructured/Mesoporous Silica Nanofibers Jianfang Wang, Jinping Zhang, Beverly Y. Asoo, and Galen D. Stucky pp 13966–13967 DOI: 10.1021/ja036967v Supporting Info

Association Lifetimes of Hydrophobic Amino Acid Pairs Measured Directly from Molecular Dynamics Simulations Hongbo Yang and Adrian H. Elcock pp 13968–13969 DOI: 10.1021/ja037010v

Conversion of Homocysteine to Methionine by Methionine Synthase: A Density Functional Study Kasper P. Jensen and Ulf Ryde pp 13970–13971 DOI: 10.1021/ja034697a Supporting Info

Significant Kinetic Solvent Isotope Effects in Folding of the Catalytic RNA from the Hepatitis Delta Virus Rebecca A. Tinsley, Dinari A. Harris, and Nils G. Walter pp 13972–13973 DOI: 10.1021/ja037870b Supporting Info

Synthesis of Ferrocene/Hydrofullerene Hybrid and Functionalized Bucky Ferrocenes Motoki Toganoh, Yutaka Matsuo, and Eiichi Nakamura pp 13974–13975 DOI: 10.1021/ja037335b Supporting Info

An Azide-Bridged Homospin Single-Chain Magnet:  [Co(2,2‘-bithiazoline)(N3)2]n Tian-Fu Liu, Dan Fu, Song Gao, Yuan-Zhu Zhang, Hao-Ling Sun, Gang Su, and Yong-Jiang Liu pp 13976–13977 DOI: 10.1021/ja0380751 Supporting Info

Insights into the Origin of High Activity and Stability of Catalysts Derived from Bulky, Electron-Rich Monophosphinobiaryl Ligands in the Pd-Catalyzed C−N Bond Formation Eric R. Strieter, Donna G. Blackmond, and Stephen L. Buchwald pp 13978–13980 DOI: 10.1021/ja037932y Supporting Info

Individual Solvent/Solute Interactions through Social Isomerism Alessandro Scarso, Alexander Shivanyuk, and Julius Rebek, Jr. pp 13981–13983 DOI: 10.1021/ja037808e

Kinetic Evidence for the Existence and Mechanism of Formation of a Barrel Stave Structure from Pore-Forming Dendrimers Jianbing Zhang, Bingwen Jing, and Steven L. Regen pp 13984–13987 DOI: 10.1021/ja036390h Supporting Info

Free-Energy Calculations of Protein−Ligand Cation−π and Amino−π Interactions: From Vacuum to Proteinlike Environments Christophe Biot, Eric Buisine, and Marianne Rooman pp 13988–13994 DOI: 10.1021/ja035223e Supporting Info

Isolation of Protein Ligands from Large Peptoid Libraries Prasanna G. Alluri, M. Muralidhar Reddy, Kiran Bachhawat-Sikder, Hernando J. Olivos, and Thomas Kodadek pp 13995–14004 DOI: 10.1021/ja036417x Supporting Info

A Transient Product of DNA Alkylation Can Be Stabilized by Binding Localization Willem F. Veldhuyzen, Praveen Pande, and Steven E. Rokita pp 14005–14013 DOI: 10.1021/ja036943o Supporting Info

Homoanomeric Effects in Six-Membered Heterocycles Igor V. Alabugin, Mariappan Manoharan, and Tarek A. Zeidan pp 14014–14031 DOI: 10.1021/ja037304g Supporting Info

Origin of Strong Chiroptical Activities in Films of Nonafluorenes with a Varying Extent of Pendant Chirality Yanhou Geng, Anita Trajkovska, Sean W. Culligan, Jane J. Ou, H. M. Philip Chen, Dimitris Katsis, and Shaw H. Chen pp 14032–14038 DOI: 10.1021/ja037733e Supporting Info

End Coupling of Block Copolymer Nanotubes to Nanospheres Guojun Liu, Xiaohu Yan, Zhao Li, Jiayun Zhou, and Scott Duncan pp 14039–14045 DOI: 10.1021/ja034847h Supporting Info

Ferromagnetic and Antiferromagnetic Intermolecular Interactions in a New Family of Mn4 Complexes with an Energy Barrier to Magnetization Reversal Colette Boskovic, Roland Bircher, Philip L. W. Tregenna-Piggott, Hans U. Güdel, Carley Paulsen, Wolfgang Wernsdorfer, Anne-Laure Barra, Eugene Khatsko, Antonia Neels, and Helen Stoeckli-Evans pp 14046–14058 DOI: 10.1021/ja0367086 Supporting Info

Derivatization of Deltahedral Zintl Ions by Nucleophilic Addition:  [Ph−Ge9−SbPh2]2- and [Ph2Sb−Ge9−Ge9−SbPh2]4- Angel Ugrinov and Slavi C. Sevov pp 14059–14064 DOI: 10.1021/ja037007b Supporting Info

Hydrogen-Bond Cooperativity, Vibrational Coupling, and Dependence of Helix Stability on Changes in Amino Acid Sequence in Small 310-Helical Peptides. A Density Functional Theory Study Robert Wieczorek and J. J. Dannenberg pp 14065–14071 DOI: 10.1021/ja034034t Supporting Info

Probing the Intrinsic Electronic Structure of the Cubane [4Fe−4S] Cluster:  Nature's Favorite Cluster for Electron Transfer and Storage Xue-Bin Wang, Shuqiang Niu, Xin Yang, Saad K. Ibrahim, Christopher J. Pickett, Toshiko Ichiye, and Lai-Sheng Wang pp 14072–14081 DOI: 10.1021/ja036831x

Theoretical Study of Cisplatin Binding to Purine Bases:  Why Does Cisplatin Prefer Guanine over Adenine? Mu-Hyun Baik, Richard A. Friesner, and Stephen J. Lippard pp 14082–14092 DOI: 10.1021/ja036960d Supporting Info

Protein-Based Radicals in the Catalase-Peroxidase of Synechocystis PCC6803:  A Multifrequency EPR Investigation of Wild-Type and Variants on the Environment of the Heme Active Site Anabella Ivancich, Christa Jakopitsch, Markus Auer, Sun Un, and Christian Obinger pp 14093–14102 DOI: 10.1021/ja035582+ Supporting Info

Symmetry Switching of the Fluorescent Excited State in α,ω-Diphenylpolyynes Yasutomo Nagano, Tadaaki Ikoma, Kimio Akiyama, and Shozo Tero-Kubota pp 14103–14112 DOI: 10.1021/ja035173d

Molecular Design of Free Volume as a Route to Low-κ Dielectric Materials Timothy M. Long and Timothy M. Swager pp 14113–14119 DOI: 10.1021/ja0360945

The Total Synthesis of (+)-Hapalindole Q by an Organomediated Diels−Alder Reaction Aaron C. Kinsman and Michael A. Kerr pp 14120–14125 DOI: 10.1021/ja036191y Supporting Info

Ambident Reactivity of the Thiocyanate Anion Revisited:  Can the Product Ratio Be Explained by the Hard Soft Acid Base Principle? Robert Loos, Shinjiro Kobayashi, and Herbert Mayr pp 14126–14132 DOI: 10.1021/ja037317u Supporting Info

Chiral Bis-π-allylpalladium Complex Catalyzed Asymmetric Allylation of Imines:  Enhancement of the Enantioselectivity and Chemical Yield in the Presence of Water Rodney A. Fernandes, Anton Stimac, and Yoshinori Yamamoto pp 14133–14139 DOI: 10.1021/ja037272x Supporting Info

Stereoselective Palladium-Catalyzed Carbocyclization of Allenic Allylic Carboxylates Johan Franzén, Joakim Löfstedt, Jennica Falk, and Jan-E. Bäckvall pp 14140–14148 DOI: 10.1021/ja037398u Supporting Info

Nucleophilic Additions to Fused Bicyclic Five-Membered Ring Oxocarbenium Ions:  Evidence for Preferential Attack on the Inside Face Deborah M. Smith, Michelle B. Tran, and K. A. Woerpel pp 14149–14152 DOI: 10.1021/ja0375176 Supporting Info

Experimental and Theoretical Investigation of Reversible Interconversion, Thermal Reactions, and Wavelength-Dependent Photochemistry of Diazo Meldrum's Acid and Its Diazirine Isomer, 6,6-Dimethyl-5,7-dioxa-1,2-diaza-spiro[2,5]oct-1-ene-4,8-dione1 Aneta Bogdanova and Vladimir V. Popik pp 14153–14162 DOI: 10.1021/ja037637d Supporting Info

Highly Practical and General Synthesis of Monodisperse Linear π-Conjugated Oligoenynes and Oligoenediynes with Either trans- or cis-Olefin Configuration Yuuki Takayama, Christophe Delas, Kenji Muraoka, Minoru Uemura, and Fumie Sato pp 14163–14167 DOI: 10.1021/ja037975e Supporting Info

Metal-Core−Organic Shell Dendrimers as Unimolecular Micelles K. R. Gopidas, James K. Whitesell, and Marye Anne Fox pp 14168–14180 DOI: 10.1021/ja036626h Supporting Info

Molecular Acrobatics:  Self-Assembly of Calixarene-Porphyrin Cages Laura Baldini, Pablo Ballester, Alessandro Casnati, Rosa M. Gomila, Christopher A. Hunter, Francesco Sansone, and Rocco Ungaro pp 14181–14189 DOI: 10.1021/ja036758a

Porphyrazines with Annulated Diazepine Rings. 2. Alternative Synthetic Route to Tetrakis-2,3-(5,7-diphenyl-1,4-diazepino)porphyrazines:  New Metal Complexes, General Physicochemical Data, Ultraviolet−Visible Linear and Optical Limiting Behavior, and Electrochemical and Spectroelectrochemical Properties Maria Pia Donzello, Danilo Dini, Giuseppe D'Arcangelo, Claudio Ercolani, Riqiang Zhan, Zhongping Ou, Pavel A. Stuzhin, and Karl M. Kadish pp 14190–14204 DOI: 10.1021/ja0344361 Supporting Info

Anomalous Behavior of Atomic Hydrogen Interacting with Gold Clusters Stefan Buckart, Gerd Ganteför, Young Dok Kim, and Puru Jena pp 14205–14209 DOI: 10.1021/ja036544t

Quantitative Measure for the “Nakedness” of Fluoride Ion Sources [J. Am. Chem. Soc. 2003, 125, 9457−9461]. Karl O. Christe and H. Donald Brooke Jenkins p 14210 DOI: 10.1021/ja038167q

Issue 47

Iridium-Mediated Asymmetric Hydrogenation of 2,3-Diphenylbutadiene:  A Revealing Kinetic Study Xiuhua Cui and Kevin Burgess pp 14212–14213 DOI: 10.1021/ja037653a Supporting Info

Orientation and Conformation of Cell-Penetrating Peptide Penetratin in Phospholipid Vesicle Membranes Determined by Polarized-Light Spectroscopy Christina E. B. Brattwall, Per Lincoln, and Bengt Nordén pp 14214–14215 DOI: 10.1021/ja0366989 Supporting Info

Multiple Intermolecular Interaction Modes of Positively Charged Residues with Adenine in ATP-Binding Proteins Lisong Mao, Yanli Wang, Yuemin Liu, and Xiche Hu pp 14216–14217 DOI: 10.1021/ja036096p Supporting Info

Surface Vibrational Spectroscopy on Shear-Aligned Poly(tetrafluoroethylene) Films Na Ji, Victor Ostroverkhov, François Lagugné-Labarthet, and Yuen-Ron Shen pp 14218–14219 DOI: 10.1021/ja037964l

Spectroscopy and Reactivity of a Photogenerated Tryptophan Radical in a Structurally Defined Protein Environment Jeremiah E. Miller, Cristian Grdinaru, Brian R. Crane, Angel J. Di Bilio, William A. Wehbi, Sun Un, Jay R. Winkler, and Harry B. Gray pp 14220–14221 DOI: 10.1021/ja037203i Supporting Info

High-Sensitivity Observation of Dipolar Exchange and NOEs between Exchangeable Protons in Proteins by 3D Solid-State NMR Spectroscopy Eric K. Paulson, Corey R. Morcombe, Vadim Gaponenko, Barbara Dancheck, R. Andrew Byrd, and Kurt W. Zilm pp 14222–14223 DOI: 10.1021/ja037559u

Synergy between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type Ana Galet, Virginie Niel, M. Carmen Muñoz, and José A. Real pp 14224–14225 DOI: 10.1021/ja0377347 Supporting Info

Insulating Tubular BN Sheathing on Semiconducting Nanowires Ying-Chun Zhu, Yoshio Bando, Dong-Feng Xue, Fang-Fang Xu, and Dmitri Golberg pp 14226–14227 DOI: 10.1021/ja0381196 Supporting Info

Jahn−Teller Distortion in the Phosphorescent Excited State of Three-Coordinate Au(I) Phosphine Complexes Khaldoon A. Barakat, Thomas R. Cundari, and Mohammad A. Omary pp 14228–14229 DOI: 10.1021/ja036508u Supporting Info

RNA Degradation in Cell Extracts:  Real-Time Monitoring by Fluorescence Resonance Energy Transfer Sarah A. Uhler, Dawen Cai, Yunfang Man, Carina Figge, and Nils G. Walter pp 14230–14231 DOI: 10.1021/ja036854b Supporting Info

Quantum Chemistry Can Locally Improve Protein Crystal Structures Ulf Ryde and Kristina Nilsson pp 14232–14233 DOI: 10.1021/ja0365328 Supporting Info

A Hexapeptide Motif that Electrostatically Binds to the Surface of Titanium Ken-Ichi Sano and Kiyotaka Shiba pp 14234–14235 DOI: 10.1021/ja038414q Supporting Info

The Post-Polyketide Synthase Modification Steps in the Biosynthesis of the Antitumor Agent Ansamitocin by Actinosynnema pretiosum Peter Spiteller, Linquan Bai, Guangdong Shang, Brian J. Carroll, Tin-Wein Yu, and Heinz G. Floss pp 14236–14237 DOI: 10.1021/ja038166y Supporting Info

A New Approach to the Chemical Synthesis of Keto-Proteins David Tumelty, Maia Carnevali, and Les P. Miranda pp 14238–14239 DOI: 10.1021/ja037357y Supporting Info

A Programmable Molecular Diode Driven by Charge-Induced Conformational Changes Pedro A. Derosa, Suneel Guda, and Jorge M. Seminario pp 14240–14241 DOI: 10.1021/ja035071n

Oxidative Cycloamination of Olefins with Aziridines as a Versatile Route to Saturated Nitrogen-Containing Heterocycles Mikio Sasaki and Andrei K. Yudin pp 14242–14243 DOI: 10.1021/ja037726q Supporting Info

Fast Protein Structure Prediction Using Monte Carlo Simulations with Modal Moves Paolo Carnevali, Gergely Tóth, Garrick Toubassi, and Siavash N. Meshkat pp 14244–14245 DOI: 10.1021/ja036647b Supporting Info

Parallel Molecular Computations of Pairwise Exclusive-Or (XOR) Using DNA “String Tile” Self-Assembly Hao Yan, Liping Feng, Thomas H. LaBean, and John H. Reif pp 14246–14247 DOI: 10.1021/ja036676m Supporting Info

Versatile Fluorescence Probes of Protein Kinase Activity Melissa D. Shults and Barbara Imperiali pp 14248–14249 DOI: 10.1021/ja0380502 Supporting Info

Fast Mapping of Protein−Protein Interfaces by NMR Spectroscopy Michael L. Reese and Volker Dötsch pp 14250–14251 DOI: 10.1021/ja037640x Supporting Info

Orthogonal Self-Assembly of Low Molecular Weight Hydrogelators and Surfactants André Heeres, Cornelia van der Pol, Marc Stuart, Arianna Friggeri, Ben L. Feringa, and Jan van Esch pp 14252–14253 DOI: 10.1021/ja036954h Supporting Info

Aryl−Oxygen Bond Cleavage by a Trihydride-Bridging Ditantalum Complex Hiroyuki Kawaguchi and Tsukasa Matsuo pp 14254–14255 DOI: 10.1021/ja037551k Supporting Info

Radical Reactions of Didehydroarenes with a 1,4-Relationship F. Sedinam Amegayibor, John J. Nash, and Hilkka I. Kenttämaa pp 14256–14257 DOI: 10.1021/ja0360079 Supporting Info

Laser-Induced Temperature Jump Electrochemistry on Gold Nanoparticle-Coated Electrodes Lisa B. Lowe, Scott H. Brewer, Stephan Krämer, Ryan R. Fuierer, Guoguang Qian, Chiamaka O. Agbasi-Porter, Selina Moses, Stefan Franzen, and Daniel L. Feldheim pp 14258–14259 DOI: 10.1021/ja036672h Supporting Info

Asymmetric, Catalytic Synthesis of α-Chiral Amines Using a Novel Bis(phosphine) Monoxide Chiral Ligand Alessandro A. Boezio, Julien Pytkowicz, Alexandre Côté, and André B. Charette pp 14260–14261 DOI: 10.1021/ja038291+ Supporting Info

γ-Allyl Phosphinoyl Phenyl Sulfone (GAPPS):  A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3-Dienes Xiaojin Li, Douglas Lantrip, and Philip L. Fuchs pp 14262–14263 DOI: 10.1021/ja0377596 Supporting Info

A Monometallic f Element Complex of Dinitrogen:  (C5Me5)3U(η1-N2) William J. Evans, Stosh A. Kozimor, and Joseph W. Ziller pp 14264–14265 DOI: 10.1021/ja037647e Supporting Info

Accelerating Effect of a Proton on the Reduction of CO2 Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex Hideki Hayashi, Seiji Ogo, Tsutomu Abura, and Shunichi Fukuzumi pp 14266–14267 DOI: 10.1021/ja036117f Supporting Info

Organic Functionalization and Optical Properties of Carbon Onions Vasilios Georgakilas, Dirk M. Guldi, Raffaella Signorini, Renato Bozio, and Maurizio Prato pp 14268–14269 DOI: 10.1021/ja0342805 Supporting Info

A “Turn-On” Fluorescent Sensor for the Selective Detection of Mercuric Ion in Aqueous Media Elizabeth M. Nolan and Stephen J. Lippard pp 14270–14271 DOI: 10.1021/ja037995g Supporting Info

Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity Christoph A. Kiener, Chutian Shu, Christopher Incarvito, and John F. Hartwig pp 14272–14273 DOI: 10.1021/ja038319h Supporting Info

A Highly Stable Gadolinium Complex with a Fast, Associative Mechanism of Water Exchange Marlon K. Thompson, Mauro Botta, Gaëlle Nicolle, Lothar Helm, Silvio Aime, André E. Merbach, and Kenneth N. Raymond pp 14274–14275 DOI: 10.1021/ja037441d Supporting Info

Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes Suzanne A. Blum, Patrick J. Walsh, and Robert G. Bergman pp 14276–14277 DOI: 10.1021/ja037267t Supporting Info

Polarizing the Nazarov Cyclization:  Efficient Catalysis under Mild Conditions Wei He, Xiufeng Sun, and Alison J. Frontier pp 14278–14279 DOI: 10.1021/ja037910b Supporting Info

Single-Phase and Gram-Scale Routes toward Nearly Monodisperse Au and Other Noble Metal Nanocrystals Nikhil R. Jana and Xiaogang Peng pp 14280–14281 DOI: 10.1021/ja038219b Supporting Info

The 4-Oxalocrotonate Tautomerase- and YwhB-Catalyzed Hydration of 3E-Haloacrylates:  Implications for the Evolution of New Enzymatic Activities Susan C. Wang, William H. Johnson, Jr., and Christian P. Whitman pp 14282–14283 DOI: 10.1021/ja0370948

Nanocrystalline Todorokite-Like Manganese Oxide Produced by Bacterial Catalysis Hack-Sung Kim, Pablo A. Pastén, Jean-François Gaillard, and Peter C. Stair pp 14284–14285 DOI: 10.1021/ja0375784 Supporting Info

Intermolecular, Markovnikov Hydroamination of Vinylarenes with Alkylamines Masaru Utsunomiya and John F. Hartwig pp 14286–14287 DOI: 10.1021/ja0375535 Supporting Info

Regioselectivity in the Stille Coupling Reactions of 3,5-Dibromo-2-pyrone Won-Suk Kim, Hyung-Jin Kim, and Cheon-Gyu Cho pp 14288–14289 DOI: 10.1021/ja037043a Supporting Info

New Structures from Multiple Rearrangements of Propargylic Dialkoxy Disulfides Samuel Braverman, Tatiana Pechenick, Hugo E. Gottlieb, and Milon Sprecher pp 14290–14291 DOI: 10.1021/ja036962y Supporting Info

Alkane C−H Activation and Catalysis by an O-Donor Ligated Iridium Complex Antek G. Wong-Foy, Gaurav Bhalla, Xiang Yang Liu, and Roy A. Periana pp 14292–14293 DOI: 10.1021/ja037849a Supporting Info

Total Synthesis of Gymnocin-A Chihiro Tsukano and Makoto Sasaki pp 14294–14295 DOI: 10.1021/ja038547b Supporting Info

Evidence for Homo-Conjugation between Two Revolving 14π-Electron Systems in 10b-Methyl-10c-[2-(10b,10c-dimethyl-10b,10c-dihydropyrenyl)]-10b,10c-dihydropyrene Jianping Jiang and Yee-Hing Lai pp 14296–14297 DOI: 10.1021/ja0382260 Supporting Info

Rational Design of Transglutaminase Substrate Peptides for Rapid Enzymatic Formation of Hydrogels Bi-Huang Hu and Phillip B. Messersmith pp 14298–14299 DOI: 10.1021/ja038593b Supporting Info

Crystal Structure and Hydrogen Bonding System in Cellulose Iα from Synchrotron X-ray and Neutron Fiber Diffraction Yoshiharu Nishiyama, Junji Sugiyama, Henri Chanzy, and Paul Langan pp 14300–14306 DOI: 10.1021/ja037055w Supporting Info

Enhancing the Modularity of the Modular Polyketide Synthases:  Transacylation in Modular Polyketide Synthases Catalyzed by Malonyl-CoA:ACP Transacylase Pawan Kumar, Andrew T. Koppisch, David E. Cane, and Chaitan Khosla pp 14307–14312 DOI: 10.1021/ja037429l Supporting Info

Iminosugar Glycosidase Inhibitors:  Structural and Thermodynamic Dissection of the Binding of Isofagomine and 1-Deoxynojirimycin to β-Glucosidases David L. Zechel, Alisdair B. Boraston, Tracey Gloster, Catherine M. Boraston, James M. Macdonald, D. Matthew G. Tilbrook, Robert V. Stick, and Gideon J. Davies pp 14313–14323 DOI: 10.1021/ja036833h

Disulfide Bond Isomerization in Basic Pancreatic Trypsin Inhibitor:  Multisite Chemical Exchange Quantified by CPMG Relaxation Dispersion and Chemical Shift Modeling Michael J. Grey, Chunyu Wang, and Arthur G. Palmer, III pp 14324–14335 DOI: 10.1021/ja0367389

Molecular Recognition of Protein Surfaces:  High Affinity Ligands for the CBP KIX Domain Stacey E. Rutledge, Heather M. Volkman, and Alanna Schepartz pp 14336–14347 DOI: 10.1021/ja034508o Supporting Info

Anion-Mediated Transfer of Polyarginine across Liquid and Bilayer Membranes Naomi Sakai and Stefan Matile pp 14348–14356 DOI: 10.1021/ja037601l

Enzymatic Synthesis of Chondroitin and Its Derivatives Catalyzed by Hyaluronidase Shiro Kobayashi, Shun-ichi Fujikawa, and Masashi Ohmae pp 14357–14369 DOI: 10.1021/ja036584x

Superoxide Dismutase Targets NO from GSNO to Cysβ93 of Oxyhemoglobin in Concentrated but Not Dilute Solutions of the Protein Andrea A. Romeo, John A. Capobianco, and Ann M. English pp 14370–14378 DOI: 10.1021/ja0289752

Universal NMR Databases for Contiguous Polyols Shuhei Higashibayashi, Werngard Czechtizky, Yoshihisa Kobayashi, and Yoshito Kishi pp 14379–14393 DOI: 10.1021/ja0375481 Supporting Info

Prototypal Dithiazolodithiazolyl Radicals:  Synthesis, Structures, and Transport Properties Leanne Beer, James F. Britten, Jaclyn L. Brusso, A. Wallace Cordes, Robert C. Haddon, Mikhail E. Itkis, Douglas S. MacGregor, Richard T. Oakley, Robert W. Reed, and Craig M. Robertson pp 14394–14403 DOI: 10.1021/ja0371350 Supporting Info

Phosphine Coordination Complexes of the Diphenylphosphenium Cation:  A Versatile Synthetic Methodology for P−P Bond Formation Neil Burford, Paul J. Ragogna, Robert McDonald, and Michael J. Ferguson pp 14404–14410 DOI: 10.1021/ja036649w Supporting Info

Ketone Enolization by Lithium Hexamethyldisilazide:  Structural and Rate Studies of the Accelerating Effects of Trialkylamines Pinjing Zhao and David B. Collum pp 14411–14424 DOI: 10.1021/ja030168v Supporting Info

A Computational Study of the Cycloaddition of Thiobenzophenone S-Methylide to Thiobenzophenone Reiner Sustmann, Willi Sicking, and Rolf Huisgen pp 14425–14434 DOI: 10.1021/ja0377551 Supporting Info

Multicomponent Linchpin Couplings. Reaction of Dithiane Anions with Terminal Epoxides, Epichlorohydrin, and Vinyl Epoxides:  Efficient, Rapid, and Stereocontrolled Assembly of Advanced Fragments for Complex Molecule Synthesis Amos B. Smith, III, Suresh M. Pitram, Armen M. Boldi, Matthew J. Gaunt, Chris Sfouggatakis, and William H. Moser pp 14435–14445 DOI: 10.1021/ja0376238 Supporting Info

Exclusive Formation of α-Methyleneoxetanes in Ketene−Alkene Cycloadditions. Evidence for Intervention of Both an α-Methyleneoxetane and the Subsequent 1,4-Zwitterion Takahisa Machiguchi, Junko Okamoto, Junpei Takachi, Toshio Hasegawa, Shinichi Yamabe, and Tsutomu Minato pp 14446–14448 DOI: 10.1021/ja030191g Supporting Info

Ammonium Cyanate Shows N−H···N Hydrogen Bonding, Not N−H···O Elizabeth J. MacLean, Kenneth D. M. Harris, Benson M. Kariuki, Simon J. Kitchin, Rik R. Tykwinski, Ian P. Swainson, and Jack D. Dunitz pp 14449–14451 DOI: 10.1021/ja021156x Supporting Info

A Reverse Turn Structure Induced by a d,l-α-Aminoxy Acid Dimer Dan Yang, Jin Qu, Wei Li, De-Ping Wang, Yi Ren, and Yun-Dong Wu pp 14452–14457 DOI: 10.1021/ja029514j Supporting Info

Ion Pairing in Fast-Exchange Host−Guest Systems:  Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions Feihe Huang, Jason W. Jones, Carla Slebodnick, and Harry W. Gibson pp 14458–14464 DOI: 10.1021/ja036606f Supporting Info

Reversible Light-Driven Structural Changes between the Mono- and Bilayer Stacking Alignments in 4-Octadecyloxystilbazolium Arylcarboxylate Films Osamu Ohtani, Hiroki Kato, Tatsuto Yui, and Katsuhiko Takagi pp 14465–14472 DOI: 10.1021/ja030310s Supporting Info

Synthesis of Porous Emulsion-Templated Polymers Using High Internal Phase CO2-in-Water Emulsions R. Butler, I. Hopkinson, and A. I. Cooper pp 14473–14481 DOI: 10.1021/ja037570u Supporting Info

Organotitanium-Mediated Stereoselective Coordinative/Insertive Homopolymerizations and Copolymerizations of Styrene and Methyl Methacrylate Tryg R. Jensen, Sung Cheol Yoon, Aswini K. Dash, Lubin Luo, and Tobin J. Marks pp 14482–14494 DOI: 10.1021/ja0363664 Supporting Info

Correspondence between Molecular Functionality and Crystal Structures. Supramolecular Chemistry of a Family of Homologated Aminophenols Venu R. Vangala, Balakrishna R. Bhogala, Archan Dey, Gautam R. Desiraju, Charlotte K. Broder, Philip S. Smith, Raju Mondal, Judith A. K. Howard, and Chick C. Wilson pp 14495–14509 DOI: 10.1021/ja037227p Supporting Info

Pathways for Photoinduced Charge Separation in DNA Hairpins D. Beljonne, G. Pourtois, M. A. Ratner, and J. L. Brédas pp 14510–14517 DOI: 10.1021/ja035596f

The Effect of Global Compaction on the Local Secondary Structure of Folded Dendrimers Baohua Huang, Matthew A. Prantil, Terry L. Gustafson, and Jon R. Parquette pp 14518–14530 DOI: 10.1021/ja037895a Supporting Info

Electrospun MEH-PPV/SBA-15 Composite Nanofibers Using a Dual Syringe Method Sudha Madhugiri, Alan Dalton, Jose Gutierrez, John P. Ferraris, and Kenneth J. Balkus Jr. pp 14531–14538 DOI: 10.1021/ja030326i Supporting Info

Low-Temperature Synthesis of Soluble and Processable Organic-Capped Anatase TiO2 Nanorods P. Davide Cozzoli, Andreas Kornowski, and Horst Weller pp 14539–14548 DOI: 10.1021/ja036505h

Template Burning inside TS-1 and Fe-MFI Molecular Sieves:  An in Situ XRPD Study Marco Milanesio, Gilberto Artioli, Alessandro F. Gualtieri, Luca Palin, and Carlo Lamberti pp 14549–14558 DOI: 10.1021/ja037229+

Synthesis of Face-Centered Tetragonal FePt Nanoparticles and Granular Films from Pt@Fe2O3 Core−Shell Nanoparticles Xiaowei Teng and Hong Yang pp 14559–14563 DOI: 10.1021/ja0376700 Supporting Info

Fluorescence Quenching of Dyes by Tryptophan:  Interactions at Atomic Detail from Combination of Experiment and Computer Simulation Andrea C. Vaiana, Hannes Neuweiler, Andreas Schulz, Jürgen Wolfrum, Markus Sauer, and Jeremy C. Smith pp 14564–14572 DOI: 10.1021/ja036082j Supporting Info

Novel Microporous Lanthanide Silicates with Tobermorite-Like Structure Artur Ferreira, Duarte Ananias, Luís D. Carlos, Cláudia M. Morais, and João Rocha pp 14573–14579 DOI: 10.1021/ja036988p Supporting Info

Degradation of Myoglobin by Polymeric Artificial Metalloproteases Containing Catalytic Modules with Various Catalytic Group Densities:  Site Selectivity in Peptide Bond Cleavage Chang Eun Yoo, Pil Seok Chae, Jung Eun Kim, Eui June Jeong, and Junghun Suh pp 14580–14589 DOI: 10.1021/ja034730t Supporting Info

Solvatomagnetism-Induced Faraday Effect in a Cobalt Hexacyanochromate-Based Magnet Yusuke Sato, Shin-ichi Ohkoshi, Ken-ichi Arai, Masanori Tozawa, and Kazuhito Hashimoto pp 14590–14595 DOI: 10.1021/ja030375v

Role of Entropy in Increased Rates of Intramolecular Reactions Anthony A. Armstrong and L. Mario Amzel pp 14596–14602 DOI: 10.1021/ja0344359

Theoretical Study of a New DNA Structure:  The Antiparallel Hoogsteen Duplex Elena Cubero, Nicola G. A. Abrescia, Juan A. Subirana, F. Javier Luque, and Modesto Orozco pp 14603–14612 DOI: 10.1021/ja035918f Supporting Info

Millisecond Kinetics on a Microfluidic Chip Using Nanoliters of Reagents Helen Song and Rustem F. Ismagilov pp 14613–14619 DOI: 10.1021/ja0354566

A General NMR Method for Rapid, Efficient, and Reliable Biochemical Screening Claudio Dalvit, Elena Ardini, Maria Flocco, Gian Paolo Fogliatto, Nicola Mongelli, and Marina Veronesi pp 14620–14625 DOI: 10.1021/ja038128e Supporting Info

Isomeric Structures and Visible Electronic Spectrum of the C7H3 Radicals Hongbin Ding, Thomas Pino, Felix Güthe, and John P. Maier pp 14626–14630 DOI: 10.1021/ja029650o

Ne3−NH3 van der Waals Tetramer:  Rotational Spectra and ab Initio Study of the Microsolvation of NH3 with Rare Gas Atoms Jennifer van Wijngaarden and Wolfgang Jäger pp 14631–14641 DOI: 10.1021/ja035252p Supporting Info

Overlooked Difference between Hydrogen Bonds of Equal Strength Formed between Catechol and an Oxygen or Nitrogen Base. Experiments and DFT Calculations Mario C. Foti, Gino A. DiLabio, and K. U. Ingold pp 14642–14647 DOI: 10.1021/ja036168c Supporting Info

Intermolecular Transition Metal-Catalyzed [4 + 2 + 2] Cycloaddition Reactions:  A New Approach to the Construction of Eight-Membered Rings   [J. Am. Chem. Soc. 2002, 124 (30), 8782−8783].  P. Andrew Evans, John E. Robinson, Erich W. Baum, and Aleem N. Fazal p 14648 DOI: 10.1021/ja033458k

MALDI-TOF Mass Spectrometry of Synthetic Polymers By Harald Pasch (Deutsches Kunststoff-Institut, Darmstadt, Germany) and Wolfgang Schrepp (BASF AG, Ludwigshafen, Germany). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xviii + 298 pp. $89.95. ISBN 3-540-44259-6. Mehdi Moini p 14649 DOI: 10.1021/ja033564m

Progress in the Chemistry of Organic Natural Products, 86 Edited by W. Herz (The Florida State University, Tallahassee), H. Falk (Johannes-Kepler-Universität), and G. W. Kirby (University of Glasgow). Featuring “Monopyrrolic Natural Compounds Including Tetramic Acid Derivatives” by A. Gossauer (University of Fribourg). Springer-Verlag:  Wien. 2003. viii + 222 pp. $149.00. ISBN 3-211-83889-9. Philip DeShong pp 14649–14650 DOI: 10.1021/ja0335869

Methods in Polyphenol Analysis Edited by Celestino Santos-Buelga (University of Salamanca) and Gary Williamson (Nestlé Research Center, Lausanne). Royal Society of Chemistry:  Cambridge. 2003. xvi + 384 pp. $199.00. ISBN 0-85404-580-5. Paul W. Paré p 14650 DOI: 10.1021/ja033571a

Issue 48

Oligomeric Ligands for Luminescent and Stable Nanocrystal Quantum Dots Sungjee Kim and Moungi G. Bawendi pp 14652–14653 DOI: 10.1021/ja0368094 Supporting Info

The dapE-encoded N-Succinyl-l,l-Diaminopimelic Acid Desuccinylase from Haemophilus influenzae Is a Dinuclear Metallohydrolase Nathaniel J. Cosper, David L. Bienvenue, Jacob E. Shokes, Danuta M. Gilner, Takashi Tsukamoto, Robert A. Scott, and Richard C. Holz pp 14654–14655 DOI: 10.1021/ja036650v Supporting Info

Biosynthesis of CaCO3 Crystals of Complex Morphology Using a Fungus and an Actinomycete Debabrata Rautaray, Absar Ahmad, and Murali Sastry pp 14656–14657 DOI: 10.1021/ja0374877 Supporting Info

Direct Structure Determination of a Multicomponent Molecular Crystal Prepared by a Solid-State Grinding Procedure Eugene Y. Cheung, Simon J. Kitchin, Kenneth D. M. Harris, Yoshitane Imai, Nobuo Tajima, and Reiko Kuroda pp 14658–14659 DOI: 10.1021/ja030506s Supporting Info

Step-Enhanced Selectivity of NO Reduction on Platinum-Group Metals Zhi-Pan Liu, Stephen J. Jenkins, and David A. King pp 14660–14661 DOI: 10.1021/ja0372208

Site-Specific Incorporation of a Redox-Active Amino Acid into Proteins Lital Alfonta, Zhiwen Zhang, Sean Uryu, Joseph A. Loo, and Peter G. Schultz pp 14662–14663 DOI: 10.1021/ja038242x

A Triplet Carbene Surviving a Week in Solution at Room Temperature Eri Iwamoto, Katsuyuki Hirai, and Hideo Tomioka pp 14664–14665 DOI: 10.1021/ja038423z Supporting Info

Determining the Solution State Orientation of a Ti Enolate via Stable Isotope Labeling, NMR Spectroscopy, and Modeling Studies David B. Kimball, Ryszard Michalczyk, Eddie Moody, Morgane Ollivault-Shiflett, Karl De Jesus, and Louis A. “Pete” Silks, III pp 14666–14667 DOI: 10.1021/ja036414k Supporting Info

Fluorescent, Through-Bond Energy Transfer Cassettes for Labeling Multiple Biological Molecules in One Experiment Guan-Sheng Jiao, Lars H. Thoresen, and Kevin Burgess pp 14668–14669 DOI: 10.1021/ja037193l Supporting Info

Diversity-Oriented Synthesis of Tamoxifen-type Tetrasubstituted Olefins Kenichiro Itami, Toshiyuki Kamei, and Jun-ichi Yoshida pp 14670–14671 DOI: 10.1021/ja037566i Supporting Info

Identification from a Combinatorial Library of a Small Molecule that Selectively Induces Apoptosis in Cancer Cells Vitaliy Nesterenko, Karson S. Putt, and Paul J. Hergenrother pp 14672–14673 DOI: 10.1021/ja038043d Supporting Info

First Direct Evidence for Stereospecific Olefin Epoxidation and Alkane Hydroxylation by an Oxoiron(IV) Porphyrin Complex Wonwoo Nam, Se-Eun Park, In Kyung Lim, Mi Hee Lim, Jongki Hong, and Jinheung Kim pp 14674–14675 DOI: 10.1021/ja0368204 Supporting Info

Raman Dye-Labeled Nanoparticle Probes for Proteins Y. Charles Cao, Rongchao Jin, Jwa-Min Nam, C. Shad Thaxton, and Chad A. Mirkin pp 14676–14677 DOI: 10.1021/ja0366235 Supporting Info

Reversible Switching of High-Speed Air−Liquid Two-Phase Flows Using Electrowetting-Assisted Flow-Pattern Change Dongeun Huh, Alan H. Tkaczyk, Joong Hwan Bahng, Yu Chang, Hsien-Hung Wei, James B. Grotberg, Chang-Jin Kim, Katsuo Kurabayashi, and Shuichi Takayama pp 14678–14679 DOI: 10.1021/ja037350g Supporting Info

Self-Assembly of Monodispersed, Chiral Nanoclusters of Cysteine on the Au(110)-(1 × 2) Surface Angelika Kühnle, Trolle R. Linderoth, and Flemming Besenbacher pp 14680–14681 DOI: 10.1021/ja0377403

Reactivity and Molecular Recognition:  Amine Methylation by an Introverted Ester Byron W. Purse, Pablo Ballester, and Julius Rebek, Jr. pp 14682–14683 DOI: 10.1021/ja036595q Supporting Info

Detection of Heterogeneities in Dry and Swollen Polymer Networks by Proton Low-Field NMR Spectroscopy Kay Saalwächter pp 14684–14685 DOI: 10.1021/ja038278p

Isobutene Polymerization Using a Chelating Diborane Co-Initiator Stewart P. Lewis, Nicholas J. Taylor, Warren E. Piers, and Scott Collins pp 14686–14687 DOI: 10.1021/ja037725y Supporting Info

Highly Selective Electrocatalytic Conversion of CO2 to CO at −0.57 V (NHE) by Carbon Monoxide Dehydrogenase from Moorella thermoacetica Woonsup Shin, Sang Hee Lee, Jun Won Shin, Sang Phil Lee, and Yousung Kim pp 14688–14689 DOI: 10.1021/ja037370i

Switching of Spin States Triggered by a Phase Transition:  Spin-Crossover Properties of Self-Assembled Iron(II) Complexes with Alkyl-Tethered Triazole Ligands Tsuyohiko Fujigaya, Dong-Lin Jiang, and Takuzo Aida pp 14690–14691 DOI: 10.1021/ja038088e Supporting Info

Studies on the Biosynthesis of Asperparaline A:  Origin of the Spirosuccinimde Ring System Chandele R. Gray, Juan F. Sanz-Cervera, Louis A. Silks, and Robert M. Williams pp 14692–14693 DOI: 10.1021/ja037687i Supporting Info

Transition-Metal-Mediated Cascade Reactions:  C,C-Dicyclopropylmethylamines by Way of Double C,C-σ-Bond Insertion into Bicyclobutanes Peter Wipf, Corey R. J. Stephenson, and Kazuo Okumura pp 14694–14695 DOI: 10.1021/ja038623a Supporting Info

Intramolecular Electron Transfer in a Bacterial Sulfite Dehydrogenase Changjian Feng, Ulrike Kappler, Gordon Tollin, and John H. Enemark pp 14696–14697 DOI: 10.1021/ja038197t Supporting Info

Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates Jay C. Amicangelo and Willem R. Leenstra pp 14698–14699 DOI: 10.1021/ja030483h

“Electronic Lock” in Chromiumtricarbonyl Complex of Cycloheptatrienyltin Ilya D. Gridnev and Oleg L. Tok pp 14700–14701 DOI: 10.1021/ja0379621 Supporting Info

Enantioselective Total Synthesis of the Potent Antitumor Agent (−)-Mucocin Using a Temporary Silicon-Tethered Ring-Closing Metathesis Cross-Coupling Reaction P. Andrew Evans, Jian Cui, Santosh J. Gharpure, Alexei Polosukhin, and Hai-Ren Zhang pp 14702–14703 DOI: 10.1021/ja0384734 Supporting Info

Molecularly “Engineered” Anode Adsorbates for Probing OLED Interfacial Structure−Charge Injection/Luminance Relationships:  Large, Structure-Dependent Effects Qinglan Huang, Guennadi Evmenenko, Pulak Dutta, and Tobin J. Marks pp 14704–14705 DOI: 10.1021/ja037174b Supporting Info

Carbon Nanotube Fiber Microelectrodes Joseph Wang, Randhir P. Deo, Philippe Poulin, and Maryse Mangey pp 14706–14707 DOI: 10.1021/ja037737j Supporting Info

Comparison of “Polynaphthalenes” Prepared by Two Mechanistically Distinct Routes James P. Johnson, Dustin A. Bringley, Erin E. Wilson, Kevin D. Lewis, Larry W. Beck, and Adam J. Matzger pp 14708–14709 DOI: 10.1021/ja035695t Supporting Info

Organic/Inorganic Hybrid Vesicles Based on A Reactive Block Copolymer Jianzhong Du, Yongming Chen, Yanhong Zhang, Charles C. Han, Karl Fischer, and Manfred Schmidt pp 14710–14711 DOI: 10.1021/ja0368610 Supporting Info

Early Transition-Metal Perfluoroalkyl Complexes Felicia L. Taw, Brian L. Scott, and Jaqueline L. Kiplinger pp 14712–14713 DOI: 10.1021/ja038527+ Supporting Info

Direct Kinetic Studies of Atom Transfer and Electron Transfer Reactions of Hydroperoxo and High-Valent Oxo Complexes of Chromium Oleg Pestovsky and Andreja Bakac pp 14714–14715 DOI: 10.1021/ja0382213 Supporting Info

Aptamers Switch on Fluorescence of Triphenylmethane Dyes Jeremy R. Babendure, Stephen R. Adams, and Roger Y. Tsien pp 14716–14717 DOI: 10.1021/ja037994o Supporting Info

Photoinduced NO Release by Visible Light Irradiation from Pyrazine-Bridged Nitrosyl Ruthenium Complexes Marilia G. Sauaia, Renata G. de Lima, Antonio C. Tedesco, and Roberto S. da Silva pp 14718–14719 DOI: 10.1021/ja0376801

Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C2B9H11)2]- Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C2B9H11)2]- Isabel Rojo, Francesc Teixidor, Raikko Kivekäs, Reijo Sillanpää, and Clara Viñas pp 14720–14721 DOI: 10.1021/ja037279e Supporting Info

Total Synthesis of (+)-Macquarimicin A Ryosuke Munakata, Hironori Katakai, Tatsuo Ueki, Jun Kurosaka, Ken-ichi Takao, and Kin-ichi Tadano pp 14722–14723 DOI: 10.1021/ja038732p Supporting Info

Cyclooctanoid Ring Systems from Mixed Acetals via Heteroatom-Assisted [1,2]-Shift of Oxonium Ylides Fredrik P. Marmsäter, Graham K. Murphy, and F. G. West pp 14724–14725 DOI: 10.1021/ja0387249 Supporting Info

Cross-Couplings of Unactivated Secondary Alkyl Halides:  Room-Temperature Nickel-Catalyzed Negishi Reactions of Alkyl Bromides and Iodides Jianrong (Steve) Zhou and Gregory C. Fu pp 14726–14727 DOI: 10.1021/ja0389366 Supporting Info

Ligand Binding in a Docking Site of Cytochrome c Oxidase:  A Time-Resolved Step-Scan Fourier Transform Infrared Study Constantinos Koutsoupakis, Tewfik Soulimane, and Constantinos Varotsis pp 14728–14732 DOI: 10.1021/ja036107e

Synthesis and Spectroscopic Analysis of Chromophoric Lipids Inducing pH-Dependent Liposome Fusion Takenori Tomohiro, Yoshikatsu Ogawa, Hiroaki Okuno, and Masato Kodaka pp 14733–14740 DOI: 10.1021/ja037796x Supporting Info

Supramolecular Helices via Self-Assembly of 8-Oxoguanosines Tatiana Giorgi, Stefano Lena, Paolo Mariani, Mauro A. Cremonini, Stefano Masiero, Silvia Pieraccini, Jürgen P. Rabe, Paolo Samorì, Gian Piero Spada, and Giovanni Gottarelli pp 14741–14749 DOI: 10.1021/ja0364827 Supporting Info

Copper(I) Chloride Initiated Decomposition of 7-Phosphanorbornadiene. Evidence for a Solvent-Assisted Catalytic Mechanism Koop Lammertsma, Andreas W. Ehlers, and Michael L. McKee pp 14750–14759 DOI: 10.1021/ja0349958 Supporting Info

Crystal and Molecular Structures of Ionophore−Siderophore Host−Guest Supramolecular Assemblies Relevant to Molecular Recognition Suraj Dhungana, Peter S. White, and Alvin L. Crumbliss pp 14760–14767 DOI: 10.1021/ja035778+ Supporting Info

C2-Symmetric Bis(oxazolinato)lanthanide Catalysts for Enantioselective Intramolecular Hydroamination/Cyclization Sukwon Hong, Shun Tian, Matthew V. Metz, and Tobin J. Marks pp 14768–14783 DOI: 10.1021/ja0364672 Supporting Info

Spectroscopic Studies of the Met182Thr Mutant of Nitrite Reductase:  Role of the Axial Ligand in the Geometric and Electronic Structure of Blue and Green Copper Sites Lipika Basumallick, Robert K. Szilagyi, Yiwei Zhao, James P. Shapleigh, Charles P. Scholes, and Edward I. Solomon pp 14784–14792 DOI: 10.1021/ja037232t Supporting Info

Adsorbed Surfactants as Templates for the Synthesis of Morphologically Controlled Polyaniline and Polypyrrole Nanostructures on Flat Surfaces:  From Spheres to Wires to Flat Films Andrew D. W. Carswell, Edgar A. O'Rear, and Brian P. Grady pp 14793–14800 DOI: 10.1021/ja0365983 Supporting Info

The Standard Redox Potential of the Phenyl Radical/Anion Couple Claude P. Andrieux and Jean Pinson pp 14801–14806 DOI: 10.1021/ja0374574

Energetics of Phosphate Binding to Ammonium and Guanidinium Containing Metallo-Receptors in Water Suzanne L. Tobey and Eric V. Anslyn pp 14807–14815 DOI: 10.1021/ja030507k Supporting Info

Structures, Electronic States, and Electroluminescent Properties of a Zinc(II) 2-(2-Hydroxyphenyl)benzothiazolate Complex Gui Yu, Shiwei Yin, Yunqi Liu, Zhigang Shuai, and Daoben Zhu pp 14816–14824 DOI: 10.1021/ja0371505 Supporting Info

Circular Dichroism Imaging Microscopy:  Application to Enantiomorphous Twinning in Biaxial Crystals of 1,8-Dihydroxyanthraquinone Kacey Claborn, Eileen Puklin-Faucher, Miki Kurimoto, Werner Kaminsky, and Bart Kahr pp 14825–14831 DOI: 10.1021/ja035644w

Dendrimer-Encapsulated Nanoparticle Precursors to Supported Platinum Catalysts Huifang Lang, R. Alan May, Brianna L. Iversen, and Bert D. Chandler pp 14832–14836 DOI: 10.1021/ja0364120 Supporting Info

Direct Growth of Shape-Controlled Nanocrystals on Nanotubes via Biological Recognition Lingtao Yu, Ipsita A. Banerjee, and Hiroshi Matsui pp 14837–14840 DOI: 10.1021/ja037117i Supporting Info

Ab Initio Folding of Helix Bundle Proteins Using Molecular Dynamics Simulations Soonmin Jang, Eunae Kim, Seokmin Shin, and Youngshang Pak pp 14841–14846 DOI: 10.1021/ja034701i

Acrylate Formation via Metal-Assisted C−C Coupling between CO2 and C2H4:  Reaction Mechanism as Revealed from Density Functional Calculations Gábor Schubert and Imre Pápai pp 14847–14858 DOI: 10.1021/ja035791u Supporting Info

On the Value of c:  Can Low Affinity Systems Be Studied by Isothermal Titration Calorimetry? W. Bruce Turnbull and Antonio H. Daranas pp 14859–14866 DOI: 10.1021/ja036166s Supporting Info

One-Bond, Two-Bond, and Three-Bond Mechanisms in Thermal Deazetizations of 2,3-Diazabicyclo[2.2.2]oct-2-enes, trans-Azomethane, and 2,3-Diazabicyclo[2.2.1]hept-2-ene Kelli S. Khuong and K. N. Houk pp 14867–14883 DOI: 10.1021/ja038198l Supporting Info

Rhodium-Catalyzed Asymmetric Ring Opening Reactions of Oxabicyclic Alkenes:  Application of Halide Effects in the Development of a General Process Mark Lautens, Keith Fagnou, and Dingqiao Yang pp 14884–14892 DOI: 10.1021/ja034845x Supporting Info

Sidewall Functionalization of Single-Walled Carbon Nanotubes by Addition of Dichlorocarbene Hui Hu, Bin Zhao, Mark A. Hamon, Katalin Kamaras, Mikhail E. Itkis, and Robert C. Haddon pp 14893–14900 DOI: 10.1021/ja0356737

Ring-Opening Metathesis/Oxy-Cope Rearrangement:  A New Strategy for the Synthesis of Bicyclic Medium Ring-Containing Compounds Brian H. White and Marc L. Snapper pp 14901–14904 DOI: 10.1021/ja037656n Supporting Info

Formation and Cleavage of Aromatic Disulfide Radical Anions Sabrina Antonello, Kim Daasbjerg, Henrik Jensen, Ferdinando Taddei, and Flavio Maran pp 14905–14916 DOI: 10.1021/ja036380g Supporting Info

Selective Solid State Photooxidant Tracy L. Morkin, Nicholas J. Turro, Mark H. Kleinman, Cheyenne S. Brindle, Wolfgang H. Kramer, and Ian R. Gould pp 14917–14924 DOI: 10.1021/ja0368406

Vibrational Response of Nanorods to Ultrafast Laser Induced Heating:  Theoretical and Experimental Analysis Min Hu, Xuan Wang, Gregory V. Hartland, Paul Mulvaney, Jorge Perez Juste, and John E. Sader pp 14925–14933 DOI: 10.1021/ja037443y Supporting Info

Photochemistry of 1-(N,N-Diethylamino)diazen-1-ium-1,2-diolate:  An Experimental and Computational Investigation Christopher M. Pavlos, Andrew D. Cohen, Raechelle A. D'Sa, R. B. Sunoj, Walter A. Wasylenko, Preeya Kapur, Heather A. Relyea, Neema A. Kumar, Christopher M. Hadad, and John P. Toscano pp 14934–14940 DOI: 10.1021/ja034487y Supporting Info

Chelate Effect and Thermodynamics of Metal Complex Formation in Solution:  A Quantum Chemical Study Valérie Vallet, Ulf Wahlgren, and Ingmar Grenthe pp 14941–14950 DOI: 10.1021/ja036646j Supporting Info

Molecular Logic:  A Half-Subtractor Based on Tetraphenylporphyrin   [J. Am. Chem. Soc. 2003, 125, 11198−11199].  Steven J. Langford and Trevor Yann p 14951 DOI: 10.1021/ja038843o

Functional Analogues of the Dioxygen Reduction Site in Cytochrome Oxidase:  Mechanistic Aspects and Possible Effects of CuB  [J. Am. Chem. Soc. 2002, 124, 11923−11935].  Roman Boulatov, James P. Collman, Irina M. Shiryaeva, and Christopher J. Sunderland p 14951 DOI: 10.1021/ja039122s

Advances in Chemical Physics. Volume 126 Edited by I. Prigogine (The University of Texas-Austin and Université Libre de Bruxelles) and Stuart A. Rice (The University of Chicago). John Wiley & Sons, Inc.:  Hoboken, NJ. 2003. x + 306 pp. $175.00. ISBN 0-471-23582-2. David A. Dixon p 14952 DOI: 10.1021/ja033544k

Issue 49

Spectroscopic Analysis of Liquid/Liquid Interfaces in Multiphase Microflows Akihide Hibara, Masaki Nonaka, Manabu Tokeshi, and Takehiko Kitamori pp 14954–14955 DOI: 10.1021/ja037308l Supporting Info

Deformation of Porous Molecular Networks Induced by the Exchange of Guests in Single Crystals Okba Saied, Thierry Maris, and James D. Wuest pp 14956–14957 DOI: 10.1021/ja037465k Supporting Info

Frozen-Solution Conformational Analysis by REDOR Spectroscopy Luis J. Smith, Fabien P. Boulineau, Daniel Raftery, and Alexander Wei pp 14958–14959 DOI: 10.1021/ja036526b Supporting Info

Synthesis of Very Small TiO2 Nanocrystals in a Room-Temperature Ionic Liquid and Their Self-Assembly toward Mesoporous Spherical Aggregates Yong Zhou and Markus Antonietti pp 14960–14961 DOI: 10.1021/ja0380998 Supporting Info

Quaternary Self-Organization of Porphyrin and Fullerene Units by Clusterization with Gold Nanoparticles on SnO2 Electrodes for Organic Solar Cells Taku Hasobe, Hiroshi Imahori, Prashant V. Kamat, and Shunichi Fukuzumi pp 14962–14963 DOI: 10.1021/ja0377192 Supporting Info

In Situ Scanning Tunneling Microscopy of DNA-Modified Gold Surfaces:  Bias and Mismatch Dependence Donato M. Ceres and Jacqueline K. Barton pp 14964–14965 DOI: 10.1021/ja0384476 Supporting Info

Lipid/Protein Interactions and the Membrane/Water Interfacial Region Carmen Domene, Peter J. Bond, Sundeep S. Deol, and Mark S. P. Sansom pp 14966–14967 DOI: 10.1021/ja0364874 Supporting Info

Bias-Dependent Visualization of Electron Donor (D) and Electron Acceptor (A) Moieties in a Chiral DAD Triad Molecule Atsushi Miura, Zhijian Chen, Hiroshi Uji-i, Steven De Feyter, Magdalena Zdanowska, Pascal Jonkheijm, Albertus P. H. J. Schenning, E. W. Meijer, Frank Würthner, and Frans C. De Schryver pp 14968–14969 DOI: 10.1021/ja037407z Supporting Info

Induced Protein Dimerization in Vivo through Covalent Labeling Susanne Gendreizig, Maik Kindermann, and Kai Johnsson pp 14970–14971 DOI: 10.1021/ja037883p Supporting Info

Self-Assembled Nanotubes that Reversibly Bind Acetic Acid Guests Linda S. Shimizu, Andrew D. Hughes, Mark D. Smith, Matthew J. Davis, B. Paul Zhang, Hans-Conrad zur Loye, and Ken D. Shimizu pp 14972–14973 DOI: 10.1021/ja036515i Supporting Info

Photochemical Charge Transfer and Trapping at the Interface between an Organic Adlayer and an Oxide Semiconductor Michael A. Henderson, J. Michael White, Hiroshi Uetsuka, and Hiroshi Onishi pp 14974–14975 DOI: 10.1021/ja037764+

Two-Dimensional Self-Organization of Phthalocyanine and Porphyrin:  Dependence on the Crystallographic Orientation of Au Koji Suto, Soichiro Yoshimoto, and Kingo Itaya pp 14976–14977 DOI: 10.1021/ja038857u Supporting Info

New Routes to the Detection of Relaxation Allowed Coherence Transfer in Paramagnetic Molecules Fathia Kateb and Mario Piccioli pp 14978–14979 DOI: 10.1021/ja038101v Supporting Info

Rhenium-Promoted Diastereo- and Enantioselective Cyclopentannulation Reactions:  Furans as 1,3-Propene Dipoles Lee A. Friedman, Fei You, Michal Sabat, and W. Dean Harman pp 14980–14981 DOI: 10.1021/ja0304143 Supporting Info

Constraining Asymmetric Organometallic Catalysts within Mesoporous Supports Boosts Their Enantioselectivity Robert Raja, John Meurig Thomas, Matthew D. Jones, Brian F. G. Johnson, and David E. W. Vaughan pp 14982–14983 DOI: 10.1021/ja030381r Supporting Info

Metal-Centered Photoinduced Electron Transfer Reduction of a Gold(III) Porphyrin Cation Linked with a Zinc Porphyrin to Produce a Long-Lived Charge-Separated State in Nonpolar Solvents Shunichi Fukuzumi, Kei Ohkubo, W enbo E, Zhongping Ou, Jianguo Shao, Karl M. Kadish, James A. Hutchison, Kenneth P. Ghiggino, Paul J. Sintic, and Maxwell J. Crossley pp 14984–14985 DOI: 10.1021/ja037214b Supporting Info

Replication of Vertical Features Smaller than 2 nm by Soft Lithography Byron D. Gates and George M. Whitesides pp 14986–14987 DOI: 10.1021/ja0367647 Supporting Info

Pulsed ELDOR Spectroscopy Measures the Distance between the Two Tyrosyl Radicals in the R2 Subunit of the E. coli Ribonucleotide Reductase Marina Bennati, Axel Weber, Jelena Antonic, Deborah L. Perlstein, John Robblee, and JoAnne Stubbe pp 14988–14989 DOI: 10.1021/ja0362095 Supporting Info

C5-Methylation of Cytosine in B-DNA Thermodynamically and Kinetically Stabilizes BI Christine Rauch, Michael Trieb, Bernd Wellenzohn, Markus Loferer, Andreas Voegele, Fajar R. Wibowo, and Klaus R. Liedl pp 14990–14991 DOI: 10.1021/ja037218g Supporting Info

Asymmetric Intermolecular Pauson−Khand Reactions of Unstrained Olefins:  The (o-Dimethylamino)phenylsulfinyl Group as an Efficient Chiral Auxiliary Marta Rodríguez Rivero, Juan Carlos de la Rosa, and Juan Carlos Carretero pp 14992–14993 DOI: 10.1021/ja038491l Supporting Info

Dynamic Interfaces between Cells and Surfaces:  Electroactive Substrates that Sequentially Release and Attach Cells Woon-Seok Yeo, Muhammad N. Yousaf, and Milan Mrksich pp 14994–14995 DOI: 10.1021/ja038265b Supporting Info

Control over the Wettability of an Aligned Carbon Nanotube Film Taolei Sun, Guojie Wang, Huan Liu, Lin Feng, Lei Jiang, and Daoben Zhu pp 14996–14997 DOI: 10.1021/ja038026o Supporting Info

Epitaxial Electrodeposition of Prussian Blue Thin Films on Single-Crystal Au(110) Shuji Nakanishi, Guotao Lu, Hiten M. Kothari, Eric W. Bohannan, and Jay A. Switzer pp 14998–14999 DOI: 10.1021/ja0381151

The Total Synthesis of (−)-Lemonomycin Eric R. Ashley, Ernest G. Cruz, and Brian M. Stoltz pp 15000–15001 DOI: 10.1021/ja039223q Supporting Info

An Examination of Metal−Ligand Binding Modes in Rubidium Diphenylmethanide Jacob S. Alexander, Damian G. Allis, Bruce S. Hudson, and Karin Ruhlandt-Senge pp 15002–15003 DOI: 10.1021/ja037201y Supporting Info

Aromatic Hydroxylation by Cytochrome P450:  Model Calculations of Mechanism and Substituent Effects Christine M. Bathelt, Lars Ridder, Adrian J. Mulholland, and Jeremy N. Harvey pp 15004–15005 DOI: 10.1021/ja035590q Supporting Info

The Synthesis of Phosphaisocoumarins by Cu(I)-Catalyzed Intramolecular Cyclization of o-Ethynylphenylphosphonic Acid Monoesters Ai-Yun Peng and Yi-Xiang Ding pp 15006–15007 DOI: 10.1021/ja038627f Supporting Info

β-Deuterium Isotope Effects on Amine Basicity, “Inductive” and Stereochemical Charles L. Perrin, Brian K. Ohta, and Joshua Kuperman pp 15008–15009 DOI: 10.1021/ja038343v

Oxygen Activation and Electron Transfer in Flavocytochrome P450 BM3 Tobias W. B. Ost, Jonathan Clark, Christopher G. Mowat, Caroline S. Miles, Malcolm D. Walkinshaw, Graeme A. Reid, Stephen K. Chapman, and Simon Daff pp 15010–15020 DOI: 10.1021/ja035731o

Two-Repeat Human Telomeric d(TAGGGTTAGGGT) Sequence Forms Interconverting Parallel and Antiparallel G-Quadruplexes in Solution:  Distinct Topologies, Thermodynamic Properties, and Folding/Unfolding Kinetics Anh Tuân Phan and Dinshaw J. Patel pp 15021–15027 DOI: 10.1021/ja037616j Supporting Info

What Is So Special about Arg 55 in the Catalysis of Cyclophilin A? Insights from Hybrid QM/MM Simulations Guohui Li and Qiang Cui pp 15028–15038 DOI: 10.1021/ja0367851

Crystal Structures of Two Complexes of the Rare-Earth-DOTA-Binding Antibody 2D12.5:  Ligand Generality from a Chiral System Todd M. Corneillie, Andrew J. Fisher, and Claude F. Meares pp 15039–15048 DOI: 10.1021/ja037236y Supporting Info

Mechanism of the Glutathione Transferase-Catalyzed Conversion of Antitumor 2-Crotonyloxymethyl-2-cycloalkenones to GSH Adducts Diana S. Hamilton, Xiyun Zhang, Zhebo Ding, Ina Hubatsch, Bengt Mannervik, K. N. Houk, Bruce Ganem, and Donald J. Creighton pp 15049–15058 DOI: 10.1021/ja030396p

Preparation and pH Triggered Inversion of Vesicles from Poly(acrylic Acid)-block-Polystyrene-block-Poly(4-vinyl Pyridine) Futian Liu and Adi Eisenberg pp 15059–15064 DOI: 10.1021/ja038142r Supporting Info

Probing the Role of the C−H···O Hydrogen Bond Stabilized Polypeptide Chain Reversal at the C-terminus of Designed Peptide Helices. Structural Characterization of Three Decapeptides Subrayashastry Aravinda, Narayanaswamy Shamala, Abhishek Bandyopadhyay, and Padmanabhan Balaram pp 15065–15075 DOI: 10.1021/ja0372762 Supporting Info

Increased Speed of Rotation for the Smallest Light-Driven Molecular Motor Matthijs K. J. ter Wiel, Richard A. van Delden, Auke Meetsma, and Ben L. Feringa pp 15076–15086 DOI: 10.1021/ja036782o Supporting Info

Is a Small Number of Charge Neutralizations Sufficient to Bend Nucleosome Core DNA onto Its Superhelical Ramp? Gerald S. Manning pp 15087–15092 DOI: 10.1021/ja030320t

Hydrogen Bonding Interfaces in Fullerene•TTF Ensembles Margarita Segura, Luis Sánchez, Javier de Mendoza, Nazario Martín, and Dirk M. Guldi pp 15093–15100 DOI: 10.1021/ja036358n Supporting Info

Water-Compatible Molecularly Imprinted Polymers Obtained via High-Throughput Synthesis and Experimental Design Beate Dirion, Zoe Cobb, Eric Schillinger, Lars I. Andersson, and Börje Sellergren pp 15101–15109 DOI: 10.1021/ja0355473

Heats of Formation of [2.2]Paracyclophane-1-ene and [2.2]Paracyclophane-1,9-diene − An Experimental Study Armin de Meijere, Sergei I. Kozhushkov, Karsten Rauch, Heiko Schill, Sergey P. Verevkin, Martin Kümmerlin, Hans-Dieter Beckhaus, Christoph Rüchardt, and Dmitrii S. Yufit pp 15110–15113 DOI: 10.1021/ja0374628 Supporting Info

Lithium Diisopropylamide-Mediated Lithiations of Imines:  Insights into Highly Structure-Dependent Rates and Selectivities Songping Liao and David B. Collum pp 15114–15127 DOI: 10.1021/ja030409z Supporting Info

Hydrazide-Based Quadruply Hydrogen-Bonded Heterodimers. Structure, Assembling Selectivity, and Supramolecular Substitution Xin Zhao, Xiao-Zhong Wang, Xi-Kui Jiang, Ying-Qi Chen, Zhan-Ting Li, and Guang-Ju Chen pp 15128–15139 DOI: 10.1021/ja037312x Supporting Info

Water-Mediated Association Provides an Ion Pair Receptor Frank W. Kotch, Vladimir Sidorov, Yiu-Fai Lam, Katherine J. Kayser, Hojun Li, Mark S. Kaucher, and Jeffery T. Davis pp 15140–15150 DOI: 10.1021/ja0364165 Supporting Info

Solid-State Synthesis of a Conducting Polythiophene via an Unprecedented Heterocyclic Coupling Reaction Hong Meng, Dmitrii F. Perepichka, Michael Bendikov, Fred Wudl, Grant Z. Pan, Wenjiang Yu, Wenjian Dong, and Stuart Brown pp 15151–15162 DOI: 10.1021/ja037115y Supporting Info

Why Are Silyl Ethers Conformationally Different from Alkyl Ethers? Chair−Chair Conformational Equilibria in Silyloxycyclohexanes and Their Dependence on the Substituents on Silicon. The Wider Roles of Eclipsing, of 1,3-Repulsive Steric Interactions, and of Attractive Steric Interactions Cecilia H. Marzabadi, J. Edgar Anderson, Jorge Gonzalez-Outeirino, Piers R. J. Gaffney, Christopher G. H. White, Derek A. Tocher, and Louis J. Todaro pp 15163–15173 DOI: 10.1021/ja035936x Supporting Info

Sidewall Carboxylic Acid Functionalization of Single-Walled Carbon Nanotubes Haiqing Peng, Lawrence B. Alemany, John L. Margrave, and Valery N. Khabashesku pp 15174–15182 DOI: 10.1021/ja037746s

Phase Transformation Driven by Valence Electron Concentration:  Tuning Interslab Bond Distances in Gd5GaxGe4-x Yurij Mozharivskyj, Wonyoung Choe, Alexandra O. Pecharsky, and Gordon J. Miller pp 15183–15190 DOI: 10.1021/ja037649z Supporting Info

An Evaluation of Amide Group Planarity in 7-Azabicyclo[2.2.1]heptane Amides. Low Amide Bond Rotation Barrier in Solution Yuko Otani, Osamu Nagae, Yuji Naruse, Satoshi Inagaki, Masashi Ohno, Kentaro Yamaguchi, Gaku Yamamoto, Masanobu Uchiyama, and Tomohiko Ohwada pp 15191–15199 DOI: 10.1021/ja036644z Supporting Info

Theoretical Study of Samarium (II) Carbenoid (ISmCH2I) Promoted Cyclopropanation Reactions with Ethylene and the Effect of THF Solvent on the Reaction Pathways Cunyuan Zhao, Dongqi Wang, and David Lee Phillips pp 15200–15209 DOI: 10.1021/ja030280t Supporting Info

Thermal Activation of Hydrocarbon C−H Bonds Initiated by a Tungsten Allyl Complex Stephen H. K. Ng, Craig S. Adams, Trevor W. Hayton, Peter Legzdins, and Brian O. Patrick pp 15210–15223 DOI: 10.1021/ja037076q Supporting Info

Theoretical Investigation of the “CO in”−“CO out” Isomerization in a [2Fe−2S] Ferredoxin:  Free Energy Profiles and Redox States Francesco Pizzitutti, Pierre Sétif, and Massimo Marchi pp 15224–15232 DOI: 10.1021/ja0370286

Molecular Dynamics Simulation of the Formation, Structure, and Dynamics of Small Phospholipid Vesicles Siewert J. Marrink and Alan E. Mark pp 15233–15242 DOI: 10.1021/ja0352092

Optically Activated Functionalization Reactions in Si Quantum Dots Fernando A. Reboredo, Eric Schwegler, and Giulia Galli pp 15243–15249 DOI: 10.1021/ja035254+

Molecular Quantum Cellular Automata Cells. Electric Field Driven Switching of a Silicon Surface Bound Array of Vertically Oriented Two-Dot Molecular Quantum Cellular Automata Hua Qi, Sharad Sharma, Zhaohui Li, Gregory L. Snider, Alexei O. Orlov, Craig S. Lent, and Thomas P. Fehlner pp 15250–15259 DOI: 10.1021/ja0371909 Supporting Info

Evidence for an Initiation of the Methanol-to-Olefin Process by Reactive Surface Methoxy Groups on Acidic Zeolite Catalysts Wei Wang, Andreas Buchholz, Michael Seiler, and Michael Hunger pp 15260–15267 DOI: 10.1021/ja0304244

Carbon Dioxide-in-Water Microemulsions [J. Am. Chem. Soc. 2003, 125, 3181−3189]. C. Ted Lee, Jr., Won Ryoo, P. Griffin Smith, Jr., Jose Arellano, Daniel R. Mitchell, Richard J. Lagow, Stephen E. Webber, and Keith P. Johnston p 15268 DOI: 10.1021/ja0334614

A Density Functional Theory Study Clarifying the Reactions of Conjugated Ketenes with Formaldimine. A Plethora of Pericyclic and Pseudopericyclic Pathways [J. Am. Chem. Soc. 2002, 124, 5231−5241]. Chun Zhou and David M. Birney p 15268 DOI: 10.1021/ja033462w

Organolithiums in Enantioselective Synthesis. Topics in Organometallic Chemistry, Volume 5 Edited by David M. Hodgson (University of Oxford). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. x + 320 pp. $229.00. ISBN 3-540-00104-2. Brian L. Pagenkopf p 15269 DOI: 10.1021/ja033581b

Chemical Applications of Synchrotron Radiation. Part I:  Dynamics and VUV Spectroscopy and Part II:  X-ray Applications Edited by Tsun-Kong Sham (University of Western Ontario). World Scientific:  Singapore, River Edge, London. 2002. 1304 pp. $198 (Set). ISBN 981-02-4480-0 (Set). Marten denBoer pp 15269–15270 DOI: 10.1021/ja025316g

Crystal Design:  Structure and Function. Perspectives in Supramolecular Chemistry, Volume 7 Edited by Gautam R. Desiraju (University of Hyderabad). John Wiley & Sons, Ltd.:  Chichester. 2003. xii + 408 pp. $265.00. ISBN 0-470-84333-0. Christopher J. Ziegler p 15270 DOI: 10.1021/ja033589l

Issue 50

Fast Nitroxyl Trapping by Ferric Porphyrins Sara E. Bari, Marcelo A. Martí, Valentín T. Amorebieta, Darío A. Estrin, and Fabio Doctorovich pp 15272–15273 DOI: 10.1021/ja036370f Supporting Info

Template Synthesis and Single-Molecule Magnetism Properties of a Complex with Spin S = 16 and a [Mn8O8]8+ Saddle-Like Core Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, Brian Moulton, Michael J. Zaworotko, and George Christou pp 15274–15275 DOI: 10.1021/ja0385134 Supporting Info

Controlling Diaza-Cope Rearrangement Reactions with Resonance-Assisted Hydrogen Bonds Jik Chin, Fabrizio Mancin, Nirusha Thavarajah, Donghyung Lee, Alan Lough, and Doo Soo Chung pp 15276–15277 DOI: 10.1021/ja0387554 Supporting Info

Micropatterning of Organic Semiconductor Microcrystalline Materials and OFET Fabrication by “Hot Lift Off” Zhe Wang, Jian Zhang, Rubo Xing, Jianfeng Yuan, Donghang Yan, and Yanchun Han pp 15278–15279 DOI: 10.1021/ja036581k Supporting Info

Potent Small-Molecule Binding to a Dynamic Hot Spot on IL-2 Christopher D. Thanos, Mike Randal, and James A. Wells pp 15280–15281 DOI: 10.1021/ja0382617 Supporting Info

Unique Charge Transfer Properties of the Four-Base π-Stacks in Z-DNA Ryu Tashiro and Hiroshi Sugiyama pp 15282–15283 DOI: 10.1021/ja0380291 Supporting Info

Total Synthesis of (±)-Didehydrostemofoline (Asparagamine A) and (±)-Isodidehydrostemofoline Markus Brüggemann, Andrew I. McDonald, Larry E. Overman, Mark D. Rosen, Lothar Schwink, and Jeremy P. Scott pp 15284–15285 DOI: 10.1021/ja0388820 Supporting Info

β-Diiminate Platinum Complexes for Alkane Dehydrogenation Ulrich Fekl, Werner Kaminsky, and Karen I. Goldberg pp 15286–15287 DOI: 10.1021/ja037781z Supporting Info

A Paramagnetic CEST Agent for Imaging Glucose by MRI Shanrong Zhang, Robert Trokowski, and A. Dean Sherry pp 15288–15289 DOI: 10.1021/ja038345f Supporting Info

Oxygen Is Electroreduced to Water on a “Wired” Enzyme Electrode at a Lesser Overpotential than on Platinum Nicolas Mano, Jose L. Fernandez, Yousung Kim, Woonsup Shin, Allen J. Bard, and Adam Heller pp 15290–15291 DOI: 10.1021/ja038285d

Palladium-Catalyzed Stille Cross-Couplings of Sulfonyl Chlorides and Organostannanes Srinivas Reddy Dubbaka and Pierre Vogel pp 15292–15293 DOI: 10.1021/ja038328q Supporting Info

Redox State Dependence of Single Molecule Conductivity Wolfgang Haiss, Harm van Zalinge, Simon J. Higgins, Donald Bethell, Horst Höbenreich, David J. Schiffrin, and Richard J. Nichols pp 15294–15295 DOI: 10.1021/ja038214e Supporting Info

Glycosidase−Substrate Interactions Analysis by STD-NMR Spectroscopy:  Study of α-l-Fucosidase Olivier Berteau, Corine Sandström, Julie Bielicki, Donald S. Anson, and Lennart Kenne pp 15296–15297 DOI: 10.1021/ja038562g Supporting Info

First Estimation of C4−H Bond Dissociation Energies of NADH and Its Radical Cation in Aqueous Solution Xiao-Qing Zhu, Yuan Yang, Ming Zhang, and Jin-Pei Cheng pp 15298–15299 DOI: 10.1021/ja0385179 Supporting Info

Shape Memory Effect Exhibited by Smectic-C Liquid Crystalline Elastomers Ingrid A. Rousseau and Patrick T. Mather pp 15300–15301 DOI: 10.1021/ja039001s Supporting Info

Orthogonal Control of Dissociation Dynamics Relative to Thermodynamics in a Main-Chain Reversible Polymer Wayne C. Yount, Hemraj Juwarker, and Stephen L. Craig pp 15302–15303 DOI: 10.1021/ja036709y Supporting Info

Synthesis, Structure, and Reaction of 1-Alkynyl(aryl)-λ3-bromanes Masahito Ochiai, Yoshio Nishi, Satoru Goto, Motoo Shiro, and Hermann J. Frohn pp 15304–15305 DOI: 10.1021/ja038777q Supporting Info

Switching by Pulse Electric Field of the Elevated Enzymatic Reaction in the Core of Polyion Complex Micelles Atsushi Harada and Kazunori Kataoka pp 15306–15307 DOI: 10.1021/ja038572h Supporting Info

The Surprising Nitrogen-Analogue Chemistry of the Methyltrioxorhenium-Catalyzed Olefin Epoxidation Dirk V. Deubel pp 15308–15309 DOI: 10.1021/ja039066v Supporting Info

Characterization of the Triplet State of Tris(8-hydroxyquinoline)aluminium(III) in Benzene Solution Hugh D. Burrows, Mariana Fernandes, J. Seixas de Melo, Andrew P. Monkman, and Suppiah Navaratnam pp 15310–15311 DOI: 10.1021/ja037254f Supporting Info

Aerobic Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide Shun-Ichi Murahashi, Naruyoshi Komiya, Hiroyuki Terai, and Takahiro Nakae pp 15312–15313 DOI: 10.1021/ja0390303 Supporting Info

Conformational Studies of a Bombolitin III-Derived Peptide Mimicking the Four-Helix Bundle Structural Motif of Proteins Elisabetta Schievano, Stefano Mammi, Luca Monticelli, Marta Ciardella, and Evaristo Peggion pp 15314–15323 DOI: 10.1021/ja0300970 Supporting Info

Ureases:  Quantum Chemical Calculations on Cluster Models Dimas Suárez, Natalia Díaz, and Kenneth M. Merz, Jr. pp 15324–15337 DOI: 10.1021/ja030145g Supporting Info

Propagation of Melting Cooperativity along the Phosphodiester Backbone of DNA Jessica Becaud, Isabelle Pompizi, and Christian J. Leumann pp 15338–15342 DOI: 10.1021/ja035313j Supporting Info

The A-Cluster in Subunit β of the Acetyl-CoA Decarbonylase/Synthase Complex from Methanosarcina thermophila: Ni and Fe K-Edge XANES and EXAFS Analyses Weiwei Gu, Simonida Gencic, Stephen P. Cramer, and David A. Grahame pp 15343–15351 DOI: 10.1021/ja036602a Supporting Info

Protein Film Voltammetry of Rhodobacter Capsulatus Xanthine Dehydrogenase Kondo François Aguey-Zinsou, Paul V. Bernhardt, and Silke Leimkühler pp 15352–15358 DOI: 10.1021/ja037940e Supporting Info

A Molecular Switch in Amyloid Assembly:  Met35 and Amyloid β-Protein Oligomerization Gal Bitan, Bogdan Tarus, Sabrina S. Vollers, Hilal A. Lashuel, Margaret M. Condron, John E. Straub, and David B. Teplow pp 15359–15365 DOI: 10.1021/ja0349296 Supporting Info

Direct Evaluation of a Mechanism for Activation of the RecA Nucleoprotein Filament Alberto I. Roca and Scott F. Singleton pp 15366–15375 DOI: 10.1021/ja0270165

Hemilabile Ligands in Organolithium Chemistry:  Substituent Effects on Lithium Ion Chelation Antonio Ramírez, Emil Lobkovsky, and David B. Collum pp 15376–15387 DOI: 10.1021/ja030322d Supporting Info

Infrared Study of the Stability and Folding Kinetics of a 15-Residue β-Hairpin Yao Xu, Rolando Oyola, and Feng Gai pp 15388–15394 DOI: 10.1021/ja037053b Supporting Info

Catalysis of the Photo-Fries Reaction:  Antibody-Mediated Stabilization of High Energy States Tobin J. Dickerson, Martin R. Tremblay, Timothy Z. Hoffman, Diana I. Ruiz, and Kim D. Janda pp 15395–15401 DOI: 10.1021/ja038016n

Axial Chirality in 1,4-Disubstituted (ZZ)-1,3-Dienes. Surprisingly Low Energies of Activation for the Enantiomerization in Synthetically Useful Fluxional Molecules Sandra Warren, Albert Chow, Gideon Fraenkel, and T. V. RajanBabu pp 15402–15410 DOI: 10.1021/ja035136m Supporting Info

Ionic Liquids by Proton Transfer:  Vapor Pressure, Conductivity, and the Relevance of ΔpKa from Aqueous Solutions Masahiro Yoshizawa, Wu Xu, and C. Austen Angell pp 15411–15419 DOI: 10.1021/ja035783d

Dimerizations of Nitrile Oxides to Furoxans Are Stepwise via Dinitrosoalkene Diradicals:  A Density Functional Theory Study Zhi-Xiang Yu, Pierluigi Caramella, and K. N. Houk pp 15420–15425 DOI: 10.1021/ja037325a Supporting Info

Mechanisms of Exchange Modulation in Trimethylenemethane-type Biradicals:  The Roles of Conformation and Spin Density David A. Shultz, Rosario M. Fico, Jr., Hyoyoung Lee, Jeff W. Kampf, Kristin Kirschbaum, A. Alan Pinkerton, and Paul D. Boyle pp 15426–15432 DOI: 10.1021/ja037787o Supporting Info

Total Synthesis of Apoptolidin:  Construction of Enantiomerically Pure Fragments K. C. Nicolaou, Konstantina C. Fylaktakidou, Holger Monenschein, Yiwei Li, Bernd Weyershausen, Helen J. Mitchell, Heng-xu Wei, Prasuna Guntupalli, David Hepworth, and Kazuyuki Sugita pp 15433–15442 DOI: 10.1021/ja0304953 Supporting Info

Total Synthesis of Apoptolidin:  Completion of the Synthesis and Analogue Synthesis and Evaluation K. C. Nicolaou, Yiwei Li, Kazuyuki Sugita, Holger Monenschein, Prasuna Guntupalli, Helen J. Mitchell, Konstantina C. Fylaktakidou, Dionisios Vourloumis, Paraskevi Giannakakou, and Aurora O'Brate pp 15443–15454 DOI: 10.1021/ja030496v Supporting Info

Kinetic and Thermodynamic Barriers to Carbon and Oxygen Alkylation of Phenol and Phenoxide Ion by the 1-(4-Methoxyphenyl)ethyl Carbocation Yutaka Tsuji, Maria M. Toteva, Heather A. Garth, and John P. Richard pp 15455–15465 DOI: 10.1021/ja037328n Supporting Info

Mechanisms of Metal Ion Transfer into Room-Temperature Ionic Liquids:  The Role of Anion Exchange Mark P. Jensen, Jörg Neuefeind, James V. Beitz, S. Skanthakumar, and L. Soderholm pp 15466–15473 DOI: 10.1021/ja037577b Supporting Info

Synthesis, Structure, and Photophysical and Electrochemical Properties of a π-Stacked Polymer Tamaki Nakano and Tohru Yade pp 15474–15484 DOI: 10.1021/ja037836x Supporting Info

Dendritic Molecular Capsules for Hydrophobic Compounds Meredith T. Morgan, Michael A. Carnahan, Chad E. Immoos, Anthony A. Ribeiro, Stella Finkelstein, Stephen J. Lee, and Mark W. Grinstaff pp 15485–15489 DOI: 10.1021/ja0347383 Supporting Info

Assembly of an Electronically Switchable Rotaxane on the Surface of a Titanium Dioxide Nanoparticle Brenda Long, Kirill Nikitin, and Donald Fitzmaurice pp 15490–15498 DOI: 10.1021/ja037592g Supporting Info

Synthesis of Amphiphilic Phenylazophenyl Glycosides and a Study of Their Liquid Crystal Properties Nicolas Laurent, Dominique Lafont, Fabienne Dumoulin, Paul Boullanger, Grahame Mackenzie, Paul H. J. Kouwer, and John W. Goodby pp 15499–15506 DOI: 10.1021/ja037347x Supporting Info

Spherical Sila- and Germa-Homoaromaticity Zhongfang Chen, Andreas Hirsch, Shigeru Nagase, Walter Thiel, and Paul von Ragué Schleyer pp 15507–15511 DOI: 10.1021/ja038005u Supporting Info

Total Syntheses of Amphidinolide T1, T3, T4, and T5 Christophe Aïssa, Ricardo Riveiros, Jacques Ragot, and Alois Fürstner pp 15512–15520 DOI: 10.1021/ja038216z Supporting Info

Stereochemistry of Nucleophilic Substitution Reactions Depending upon Substituent:  Evidence for Electrostatic Stabilization of Pseudoaxial Conformers of Oxocarbenium Ions by Heteroatom Substituents Leticia Ayala, Claudia G. Lucero, Jan Antoinette C. Romero, Sarah A. Tabacco, and K. A. Woerpel pp 15521–15528 DOI: 10.1021/ja037935a Supporting Info

Preparation of Thin Silica Films with Controlled Thickness and Tunable Refractive Index Jason H. Rouse and Gregory S. Ferguson pp 15529–15536 DOI: 10.1021/ja036241z

Isolation and Characterization of Nongeminal Cyclic Methylphenylphosphazene Tetramers June-Ho Jung, Julia C. Pomeroy, Hongming Zhang, and Patty Wisian-Neilson pp 15537–15542 DOI: 10.1021/ja0374168 Supporting Info

Cluster-to-Metal Magnetic Coupling:  Synthesis and Characterization of 25-Electron [Re6-nOsnSe8(CN)6](5-n)- (n = 1, 2) Clusters and {Re6-nOsnSe8[CNCu(Me6tren)]6}9+ (n = 0, 1, 2) Assemblies Eric G. Tulsky, Nathan R. M. Crawford, Stéphane A. Baudron, Patrick Batail, and Jeffrey R. Long pp 15543–15553 DOI: 10.1021/ja037444q Supporting Info

Mixed-Valent {FeIV(μ-O)(μ-carboxylato)2FeIII}3+ Core Leonardo D. Slep, Ana Mijovilovich, Wolfram Meyer-Klaucke, Thomas Weyhermüller, Eckhard Bill, Eberhard Bothe, Frank Neese, and Karl Wieghardt pp 15554–15570 DOI: 10.1021/ja030377f Supporting Info

The Primary Photodynamics of Aqueous Nitrate:  Formation of Peroxynitrite Dorte Madsen, Jane Larsen, Svend Knak Jensen, Søren R. Keiding, and Jan Thøgersen pp 15571–15576 DOI: 10.1021/ja030135f

Continuous Flow Hydroformylation of Alkenes in Supercritical Fluid−Ionic Liquid Biphasic Systems Paul B. Webb, Murielle F. Sellin, Thulani E. Kunene, Sylvia Williamson, Alexandra M. Z. Slawin, and David J. Cole-Hamilton pp 15577–15588 DOI: 10.1021/ja035967s Supporting Info

Colloidal Crystal Films:  Advances in Universality and Perfection Sean Wong, Vladimir Kitaev, and Geoffrey A. Ozin pp 15589–15598 DOI: 10.1021/ja0379969 Supporting Info

Electronic Structure of 1 to 2 nm Diameter Silicon Core/Shell Nanocrystals:  Surface Chemistry, Optical Spectra, Charge Transfer, and Doping Zhiyong Zhou, Richard A. Friesner, and Louis Brus pp 15599–15607 DOI: 10.1021/ja036443v Supporting Info

True Stabilization Energies for the Optimal Planar Hydrogen-Bonded and Stacked Structures of Guanine···Cytosine, Adenine···Thymine, and Their 9- and 1-Methyl Derivatives:  Complete Basis Set Calculations at the MP2 and CCSD(T) Levels and Comparison with Experiment Petr Jureka and Pavel Hobza pp 15608–15613 DOI: 10.1021/ja036611j

Characterization of Hydrogen Bonds in the Interactions between the Hydroperoxyl Radical and Organic Acids Renato L. T. Parreira and Sérgio E. Galembeck pp 15614–15622 DOI: 10.1021/ja036846v Supporting Info

13C−13C Rotational Resonance Width Distance Measurements in Uniformly 13C-Labeled Peptides Ramesh Ramachandran, Vladimir Ladizhansky, Vikram S. Bajaj, and Robert G. Griffin pp 15623–15629 DOI: 10.1021/ja037761x

Probing the Mechanism of Aqueous Two-Phase System Formation for α-Elastin On-Chip Yanjie Zhang, Hanbin Mao, and Paul S. Cremer pp 15630–15635 DOI: 10.1021/ja037869c

Excited-State Metal-to-Ligand Charge Transfer Dynamics of a Ruthenium(II) Dye in Solution and Adsorbed on TiO2 Nanoparticles from Resonance Raman Spectroscopy Lian C. T. Shoute and Glen R. Loppnow pp 15636–15646 DOI: 10.1021/ja035231v Supporting Info

On the Origin of Residual Dipolar Couplings from Denatured Proteins Martti Louhivuori, Kimmo Pääkkönen, Kai Fredriksson, Perttu Permi, Juhani Lounila, and Arto Annila pp 15647–15650 DOI: 10.1021/ja035427v

Origin of High Second- and Third-Order Nonlinear Optical Response in Ammonio/Borato Diphenylpolyene Zwitterions:  the Remarkable Role of Polarized Aromatic Groups Victor M. Geskin, Christoph Lambert, and Jean-Luc Brédas pp 15651–15658 DOI: 10.1021/ja035862p Supporting Info

Remarkable Solvent-Dependent Excited-State Chirality:  A Molecular Modulator of Circularly Polarized Luminescence Richard A. van Delden, Nina P. M. Huck, Jacob J. Piet, John M. Warman, Stefan C. J. Meskers, Harry P. J. M. Dekkers, and Ben L. Feringa pp 15659–15665 DOI: 10.1021/ja036874d Supporting Info

Unusual Salt Stability in Highly Charged Diblock Co-polypeptide Hydrogels Andrew P. Nowak, Victor Breedveld, David J. Pine, and Timothy J. Deming pp 15666–15670 DOI: 10.1021/ja0381050 Supporting Info

Ion Solvation Thermodynamics from Simulation with a Polarizable Force Field Alan Grossfield, Pengyu Ren, and Jay W. Ponder pp 15671–15682 DOI: 10.1021/ja037005r

Probing Molecular Conformations with Electron Momentum Spectroscopy:  The Case of n-Butane [J. Am. Chem. Soc. 2001, 123, 4049−4061]. M. S. Deleuze, W. N. Pang, A. Salam, and R. C. Shang p 15683 DOI: 10.1021/ja033460b

Molecular Pathomechanisms and New Trends in Drug Research Edited by György Kéri (Semmelweis University, Budapest) and Istvan Toth (University of Queensland, Brisbane). Taylor & Francis:  London and New York. 2003. xviii + 636 pp. $105.00. ISBN 0-415-27725-6. Kevin Dalby p 15684 DOI: 10.1021/ja033555d

Progress in Heterocyclic Chemistry, Volume 15 Edited by Gordon W. Gribble (Dartmouth College) and John A. Joule (University of Manchester). Pergamon (An Imprint of Elsevier Science, Ltd.):  Kidlington. 2003. viii + 466 pp. $232.00. ISBN 0-08-0442887-0. p 15684 DOI: 10.1021/ja033613v

Ionic Liquids as Green Solvents:  Progress and Prospects Edited by Robin D. Rogers (The University of Alabama) and Kenneth R. Seddon (The Queen's University of Belfast). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2003. xvi + 600 pp. $165.00. ISBN 0-8412-3856-1. p 15684 DOI: 10.1021/ja033614n

Issue 51

Rare Fluctuations of Native Proteins Sampled by Equilibrium Hydrogen Exchange Michele Vendruscolo, Emanuele Paci, Christopher M. Dobson, and Martin Karplus pp 15686–15687 DOI: 10.1021/ja036523z

Geometric Disassembly of Dendrimers:  Dendritic Amplification Michael L. Szalai, Robert M. Kevwitch, and Dominic V. McGrath pp 15688–15689 DOI: 10.1021/ja0386694 Supporting Info

Trans Doubly N-Confused Porphyrins:  Cu(III) Complexation and Formation of Rodlike Hydrogen-Bonding Networks Hiromitsu Maeda, Atsuhiro Osuka, and Hiroyuki Furuta pp 15690–15691 DOI: 10.1021/ja038519t Supporting Info

Metal-Stabilized Phenoxonium Cation Arkadi Vigalok, Boris Rybtchinski, Yael Gozin, Tehila S. Koblenz, Yehoshoa Ben-David, Haim Rozenberg, and David Milstein pp 15692–15693 DOI: 10.1021/ja0385639 Supporting Info

Fundamental Role of the Fostriecin Unsaturated Lactone and Implications for Selective Protein Phosphatase Inhibition Suzanne B. Buck, Christophe Hardouin, Satoshi Ichikawa, Danielle R. Soenen, C.-M. Gauss, Inkyu Hwang, Mark R. Swingle, Kathy M. Bonness, Richard E. Honkanen, and Dale L. Boger pp 15694–15695 DOI: 10.1021/ja038672n Supporting Info

Optical Rotation of Noncovalent Aggregates Michael-Rock Goldsmith, Nilu Jayasuriya, David N. Beratan, and Peter Wipf pp 15696–15697 DOI: 10.1021/ja0376893 Supporting Info

Extending Lifetimes of Lanthanide-Based Near-Infrared Emitters (Nd, Yb) in the Millisecond Range through Cr(III) Sensitization in Discrete Bimetallic Edifices Daniel Imbert, Martine Cantuel, Jean-Claude G. Bünzli, Gérald Bernardinelli, and Claude Piguet pp 15698–15699 DOI: 10.1021/ja0386501 Supporting Info

Ageladine A: An Antiangiogenic Matrixmetalloproteinase Inhibitor from the Marine Sponge Agelas nakamurai1 Masaki Fujita, Yoichi Nakao, Shigeki Matsunaga, Motoharu Seiki, Yoshifumi Itoh, Jun Yamashita, Rob W. M. van Soest, and Nobuhiro Fusetani pp 15700–15701 DOI: 10.1021/ja038025w Supporting Info

Using Biofunctional Magnetic Nanoparticles to Capture Vancomycin-Resistant Enterococci and Other Gram-Positive Bacteria at Ultralow Concentration Hongwei Gu, Pak-Leung Ho, Kenneth W. T. Tsang, Ling Wang, and Bing Xu pp 15702–15703 DOI: 10.1021/ja0359310 Supporting Info

Design of a Cyclic Peptide that Targets a Viral RNA Steven T. Runyon and Joseph D. Puglisi pp 15704–15705 DOI: 10.1021/ja036344h

Ligand Specificity Modulated by Prolyl Imide Bond Cis/Trans Isomerization in the Itk SH2 Domain:  A Quantitative NMR Study Patrick J. Breheny, Alain Laederach, D. Bruce Fulton, and Amy H. Andreotti pp 15706–15707 DOI: 10.1021/ja0375380 Supporting Info

Activation of N2O Reduction by the Fully Reduced μ4-Sulfide Bridged Tetranuclear CuZ Cluster in Nitrous Oxide Reductase Somdatta Ghosh, Serge I. Gorelsky, Peng Chen, Inês Cabrito, Jos J.G. Moura, Isabel Moura, andIsabel Moura, and Edward I. Solomon pp 15708–15709 DOI: 10.1021/ja038344n Supporting Info

Role of Ligand Bending in the Photodissociation of O2 vs CO-heme:  A Time-Dependent Density Functional Study Filippo De Angelis, Roberto Car, and Thomas G. Spiro pp 15710–15711 DOI: 10.1021/ja037373v Supporting Info

An Easy Sonochemical Route for the Encapsulation of Tetracycline In Bovine Serum Albumin Microspheres S. Avivi (Levi), Y. Nitzan, R. Dror, and A. Gedanken pp 15712–15713 DOI: 10.1021/ja036834+ Supporting Info

Infrared Spectroscopy of Neutral C7H7 Isomers:  Benzyl and Tropyl Rob G. Satink, Gerard Meijer, and Gert von Helden pp 15714–15715 DOI: 10.1021/ja038329i Supporting Info

The Structures of Vanadium Oxide Cluster−Ethene Complexes. A Combined IR Multiple Photon Dissociation Spectroscopy and DFT Calculation Study André Fielicke, Roland Mitrić, Gerard Meijer, Vlasta Bonaić-Koutecký, and Gert von Helden pp 15716–15717 DOI: 10.1021/ja036264d Supporting Info

Large-Scale Synthesis of Single-Crystalline Perovskite Nanostructures Yuanbing Mao, Sarbajit Banerjee, and Stanislaus S. Wong pp 15718–15719 DOI: 10.1021/ja038192w Supporting Info

Amplified Nucleic Acid Sensing Using Programmed Self-Cleaving DNAzyme Shinsuke Sando, Toshinori Sasaki, Keiichiro Kanatani, and Yasuhiro Aoyama pp 15720–15721 DOI: 10.1021/ja0386492 Supporting Info

A Novel Supramolecular Multicolor Thermometer by Self-Assembly of a π-Extended Zinc Porphyrin Complex Akihiko Tsuda, Shigeru Sakamoto, Kentaro Yamaguchi, and Takuzo Aida pp 15722–15723 DOI: 10.1021/ja038349k Supporting Info

Application of NMR SHAPES Screening to an RNA Target Eric C. Johnson, Victoria A. Feher, Jeffrey W. Peng, Jonathan M. Moore, and James R. Williamson pp 15724–15725 DOI: 10.1021/ja037499s

Stereochemically Controlled PMMA-Exfoliated Silicate Nanocomposites Using Intergallery-Anchored Metallocenium Cations Wesley R. Mariott and Eugene Y.-X. Chen pp 15726–15727 DOI: 10.1021/ja038522c Supporting Info

Collagen−Protein Interactions Mapped by Phototriggered Thiol Introduction Norihisa Yasui and Takaki Koide pp 15728–15729 DOI: 10.1021/ja038148g Supporting Info

Mechanistic Diversity of Fosfomycin Resistance in Pathogenic Microorganisms Kerry L. Fillgrove, Svetlana Pakhomova, Marcia E. Newcomer, and Richard N. Armstrong pp 15730–15731 DOI: 10.1021/ja039307z Supporting Info

Long-Distance Radical Cation Migration in Duplex DNA:  The Effect of Contiguous A·A and T·T Mismatches on Efficiency and Mechanism Nathan W. Schlientz and Gary B. Schuster pp 15732–15733 DOI: 10.1021/ja0382359 Supporting Info

Evidence for Alkane Coordination to an Electron-Rich Uranium Center Ingrid Castro-Rodriguez, Hidetaka Nakai, Peter Gantzel, Lev N. Zakharov, Arnold L. Rheingold, and Karsten Meyer pp 15734–15735 DOI: 10.1021/ja0379316 Supporting Info

Semiconductor Quantum Dots for Photodynamic Therapy Anna C. S. Samia, Xiaobo Chen, and Clemens Burda pp 15736–15737 DOI: 10.1021/ja0386905 Supporting Info

Electrochemical Generation of C602+ and C603+ Carlo Bruno, Iouri Doubitski, Massimo Marcaccio, Francesco Paolucci, Demis Paolucci, and Antonio Zaopo pp 15738–15739 DOI: 10.1021/ja0388515 Supporting Info

1H−1H Dipolar Couplings Provide a Unique Probe of RNA Backbone Structure Emeric Miclet, Erin O'Neil-Cabello, Edward P. Nikonowicz, David Live, and Ad Bax pp 15740–15741 DOI: 10.1021/ja0388212 Supporting Info

Chiral Bisphosphine BINAP-Stabilized Gold and Palladium Nanoparticles with Small Size and Their Palladium Nanoparticle-Catalyzed Asymmetric Reaction Masaru Tamura and Hisashi Fujihara pp 15742–15743 DOI: 10.1021/ja0369055

Versatile Synthesis of Small NLO-Active Molecules Forming Amorphous Materials with Spontaneous Second-Order NLO Response Eléna Ishow, Cyril Bellaïche, Laurent Bouteiller, Keitaro Nakatani, and Jacques A. Delaire pp 15744–15745 DOI: 10.1021/ja038207q Supporting Info

Synthesis of (3S,5R)-Carbapenam-3-carboxylic Acid and Its Role in Carbapenem Biosynthesis and the Stereoinversion Problem Anthony Stapon, Rongfeng Li, and Craig A. Townsend pp 15746–15747 DOI: 10.1021/ja037665w

Catalytic Enantioselective Iodocyclization of γ-Hydroxy-cis-alkenes Sung Ho Kang, Sung Bae Lee, and Chul Min Park pp 15748–15749 DOI: 10.1021/ja0369921 Supporting Info

Direct Observation of Cα−Hα···OC Hydrogen Bonds in Proteins by Interresidue h3JCαC‘ Scalar Couplings Florence Cordier, Michael Barfield, and Stephan Grzesiek pp 15750–15751 DOI: 10.1021/ja038616m Supporting Info

NN Bond Cleavage by a Low-Coordinate Iron(II) Hydride Complex Jeremy M. Smith, Rene J. Lachicotte, and Patrick L. Holland pp 15752–15753 DOI: 10.1021/ja038152s Supporting Info

Synthesis of Monodisperse Superparamagnetic Fe/Silica Nanospherical Composites Pedro Tartaj and Carlos J. Serna pp 15754–15755 DOI: 10.1021/ja0380594 Supporting Info

Adsorption States and Modifier−Substrate Interactions on Pt(111) Relevant to the Enantioselective Hydrogenation of Alkyl Pyruvates in the Orito Reaction S. Lavoie, M.-A. Laliberté, and P. H. McBreen pp 15756–15757 DOI: 10.1021/ja036700w Supporting Info

Formation of Surface CN from the Coupling of C and N Atoms on Pt(111) Eldad Herceg and Michael Trenary pp 15758–15759 DOI: 10.1021/ja037612e

Rhenium-Catalyzed Coupling of Propargyl Alcohols and Allyl Silanes Michael R. Luzung and F. Dean Toste pp 15760–15761 DOI: 10.1021/ja039124c Supporting Info

Ruthenium-Catalyzed Aromatization of Aromatic Enynes via the 1,2-Migration of Halo and Aryl Groups:  A New Process Involving Electrocyclization and Skeletal Rearrangement Hung-Chin Shen, Sitaram Pal, Jian-Jou Lian, and Rai-Shung Liu pp 15762–15763 DOI: 10.1021/ja0379159 Supporting Info

Quantifying the Effects of Deuterium Substitution on Phospholipid Mixing in Bilayer Membranes. A Nearest-Neighbor Recognition Investigation Nobuya Tokutake, Bingwen Jing, Honghua Cao, and Steven L. Regen pp 15764–15766 DOI: 10.1021/ja038106s

Methyl Side-Chain Dynamics in Proteins Using Selective Enrichment with a Single Isotopomer Michael M. Chaykovski, Lynnette C. Bae, Minn-Chang Cheng, Jenny H. Murray, Kenneth E. Tortolani, Rui Zhang, Kothandaraman Seshadri, John H. B. C. Findlay, Shih-Yang Hsieh, Arnout P. Kalverda, Steve W. Homans, and Jonathan Miles Brown pp 15767–15771 DOI: 10.1021/ja0368608 Supporting Info

Nitrogen Binding to the FeMo-Cofactor of Nitrogenase Johannes Schimpl, Helena M. Petrilli, and Peter E. Blöchl pp 15772–15778 DOI: 10.1021/ja0367997 Supporting Info

Active Species of Horseradish Peroxidase (HRP) and Cytochrome P450:  Two Electronic Chameleons Sam P. deVisser, Sason Shaik, Pankaz K. Sharma, Devesh Kumar, and Walter Thiel pp 15779–15788 DOI: 10.1021/ja0380906 Supporting Info

Model Systems for Flavoenzyme Activity:  Relationships between Cofactor Structure, Binding and Redox Properties Yves-Marie Legrand, Mark Gray, Graeme Cooke, and Vincent M. Rotello pp 15789–15795 DOI: 10.1021/ja036940b Supporting Info

Synthetic Enantiopure Aziridinomitosenes:  Preparation, Reactivity, and DNA Alkylation Studies Edwin Vedejs, B. N. Naidu, Artis Klapars, Don L. Warner, Ven-shun Li, Younghwa Na, and Harold Kohn pp 15796–15806 DOI: 10.1021/ja030452m Supporting Info

NMR Spectra of a Microcrystalline Protein at 30 kHz MAS Matthias Ernst, Andreas Detken, Anja Böckmann, and Beat H. Meier pp 15807–15810 DOI: 10.1021/ja0369966

DNA-Templated Dimerization of Hairpin Polyamides Adam T. Poulin-Kerstien and Peter B. Dervan pp 15811–15821 DOI: 10.1021/ja030494a Supporting Info

Variable Coordination Geometries at the Diiron(II) Active Site of Ribonucleotide Reductase R2 Walter C. Voegtli, Monika Sommerhalter, Lana Saleh, Jeffrey Baldwin, J. Martin Bollinger, Jr., and Amy C. Rosenzweig pp 15822–15830 DOI: 10.1021/ja0370387

Sensitive High Resolution Inverse Detection NMR Spectroscopy of Proteins in the Solid State Eric K. Paulson, Corey R. Morcombe, Vadim Gaponenko, Barbara Dancheck, R. Andrew Byrd, and Kurt W. Zilm pp 15831–15836 DOI: 10.1021/ja037315+

Catalytic Asymmetric Michael Reaction of β-Keto Esters:  Effects of the Linker Heteroatom in Linked-BINOL Keisuke Majima, Ryo Takita, Akihiro Okada, Takashi Ohshima, and Masakatsu Shibasaki pp 15837–15845 DOI: 10.1021/ja037635t Supporting Info

HYSCORE Spectroscopy in the Cytochrome b559 of the Photosystem II Reaction Center Inés García-Rubio, Jesús I. Martínez, Rafael Picorel, Inmaculada Yruela, and Pablo J. Alonso pp 15846–15854 DOI: 10.1021/ja035364g Supporting Info

Conformational Behavior of β-Proline Oligomers Leah M. Sandvoss and Heather A. Carlson pp 15855–15862 DOI: 10.1021/ja036471d Supporting Info

Spectroscopic Evidence for a Persistent Benzenium Cation in Zeolite H-Beta Morten Bjørgen, Francesca Bonino, Stein Kolboe, Karl-Petter Lillerud, Adriano Zecchina, and Silvia Bordiga pp 15863–15868 DOI: 10.1021/ja037073d Supporting Info

Thermal Stereomutations and Stereochemically Elucidated [1,3]-Carbon Sigmatropic Shifts of 1-(E)-Propenyl-2-methylcyclobutanes Giving 3,4-Dimethylcyclohexenes John E. Baldwin and Richard C. Burrell pp 15869–15877 DOI: 10.1021/ja030516t

Intramolecular Hydroamination/Cyclization of Conjugated Aminodienes Catalyzed by Organolanthanide Complexes. Scope, Diastereo- and Enantioselectivity, and Reaction Mechanism Sukwon Hong, Amber M. Kawaoka, and Tobin J. Marks pp 15878–15892 DOI: 10.1021/ja036266y Supporting Info

Lithium 2,2,6,6-Tetramethylpiperidide-Mediated α- and β-Lithiations of Epoxides:  Solvent-Dependent Mechanisms Sean H. Wiedemann, Antonio Ramírez, and David B. Collum pp 15893–15901 DOI: 10.1021/ja0304087 Supporting Info

Isotope Effects and the Nature of Selectivity in Rhodium-Catalyzed Cyclopropanations Daniel T. Nowlan III, Timothy M. Gregg, Huw M. L. Davies, and Daniel A. Singleton pp 15902–15911 DOI: 10.1021/ja036025q Supporting Info

Y-Shaped Amphiphilic Brushes with Switchable Micellar Surface Structures Duangrut Julthongpiput, Yen-Hsi Lin, Jing Teng, Eugene R. Zubarev, and Vladimir V. Tsukruk pp 15912–15921 DOI: 10.1021/ja038051u Supporting Info

Structural Characterization of Crystalline Ternary Inclusion Compounds at the Air−Water Interface David J. Plaut, Stephen M. Martin, Kristian Kjaer, Markus J. Weygand, Meir Lahav, Leslie Leiserowitz, Isabelle Weissbuch, and Michael D. Ward pp 15922–15934 DOI: 10.1021/ja0371404 Supporting Info

Photoinitiated Polymerization of Columnar Stacks of Self-Assembled Trialkyl-1,3,5-benzenetricarboxamide Derivatives Mitsutoshi Masuda, Pascal Jonkheijm, Rint P. Sijbesma, and E. W. Meijer pp 15935–15940 DOI: 10.1021/ja037927u Supporting Info

Transfer of π-Conjugated Columnar Stacks from Solution to Surfaces Pascal Jonkheijm, Freek J. M. Hoeben, Ralf Kleppinger, Jeroen van Herrikhuyzen, Albertus P. H. J. Schenning, and E. W. Meijer pp 15941–15949 DOI: 10.1021/ja0383118 Supporting Info

Intervalence (Charge-Resonance) Transitions in Organic Mixed-Valence Systems. Through-Space versus Through-Bond Electron Transfer between Bridged Aromatic (Redox) Centers D.-L. Sun, S. V. Rosokha, S. V. Lindeman, and J. K. Kochi pp 15950–15963 DOI: 10.1021/ja037867s Supporting Info

Hole Transfer in a C-Shaped Molecule:  Conformational Freedom versus Solvent-Mediated Coupling Jocelyn M. Nadeau, Min Liu, David H. Waldeck, and Matthew B. Zimmt pp 15964–15973 DOI: 10.1021/ja0372917

Application of Isomorphous Replacement in the Structure Determination of a Cubic Liquid Crystal Phase and Location of Counterions Daniel R. Dukeson, Goran Ungar, Venkatachalapathy S. K. Balagurusamy, Virgil Percec, Gary A. Johansson, and Martin Glodde pp 15974–15980 DOI: 10.1021/ja037380j Supporting Info

Surfactant-Assisted Elimination of a High Energy Facet as a Means of Controlling the Shapes of TiO2 Nanocrystals Young-wook Jun, Maria F. Casula, Jae-Hwan Sim, Sang Youl Kim, Jinwoo Cheon, and A. Paul Alivisatos pp 15981–15985 DOI: 10.1021/ja0369515 Supporting Info

Low-Spin Ferriheme Models of the Cytochromes:  Correlation of Molecular Structure with EPR Spectral Type Liliya A. Yatsunyk, Michael D. Carducci, and F. Ann Walker pp 15986–16005 DOI: 10.1021/ja036398r Supporting Info

Probing Photoelectrochemical Processes in Au−CdS Nanoparticle Arrays by Surface Plasmon Resonance:  Application for the Detection of Acetylcholine Esterase Inhibitors Maya Zayats, Andrei B. Kharitonov, Svetlana P. Pogorelova, Oleg Lioubashevski, Eugenii Katz, and Itamar Willner pp 16006–16014 DOI: 10.1021/ja0379215

Polymerization from the Surface of Single-Walled Carbon Nanotubes − Preparation and Characterization of Nanocomposites Zhaoling Yao, Nadi Braidy, Gianluigi A. Botton, and Alex Adronov pp 16015–16024 DOI: 10.1021/ja037564y Supporting Info

Systematic Synthesis and Characterization of Single-Crystal Lanthanide Orthophosphate Nanowires Yue-Ping Fang, An-Wu Xu, Rui-Qi Song, Hua-Xin Zhang, Li-Ping You, Jimmy C. Yu, and Han-Qin Liu pp 16025–16034 DOI: 10.1021/ja037280d Supporting Info

Structure of the First Silicate Molecular Sieve with 18-Ring Pore Openings, ECR-34 Karl G. Strohmaier and David E. W. Vaughan pp 16035–16039 DOI: 10.1021/ja0371653 Supporting Info

M2(hpp)4Cl2 and M2(hpp)4, Where M = Mo and W:  Preparations, Structure and Bonding, and Comparisons with C2, C2H2, and C2Cl2 and the Hypothetical Molecules M2(hpp)4(H)2 Malcolm H. Chisholm, Judith Gallucci, Christopher M. Hadad, John C. Huffman, and Paul J. Wilson pp 16040–16049 DOI: 10.1021/ja0301065 Supporting Info

Solventless Synthesis of Monodisperse Cu2S Nanorods, Nanodisks, and Nanoplatelets Michael B. Sigman, Jr., Ali Ghezelbash, Tobias Hanrath, Aaron E. Saunders, Frank Lee, and Brian A. Korgel pp 16050–16057 DOI: 10.1021/ja037688a

Syntheses, Characterizations, and Coordination Chemistry of the 10-Vertex Phosphadicarbaboranes 6-R-arachno-6,8,9-PC2B7H11 and 6-R-arachno-6,5,7-PC2B7H11 Daewon Hong, Scott E. Rathmill, Patrick J. Carroll, and Larry G. Sneddon pp 16058–16073 DOI: 10.1021/ja037799+ Supporting Info

Bonding Self-Assembled, Compact Organophosphonate Monolayers to the Native Oxide Surface of Silicon Eric L. Hanson, Jeffrey Schwartz, Bert Nickel, Norbert Koch, and Mehmet Fatih Danisman pp 16074–16080 DOI: 10.1021/ja035956z Supporting Info

Polymorphic Forms of a Gold(I) Arylacetylide Complex with Contrasting Phosphorescent Characteristics Wei Lu, Nianyong Zhu, and Chi-Ming Che pp 16081–16088 DOI: 10.1021/ja0382415 Supporting Info

Theoretical Analysis of the Electronic Structure and Bonding Stability of the TCNE Dimer Dianion (TCNE)22- Jacek Jakowski and Jack Simons pp 16089–16096 DOI: 10.1021/ja030240p

Assessment of Cooperativity in Self-Assembly Gianfranco Ercolani pp 16097–16103 DOI: 10.1021/ja038396c

Pseudomultidimensional NMR by Spin-State Selective Off-Resonance Decoupling Christy Rani R. Grace and Roland Riek pp 16104–16113 DOI: 10.1021/ja035689x

Iridium-Catalyzed Borylation of Benzene with Diboron. Theoretical Elucidation of Catalytic Cycle Including Unusual Iridium(V) Intermediate Hitoshi Tamura, Hideki Yamazaki, Hirofumi Sato, and Shigeyoshi Sakaki pp 16114–16126 DOI: 10.1021/ja0302937 Supporting Info

Antiparallel Triple Helices. Structural Characteristics and Stabilization by 8-Amino Derivatives Anna Aviñó, Elena Cubero, Carlos González, Ramon Eritja, and Modesto Orozco pp 16127–16138 DOI: 10.1021/ja035039t Supporting Info

A CASSCF/MR-CI Study toward the Understanding of Wavelength-Dependent and Geometrically Memorized Photodissociation of Formic Acid Hong-Yuan He and Wei-Hai Fang pp 16139–16147 DOI: 10.1021/ja0363157 Supporting Info

Probing Chiral Selective Reactions Using a Revised Kataura Plot for the Interpretation of Single-Walled Carbon Nanotube Spectroscopy Michael S. Strano pp 16148–16153 DOI: 10.1021/ja036791x Supporting Info

ICP Emission Spectrometry:  A Practical Guide By Joachim Nölte (AnalytikSupport, Owingen, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2003. xii + 268 pp. $49.50. ISBN 3-527-30672-2. Robert D. Koons p 16154 DOI: 10.1021/ja033561+

Nitrogen, Oxygen and Sulfur Ylide Chemistry. A Practical Approach in Chemistry Edited by J. Stephen Clark (University of Nottingham). Oxford University Press:  Oxford. 2002. xvi + 298 pp. $148.00. ISBN 0-19-850017-3. p 16154 DOI: 10.1021/ja033584o

Compendium of Organic Synthetic Methods, Volume 11 By Michael B. Smith (University of Connecticut). John Wiley & Sons, Inc.:  Hoboken, NJ. 2003. xxii + 796 pp. $115.00. ISBN 0-471-25965-9. p 16154 DOI: 10.1021/ja0335972

Utilization of Greenhouse Gases Edited by Chang-jun Liu (Tianjin University), Richard G. Mallinson (University of Oklahoma), and Michele Aresta (University of Bari). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2003. xii + 412 pp. $145.00. ISBN 0-8412-3827-8. p 16154 DOI: 10.1021/ja033607z

Advances in High Pressure Bioscience and Biotechnology II Edited by Roland Winter (University of Dortmund). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xvi + 490 pp. $279.00. ISBN 3-540-00977-9. pp 16154–16155 DOI: 10.1021/ja033598u

Protein NMR for the Millennium. Biological Magnetic Resonance, Volume 20 Edited by N. Rama Krishna (University of Alabama at Birmingham) and Lawrence J. Berliner (University of Denver). Kluwer Academic/Plenum Publishers:  New York. 2003. xii + 342 pp. $135.00. ISBN 0-306-47448-4. Dr. Richard W. KriwackiDr. Charles Galea pp 16155–16156 DOI: 10.1021/ja033559i

Issue 52

Biindanylidenes:  Role of Central Bond Torsion in Nonvertical Triplet Excitation Transfer to the Stilbenes Jack Saltiel, Jonathan E. Mace, Lucas P. Watkins, David A. Gormin, Ronald J. Clark, and Olga Dmitrenko pp 16158–16159 DOI: 10.1021/ja038087m Supporting Info

An Iron−Peroxo Porphyrin Complex:  New Synthesis and Reactivity Toward a Cu(II) Complex Giving a Heme−Peroxo−Copper Adduct Eduardo E. Chufán and Kenneth D. Karlin pp 16160–16161 DOI: 10.1021/ja036632d Supporting Info

A Chemoenzymatic Approach toward the Rapid and Sensitive Detection of O-GlcNAc Posttranslational Modifications Nelly Khidekel, Sabine Arndt, Nathan Lamarre-Vincent, Alexander Lippert, Katherine G. Poulin-Kerstien, Boopathy Ramakrishnan, Pradman K. Qasba, and Linda C. Hsieh-Wilson pp 16162–16163 DOI: 10.1021/ja038545r Supporting Info

Measurements of Single-Molecule Electromechanical Properties Bingqian Xu, Xiaoyin Xiao, and Nongjian J. Tao pp 16164–16165 DOI: 10.1021/ja038949j Supporting Info

Synthesis of Porous Wires from Directed Assemblies of Nanospheres Feng Li, Jibao He, Weilie L. Zhou, and John B. Wiley pp 16166–16167 DOI: 10.1021/ja038452+ Supporting Info

Cadmium Selenide Quantum Wires and the Transition from 3D to 2D Confinement Heng Yu, Jingbo Li, Richard A. Loomis, Patrick C. Gibbons, Lin-Wang Wang, and William E. Buhro pp 16168–16169 DOI: 10.1021/ja037971+ Supporting Info

A New Self-Penetrating Uniform Net, (8,4) (or 86), Containing Planar Four-Coordinate Nodes Ming-Liang Tong, Xiao-Ming Chen, and Stuart R. Batten pp 16170–16171 DOI: 10.1021/ja0383266 Supporting Info

Conversion of a Tyrosine Kinase Protein Substrate to a High Affinity Ligand by ATP Linkage Kui Shen and Philip A. Cole pp 16172–16173 DOI: 10.1021/ja0380401 Supporting Info

Detection of Amines and Unprotected Amino Acids in Aqueous Conditions by Formation of Highly Fluorescent Iminium Ions Ellen K. Feuster and Timothy E. Glass pp 16174–16175 DOI: 10.1021/ja036434m Supporting Info

A Solution-Phase, Precursor Route to Polycrystalline SnO2 Nanowires That Can Be Used for Gas Sensing under Ambient Conditions Yuliang Wang, Xuchuan Jiang, and Younan Xia pp 16176–16177 DOI: 10.1021/ja037743f Supporting Info

Heterobimetallic Catalysis in Asymmetric 1,4-Addition of O-Alkylhydroxylamine to Enones Noriyuki Yamagiwa, Shigeki Matsunaga, and Masakatsu Shibasaki pp 16178–16179 DOI: 10.1021/ja038688d Supporting Info

Discrimination of Guests Encapsulation in Large Hexameric Molecular Capsules in Solution:  Pyrogallol[4]arene versus Resorcin[4]arene Capsules Liat Avram and Yoram Cohen pp 16180–16181 DOI: 10.1021/ja0377394 Supporting Info

Unraveling the Mystery Surrounding Cholesterol's Condensing Effect Honghua Cao, Nobuya Tokutake, and Steven L. Regen pp 16182–16183 DOI: 10.1021/ja039172x Supporting Info

Assessing the Magnitude of Folding Forces along the Oxidative Folding Pathway of Multi-Disulfide-Containing Proteins Mahesh Narayan, Guoqiang Xu, Suzanne K. Schultz, and Harold A. Scheraga pp 16184–16185 DOI: 10.1021/ja0305398

Monopod, Bipod, Tripod, and Tetrapod Gold Nanocrystals Sihai Chen, Zhong Lin Wang, John Ballato, Stephen H. Foulger, and David L. Carroll pp 16186–16187 DOI: 10.1021/ja038927x Supporting Info

Rotational Isomerism in Acetic Acid:  The First Experimental Observation of the High-Energy Conformer Ermelinda M. S. Maçôas, Leonid Khriachtchev, Mika Pettersson, Rui Fausto, and Markku Räsänen pp 16188–16189 DOI: 10.1021/ja038341a

Uncoupled Forms of Tyrosine Hydroxylase Unmask Kinetic Isotope Effects on Chemical Steps Patrick A. Frantom and Paul F. Fitzpatrick pp 16190–16191 DOI: 10.1021/ja0383165 Supporting Info

Adsorption Isotherm and Other Properties of Methane in Zeolite A from an Intermolecular Potential Derived from ab Initio Calculations Pradip Kr. Ghorai, Marcel Sluiter, Subramanian Yashonath, and Y. Kawazoe pp 16192–16193 DOI: 10.1021/ja037274h Supporting Info

A General Method for the Suzuki−Miyaura Cross-Coupling of Sterically Hindered Aryl Chlorides:  Synthesis of Di- and Tri-ortho-substituted Biaryls in 2-Propanol at Room Temperature Oscar Navarro, Roy A. Kelly, III, and Steven P. Nolan pp 16194–16195 DOI: 10.1021/ja038631r Supporting Info

Nanocable-Aligned ZnS Tetrapod Nanocrystals Ying-Chun Zhu, Yoshio Bando, Dong-Feng Xue, and Dmitri Golberg pp 16196–16197 DOI: 10.1021/ja037965d Supporting Info

Long-Lived Charge-Separated State Leading to DNA Damage through Hole Transfer Kiyohiko Kawai, Tadao Takada, Takayoshi Nagai, Xichen Cai, Akira Sugimoto, Mamoru Fujitsuka, and Tetsuro Majima pp 16198–16199 DOI: 10.1021/ja038309g

Synthesis of Optically Active Oligonaphthalenes via Second-Order Asymmetric Transformation Kazunori Tsubaki, Masaya Miura, Hiroshi Morikawa, Hiroyuki Tanaka, Takeo Kawabata, Takumi Furuta, Kiyoshi Tanaka, and Kaoru Fuji pp 16200–16201 DOI: 10.1021/ja038910e Supporting Info

Efficient Aziridination of Olefins Catalyzed by a Unique Disilver(I) Compound Yong Cui and Chuan He pp 16202–16203 DOI: 10.1021/ja038668b Supporting Info

Theoretical Analysis of Peroxynitrous Acid:  Characterization of Its Elusive Biradicaloid (HO···ONO) Singlet States Robert D. Bach, Olga Dmitrenko, and Carlos M. Estévez pp 16204–16205 DOI: 10.1021/ja038524x Supporting Info

Novel Reversible Ionic-to-Covalent Transition in a Highly Conducting TTF Derivative Clifton Kwang-Fu Shen, Hieu M. Duong, Gursel Sonmez, and Fred Wudl pp 16206–16207 DOI: 10.1021/ja037621n Supporting Info

Kinetic Isotope Effects on the Rate-Limiting Step of Heme Oxygenase Catalysis Indicate Concerted Proton Transfer/Heme Hydroxylation Roman Davydov, Toshitaka Matsui, Hiroshi Fujii, Masao Ikeda-Saito, and Brian M. Hoffman pp 16208–16209 DOI: 10.1021/ja038923s

Density Functional Study of the Insertion and Ring-Opening Mechanism of MCP over Cp2LaH and Cp2LuH Catalysts Yi Luo, Parasuraman Selvam, Akira Endou, Momoji Kubo, and Akira Miyamoto pp 16210–16212 DOI: 10.1021/ja036636i Supporting Info

Elimination of Oxidative Degradation during the per-O-Methylation of Carbohydrates Ionel Ciucanu, and Catherine E. Costello pp 16213–16219 DOI: 10.1021/ja035660t

On the Extended β-Conformation Propensity of Polypeptides at High Temperature Wei Yuan Yang, Edgar Larios, and Martin Gruebele pp 16220–16227 DOI: 10.1021/ja0360081

Design and Construction of Glutamine Binding Proteins with a Self-Adhering Capability to Unmodified Hydrophobic Surfaces as Reagentless Fluorescence Sensing Devices Akira Wada, Masayasu Mie, Masuo Aizawa, Pedro Lahoud, Anthony E. G. Cass, and Eiry Kobatake pp 16228–16234 DOI: 10.1021/ja036459l Supporting Info

Probing the Requirements for Recognition and Catalysis in Fpg and MutY with Nonpolar Adenine Isosteres Anthony W. Francis, Sandra A. Helquist, Eric T. Kool, and Sheila S. David pp 16235–16242 DOI: 10.1021/ja0374426

Development of a New Family of Conformationally Restricted Peptides as Potent Nucleators of β-Turns. Design, Synthesis, Structure, and Biological Evaluation of a β-Lactam Peptide Analogue of Melanostatin Claudio Palomo, Jesus M. Aizpurua, Ana Benito, José Ignacio Miranda, Raluca M. Fratila, Carlos Matute, Maria Domercq, Federico Gago, Sonsoles Martin-Santamaria, and Anthony Linden pp 16243–16260 DOI: 10.1021/ja038180a Supporting Info

Chemical Characterization of α-Oxohydrazone Ligation on Colloids:  toward Grafting Molecular Addresses onto Biological Vectors P. Chenevier, L. Bourel-Bonnet, and D. Roux pp 16261–16270 DOI: 10.1021/ja0370746 Supporting Info

On the Nature of the Multivalency Effect:  A Thermodynamic Model Pavel I. Kitov and David R. Bundle pp 16271–16284 DOI: 10.1021/ja038223n Supporting Info

Folding of a Stable DNA Motif Involves a Highly Cooperative Network of Interactions Ellen M. Moody and Philip C. Bevilacqua pp 16285–16293 DOI: 10.1021/ja038897y

Nucleation−Elongation Polymerization under Imbalanced Stoichiometry Dahui Zhao and Jeffrey S. Moore pp 16294–16299 DOI: 10.1021/ja038252y Supporting Info

β-Octafluorocorroles Erik Steene, Abhishek Dey, and Abhik Ghosh pp 16300–16309 DOI: 10.1021/ja021158h Supporting Info

Intramolecular Cycloadditions of Cyclobutadiene with Dienes:  Experimental and Computational Studies of the Competing (2 + 2) and (4 + 2) Modes of Reaction John Limanto, Kelli S. Khuong, K. N. Houk, and Marc L. Snapper pp 16310–16321 DOI: 10.1021/ja0380547 Supporting Info

A Mechanism-Based Inhibitor Targeting the dd-Transpeptidase Activity of Bacterial Penicillin-Binding Proteins Mijoon Lee, Dusan Hesek, Maxim Suvorov, Wenlin Lee, Sergei Vakulenko, and Shahriar Mobashery pp 16322–16326 DOI: 10.1021/ja038445l Supporting Info

Hydroxy- and Silyloxy-Substituted TEMPO Derivatives for the Living Free-Radical Polymerization of Styrene and n-Butyl Acrylate:  Synthesis, Kinetics, and Mechanistic Studies Christoph Alexander Knoop and Armido Studer pp 16327–16333 DOI: 10.1021/ja037948o Supporting Info

Convergent Synthesis of a GPI Containing an Acylated Inositol Jie Xue and Zhongwu Guo pp 16334–16339 DOI: 10.1021/ja0382157 Supporting Info

A Superoxo-Ferrous State in a Reduced Oxy-Ferrous Hemoprotein and Model Compounds Roman Davydov, James D. Satterlee, Hiroshi Fujii, Alexandra Sauer-Masarwa, Daryle H. Busch, and Brian M. Hoffman pp 16340–16346 DOI: 10.1021/ja037037e

Trans Influence on the Rate of Reductive Elimination. Reductive Elimination of Amines from Isomeric Arylpalladium Amides with Unsymmetrical Coordination Spheres Makoto Yamashita, Jose V. Cuevas Vicario, and John F. Hartwig pp 16347–16360 DOI: 10.1021/ja037425g

Chemical Compounds Formed from Diacetylene and Rare-Gas Atoms:  HKrC4H and HXeC4H Hanna Tanskanen, Leonid Khriachtchev, Jan Lundell, Harri Kiljunen, and Markku Räsänen pp 16361–16366 DOI: 10.1021/ja038610x

Ruthenacarboranes from the Reaction of nido-1,2-(Cp*RuH)2B3H7 with HCCCO2Me, Cp* = η5-C5Me5. Hydrometalation, Alkyne Incorporation, and Functional Group Modification via Cooperative Metal−Boron Interactions within a Metallaborane Cluster Framework Hong Yan, Alicia M. Beatty, and Thomas P. Fehlner pp 16367–16382 DOI: 10.1021/ja038444t Supporting Info

β-Sheet Preferences from First Principles Jan Rossmeisl, Iben Kristensen, Misha Gregersen, Karsten W. Jacobsen, and Jens K. Nørskov pp 16383–16386 DOI: 10.1021/ja0359658

A Density Functional Theory Investigation of Fe−N−O Bonding in Heme Proteins and Model Systems Yong Zhang, William Gossman, and Eric Oldfield pp 16387–16396 DOI: 10.1021/ja030340v Supporting Info

Nonplanarity at Tri-coordinated Aluminum and Gallium:  Cyclic Structures for X3Hnm (X = B, Al, Ga) Gantasala N. Srinivas, Anakuthil Anoop, Eluvathingal D. Jemmis, Tracy P. Hamilton, Koop Lammertsma, Jerzy Leszczynski, and Henry F. Schaefer, III pp 16397–16407 DOI: 10.1021/ja036868h Supporting Info

NMR Study on the Photoresponsive DNA Tethering an Azobenzene. Assignment of the Absolute Configuration of Two Diastereomers and Structure Determination of Their Duplexes in the trans-Form Xingguo Liang, Hiroyuki Asanuma, Hiromu Kashida, Akitsugu Takasu, Taiichi Sakamoto, Gota Kawai, and Makoto Komiyama pp 16408–16415 DOI: 10.1021/ja037248j Supporting Info

Determination of the Active Site Protonation State of β-Secretase from Molecular Dynamics Simulation and Docking Experiment:  Implications for Structure-Based Inhibitor Design Hwangseo Park and Sangyoub Lee pp 16416–16422 DOI: 10.1021/ja0304493

13C Direct Detection Experiments on the Paramagnetic Oxidized Monomeric Copper, Zinc Superoxide Dismutase Wolfgang Bermel, Ivano Bertini, Isabella C. Felli, Rainer Kümmerle, and Roberta Pierattelli pp 16423–16429 DOI: 10.1021/ja037676p Supporting Info

Phase Switching of a Single Isomeric Molecule and Associated Characteristic Rectification Satoshi Yasuda, Tohru Nakamura, Mutsuyoshi Matsumoto, and Hidemi Shigekawa pp 16430–16433 DOI: 10.1021/ja038233o Supporting Info

A Nonempirical Anisotropic Atom−Atom Model Potential for Chlorobenzene Crystals Graeme M. Day and Sarah L. Price pp 16434–16443 DOI: 10.1021/ja0383625 Supporting Info

Electron Transfer and Singlet Oxygen Mechanisms in the Photooxygenation of Dibutyl Sulfide and Thioanisole in MeCN Sensitized by N-Methylquinolinium Tetrafluoborate and 9,10-Dicyanoanthracene. The Probable Involvement of a Thiadioxirane Intermediate in Electron Transfer Photooxygenations Enrico Baciocchi, Tiziana Del Giacco, Fausto Elisei, Maria Francesca Gerini, Maurizio Guerra, Andrea Lapi, and Prisca Liberali pp 16444–16454 DOI: 10.1021/ja037591o Supporting Info

Insights into the Structure of Cyclohexane from Femtosecond Degenerate Four-Wave Mixing Spectroscopy and Ab Initio Calculations Christoph Riehn, Victor V. Matylitsky, Włodzimierz Jarzba, Bernd Brutschy, P. Tarakeshwar, and Kwang S. Kim pp 16455–16462 DOI: 10.1021/ja036615o Supporting Info

Hole-Catalyzed Epoxidation [J. Am. Chem. Soc. 1991, 113, 3613−3614]. Nathan L. Bauld and Gholam Mirafzal p 16463 DOI: 10.1021/ja033463o

Is Hole Transfer Involved in Metalloporphyrin-Catalyzed Epoxidation? [J. Am. Chem. Soc. 1993, 115, 7653−7664]. Taisun Kim, Gholam A. Mirafzal, Jianping Liu, and Nathan L. Bauld p 16463 DOI: 10.1021/ja0334659